RU2017116832A - Интеграция получения синтез-газа от парового риформинга и сухого риформинга - Google Patents

Интеграция получения синтез-газа от парового риформинга и сухого риформинга Download PDF

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RU2017116832A
RU2017116832A RU2017116832A RU2017116832A RU2017116832A RU 2017116832 A RU2017116832 A RU 2017116832A RU 2017116832 A RU2017116832 A RU 2017116832A RU 2017116832 A RU2017116832 A RU 2017116832A RU 2017116832 A RU2017116832 A RU 2017116832A
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catalyst
mixture
carbon monoxide
methanol
production
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Агхаддин МАМЕДОВ
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Сабик Глобал Текнолоджис Б.В.
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    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
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    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0238—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a carbon dioxide reforming step
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
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    • C01B2203/1052—Nickel or cobalt catalysts
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/141—At least two reforming, decomposition or partial oxidation steps in parallel
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    • C01—INORGANIC CHEMISTRY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82—Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36 with rare earths or actinides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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  • Chemical & Material Sciences (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
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  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (26)

1. Способ конверсии метана в олефин и метанол, включающий:
a. контакт метана, диоксида углерода и кислорода с катализатором окислительного сухого риформинга с получением продукционной смеси окислительного сухого риформинга, содержащей монооксид углерода, водород и воду;
b. контакт метана и воды с катализатором парового риформинга с получением продукционной смеси парового риформинга, содержащей монооксид углерода и водород;
c. контакт продукционной смеси окислительного сухого риформинга с катализатором получения олефинов с получением олефиновой продукционной смеси, содержащей олефин и монооксид углерода;
d. выделение монооксида углерода из олефиновой продукционной смеси с получением выделенного монооксида углерода;
e. объединение выделенного монооксида углерода, по меньшей мере, с частью продукционной смеси парового риформинга с получением смеси для получения метанола и
f. контакт смеси для получения метанола с катализатором получения метанола с получением метанола.
2. Способ по п. 1, в котором катализатор окислительного сухого риформинга содержит твердый носитель.
3. Способ по п. 2, в котором твердый носитель содержит по меньшей мере один носитель, выбранный из группы, состоящей из оксида алюминия, диоксида кремния и оксида магния.
4. Способ по п. 1, в котором катализатор окислительного сухого риформинга содержит никель.
5. Способ по п. 4, в котором катализатор окислительного сухого риформинга содержит никель в количестве от приблизительно 2 масс. % до приблизительно 15 масс. % относительно общей массы катализатора.
6. Способ по п. 4, в котором катализатор окислительного сухого риформинга содержит основной оксид металла.
7. Способ по п. 6, в котором основной оксид металла содержит оксид лантана (III).
8. Способ по п. 4, в котором катализатор окислительного сухого риформинга содержит благородный металл.
9. Способ по п. 8, в котором благородный металл содержит по меньшей мере один благородный металл, выбранный из группы, состоящей из платины и рутения.
10. Способ по п. 8, в котором катализатор окислительного сухого риформинга содержит благородный металл в количестве от приблизительно 0,1 масс. % до приблизительно 2 масс. % относительно общей массы катализатора.
11. Способ по п. 1, в котором смесь для получения метанола содержит водород и монооксид углерода в мольном отношении приблизительно 2:1.
12. Способ по п. 1, в котором контакт метана, диоксида углерода и кислорода с катализатором окислительного сухого риформинга, контакт метана и воды с катализатором парового риформинга, контакт продукционной смеси окислительного сухого риформинга с катализатором получения олефинов и контакт смеси для получения метанола с катализатором получения метанола происходит одновременно.
13. Способ по п. 1, в котором олефин содержит этилен.
14. Способ конверсии метана в этилен и метанол, включающий:
a. контакт метана, диоксида углерода и кислорода с катализатором окислительного сухого риформинга с получением продукционной смеси окислительного сухого риформинга, содержащей монооксид углерода, водород и воду, причем катализатор окислительного сухого риформинга содержит никель, основной оксид металла и благородный металл;
b. контакт метана и воды с катализатором парового риформинга с получением продукционной смеси парового риформинга, содержащей монооксид углерода и водород;
c. контакт продукционной смеси окислительного сухого риформинга с катализатором получения олефинов с получением олефиновой продукционной смеси, содержащей этилен и монооксид углерода;
d. выделение монооксида углерода из олефиновой продукционной смеси с получением выделенного монооксида углерода;
e. объединение выделенного монооксида углерода, по меньшей мере, с частью продукционной смеси парового риформинга с получением смеси для получения метанола и
f. контакт смеси для получения метанола с катализатором получения метанола с получением метанола.
RU2017116832A 2014-10-27 2015-10-23 Интеграция получения синтез-газа от парового риформинга и сухого риформинга RU2017116832A (ru)

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