RU2328463C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2328463C1
RU2328463C1 RU2006144301/03A RU2006144301A RU2328463C1 RU 2328463 C1 RU2328463 C1 RU 2328463C1 RU 2006144301/03 A RU2006144301/03 A RU 2006144301/03A RU 2006144301 A RU2006144301 A RU 2006144301A RU 2328463 C1 RU2328463 C1 RU 2328463C1
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RU
Russia
Prior art keywords
glaze
cuo
tio
cao
mgo
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RU2006144301/03A
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Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Application filed by Юлия Алексеевна Щепочкина filed Critical Юлия Алексеевна Щепочкина
Priority to RU2006144301/03A priority Critical patent/RU2328463C1/en
Application granted granted Critical
Publication of RU2328463C1 publication Critical patent/RU2328463C1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: chemistry.
SUBSTANCE: invention relates to the compositions of glazes used for covering the decorative tiles, household and domestic products, and tableware. The glaze contains SiO2, Al2O3, MgO, TiO2, B2O3, Na2O, CaO, CuO and supplemental ZrO2 at the following ratio, in mass percent: 50.5-54.5 of SiO2, 5.0-10.0 of Al2O3, 3.0-5.0 of MgO, 10.0-12.0 of TiO2, 10.0-12.0 of B2O3, 2.0-3.0 of Na2O, 1.0-2.0 of CaO, 0.5-1.5 of CuO, 8.0-10.0 of ZrO2.
EFFECT: thermostability of glaze is increased.
1 tbl

Description

Изобретение относится к области технологии силикатов и касается составов глазурей, используемых для покрытия облицовочной плитки, изделий хозяйственно-бытового назначения, посуды.The invention relates to the field of technology of silicates and relates to compositions of glazes used to cover tiles, household products, utensils.

Известна глазурь, включающая, мас.%: SiO2 32,47-35,63; Al2O3 7,31-10,92; B2O3 15,2-19,34; CaO 1,94-3,43; Na2O 2,05-2,82; K2O 1,25-1,8; TiO2 7,33-9,54; ZnO 15,7-21,8; по крайней мере один компонент из группы MnO2, CuO, Cr2O3, Fe2O3, Co3O4 2,49-9,0 [1].Glaze is known, including, wt.%: SiO 2 32,47-35,63; Al 2 O 3 7.31-10.92; B 2 O 3 15.2-19.34; CaO 1.94-3.43; Na 2 O 2.05-2.82; K 2 O 1.25-1.8; TiO 2 7.33-9.54; ZnO 15.7-21.8; at least one component from the group of MnO 2 , CuO, Cr 2 O 3 , Fe 2 O 3 , Co 3 O 4 2.49-9.0 [1].

Известна глазурь, содержащая, мас.%: SiO2 30,5-49,0; Al2O3 4,5-14,6; MgO 3,6-7,0; TiO2 7,0-15,0; B2O3 9,0-15,2; Na2O 8,5-20,5; по крайней мере два компонента из группы CaO, CuO, Cr2O3, NiO, Fe2O3, MnO2 6,0-14,5 [2].Known glaze containing, in wt.%: SiO 2 30.5-49.0; Al 2 O 3 4.5-14.6; MgO 3.6-7.0; TiO 2 7.0-15.0; B 2 O 3 9.0-15.2; Na 2 O 8.5-20.5; at least two components from the group CaO, CuO, Cr 2 O 3 , NiO, Fe 2 O 3 , MnO 2 6.0-14.5 [2].

