RU2322408C1 - Glaze - Google Patents

Glaze Download PDF

Info

Publication number
RU2322408C1
RU2322408C1 RU2006135782/03A RU2006135782A RU2322408C1 RU 2322408 C1 RU2322408 C1 RU 2322408C1 RU 2006135782/03 A RU2006135782/03 A RU 2006135782/03A RU 2006135782 A RU2006135782 A RU 2006135782A RU 2322408 C1 RU2322408 C1 RU 2322408C1
Authority
RU
Russia
Prior art keywords
glaze
tio
sio
zro
cao
Prior art date
Application number
RU2006135782/03A
Other languages
Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
Original Assignee
Юлия Алексеевна Щепочкина
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006135782/03A priority Critical patent/RU2322408C1/en
Application granted granted Critical
Publication of RU2322408C1 publication Critical patent/RU2322408C1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: technology of silicates, composition of fritted glazes used for manufacture of facing tiles.
SUBSTANCE: proposed glaze contains the following components, mass-%: SiO2, 63.0-67.0; Al2O3, 3.0-5.0; B2O3, 14.0-16.0; CaO, 1.0-2.0; MgO, 1.0-2.0; K2O, 2.0-4.0; TiO2, 4.0-6.0; SnO2, 2.0-3.0; ZrO2, 2.0-3.0.
EFFECT: enhanced heat resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, в частности к составам фриттованных глазурей, которые могут быть использованы в производстве облицовочной плитки, изразцов.The invention relates to the field of technology of silicates, in particular to compositions of fritted glazes that can be used in the manufacture of tiles, tiles.

Известна глазурь, содержащая, мас.%: SiO2 56,93-62,92; Al2O3 3,77-7,63; B2O3 15,62-23,67; K2O 1,34-2,82; Na2O 7,34-8,43; TiO2 3,58-3,94 /1/.Known glaze containing, in wt.%: SiO 2 56.93-62.92; Al 2 O 3 3.77-7.63; B 2 O 3 15.62-23.67; K 2 O 1.34-2.82; Na 2 O, 7.34-8.43; TiO 2 3.58-3.94 / 1 /.

Известна глазурь, содержащая, мас.%: SiO2 62,36-66,24; Al2O3 2,73-4,96; B2O3 17,64-18,33; CaO 1,09-1,4; MgO 0,37-0,48; Na2O 9,34-11,46; K2O 0,38-0,49; Fe2O3 0,7-0,91; TiO2 0,05-0,07 /2/.Known glaze containing, in wt.%: SiO 2 62.36-66.24; Al 2 O 3 2.73-4.96; B 2 O 3 17.64-18.33; CaO 1.09-1.4; MgO 0.37-0.48; Na 2 O 9.34-11.46; K 2 O 0.38-0.49; Fe 2 O 3 0.7-0.91; TiO 2 0.05-0.07 / 2 /.

Цель изобретения состоит в повышении термостойкости глазури.The purpose of the invention is to increase the heat resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят SnO2 и ZrO2 при следующем соотношении компонентов, мас.%: SiO2 63,0-67,0; Al2O3 3,0-5,0; B2O3 14,0-16,0; CaO 1,0-2,0; MgO 1,0-2,0; K2O 2,0-4,0; TiO2 4,0-6,0; SnO2 2,0-3,0; ZrO2 2,0-3,0.The goal is achieved by the fact that SnO 2 and ZrO 2 are additionally added to the glaze in the following ratio of components, wt.%: SiO 2 63.0-67.0; Al 2 O 3 3.0-5.0; B 2 O 3 14.0-16.0; CaO 1.0-2.0; MgO 1.0-2.0; K 2 O 2.0-4.0; TiO 2 4.0-6.0; SnO 2 2.0-3.0; ZrO 2 2.0-3.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

