RU2335469C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2335469C1
RU2335469C1 RU2006146134/03A RU2006146134A RU2335469C1 RU 2335469 C1 RU2335469 C1 RU 2335469C1 RU 2006146134/03 A RU2006146134/03 A RU 2006146134/03A RU 2006146134 A RU2006146134 A RU 2006146134A RU 2335469 C1 RU2335469 C1 RU 2335469C1
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RU
Russia
Prior art keywords
glaze
zro
zno
cao
tio
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RU2006146134/03A
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Russian (ru)
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RU2006146134A (en
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Priority to RU2006146134/03A priority Critical patent/RU2335469C1/en
Publication of RU2006146134A publication Critical patent/RU2006146134A/en
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: chemistry.
SUBSTANCE: invention concerns fritted glaze compositions used in production of tile and pottery utensils. The glaze includes SiO2, Al2O3, Fe2O3, TiO2, CaO, MgO, Na2O, K2O, ZrO2, B2O3, ZnO, CuO at the following component ratio, wt %: SiO2 - 54.0-58.0; Al2O3 - 3.0-5.0; Fe2O3 - 0.2-0.4; TiO2 - 4.0-6.0; CaO - 3.0-5.0; MgO - 1.0-2.0; Na2O - 1.0-2.0; K2O - 1.0-2.0; ZrO2 - 3.0-5.0; B2O3 - 16.0-18.0; ZnO - 3.0-5.0; CuO - 0.8-1.6.
EFFECT: increased heat resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов и касается составов фриттованных глазурей, используемых в производстве облицовочной плитки, изделий бытовой керамики.The invention relates to the field of technology of silicates and relates to compositions of fritted glazes used in the manufacture of facing tiles, household ceramics.

Известна глазурь, содержащая, мас.%: SiO2 36,2-43,0; Al2O3 2,1-8,4; CaO 4,8-5,0; Na2O 5,0-5,3; ZrO2 5,3-8,4; B2O3 28,6-32,3; ZnO 7,4-8,4 [1].Known glaze containing, wt.%: SiO 2 36,2-43,0; Al 2 O 3 2.1-8.4; CaO 4.8-5.0; Na 2 O 5.0-5.3; ZrO 2 5.3-8.4; B 2 O 3 28.6-32.3; ZnO 7.4-8.4 [1].

Известна глазурь, содержащая, мас.%: SiO2 46,44-53,71; Al2O3 2,65-3,6; Fe2O3 0,15-0,22; TiO2 0,05-0,06; CaO 0,36-0,44; MgO 0,2-0,29; Na2O 0,2-0,35; K2O 7,36-11,88; ZrO2 5,35-8,62; B2O3 11,79-24,33; ZnO 5,02-14,56; CuO 0,62-1,75 [2].Known glaze containing, wt.%: SiO 2 46,44-53,71; Al 2 O 3 2.65-3.6; Fe 2 O 3 0.15-0.22; TiO 2 0.05-0.06; CaO 0.36-0.44; MgO 0.2-0.29; Na 2 O 0.2-0.35; K 2 O 7.36-11.88; ZrO 2 5.35-8.62; B 2 O 3 11.79-24.33; ZnO 5.02-14.56; CuO 0.62-1.75 [2].

Цель изобретения состоит в повышении термостойкости глазури.The purpose of the invention is to increase the heat resistance of the glaze.

Цель достигается тем, что в составе глазури компоненты находятся при следующем соотношении, мас.%: SiO2 54,0-58,0; Al2O3 3,0-5,0; Fe2O3 0,2-0,4; TiO2 4,0-6,0; CaO 3,0-5,0; MgO 1,0-2,0; Na2O 1,0-2,0; K2O 1,0-2,0; ZrO2 3,0-5,0; B2O3 16,0-18,0; ZnO 3,0-5,0; CuO 0,8-1,6.The goal is achieved in that the components of the glaze are in the following ratio, wt.%: SiO 2 54.0-58.0; Al 2 O 3 3.0-5.0; Fe 2 O 3 0.2-0.4; TiO 2 4.0-6.0; CaO 3.0-5.0; MgO 1.0-2.0; Na 2 O 1.0-2.0; K 2 O 1.0-2.0; ZrO 2 3.0-5.0; B 2 O 3 16.0-18.0; ZnO 3.0-5.0; CuO 0.8-1.6.

