RU2306277C1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
RU2306277C1
RU2306277C1 RU2006119007/03A RU2006119007A RU2306277C1 RU 2306277 C1 RU2306277 C1 RU 2306277C1 RU 2006119007/03 A RU2006119007/03 A RU 2006119007/03A RU 2006119007 A RU2006119007 A RU 2006119007A RU 2306277 C1 RU2306277 C1 RU 2306277C1
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RU
Russia
Prior art keywords
glaze
cao
mgo
zro
sio
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RU2006119007/03A
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Russian (ru)
Inventor
Юли Алексеевна Щепочкина (RU)
Юлия Алексеевна Щепочкина
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Юлия Алексеевна Щепочкина
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Priority to RU2006119007/03A priority Critical patent/RU2306277C1/en
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Publication of RU2306277C1 publication Critical patent/RU2306277C1/en

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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/089—Glass compositions containing silica with 40% to 90% silica, by weight containing boron
    • C03C3/091—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium
    • C03C3/093—Glass compositions containing silica with 40% to 90% silica, by weight containing boron containing aluminium containing zinc or zirconium

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

FIELD: silicate materials.
SUBSTANCE: glaze for coating facing tiles and household-destination ware is composed of, wt %: SiO2 58.0-62.0, Al2O3 8.0-12.0, MgO 2.0-4.0, Fe2O3 0.2-0.5, CaO 4.0-8.0, K2O 2.0-4.0, BaO 2.0-4.0, ZnO 4.0-8.0, ZrO2 2.0-4.0, B2O3 4.0-5.0, CuO 0.5-1.5.
EFFECT: increased heat resistance of glaze.
1 tbl

Description

Изобретение относится к области технологии силикатов, а именно к составам фриттованных глазурей, используемых для покрытия облицовочной плитки, изделий хозяйственно-бытового назначения.The invention relates to the field of technology of silicates, and in particular to compositions of fritted glazes used to cover tiles, household products.

Известна глазурь состава, мас.%: SiO2 56,0-62,5; Al2O3 2,5-5,0; B2O3 11,0-14,0; CaO 2,0-6,0; MgO 1,5-5,0; K2O 0,5-3,0; Na2O 6,0-9,0; ZrO2 7,5-11,0 /1/.Known glaze composition, wt.%: SiO 2 56,0-62,5; Al 2 O 3 2.5-5.0; B 2 O 3 11.0-14.0; CaO 2.0-6.0; MgO 1.5-5.0; K 2 O 0.5-3.0; Na 2 O 6.0-9.0; ZrO 2 7.5-11.0 / 1 /.

Известна глазурь состава, мас.%: SiO2 59,19-63,1; Al2O3 12,16-12,85; Fe2O3 0,16-0,24; CaO 7,16-8,21; MgO 0,59-0,79; K2O 2,19-2,49; Na2O 2,01-2,25; BaO 4,88-5,44; ZnO 2,43-3,7; ZrO2 4,84-5,34 /2/.Known glaze composition, wt.%: SiO 2 59.19-63.1; Al 2 O 3 12.16-12.85; Fe 2 O 3 0.16-0.24; CaO 7.16-8.21; MgO 0.59-0.79; K 2 O 2,19-2,49; Na 2 O 2.01-2.25; BaO 4.88-5.44; ZnO 2.43-3.7; ZrO 2 4.84-5.34 / 2 /.

Целью изобретения является повышение термостойкости глазури.The aim of the invention is to increase the heat resistance of the glaze.

Цель достигается тем, что в состав глазури дополнительно вводят B2O3 и CuO при следующем соотношении компонентов, мас.%: SiO2 58,0-62,0; Al2O3 8,0-12,0; MgO 2,0-4,0; Fe2O3 0,2-0,5; CaO 4,0-8,0; K2O 2,0-4,0; BaO 2,0-4,0; ZnO 4,0-8,0; ZrO2 2,0-4,0; B2O3 4,0-5,0; CuO 0,5-1,5.The goal is achieved by the fact that B 2 O 3 and CuO are additionally introduced into the glaze composition in the following ratio of components, wt.%: SiO 2 58.0-62.0; Al 2 O 3 8.0-12.0; MgO 2.0-4.0; Fe 2 O 3 0.2-0.5; CaO 4.0-8.0; K 2 O 2.0-4.0; BaO 2.0-4.0; ZnO 4.0-8.0; ZrO 2 2.0-4.0; B 2 O 3 4.0-5.0; CuO 0.5-1.5.