  СоставStructure Компоненты, мас.%:Components, wt.%: Термостойкость, °СHeat resistance, ° С SiO2 SiO 2 Al2O3 Al 2 O 3 B2O3 B 2 O 3 CaOCao MgOMgO K2OK 2 O TiO2 TiO 2 SnO2 Sno 2 ZrO2 ZrO 2 1one 63,063.0 5,05,0 16,016,0 2,02.0 1,01,0 4,04.0 4,04.0 3,03.0 2,02.0 ~350~ 350 22 65,065.0 4,04.0 15,015.0 1,51,5 1,51,5 3,03.0 5,05,0 2,52,5 2,52,5 ~350~ 350 33 67,067.0 3,03.0 14,014.0 1,01,0 2,02.0 2,02.0 6,06.0 2,02.0 3,03.0 ~350~ 350

Фритту глазури варят при 1300-1350°С, расплав гранулируют в воду, размалывают с добавкой 45-50% воды, 1-2% беложгущейся глины, 0,1-0,2% электролита (калиевого жидкого стекла). Размол ведут до остатка не более 0,2% на сетке №005. Нанесенную на изделия глазурную суспензию обжигают при 950-1000°С.Frit glaze is boiled at 1300-1350 ° C, the melt is granulated into water, ground with the addition of 45-50% water, 1-2% white clay, 0.1-0.2% electrolyte (potassium water glass). Grinding lead to a residue of not more than 0.2% on mesh No. 005. The glaze suspension applied to the products is fired at 950-1000 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №1004285, C03C 9/00, 1982.1. USSR author's certificate No. 1004285, C03C 9/00, 1982.

2. Авторское свидетельство СССР №1765127, C03C 8/02, 1992.2. USSR Copyright Certificate No. 1765127, C03C 8/02, 1992.

Claims (1)

Глазурь, содержащая SiO2, Al2О3, В2О3, CaO, MgO, K2O, TiO2, отличающаяся тем, что дополнительно содержит SnO2 и ZrO2 при следующем соотношении компонентов, мас.%:Glaze containing SiO 2 , Al 2 O 3 , B 2 O 3 , CaO, MgO, K 2 O, TiO 2 , characterized in that it additionally contains SnO 2 and ZrO 2 in the following ratio, wt.%: SiO2 SiO 2 63,0-67,063.0-67.0 Al2O3 Al 2 O 3 3,0-5,03.0-5.0 B2O3 B 2 O 3 14,0-16,014.0-16.0 CaOCao 1,0-2,01.0-2.0 MgOMgO 1,0-2,01.0-2.0 TiO2 TiO 2 4,0-6,04.0-6.0 K2OK 2 O 2,0-4,02.0-4.0 SnO2 Sno 2 2,0-3,02.0-3.0 ZrO2 ZrO 2 2,0-3,02.0-3.0
RU2006135782/03A 2006-10-09 2006-10-09 Glaze RU2322408C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006135782/03A RU2322408C1 (en) 2006-10-09 2006-10-09 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2006135782/03A RU2322408C1 (en) 2006-10-09 2006-10-09 Glaze

Publications (1)

Publication Number Publication Date
RU2322408C1 true RU2322408C1 (en) 2008-04-20

Family

ID=39454002

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2006135782/03A RU2322408C1 (en) 2006-10-09 2006-10-09 Glaze

Country Status (1)

Country Link
RU (1) RU2322408C1 (en)

Similar Documents

Publication Publication Date Title
RU2322408C1 (en) Glaze
RU2322416C1 (en) Glaze
RU2311370C1 (en) Enamel
RU2328462C1 (en) Glaze
RU2302384C1 (en) Glaze
RU2308423C1 (en) Glaze
RU2318749C1 (en) Glaze
RU2312081C1 (en) Glass
RU2304115C1 (en) Glaze
RU2328469C1 (en) Frit for ceramic paints
RU2338707C2 (en) Glaze
RU2328463C1 (en) Glaze
RU2305076C1 (en) Glaze
RU2320586C1 (en) Glaze
RU2312083C1 (en) Glaze
RU2326834C1 (en) Glaze
RU2325356C1 (en) Glaze
RU2334703C1 (en) Glass
RU2311368C1 (en) Glaze
RU2345004C2 (en) Glaze
RU2328467C1 (en) Glaze
RU2323896C1 (en) Glass
RU2335473C1 (en) Glaze
RU2318750C1 (en) Glaze
RU2317268C1 (en) Glaze