RU2016136757A - Аминоспиртовая обработка золь-гель конверсионного покрытия, подложки, включающие такое покрытие, и способы изготовления таких подложек - Google Patents

Аминоспиртовая обработка золь-гель конверсионного покрытия, подложки, включающие такое покрытие, и способы изготовления таких подложек Download PDF

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RU2016136757A
RU2016136757A RU2016136757A RU2016136757A RU2016136757A RU 2016136757 A RU2016136757 A RU 2016136757A RU 2016136757 A RU2016136757 A RU 2016136757A RU 2016136757 A RU2016136757 A RU 2016136757A RU 2016136757 A RU2016136757 A RU 2016136757A
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amino alcohol
solution
sol
product
coating
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RU2016136757A
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RU2016136757A3 (ru
RU2654738C2 (ru
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Чарльз КЕЙЛ
Ричард АЛЬБЕРС
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Прк-Десото Интернэшнл, Инк.
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
    • C07C215/02—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
    • C07C215/04—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated
    • C07C215/06—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic
    • C07C215/10—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being saturated and acyclic with one amino group and at least two hydroxy groups bound to the carbon skeleton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00—Processes for applying liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/10—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an adhesive surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/086—Organic or non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125—Process of deposition of the inorganic material
    • C23C18/1254—Sol or sol-gel processing
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
    • C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
    • C23C18/125—Process of deposition of the inorganic material
    • C23C18/1295—Process of deposition of the inorganic material with after-treatment of the deposited inorganic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2503/00—Polyurethanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Claims (44)

