RU2157724C2 - Хроматографическое разделение изотопов эрбия - Google Patents
Хроматографическое разделение изотопов эрбия Download PDFInfo
- Publication number
- RU2157724C2 RU2157724C2 RU97101079/28A RU97101079A RU2157724C2 RU 2157724 C2 RU2157724 C2 RU 2157724C2 RU 97101079/28 A RU97101079/28 A RU 97101079/28A RU 97101079 A RU97101079 A RU 97101079A RU 2157724 C2 RU2157724 C2 RU 2157724C2
- Authority
- RU
- Russia
- Prior art keywords
- erbium
- isotope
- column
- fraction
- product
- Prior art date
Links
- 229910052691 Erbium Inorganic materials 0.000 title claims abstract description 68
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 238000013375 chromatographic separation Methods 0.000 title claims description 7
- 238000000926 separation method Methods 0.000 claims abstract description 39
- 239000002904 solvent Substances 0.000 claims abstract description 22
- 239000007864 aqueous solution Substances 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 27
- 238000011068 loading method Methods 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 20
- 239000011347 resin Substances 0.000 claims description 19
- 229920005989 resin Polymers 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 17
- 239000002253 acid Substances 0.000 claims description 15
- -1 erbium cations Chemical class 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 11
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 10
- 238000009826 distribution Methods 0.000 claims description 10
- 239000003729 cation exchange resin Substances 0.000 claims description 8
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 7
- 239000011707 mineral Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 150000002500 ions Chemical class 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 3
- 238000004587 chromatography analysis Methods 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 3
- 150000007524 organic acids Chemical class 0.000 claims 2
- 239000003929 acidic solution Substances 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 230000000155 isotopic effect Effects 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 45
- 230000005526 G1 to G0 transition Effects 0.000 description 36
- 238000002386 leaching Methods 0.000 description 23
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 229910052761 rare earth metal Inorganic materials 0.000 description 8
- 230000007423 decrease Effects 0.000 description 6
- 238000000605 extraction Methods 0.000 description 6
- 238000006073 displacement reaction Methods 0.000 description 5
- 238000010828 elution Methods 0.000 description 5
- VQCBHWLJZDBHOS-UHFFFAOYSA-N erbium(iii) oxide Chemical compound O=[Er]O[Er]=O VQCBHWLJZDBHOS-UHFFFAOYSA-N 0.000 description 5
- 150000002910 rare earth metals Chemical class 0.000 description 5
- 238000013461 design Methods 0.000 description 4
- 235000011167 hydrochloric acid Nutrition 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052688 Gadolinium Inorganic materials 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000011260 aqueous acid Substances 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 231100001261 hazardous Toxicity 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000005349 anion exchange Methods 0.000 description 2
- 239000003957 anion exchange resin Substances 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 239000000356 contaminant Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 239000012156 elution solvent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 239000003758 nuclear fuel Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 239000012508 resin bead Substances 0.000 description 2
- HLLSOEKIMZEGFV-UHFFFAOYSA-N 4-(dibutylsulfamoyl)benzoic acid Chemical compound CCCCN(CCCC)S(=O)(=O)C1=CC=C(C(O)=O)C=C1 HLLSOEKIMZEGFV-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052693 Europium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- 229910052769 Ytterbium Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- ZXGIFJXRQHZCGJ-UHFFFAOYSA-N erbium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Er+3].[Er+3] ZXGIFJXRQHZCGJ-UHFFFAOYSA-N 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 238000005372 isotope separation Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000002285 radioactive effect Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000011800 void material Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D59/00—Separation of different isotopes of the same chemical element
- B01D59/28—Separation by chemical exchange
- B01D59/30—Separation by chemical exchange by ion exchange
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/50—Conditioning of the sorbent material or stationary liquid
- G01N30/58—Conditioning of the sorbent material or stationary liquid the sorbent moving as a whole
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/264,810 | 1994-06-23 | ||
US08/264,810 US5437795A (en) | 1994-06-23 | 1994-06-23 | Chromatographic separation of erbium isotopes |
Publications (2)
Publication Number | Publication Date |
