RU2017114883A - Ламинирующий клей с низким содержанием мономера - Google Patents
Ламинирующий клей с низким содержанием мономера Download PDFInfo
- Publication number
- RU2017114883A RU2017114883A RU2017114883A RU2017114883A RU2017114883A RU 2017114883 A RU2017114883 A RU 2017114883A RU 2017114883 A RU2017114883 A RU 2017114883A RU 2017114883 A RU2017114883 A RU 2017114883A RU 2017114883 A RU2017114883 A RU 2017114883A
- Authority
- RU
- Russia
- Prior art keywords
- laminating adhesive
- composition
- prepolymer
- polyol
- reaction product
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
- C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
- Polyurethanes Or Polyureas (AREA)
Claims (13)
1. Композиция ламинирующего клея, содержащая
a) первый форполимер, содержащий продукт взаимодействия метилендифенилдиизоцианата и первого полиола, и
b) второй форполимер, содержащий продукт взаимодействия изоцианата и второго полиола, причем указанный второй форполимер содержит менее 0,1 массового процента свободных мономеров изоцианата
при этом указанная композиция ламинирующего клея по существу не содержит растворителей.
2. Композиция ламинирующего клея по п. 1, отличающаяся тем, что указанный первый форполимер содержится в количестве от 0,1 массового процента до 99,9 массовых процентов, и указанный второй форполимер содержится в количестве от 0,1 массового процента до 99,9 массовых процентов относительно общей массы указанной водной композиции.
3. Композиция ламинирующего клея по любому из пп. 1 и 2, отличающаяся тем, что указанные первый полиол и второй полиол являются одинаковыми или разными и выбраны из группы, состоящей из простых полиэфиров, сложных полиэфиров и комбинаций указанных соединений.
4. Композиция ламинирующего клея по любому из пп. 1 – 3, отличающаяся тем, что метилендифенилдиизоцианат в первом форполимере представляет собой 4,4'-метилендифенилдиизоцианат.
5. Композиция ламинирующего клея по п. 1, отличающаяся тем, что изоцианат во втором форполимере содержит толуолдиизоцианат.
6. Способ получения композиции ламинирующего клея, включающий смешивание
i) первого форполимера, содержащего продукт взаимодействия метилендифенилдиизоцианата и первого полиола, и
ii) второго форполимера, содержащего продукт взаимодействия изоцианата, содержащего менее 0,1 массового процента свободных мономеров, и второго полиола.
7. Способ по п. 6, отличающийся тем, что i) и ii) смешивают при температуре в диапазоне от 20°С до 120°С.
8. Композиция ламинирующего клея по п. 1, имеющая скорость разложения первичных ароматических аминов в диапазоне от 1 до 3 дней на пленке ориентированного полиамида/полиэтиленэтилвинилацетата, содержащей 3 массовых процента этилвинилацетата.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201462063256P | 2014-10-13 | 2014-10-13 | |
| US62/063,256 | 2014-10-13 | ||
| PCT/US2015/055080 WO2016060977A1 (en) | 2014-10-13 | 2015-10-12 | Low monomer laminating adhesive |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2017114883A true RU2017114883A (ru) | 2018-10-29 |
| RU2017114883A3 RU2017114883A3 (ru) | 2019-04-17 |
| RU2741545C2 RU2741545C2 (ru) | 2021-01-26 |
Family
ID=54347891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2017114883A RU2741545C2 (ru) | 2014-10-13 | 2015-10-12 | Ламинирующий клей с низким содержанием мономера |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US20170240785A1 (ru) |
| EP (1) | EP3207070A1 (ru) |
| JP (1) | JP6821576B2 (ru) |
| CN (1) | CN106795411B (ru) |
| AR (1) | AR103004A1 (ru) |