Целью изобретения является повышение термостойкости глазури.The aim of the invention is to increase the heat resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят ZrO2, при следующем соотношении компонентов, мас.%: SiO2 50,5-54,5; Al2O3 5,0-10,0; MgO 3,0-5,0; TiO2 10,0-12,0; B2O3 10,0-12,0; Na2O 2,0-3,0; CaO 1,0-2,0; CuO 0,5-1,5; ZrO2 8,0-10,0.The goal is achieved by the fact that ZrO 2 is additionally introduced into the glaze composition, in the following ratio of components, wt.%: SiO 2 50.5-54.5; Al 2 O 3 5.0-10.0; MgO 3.0-5.0; TiO 2 10.0-12.0; B 2 O 3 10.0-12.0; Na 2 O 2.0-3.0; CaO 1.0-2.0; CuO 0.5-1.5; ZrO 2 8.0-10.0.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты глазури, мас%:Glaze components, wt%: Термостойкость (20-350°С), теплосменыHeat resistance (20-350 ° С), heat exchange SiO2 SiO 2 Al2O3 Al 2 O 3 MgOMgO TiO2 TiO 2 B2O3 B 2 O 3 Na2ONa 2 O CaOCao CuOCuO ZrO2 ZrO 2 1one 50,550,5 10,010.0 3,03.0 12,012.0 10,010.0 3,03.0 1,01,0 0,50.5 10,010.0 13-1513-15 22 52,052.0 8,08.0 4,04.0 11,011.0 11,011.0 2,52,5 1,51,5 1,01,0 9,09.0 13-1513-15 33 54,554.5 5,05,0 5,05,0 10,010.0 12,012.0 2,02.0 2,02.0 1,51,5 8,08.0 13-1513-15

Предложенная глазурь может быть получена следующим образом.The proposed glaze can be obtained as follows.

Фритту варят при 1350°С, расплав гранулируют в воду. Фритту размалывают с добавкой 3-4% глины, 0,3-0,5% буры, 0,5-1% соды, 45-50% воды. Размол проводят до прохождения через сетку № 0056. Суспензию наносят на изделия, сушат и закрепляют обжигом при 1100°С.The frit is boiled at 1350 ° C, the melt is granulated into water. The frit is ground with the addition of 3-4% clay, 0.3-0.5% borax, 0.5-1% soda, 45-50% water. The grinding is carried out before passing through the mesh No. 0056. The suspension is applied to the product, dried and fixed by firing at 1100 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР № 1315402, C 03 C 8/04, 1987.1. USSR author's certificate No. 1315402, C 03 C 8/04, 1987.

2. Авторское свидетельство СССР № 1058914, C 03 C 9/00, 1983.2. Copyright certificate of the USSR No. 1058914, C 03 C 9/00, 1983.

Claims (1)

Глазурь, содержащая SiO2, Al2O3, MgO, TiO2, B2O3, Na2O, CaO, CuO, отличающаяся тем, что дополнительно содержит ZrO2 при следующем соотношении компонентов, мас.%: SiO2 50,5-54,5; Al2O3 5,0-10,0; MgO 3,0-5,0; TiO2 10,0-12,0; B2O3 10,0-12,0; Na2O 2,0-3,0; CaO 1,0-2,0; CuO 0,5-1,5; ZrO2 8,0-10,0.Glaze containing SiO 2 , Al 2 O 3 , MgO, TiO 2 , B 2 O 3 , Na 2 O, CaO, CuO, characterized in that it further comprises ZrO 2 in the following ratio of components, wt.%: SiO 2 50, 5-54.5; Al 2 O 3 5.0-10.0; MgO 3.0-5.0; TiO 2 10.0-12.0; B 2 O 3 10.0-12.0; Na 2 O 2.0-3.0; CaO 1.0-2.0; CuO 0.5-1.5; ZrO 2 8.0-10.0.
RU2006144301/03A 2006-12-12 2006-12-12 Glaze RU2328463C1 (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Publications (1)

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RU2328463C1 true RU2328463C1 (en) 2008-07-10

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012066172A1 (en) * 2010-11-15 2012-05-24 Consejo Superior De Investigaciones Científicas (Csic) Water-repelling ceramic enamel having a metallic sheen and method for producing same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012066172A1 (en) * 2010-11-15 2012-05-24 Consejo Superior De Investigaciones Científicas (Csic) Water-repelling ceramic enamel having a metallic sheen and method for producing same
ES2382514A1 (en) * 2010-11-15 2012-06-11 Consejo Superior De Investigaciones Científicas (Csic) Water-repelling ceramic enamel having a metallic sheen and method for producing same

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