RU2017109919A - Композитные порошки из сульфонированного сложного полиэфира и серебряных наночастиц и способы их получения - Google Patents

Композитные порошки из сульфонированного сложного полиэфира и серебряных наночастиц и способы их получения Download PDF

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RU2017109919A
RU2017109919A RU2017109919A RU2017109919A RU2017109919A RU 2017109919 A RU2017109919 A RU 2017109919A RU 2017109919 A RU2017109919 A RU 2017109919A RU 2017109919 A RU2017109919 A RU 2017109919A RU 2017109919 A RU2017109919 A RU 2017109919A
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composite powder
silver nanoparticles
particles
product
sulfonated
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RU2017109919A
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RU2017109919A3 (ru
RU2761473C2 (ru
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Валери М. ФАРРУДЖИА
Баркев КЕОШКЕРИАН
Мишель Н. КРЭТЬЕН
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Зирокс Корпорейшн
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    • C08G63/688—Polyesters containing atoms other than carbon, hydrogen and oxygen containing sulfur
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    • C08J3/21—Compounding polymers with additives, e.g. colouring in the presence of a continuous liquid phase the polymer being premixed with a liquid phase
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Claims (25)

1. Композитный порошок для применения в селективном лазерном спекании, содержащий:
матрицу из сульфонированного сложного полиэфира; и
множество серебряных наночастиц, диспергированных в матрице,
где наночастицы серебра присутствуют в композитном порошке в количестве от примерно 0,5 ppm до примерно 50000 ppm;
и при этом композитный порошок дополнительно имеет размер частиц от примерно 10 мкм до примерно 300 мкм.
2. Композитный порошок по п. 1, отличающийся тем, что сульфонированный сложный полиэфир имеет температуру стеклования (Tg) от примерно 45°С до примерно 65°С.
3. Композитный порошок по п. 1, отличающийся тем, что матрица из сульфонированного сложного полиэфира содержит разветвленный полимер.
4. Композитный порошок по п. 1, отличающийся тем, что матрица из сульфонированного сложного полиэфира содержит линейный полимер.
5. Способ получения композитного порошка, включающий:
нагревание сульфонированной сложной полиэфирной смолы в растворителе, не содержащем органических соединений;
добавление раствора ионов серебра (I) к нагретой в воде смоле с получением смеси;
добавление к смеси раствора восстанавливающего агента с получением эмульсии частиц, содержащих матрицу из сульфонированного сложного полиэфира и множество наночастиц серебра, расположенных в матрице из сульфонированного сложного полиэфира;
агрегацию эмульсии частиц с получением агрегированных частиц;
коалесценцию агрегированных частиц с получением коалесцированных частиц; и
промывание коалесцированных частиц с получением композитного порошка.
6. Способ по п. 5, отличающийся тем, что воду добавляют к эмульсии частиц до стадии агрегации.
7. Способ по п. 5, отличающийся тем, что нагревание сульфонированной сложной полиэфирной смолы проводят при температуре от примерно 65°С до примерно 90°С.
8. Способ по п. 5, отличающийся тем, что агрегацию проводят при температуре от примерно 30°С до примерно 80°С.
9. Изделие, содержащее:
композитный порошок, содержащий:
матрицу из сульфонированного сложного полиэфира; и
множество серебряных наночастиц, диспергированных в матрице;
где наночастицы серебра присутствуют в композитном порошке в количестве от примерно 0,5 ppm до примерно 50000 ppm;
и при этом композитный порошок дополнительно имеет размер частиц от примерно 10 мкм до примерно 300 мкм.
10. Изделие по п. 9, отличающееся тем, что указанное изделие выбрано из группы, состоящей из биохимического сенсора, оптического датчика, противомикробного изделия, текстильного изделия, косметического продукта, электронной детали, волокна и криогенного сверхпроводящего материала.
RU2017109919A 2016-04-13 2017-03-24 Композитные порошки из сульфонированного сложного полиэфира и серебряных наночастиц и способы их получения RU2761473C2 (ru)

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US15/098,270 US9909013B2 (en) 2016-04-13 2016-04-13 Silver nanoparticle-sulfonated polyester composite powders and methods of making the same
US15/098270 2016-04-13

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RU2017109919A3 RU2017109919A3 (ru) 2020-05-28
RU2761473C2 RU2761473C2 (ru) 2021-12-08

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US (1) US9909013B2 (ru)
EP (1) EP3231831B1 (ru)
JP (1) JP6989274B2 (ru)
KR (1) KR102196870B1 (ru)
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US10216111B2 (en) * 2015-05-07 2019-02-26 Xerox Corporation Antimicrobial sulfonated polyester resin
US9877485B2 (en) * 2016-04-13 2018-01-30 Xerox Corporation Silver polyester-sulfonated nanoparticle composite filaments and methods of making the same
EP3622023B1 (en) 2017-05-12 2024-05-22 Inhibit Coatings Limited Composite resins containing silver nanoparticles
US11285661B2 (en) * 2017-11-08 2022-03-29 Canon Kabushiki Kaisha Powder for ceramic shaping and ceramic shaping method using the same
WO2020132215A1 (en) * 2018-12-19 2020-06-25 Seurat Technologies, Inc. Additive manufacturing system using a pulse modulated laser for two-dimensional printing
US11203696B1 (en) * 2019-01-16 2021-12-21 United States Of America As Represented By The Secretary Of The Air Force Selective reshaping of nanoparticles in three dimensional articles
US11597805B2 (en) * 2019-04-10 2023-03-07 Xerox Corporation Method for producing sulfone polymer micro-particles for SLS 3D printing
DE102020119683A1 (de) 2020-06-25 2021-12-30 Rehau Ag + Co Verfahren zur Herstellung eines Bauteils im Wege der additiven Fertigung
CN113388145A (zh) * 2021-06-04 2021-09-14 北京工商大学 一种抗菌砧板及其制备方法