В таблице приведены составы глазури.The table shows the glaze compositions.

ТаблицаTable СоставStructure Компоненты, мас.%:Components, wt.%: Термостойкость, теплосменыHeat resistance, heat exchange SiO2 SiO 2 Al2O3 Al 2 O 3 MgOMgO Fe2O3 Fe 2 O 3 CaOCao K2OK 2 O BaOBao ZnOZno ZrO2 ZrO 2 B2O3 B 2 O 3 CuOCuO 1one 58,058.0 12,012.0 2,02.0 0,50.5 8,08.0 2,02.0 4,04.0 4,04.0 4,04.0 4,04.0 1,51,5 18-2018-20 22 60,060.0 10,010.0 3,03.0 0,20.2 6,06.0 3,003.00 3,03.0 6,06.0 3,03.0 4,54,5 1,31.3 18-2018-20 33 62,062.0 8,08.0 4,04.0 0,50.5 4,04.0 4,04.0 2,02.0 8,08.0 2,02.0 5,05,0 0,50.5 15-1815-18

Фритту варят при 1300-1350°С, расплав гранулируют в воду.The frit is boiled at 1300-1350 ° C, the melt is granulated in water.

Фритту с добавкой 0,1-0,2% электролита, 45-50% воды размалывают до остатка не более 0,2% на сетке №0056. Суспензию наносят на изделия и закрепляют обжигом при 950-1000°С.Frit with the addition of 0.1-0.2% electrolyte, 45-50% of water is ground to a residue of not more than 0.2% on mesh No. 0056. The suspension is applied to the products and fixed by firing at 950-1000 ° C.

Источники информацииInformation sources

1. Авторское свидетельство СССР №765223, С03С 9/00, 1980.1. USSR author's certificate No. 765223, С03С 9/00, 1980.

2. Авторское свидетельство СССР №1368202, С03С 8/04, 1988.2. USSR author's certificate No. 1368202, С03С 8/04, 1988.

Claims (1)

Глазурь, содержащая SiO2, Al2O3, MgO, Fe2O3, CaO, K2O, BaO, ZnO, ZrO2, отличающаяся тем, что дополнительно содержит В2О3 и CuO при следующем соотношении компонентов, мас.%:Glaze containing SiO 2 , Al 2 O 3 , MgO, Fe 2 O 3 , CaO, K 2 O, BaO, ZnO, ZrO 2 , characterized in that it additionally contains B 2 O 3 and CuO in the following ratio of components, wt. %: SiO2 SiO 2 58,0-62,058.0-62.0 Al2О3 Al 2 About 3 8,0-12,08.0-12.0 MgO MgO 2,0-4,02.0-4.0 Fe2O3 Fe 2 O 3 0,2-0,50.2-0.5 CaO Cao 4,0-8,04.0-8.0 К2О K 2 O 2,0-4,02.0-4.0 BaO Bao 2,0-4,02.0-4.0 ZnO Zno 4,0-8,04.0-8.0 ZrO2 ZrO 2 2,0-4,02.0-4.0 B2O3 B 2 O 3 4,0-5,04.0-5.0 CuO CuO 0,5-1,50.5-1.5
RU2006119007/03A 2006-05-31 2006-05-31 Glaze RU2306277C1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
RU2006119007/03A RU2306277C1 (en) 2006-05-31 2006-05-31 Glaze

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Application Number Priority Date Filing Date Title
RU2006119007/03A RU2306277C1 (en) 2006-05-31 2006-05-31 Glaze

Publications (1)

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RU2306277C1 true RU2306277C1 (en) 2007-09-20

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2614756C1 (en) * 2016-03-15 2017-03-29 Юлия Алексеевна Щепочкина Glaze
WO2020127213A1 (en) * 2018-12-20 2020-06-25 Eurokera Copper aluminoborosilicate glass and uses thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2614756C1 (en) * 2016-03-15 2017-03-29 Юлия Алексеевна Щепочкина Glaze
WO2020127213A1 (en) * 2018-12-20 2020-06-25 Eurokera Copper aluminoborosilicate glass and uses thereof
FR3090624A1 (en) * 2018-12-20 2020-06-26 Eurokera COPPER ALUMINOBOROSILICATE GLASSES AND USES THEREOF
CN113195423A (en) * 2018-12-20 2021-07-30 欧罗克拉公司 Copper aluminoborosilicate glass and use thereof
CN113195423B (en) * 2018-12-20 2023-04-11 欧罗克拉公司 Copper aluminoborosilicate glass and use thereof

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