| BR (1) | BR112017007518B1 (ru) |
| MX (1) | MX2017004870A (ru) |
| RU (1) | RU2741545C2 (ru) |
| TW (1) | TWI747807B (ru) |
| WO (1) | WO2016060977A1 (ru) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW202033591A (zh) * | 2019-03-05 | 2020-09-16 | 美商陶氏全球科技有限責任公司 | 雙組分無溶劑黏著劑組合物 |
| WO2022094768A1 (en) * | 2020-11-03 | 2022-05-12 | Dow Global Technologies Llc | Adhesive composition |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8810701D0 (en) * | 1988-05-06 | 1988-06-08 | Bostik Ltd | Hot-melt polyurethane adhesive compositions |
| CA2055346A1 (en) * | 1990-12-21 | 1992-06-22 | John C. Tangen | Mixture of isocyanate-terminated polyurethane prepolymers having reduced set time |
| DE4232015A1 (de) * | 1992-09-24 | 1994-03-31 | Bayer Ag | Lösungsmittelfreie Zweikomponentenpolyurethanklebstoffsysteme |
| JPH10204404A (ja) * | 1997-01-16 | 1998-08-04 | Nippon Polyurethane Ind Co Ltd | ポリウレタン系二成分型接着剤 |
| EP1030869A1 (de) * | 1997-11-11 | 2000-08-30 | Henkel Kommanditgesellschaft auf Aktien | Polyurethanbindemittel mit einem niedrigen gehalt an leichtflüchtigen monomeren |
| US6784242B2 (en) * | 1997-11-11 | 2004-08-31 | Henkel Kommanditgesellschaft Auf Aktien | Polyurethane binding agents having a low content of highly volatile monomers |
| US7129312B1 (en) * | 1999-11-29 | 2006-10-31 | Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) | Adhesion promoters for monomer-free reactive polyurethanes |
| JP4399159B2 (ja) * | 2000-10-23 | 2010-01-13 | ヘンケル・アクチェンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト・アウフ・アクチェン | モノマー含有量の少ない多段硬化性の反応性接着剤 |
| US6713570B2 (en) * | 2001-07-30 | 2004-03-30 | 3M Innovative Properties Company | Moisture curing hot-melt adhesives |
| DE102004057292A1 (de) * | 2004-11-26 | 2006-06-01 | Klebchemie, M.G. Becker Gmbh & Co Kg | Verfahren zur Herstellung von reaktiven Polyurethanzusammensetzungen |
| EP1770107A1 (de) * | 2005-09-30 | 2007-04-04 | Sika Technology AG | Feuchtigkeitshärtende Polyurethanzusammensetzung |
| CN101880516B (zh) * | 2010-07-05 | 2013-01-30 | 广东多正化工科技有限公司 | 低游离mdi单体双组份无溶剂聚氨酯胶粘剂 |
| AU2012242949B2 (en) * | 2011-04-15 | 2015-09-24 | H.B. Fuller Company | Modified diphenylmethane diisocyanate-based adhesives |
-
2015
- 2015-10-12 TW TW104133400A patent/TWI747807B/zh active
- 2015-10-12 US US15/518,904 patent/US20170240785A1/en not_active Abandoned
- 2015-10-12 RU RU2017114883A patent/RU2741545C2/ru active
- 2015-10-12 WO PCT/US2015/055080 patent/WO2016060977A1/en active Application Filing
- 2015-10-12 EP EP15784882.1A patent/EP3207070A1/en active Pending
- 2015-10-12 CN CN201580054957.7A patent/CN106795411B/zh active Active
- 2015-10-12 BR BR112017007518-0A patent/BR112017007518B1/pt active IP Right Grant
- 2015-10-12 JP JP2017538924A patent/JP6821576B2/ja active Active
- 2015-10-12 MX MX2017004870A patent/MX2017004870A/es unknown
- 2015-10-13 AR ARP150103301A patent/AR103004A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| BR112017007518B1 (pt) | 2022-08-02 |
| RU2017114883A3 (ru) | 2019-04-17 |
| TWI747807B (zh) | 2021-12-01 |
| BR112017007518A2 (pt) | 2018-01-23 |
| TW201619337A (zh) | 2016-06-01 |
| US20170240785A1 (en) | 2017-08-24 |
| WO2016060977A1 (en) | 2016-04-21 |
| CN106795411A (zh) | 2017-05-31 |
| JP6821576B2 (ja) | 2021-01-27 |
| RU2741545C2 (ru) | 2021-01-26 |
| JP2017531732A (ja) | 2017-10-26 |
| AR103004A1 (es) | 2017-04-12 |
| MX2017004870A (es) | 2017-07-04 |
| EP3207070A1 (en) | 2017-08-23 |
| CN106795411B (zh) | 2021-01-29 |
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