Family Cites Families (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4247508B1 (en) 1979-12-03 1996-10-01 Dtm Corp Molding process
US4863538A (en) 1986-10-17 1989-09-05 Board Of Regents, The University Of Texas System Method and apparatus for producing parts by selective sintering
US5017753A (en) 1986-10-17 1991-05-21 Board Of Regents, The University Of Texas System Method and apparatus for producing parts by selective sintering
CN1059040C (zh) 1989-09-19 2000-11-29 佳能株式会社 静电图像显影用有机调色剂的制法
US5111998A (en) 1990-03-30 1992-05-12 Canon Kabushiki Kaisha Process for producing toner for developing electrostatic image and apparatus system therefor
US5272034A (en) 1991-07-22 1993-12-21 Mita Industrial Co., Ltd. Process for producing electrophotographic toner
US5348832A (en) 1993-06-01 1994-09-20 Xerox Corporation Toner compositions
US5393630A (en) 1993-10-04 1995-02-28 Xerox Corporation Melt mixing processes
US6140003A (en) 1994-04-01 2000-10-31 Xerox Corporation Toner compositions with charge enhancing resins
US5604076A (en) 1996-02-01 1997-02-18 Xerox Corporation Toner compositions and processes thereof
US5593807A (en) 1996-05-10 1997-01-14 Xerox Corporation Toner processes using sodium sulfonated polyester resins
US5660965A (en) 1996-06-17 1997-08-26 Xerox Corporation Toner processes
US5658704A (en) 1996-06-17 1997-08-19 Xerox Corporation Toner processes
US5648193A (en) 1996-06-17 1997-07-15 Xerox Corporation Toner processes
US6110411A (en) 1997-03-18 2000-08-29 Clausen; Christian Henning Laser sinterable thermoplastic powder
US5945245A (en) 1998-01-13 1999-08-31 Xerox Corporation Toner processes
US5853944A (en) 1998-01-13 1998-12-29 Xerox Corporation Toner processes
US5916725A (en) 1998-01-13 1999-06-29 Xerox Corporation Surfactant free toner processes
US5919595A (en) 1998-01-13 1999-07-06 Xerox Corporation Toner process with cationic salts
US5840462A (en) 1998-01-13 1998-11-24 Xerox Corporation Toner processes
IT1305576B1 (it) * 1998-09-22 2001-05-09 Novamont Spa Polimeri a carattere idrofobico caricati con complessi dell'amido.
US6054240A (en) 1999-03-31 2000-04-25 Xerox Corporation Toner compositions and processes thereof
US6020101A (en) 1999-04-21 2000-02-01 Xerox Corporation Toner composition and process thereof
US6017671A (en) 1999-05-24 2000-01-25 Xerox Corporation Toner and developer compositions
US6143457A (en) 1999-10-12 2000-11-07 Xerox Corporation Toner compositions
US6210853B1 (en) 2000-09-07 2001-04-03 Xerox Corporation Toner aggregation processes
US7312011B2 (en) 2005-01-19 2007-12-25 Xerox Corporation Super low melt and ultra low melt toners containing crystalline sulfonated polyester
US20070087023A1 (en) * 2005-03-11 2007-04-19 Ismail Ashraf A Polymer-Based Antimicrobial Agents, Methods of Making Said Agents, and Applications Using Said Agents
WO2007114895A2 (en) * 2006-04-06 2007-10-11 Z Corporation Production of three-dimensional objects by use of electromagnetic radiation
CA2682757C (en) * 2007-04-04 2014-05-27 Perlen Converting Ag Antimicrobial material
JP2012103535A (ja) * 2010-11-11 2012-05-31 Fuji Xerox Co Ltd 静電荷像現像用トナー、静電荷像現像剤、トナーカートリッジ、プロセスカートリッジ、画像形成方法、及び、画像形成装置
US8703377B2 (en) 2011-02-04 2014-04-22 Xerox Corporation Emulsion aggregation toner compositions
US8518624B2 (en) * 2011-04-15 2013-08-27 Xerox Corporation Polyester resin comprising a biopolyol
US8475994B2 (en) * 2011-08-23 2013-07-02 Xerox Corporation Toner compositions
AU2013344733B2 (en) 2012-11-14 2017-02-23 Orthopaedic Innovation Center Inc. Antimicrobial articles produced by additive manufacturing
US8974993B2 (en) * 2013-01-15 2015-03-10 Xerox Corporation UV red fluorescent EA toner
US9678451B2 (en) * 2013-09-17 2017-06-13 Xerox Corporation Emulsion aggregation toner for sensor and antibacterial applications
US9505058B2 (en) 2014-05-16 2016-11-29 Xerox Corporation Stabilized metallic nanoparticles for 3D printing
US9243141B1 (en) 2014-11-03 2016-01-26 Xerox Corporation Coated silver nanoparticle composites comprising a sulfonated polyester matrix and methods of making the same

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