RU2308423C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2308423C1
RU2308423C1 RU2006118525/03A RU2006118525A RU2308423C1 RU 2308423 C1 RU2308423 C1 RU 2308423C1 RU 2006118525/03 A RU2006118525/03 A RU 2006118525/03A RU 2006118525 A RU2006118525 A RU 2006118525A RU 2308423 C1 RU2308423 C1 RU 2308423C1
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RU
Russia
Prior art keywords
glaze
sro
zro
zno
sio
Prior art date
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RU2006118525/03A
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Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006118525/03A priority Critical patent/RU2308423C1/en
Application granted granted Critical
Publication of RU2308423C1 publication Critical patent/RU2308423C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: manufacture of facing tiles.
SUBSTANCE: proposed glaze contains the following components, mass-%: SiO2, 50.0-56.0; Al2O3, 2.0-4.0; CaO, 4.0-6.0; MgO, 2.0-6.0; Na2O, 2.0-4.0; B2O3, 6.0-10.0; ZnO, 5.0-7.0; ZrO2, 2.0-4.0; BaO, 1.7-2.7; Sb2O3, 0.1-0.2; Se, 0.1-0.2; CdO, 5.0-7.0; SrO, 5.0-7.0.
EFFECT: increased freeze resistance of glaze up to 120-170 cycles.
1 tbl

Description

Изобретение относится к области технологии силикатов, в частности к составам фриттованных глазурей, используемых в производстве облицовочной плитки.The invention relates to the field of technology of silicates, in particular to compositions of fritted glazes used in the manufacture of tiles.

Известна глазурь, содержащая, мас.%: SiO2 36,5-52,0; Na2O 2,8-6,7; B2O3 10,0-25,0; ZnO 5,5-14,4; ZrO2 12,5-25,0; SrO 1,3-8,8 /1/.Known glaze containing, in wt.%: SiO 2 36.5-52.0; Na 2 O 2,8-6,7; B 2 O 3 10.0-25.0; ZnO 5.5-14.4; ZrO 2 12.5-25.0; SrO 1.3-8.8 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 52,61-53,12; Al2O3 10,55-11,2; CaO 4,96-5,42; MgO 1,1-1,26; Na2O 3,0-3,13; K2O 1,99-2,16; B2O3 7,53-8,37; ZnO 5,78-7,72; ZrO2 7,26-8,76; Fe2O3 0,43-0,45; BaO 1,5-1,68 /2/.Known glaze containing, wt.%: SiO 2 52,61-53,12; Al 2 O 3 10.55-11.2; CaO 4.96-5.42; MgO 1.1-1.26; Na 2 O 3.0-3.13; K 2 O 1.99-2.16; B 2 O 3 7.53-8.37; ZnO 5.78-7.72; ZrO 2 7.26-8.76; Fe 2 O 3 0.43-0.45; BaO 1.5-1.68 / 2 /.

Цель изобретения - повышение морозостойкости глазури.The purpose of the invention is to increase frost resistance of glaze.

Цель изобретения достигается тем, что в состав глазури дополнительно вводят Sb2O3, Se, CdO, SrO, при следующем соотношении компонентов, мас.%: SiO2 50,0-56,0; Al2O3 2,0-4,0; CaO 4,0-6,0; MgO 2,0-6,0; Na2O 2,0-4,0; B2O3 6,0-10,0; ZnO 5,0-7,0; ZrO2 2,0-4,0; BaO 1,7-2,7; Sb2O3 0,1-0,2; Se 0,1-0,2; CdO 5,0-7,0; SrO 5,0-7,0.The purpose of the invention is achieved by the fact that Sb 2 O 3 , Se, CdO, SrO are additionally added to the glaze composition, in the following ratio of components, wt.%: SiO 2 50.0-56.0; Al 2 O 3 2.0-4.0; CaO 4.0-6.0; MgO 2.0-6.0; Na 2 O 2.0-4.0; B 2 O 3 6.0-10.0; ZnO 5.0-7.0; ZrO 2 2.0-4.0; BaO 1.7-2.7; Sb 2 O 3 0.1-0.2; Se 0.1-0.2; CdO 5.0-7.0; SrO 5.0-7.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

