RU2338707C2 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2338707C2
RU2338707C2 RU2006146092/03A RU2006146092A RU2338707C2 RU 2338707 C2 RU2338707 C2 RU 2338707C2 RU 2006146092/03 A RU2006146092/03 A RU 2006146092/03A RU 2006146092 A RU2006146092 A RU 2006146092A RU 2338707 C2 RU2338707 C2 RU 2338707C2
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RU
Russia
Prior art keywords
glaze
bao
zro
zno
sro
Prior art date
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RU2006146092/03A
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Russian (ru)
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RU2006146092A (en
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006146092/03A priority Critical patent/RU2338707C2/en
Publication of RU2006146092A publication Critical patent/RU2006146092A/en
Application granted granted Critical
Publication of RU2338707C2 publication Critical patent/RU2338707C2/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
    • C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: chemistry.
SUBSTANCE: glaze contains SiO2, Al2O3, BaO, MgO, CaO, SrO, ZnO, B2O3, TiO2 and ZrO2, with the following ratios of components, in wt %: SiO2 - 35.0-40.0; Al2O3 - 2.0-2.5; BaO - 35.5-37.0; MgO - 3.0-6.0; CaO - 2.0-6.0; SrO - 2.0-6.0; ZnO - 5.5-6.0; B2O3 - 2.0-6.0; TiO2 - 2.0-4.0; ZrO2 - 1.0-2.0.
EFFECT: increased water resistance of the glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов и касается составов фриттованных глазурей, используемых в производстве плитки, изделий декоративно-художественного и хозяйственно-бытового назначения.The invention relates to the field of technology of silicates and relates to compositions of fritted glazes used in the manufacture of tiles, decorative, artistic and household items.

Известна глазурь, включающая, мас.%: SiO2 0,05-2,0; BaO 38,0-41,9; P2O5 58,0-60,0 [1].Known glaze, including, wt.%: SiO 2 0,05-2,0; BaO 38.0-41.9; P 2 O 5 58.0-60.0 [1].

Известна глазурь, содержащая, мас.%: SiO2 25,0-40,0; Al2O3 4,0-15,0; BaO 50,0-65,0; B2O3 1,0-7,0; MgO, CaO, SrO и/или ZnO не более 5,0 [2].Known glaze containing, wt.%: SiO 2 25,0-40,0; Al 2 O 3 4.0-15.0; BaO 50.0-65.0; B 2 O 3 1.0-7.0; MgO, CaO, SrO and / or ZnO not more than 5.0 [2].

Цель изобретения состоит в повышении водостойкости глазури.The purpose of the invention is to increase the water resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят TiO2 и ZrO2 при следующем соотношении компонентов, мас.%: SiO2 35,0-40,0; Al2O3 2,0-6,0; BaO 30,0-37,0; MgO 2,0-6,0; CaO 2,0-6,0; SrO 2,0-6,0; ZnO 2,0-6,0; B2O3 2,0-6,0; TiO2 2,0-4,0; ZrO2 1,0-2,0.The goal is achieved by the fact that TiO 2 and ZrO 2 are additionally added to the glaze composition in the following ratio of components, wt.%: SiO 2 35.0-40.0; Al 2 O 3 2.0-6.0; BaO 30.0-37.0; MgO 2.0-6.0; CaO 2.0-6.0; SrO 2.0-6.0; ZnO 2.0-6.0; B 2 O 3 2.0-6.0; TiO 2 2.0-4.0; ZrO 2 1.0-2.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Воздействие кипящей воды без изменения качества глазури, чThe effect of boiling water without changing the quality of the glaze, h SiO2 SiO 2 Al2O3 Al 2 O 3 BaOBao MgOMgO CaOCao SrOSro ZnOZno B2O3 B 2 O 3 TiO2 TiO 2 ZrO2 ZrO 2 1one 35,035.0 6,06.0 37,037.0 2,02.0 6,06.0 2,02.0 6,06.0 2,02.0 2,02.0 2,02.0 ~12~ 12 22 37,537.5 4,04.0 34,534.5 4,04.0 4,04.0 4,04.0 4,04.0 4,04.0 3,03.0 1,01,0 ~16~ 16 33 40,040,0 2,02.0 30,030,0 6,06.0 2,02.0 6,06.0 2,02.0 6,06.0 4,04.0 2,02.0 ~16~ 16

Фритту глазури варят при 1250°С, расплав гранулируют в воду. Фритту размалывают с добавкой 0,1% электролита, 0,1% глины и 47,0% воды.Frit glaze is boiled at 1250 ° C, the melt is granulated in water. The frit is ground with the addition of 0.1% electrolyte, 0.1% clay and 47.0% water.

Глазурную суспензию наносят на изделия, которые сушат и обжигают при 950°С.The glaze suspension is applied to products that are dried and fired at 950 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №430080, C03C 9/00, 1974.1. USSR Copyright Certificate No. 430080, C03C 9/00, 1974.

2. Патент Японии №64-11583, C03C 8/02, 1989.2. Japan Patent No. 64-11583, C03C 8/02, 1989.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, BaO, MgO, CaO, SrO, ZnO, В2О3, отличающаяся тем, что дополнительно содержит TiO2 и ZrO2 при следующем соотношении компонентов, мас.%: SiO2 35,0-40,0; Al2О3 2,0-2,5; BaO 35,5-37,0; MgO 3,0-6,0; CaO 2,0-6,0; SrO 2,0-6,0; ZnO 5,5-6,0; В2O3 2,0-6,0; TiO2 2,0-4,0; ZrO2 1,0-2,0.Glaze containing SiO 2 , Al 2 O 3 , BaO, MgO, CaO, SrO, ZnO, B 2 O 3 , characterized in that it additionally contains TiO 2 and ZrO 2 in the following ratio of components, wt.%: SiO 2 35, 0-40.0; Al 2 O 3 2.0-2.5; BaO 35.5-37.0; MgO 3.0-6.0; CaO 2.0-6.0; SrO 2.0-6.0; ZnO 5.5-6.0; B 2 O 3 2.0-6.0; TiO 2 2.0-4.0; ZrO 2 1.0-2.0.
RU2006146092/03A 2006-12-25 2006-12-25 Glaze RU2338707C2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006146092/03A RU2338707C2 (en) 2006-12-25 2006-12-25 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006146092/03A RU2338707C2 (en) 2006-12-25 2006-12-25 Glaze

Publications (2)

Publication Number Publication Date
RU2006146092A RU2006146092A (en) 2008-07-10
RU2338707C2 true RU2338707C2 (en) 2008-11-20

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Application Number Title Priority Date Filing Date
RU2006146092/03A RU2338707C2 (en) 2006-12-25 2006-12-25 Glaze

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RU (1) RU2338707C2 (en)

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Publication number Publication date
RU2006146092A (en) 2008-07-10

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