RU2320576C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2320576C1
RU2320576C1 RU2006131934/03A RU2006131934A RU2320576C1 RU 2320576 C1 RU2320576 C1 RU 2320576C1 RU 2006131934/03 A RU2006131934/03 A RU 2006131934/03A RU 2006131934 A RU2006131934 A RU 2006131934A RU 2320576 C1 RU2320576 C1 RU 2320576C1
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RU
Russia
Prior art keywords
glaze
zno
cao
mgo
sio
Prior art date
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RU2006131934/03A
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Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Priority to RU2006131934/03A priority Critical patent/RU2320576C1/en
Application granted granted Critical
Publication of RU2320576C1 publication Critical patent/RU2320576C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/062—Glass compositions containing silica with less than 40% silica by weight
    • C03C3/064—Glass compositions containing silica with less than 40% silica by weight containing boron
    • C03C3/066—Glass compositions containing silica with less than 40% silica by weight containing boron containing zinc

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: ceramics, facing materials.
SUBSTANCE: invention relates to compositions of fritted glazes that can be used in production of facing plates. Proposed glaze comprises the following components, wt.-%: SiO2, 33.0-35.0; Al2O3, 13.0-17.0; Fe2O3, 2.0-4.0; CaO, 8.0-11.0; MgO, 8.0-10.0; K2O, 4.0-5.0; B2O3, 8.0-10.0; ZnO, 8.0-10.0; TiO2, 2.0-4.0, and BaO, 4.0-5.0. Invention provides enhancing resistance to cold and luster of glaze.
EFFECT: improved and valuable properties of glaze.
1 tbl

Description

Изобретение относится к составам фриттованных глазурей, которые могут быть использованы производстве облицовочной плитки.The invention relates to compositions of fritted glazes that can be used in the manufacture of tiles.

Известна глазурь, содержащая SiO2, Al2O3, CaO, MgO, K2O, B2O3, ZnO, Na2O, SrO [1].Known glaze containing SiO 2 , Al 2 O 3 , CaO, MgO, K 2 O, B 2 O 3 , ZnO, Na 2 O, SrO [1].

Известна глазурь, содержащая, мас.%: SiO2 33,57-34,27; Al2O3 13,37-15,95; Fe2O3 73-9,29; CaO 8,67-9,26; MgO 7,85-8,39; K2O 0,6-0,7; Na2O 6,8-7,95; B2O3 9,75-12,18; ZnO 2,96-4,99; TiO 2,34-2,45 [2].Known glaze containing, in wt.%: SiO 2 33.57-34.27; Al 2 O 3 13.37-15.95; Fe 2 O 3 73-9.29; CaO 8.67-9.26; MgO 7.85-8.39; K 2 O 0.6-0.7; Na 2 O 6.8-7.95; B 2 O 3 9.75-12.18; ZnO 2.96-4.99; TiO 2.34-2.45 [2].

Цель изобретения - повышение морозостойкости и блеска глазури.The purpose of the invention is to increase frost resistance and gloss of glaze.

Цель достигается тем, что в состав глазури дополнительно вводят BaO, при следующем соотношении компонентов, мас.%: SiO2 33,0-35,0; Al2O3 13,0-17,0; Fe2O3 2,0-4,0; CaO 8,0-10,0; MgO 8,0-10,0; K2O 4,0-5,0; B2O3 8,0-10,0; ZnO 8,0-10,0; TiO2 2,0-4,0; BaO 4,0-5,0.The goal is achieved by the fact that BaO is additionally introduced into the glaze composition, in the following ratio of components, wt.%: SiO 2 33.0-35.0; Al 2 O 3 13.0-17.0; Fe 2 O 3 2.0-4.0; CaO 8.0-10.0; MgO 8.0-10.0; K 2 O 4.0-5.0; B 2 O 3 8.0-10.0; ZnO 8.0-10.0; TiO 2 2.0-4.0; BaO 4.0-5.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас.%Components, wt.% Морозостойкость, циклыFrost resistance cycles Блеск, %Gloss,%   SiO2 SiO 2 Al2O3 Al 2 O 3 Fe2O3 Fe 2 O 3 CaOCao MgOMgO K2OK 2 O B2O3 B 2 O 3 ZnOZno TiO2 TiO 2 BaOBao 1one 33,033.0 17,017.0 2,02.0 10,010.0 8,08.0 5,05,0 8,08.0 8,08.0 4,04.0 5,05,0 120-150120-150 75-8075-80 22 34,034.0 15,015.0 3,03.0 9,09.0 9,09.0 4,54,5 9,09.0 9,09.0 3,03.0 4,54,5 120-150120-150 75-8075-80 33 35,035.0 13,013.0 4,04.0 8,08.0 10,010.0 4,04.0 10,010.0 10,010.0 2,02.0 4,04.0 120-150120-150 75-8075-80

Компоненты глазури сплавляют при 1200°С, расплат гранулируют в воду. Фритту размалывают мокрым способом с добавкой 5% глины и 0,15% электролита. Обжиг глазури проводят при 950°С и окислительной среде.The components of the glaze are fused at 1200 ° C, the payback is granulated into water. The frit is ground wet with the addition of 5% clay and 0.15% electrolyte. Glaze firing is carried out at 950 ° C and in an oxidizing environment.

Источники информацииInformation sources

1. Авторское свидетельство СССР №757492, С03С 9/00, 1980.1. USSR author's certificate No. 757492, С03С 9/00, 1980.

2. Авторское свидетельство СССР №1010031, С03С 9/00, 1983.2. USSR Author's Certificate No. 1010031, С03С 9/00, 1983.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, Fe2O3, CaO, MgO, K2O, В2О3, ZnO, TiO2, отличающаяся тем, что дополнительно содержит ВаО при следующем соотношении компонентов, мас.%: SiO2 33,0-35,0; Al2O3 13,0-17,0; Fe2O3 2,0-4,0; CaO 8,0-10,0; MgO 8,0-10,0; K2O 4,0-5,0; B2O3 8,0-10,0; ZnO 8,0-10,0; TiO2 2,0-4,0; BaO 4,0-5,0.Glaze containing SiO 2 , Al 2 O 3 , Fe 2 O 3 , CaO, MgO, K 2 O, B 2 O 3 , ZnO, TiO 2 , characterized in that it additionally contains BaO in the following ratio of components, wt.%: SiO 2 33.0-35.0; Al 2 O 3 13.0-17.0; Fe 2 O 3 2.0-4.0; CaO 8.0-10.0; MgO 8.0-10.0; K 2 O 4.0-5.0; B 2 O 3 8.0-10.0; ZnO 8.0-10.0; TiO 2 2.0-4.0; BaO 4.0-5.0.
RU2006131934/03A 2006-09-05 2006-09-05 Glaze RU2320576C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006131934/03A RU2320576C1 (en) 2006-09-05 2006-09-05 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006131934/03A RU2320576C1 (en) 2006-09-05 2006-09-05 Glaze

Publications (1)

Publication Number Publication Date
RU2320576C1 true RU2320576C1 (en) 2008-03-27

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Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006131934/03A RU2320576C1 (en) 2006-09-05 2006-09-05 Glaze

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2643832C1 (en) * 2017-02-27 2018-02-06 Юлия Алексеевна Щепочкина Glaze

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2643832C1 (en) * 2017-02-27 2018-02-06 Юлия Алексеевна Щепочкина Glaze

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