---|---|
RU97101079A RU97101079A (ru) | 1999-02-20 |
RU2157724C2 true RU2157724C2 (ru) | 2000-10-20 |
Family
ID=23007698
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU97101079/28A RU2157724C2 (ru) | 1994-06-23 | 1995-06-16 | Хроматографическое разделение изотопов эрбия |
Country Status (7)
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT2190U1 (de) * | 1997-09-08 | 1998-06-25 | Prior Eng Ag | Chromatographievorrichtung |
EP1349639B1 (fr) | 2001-01-05 | 2008-12-03 | Areva NP | Procede de separation d'isotopes |
US9056272B2 (en) * | 2006-02-28 | 2015-06-16 | Tarek A. Z. Farag | Isotopes separation and purification in an electrolytic medium |
US20100111800A1 (en) * | 2008-11-03 | 2010-05-06 | Westinghouse Electric Company Llc | PRODUCTION OF NUCLEAR GRADE ENRICHED GADOLINIUM AND ERBIUM USING VOLATILE Gd OR Er SPECIES USING AN AERODYNAMIC PROCESS |
CN115166097B (zh) * | 2022-07-26 | 2024-01-23 | 中国地质调查局西安地质调查中心(西北地质科技创新中心) | 降低设备损伤及同时分离地质样品中Li、K的方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3482376A (en) * | 1968-06-26 | 1969-12-09 | Atomic Energy Commission | Apparatus for continuous chromatographic separations |
US3511028A (en) * | 1969-01-15 | 1970-05-12 | Commerce Usa | Continuous gas-liquid chromatography method utilizing annular open columns |
EP0173484A2 (en) * | 1984-08-06 | 1986-03-05 | Westinghouse Electric Corporation | Process for the separation of gadelinium isotopes |
EP0453908A2 (en) * | 1990-04-27 | 1991-10-30 | Westinghouse Electric Corporation | Chromatographic separation of zirconium isotopes |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3615173A (en) * | 1969-04-03 | 1971-10-26 | J Oscar Winget | Separation of rare earth elements by ion exchange |
US3582263A (en) * | 1969-10-31 | 1971-06-01 | Sylvania Electric Prod | Solvent extraction process for separating gadolinium from terbium and dysprosium |
AU536948B2 (en) * | 1979-12-19 | 1984-05-31 | Asahi Kasei Kogyo Kabushiki Kaisha | Separation of rare earth metals |
US4438078A (en) * | 1982-12-20 | 1984-03-20 | Allied Corporation | Recovery of gadolinium and gallium oxides |
GB2139915B (en) * | 1983-05-19 | 1987-10-28 | Nitivy Co Ltd | Method for separating rare earth metals |
US4711768A (en) * | 1984-08-06 | 1987-12-08 | Westinghouse Electric Corp. | Process for the separation of gadolinium isotopes |
US4915843A (en) * | 1988-11-28 | 1990-04-10 | Union Oil Company Of California | Continuous displacement chromatographic method |
US5124023A (en) * | 1988-11-28 | 1992-06-23 | Union Oil Company Of California | Continuous removal of polynuclear aromatics from hydrocarbon recycle oil |
WO1991003298A1 (en) * | 1989-08-31 | 1991-03-21 | Union Oil Company Of California | Continuous high performance liquid chromatography |
US5024749A (en) * | 1990-04-20 | 1991-06-18 | Westinghouse Electric Corp. | System and method for continuous separation of isotopes |
US5110566A (en) * | 1990-07-19 | 1992-05-05 | Westinghouse Electric Corp. | Chromatographic separation of zirconium isotopes with reduced waste liquor |
US5045209A (en) * | 1990-09-24 | 1991-09-03 | Westinghouse Electric Corp. | Method for chromatographically recovering scandium and yttrium |
US5174971A (en) * | 1990-10-10 | 1992-12-29 | Westinghouse Electric Corp. | Continuous anion exchange chromatography for the separation of zirconium isotopes |
US5130001A (en) * | 1990-12-03 | 1992-07-14 | Westinghouse Electric Corp. | Uranium isotope separation by continuous anion exchange chromatography |
-
1994
- 1994-06-23 US US08/264,810 patent/US5437795A/en not_active Expired - Fee Related
-
1995
- 1995-06-01 TW TW084105559A patent/TW284700B/zh active
- 1995-06-16 RU RU97101079/28A patent/RU2157724C2/ru not_active IP Right Cessation
- 1995-06-16 EP EP95923901A patent/EP0766592B1/en not_active Expired - Lifetime
- 1995-06-16 WO PCT/US1995/007621 patent/WO1996000123A1/en active IP Right Grant
- 1995-06-16 DE DE69505379T patent/DE69505379T2/de not_active Expired - Fee Related
- 1995-06-16 JP JP8503236A patent/JPH10506043A/ja not_active Ceased
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3482376A (en) * | 1968-06-26 | 1969-12-09 | Atomic Energy Commission | Apparatus for continuous chromatographic separations |
US3511028A (en) * | 1969-01-15 | 1970-05-12 | Commerce Usa | Continuous gas-liquid chromatography method utilizing annular open columns |
EP0173484A2 (en) * | 1984-08-06 | 1986-03-05 | Westinghouse Electric Corporation | Process for the separation of gadelinium isotopes |
EP0453908A2 (en) * | 1990-04-27 | 1991-10-30 | Westinghouse Electric Corporation | Chromatographic separation of zirconium isotopes |
Also Published As
Publication number | Publication date |
---|---|
EP0766592B1 (en) | 1998-10-14 |
WO1996000123A1 (en) | 1996-01-04 |
DE69505379T2 (de) | 1999-06-02 |
DE69505379D1 (de) | 1998-11-19 |
JPH10506043A (ja) | 1998-06-16 |
EP0766592A1 (en) | 1997-04-09 |
US5437795A (en) | 1995-08-01 |
TW284700B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1996-09-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20030617 |