В таблице приведены составы глазури.The table shows the glaze compositions.

СоставStructure Компоненты, мас.%Components, wt.% Термостойкость, °СHeat resistance, ° С SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 TiO2 TiO 2 CaOCao MgOMgO Na2ONa 2 O K2OK 2 O ZrO2 ZrO 2 B2O3 B 2 O 3 ZnOZno CuOCuO 1one 58,058.0 5,05,0 0,20.2 4,04.0 3,03.0 2,02.0 1,01,0 2,02.0 3,03.0 16,016,0 5,05,0 0,80.8 320-330320-330 22 56,056.0 4,04.0 0,30.3 5,05,0 4,04.0 1,51,5 1,51,5 1,51,5 4,04.0 17,017.0 4,04.0 1,21,2 320-330320-330 33 54,054.0 3,03.0 0,40.4 6,06.0 5,05,0 1,01,0 2,02.0 1,01,0 5,05,0 18,018.0 3,03.0 1,61,6 320-330320-330

Фритту варят при 1350°С, расплав гранулируют и размалывают с добавкой 0,5% глины, 0,2% электролита, 47,0% воды. Глазурную суспензию наносят на изделия и закрепляют обжигом при 1000°С.The frit is boiled at 1350 ° C, the melt is granulated and ground with the addition of 0.5% clay, 0.2% electrolyte, 47.0% water. The glaze suspension is applied to the products and fixed by firing at 1000 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №796201, С03С 9/00, 1981.1. USSR author's certificate No. 796201, С03С 9/00, 1981.

2. Авторское свидетельство СССР №1350126, С03С 8/04, 1987.2. USSR author's certificate No. 1350126, С03С 8/04, 1987.

Claims (1)

Глазурь, содержащая SiO2, Al2O3, Fe2O3, TiO2, CaO, MgO, Na2O, K2O, ZrO2, B2O3, ZnO, CuO, отличающаяся тем, что компоненты находятся при следующем соотношении, мас.%: SiO2 54,0-58,0; Al2O3 3,0-5,0; Fe2O3 0,2-0,4; TiO2 4,0-6,0; CaO 3,0-5,0; MgO 1,0-2,0; Na2O 1,0-2,0; K2O 1,0-2,0; ZrO2 3,0-5,0; B2O3 16,0-18,0; ZnO 3,0-5,0; CuO 0,8-1,6.Glaze containing SiO 2 , Al 2 O 3 , Fe 2 O 3 , TiO 2 , CaO, MgO, Na 2 O, K 2 O, ZrO 2 , B 2 O 3 , ZnO, CuO, characterized in that the components are present at the following ratio, wt.%: SiO 2 54.0-58.0; Al 2 O 3 3.0-5.0; Fe 2 O 3 0.2-0.4; TiO 2 4.0-6.0; CaO 3.0-5.0; MgO 1.0-2.0; Na 2 O 1.0-2.0; K 2 O 1.0-2.0; ZrO 2 3.0-5.0; B 2 O 3 16.0-18.0; ZnO 3.0-5.0; CuO 0.8-1.6.
RU2006146134/03A 2006-12-25 2006-12-25 Glaze RU2335469C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006146134/03A RU2335469C1 (en) 2006-12-25 2006-12-25 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006146134/03A RU2335469C1 (en) 2006-12-25 2006-12-25 Glaze

Publications (2)

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RU2006146134A RU2006146134A (en) 2008-07-10
RU2335469C1 true RU2335469C1 (en) 2008-10-10

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