1. Изделие, включающее
подложку;
золь-гель конверсионное покрытие по меньшей мере на части подложки; и
слой обработки по меньшей мере на части золь-гель конверсионного покрытия, причем слой обработки включает аминоспирт.
2. Изделие по п. 1, кроме того включающее слой покрытия по меньшей мере на части слоя обработки.
3. Изделие по п. 2, в котором слой покрытия включает композицию покрытия на основе полиуретана.
4. Изделие по п. 1, в котором аминоспирт включает соединение, представленное формулой [N(R1)(R2)]z-R-(R'-OH)xRʺy, в которой:
x имеет значение от 1 до 3; y имеет значение от 0 до 2; z имеет значение от 1 до 3; x+y+z=4;
R1 и R2 каждый независимо включает атом водорода или группу С1-С6 алкил, и когда z больше 1, каждый R1 и каждый R2 могут быть одинаковыми или различными;
R и R' каждый независимо включает группу С1-С30 алкилен, и когда х больше 1, каждый R' могут быть одинаковыми или различными; и
Rʺ включает атом водорода или группу C1-C30 алкил, и когда y больше 1, каждый Rʺ могут быть одинаковыми или различными.
5. Изделие по п. 4, в котором х равен 1.
6. Изделие по п. 1, в котором аминоспирт включает трис(гидроксиметил)аминометан, аминометилпропандиол, аминоэтилпропандиол, аминометилпропанол, диметиламиноэтанол, аминогидроксиэтилпентандиол, аминопентандиол и/или аминометилбутанол.
7. Изделие по п. 1, в котором аминоспирт включает трис(гидроксиметил)аминометан.
8. Изделие, включающее
подложку;
золь-гель конверсионное покрытие по меньшей мере на части подложки;
слой обработки по меньшей мере на части золь-гель конверсионного покрытия, причем слой обработки включает аминоспирт; и
слой покрытия по меньшей мере на части слоя обработки, причем слой покрытия включает композицию покрытия на основе полиуретана.
9. Изделие по п. 8, в котором аминоспирт включает соединение, представленное формулой [N(R1)(R2)]z-R-(R'-OH)xRʺy, в которой:
х имеет значение от 1 до 3; y имеет значение от 0 до 2; z имеет значение от 1 до 3; x+y+z=4;
R1 и R2 каждый независимо включает атом водорода или группу C1-C6 алкил, и когда z больше 1, каждый R1 и каждый R2 могут быть одинаковыми или различными;
R и R' каждый независимо включает группу C1-C30 алкилен, и когда х больше 1, каждый R' могут быть одинаковыми или различными; и
Rʺ включает атом водорода или группу C1-C30 алкил, и когда у больше 1, каждый Rʺ могут быть одинаковыми или различными.
10. Изделие по п. 8, в котором аминоспирт включает трис(гидроксиметил)аминометан.
11. Изделие по п. 1, в котором изделие включает часть воздушно-космического транспортного средства.
12. Изделие по п. 8, в котором изделие включает часть воздушно-космического транспортного средства.
13. Способ производства изделия по п. 1, который включает
нанесение частично отвержденной золь-гель композиции по меньшей мере на часть подложки;
по меньшей мере, частичную сушку частично отвержденной золь-гель композиции, чтобы получить золь-гель конверсионное покрытие;
нанесение раствора, включающего аминоспирт, по меньшей мере на часть золь-гель покрытия; и
по меньшей мере, частичную сушку раствора, включающего аминоспирт.
14. Способ по п. 13, в котором аминоспирт присутствует в растворе в количестве больше, чем 0,5 вес. %, до предела растворимости аминоспирта в растворе, в расчете на общий вес раствора, и способ дополнительно включает промывку изделия раствором промывки после, по меньшей мере, частичной сушки раствора, включающего аминоспирт.
15. Способ по п. 13, в котором аминоспирт присутствует в растворе в количестве от более 0 до 0,5 вес. %, в расчете на общий вес раствора.
16. Способ по п. 13, в котором раствор, включающий аминоспирт, дополнительно содержит воду и/или органический растворитель.
17. Способ производства изделия по п. 2, который включает
нанесение частично отвержденной золь-гель композиции по меньшей мере на часть подложки;
по меньшей мере частичную сушку частично отвержденной золь-гель композиции, чтобы получить золь-гель конверсионное покрытие;
нанесение раствора, включающего аминоспирт, по меньшей мере на часть золь-гель конверсионного покрытия;
по меньшей мере частичную сушку раствора, включающего аминоспирт, чтобы получить слой обработки;
нанесение композиции покрытия по меньшей мере на часть слоя обработки; и отверждение композиции покрытия с получением слоя покрытия.
18. Способ по п. 17, в котором аминоспирт присутствует в растворе в количестве от более 0,5 вес. % до предела растворимости аминоспирта в растворе, в расчете на общий вес раствора, и способ дополнительно включает промывку изделия раствором промывки после, по меньшей мере, частичной сушки раствора, включающего аминоспирт.
19. Способ по п. 17, в котором аминоспирт присутствует в растворе в количестве от более 0 до 0,5 вес. %, в расчете на общий вес раствора.
20. Способ по п. 17, в котором раствор, включающий аминоспирт, дополнительно содержит воду и/или органический растворитель.
RU2016136757A 2014-02-14 2015-02-13 Аминоспиртовая обработка золь-гель конверсионного покрытия, подложки, включающие такое покрытие, и способы изготовления таких подложек RU2654738C2 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US14/180,918 2014-02-14
US14/180,918 US9562000B2 (en) 2014-02-14 2014-02-14 Amino alcohol treatment for sol-gel conversion coatings, substrates including the same, and methods of making the substrates
PCT/US2015/015816 WO2015123520A1 (en) 2014-02-14 2015-02-13 Amino alcohol treatment for sol-gel conversion coatings, substrates including the same, and methods of making the substrates

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RU2016136757A3 RU2016136757A3 (ru) 2018-03-19
RU2016136757A true RU2016136757A (ru) 2018-03-19
RU2654738C2 RU2654738C2 (ru) 2018-05-22

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EP (1) EP3104982B1 (ru)
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CN (2) CN110066991B (ru)
AU (1) AU2015218389B2 (ru)
BR (1) BR112016018624A2 (ru)
CA (1) CA2939878C (ru)
ES (1) ES2787900T3 (ru)
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US20150232413A1 (en) 2015-08-20
CN110066991B (zh) 2021-08-03
US9562000B2 (en) 2017-02-07
KR101887794B1 (ko) 2018-08-10
RU2016136757A3 (ru) 2018-03-19
CA2939878A1 (en) 2015-08-20
ES2787900T3 (es) 2020-10-19
AU2015218389A1 (en) 2016-09-15
WO2015123520A1 (en) 2015-08-20
CA2939878C (en) 2019-06-25
CN106103798A (zh) 2016-11-09
CN106103798B (zh) 2019-09-13
JP6429891B2 (ja) 2018-11-28
RU2654738C2 (ru) 2018-05-22
EP3104982A1 (en) 2016-12-21
CN110066991A (zh) 2019-07-30
JP2017507812A (ja) 2017-03-23
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EP3104982B1 (en) 2020-04-08
AU2015218389B2 (en) 2018-03-01

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