Фритту варят при 1300°С, расплав гранулируют в воду. Фритту размалывают с добавкой 0,2% электролита и 47% воды. Размол ведут до остатка не более 0,2% на сетке №005. Глазурную суспензию наносят на изделия и обжигают при 1000°С.The frit is boiled at 1300 ° C, the melt is granulated into water. The frit is ground with the addition of 0.2% electrolyte and 47% water. Grinding lead to a residue of not more than 0.2% on mesh No. 005. The glaze suspension is applied to the products and fired at 1000 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №767042, С03С 9/00, 1980.1. USSR author's certificate No. 767042, С03С 9/00, 1980.

2. Авторское свидетельство СССР №1196031, С03С 8/04, 1985.2. USSR Author's Certificate No. 1196031, С03С 8/04, 1985.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Морозостойкость, циклыFrost resistance cycles SiO2 SiO 2 Al2O3 Al 2 O 3 CaOCao MgOMgO Na2ONa 2 O B2O3 B 2 O 3 ZnOZno ZrO2 ZrO 2 BaOBao Sb2O3 Sb 2 O 3 SeSe CdOCdo SrOSro 1one 50,050,0 4,04.0 6,06.0 6,06.0 2,02.0 10,010.0 5,05,0 4,04.0 2,72.7 0,20.2 0,10.1 5,05,0 5,05,0 120-150120-150 22 53,053.0 3,03.0 5,05,0 4,04.0 3,03.0 8,08.0 6,06.0 3,03.0 2,22.2 0,10.1 0,20.2 6,06.0 6,06.0 150-170150-170 33 56,056.0 2,02.0 4,04.0 2,02.0 4,04.0 6,06.0 7,07.0 2,02.0 1,71.7 0,20.2 0,10.1 7,07.0 7,07.0 150-170150-170

Claims (1)

Глазурь, содержащая SiO2, Al2О3, CaO, MgO, Na2O, В2О3, ZnO, ZrO2, ВаО, отличающаяся тем, что дополнительно содержит Sb2O3, Se, CdO, SrO, при следующем соотношении компонентов, мас.%: SiO2 50,0-56,0; Al2O3 2,0-4,0; CaO 4,0-6,0; MgO 2,0-6,0; Na2O 2,0-4,0; В2О3 6,0-10,0; ZnO 5,0-7,0; ZrO2 2,0-4,0; ВаО 1,7-2,7; Sb2O3 0,1-0,2; Se 0,1-0,2; CdO 5,0-7,0; SrO 5,0-7,0.Glaze containing SiO 2 , Al 2 O 3 , CaO, MgO, Na 2 O, B 2 O 3 , ZnO, ZrO 2 , BaO, characterized in that it further comprises Sb 2 O 3 , Se, CdO, SrO, in the following the ratio of components, wt.%: SiO 2 50,0-56,0; Al 2 O 3 2.0-4.0; CaO 4.0-6.0; MgO 2.0-6.0; Na 2 O 2.0-4.0; B 2 O 3 6.0-10.0; ZnO 5.0-7.0; ZrO 2 2.0-4.0; BaO 1.7-2.7; Sb 2 O 3 0.1-0.2; Se 0.1-0.2; CdO 5.0-7.0; SrO 5.0-7.0.
RU2006118525/03A 2006-05-29 2006-05-29 Glaze RU2308423C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006118525/03A RU2308423C1 (en) 2006-05-29 2006-05-29 Glaze

Publications (1)

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RU2308423C1 true RU2308423C1 (en) 2007-10-20

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2616007C1 (en) * 2016-03-15 2017-04-12 Юлия Алексеевна Щепочкина Glaze

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2616007C1 (en) * 2016-03-15 2017-04-12 Юлия Алексеевна Щепочкина Glaze

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