RU2016136648A - Огнестойкие виниловые полимеры - Google Patents
Огнестойкие виниловые полимеры Download PDFInfo
- Publication number
- RU2016136648A RU2016136648A RU2016136648A RU2016136648A RU2016136648A RU 2016136648 A RU2016136648 A RU 2016136648A RU 2016136648 A RU2016136648 A RU 2016136648A RU 2016136648 A RU2016136648 A RU 2016136648A RU 2016136648 A RU2016136648 A RU 2016136648A
- Authority
- RU
- Russia
- Prior art keywords
- vinyl polymers
- paragraphs
- range
- vinyl
- polymers
- Prior art date
Links
- 229920002554 vinyl polymer Polymers 0.000 title claims 19
- 230000009970 fire resistant effect Effects 0.000 title claims 2
- 239000000203 mixture Substances 0.000 claims 8
- 229910052736 halogen Inorganic materials 0.000 claims 6
- 150000002367 halogens Chemical class 0.000 claims 5
- 150000003944 halohydrins Chemical class 0.000 claims 5
- 125000003700 epoxy group Chemical group 0.000 claims 4
- 229920000642 polymer Polymers 0.000 claims 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 239000001301 oxygen Substances 0.000 claims 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 2
- 238000002485 combustion reaction Methods 0.000 claims 2
- 239000003112 inhibitor Substances 0.000 claims 2
- 125000000466 oxiranyl group Chemical group 0.000 claims 2
- 229920001400 block copolymer Polymers 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 230000004580 weight loss Effects 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/22—Esters containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/06—Organic materials
- C09K21/08—Organic materials containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
- C08F220/325—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals containing glycidyl radical, e.g. glycidyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Fireproofing Substances (AREA)
- Epoxy Resins (AREA)
Claims (13)
1. Виниловые полимеры, содержащие галогенгидрин и эпоксигруппы, имеющие средневзвешенную молекулярную массу (Mw) по меньшей мере 40000 Да, содержание галогена в диапазоне от 0,6% до 55 мас.%, такое содержание оксирановых групп, что содержание кислорода оксиранового цикла находится в диапазоне от 1% до 3 мас.%, по отношению к содержанию галогена, и демонстрирующие потерю массы 5% при температуре по меньшей мере 240°С.
2. Виниловые полимеры по п. 1, средняя молекулярная масса которых находится в диапазоне от 40000 Да до 300000 Да.
3. Полимеры по п. 1 или 2, в которых содержание галогена находится в диапазоне от 1% до 20 мас.%.
4. Виниловые полимеры по любому из пп. 1-3, в которых содержание кислорода оксиранового цикла находится в диапазоне от 1% до 2 мас.% по отношению к содержанию галогена.
5. Виниловые полимеры по любому из пп. 1-4, в которых группы галогенгидрина представляют собой бромгидрины.
6. Огнестойкая полимерная композиция, которая включает виниловые полимеры и виниловые полимеры, содержащие галогенгидрин и эпоксигруппы, по любому из пп. 1-5.
7. Композиция по п. 5, в которой виниловые полимеры представляют собой виниловые ароматические полимеры или сополимеры.
8. Композиция по п. 6 или 7, в которой виниловые полимеры представляют собой блок-сополимеры, в которых по меньшей мере один блок представляет собой виниловый полимер, содержащий галогенгидрин и эпоксигруппы, по любому из пп. 1-5 и по меньшей мере один блок представляет собой виниловый полимер, имеющий тот же химический состав, что и виниловый полимер, содержащий галогенгидрин и эпоксигруппы.
9. Композиция по любому из пп. 6-8, в которой виниловые полимеры имеют среднюю молекулярную массу в диапазоне от 40000 Да до 300000 Да.
10. Композиция по любому из пп. 6-8, в которой виниловые полимеры имеют содержание галогена в диапазоне от 3% до 55 мас.%.
11. Композиция по любому из пп. 6-8, в которой виниловые полимеры имеют содержание кислорода оксиранового цикла в диапазоне от 1% до 2 мас.% по отношению к содержанию галогена.
12. Применение виниловых полимеров по любому из пп. 1-5 в качестве ингибитора горения.
13. Применение виниловых полимеров по любому из пп. 1-5 в качестве ингибиторов горения в полимерных композициях, содержащих виниловые полимеры.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ITMI20140544 | 2014-03-28 | ||
| ITMI2014A000544 | 2014-03-28 | ||
| PCT/IT2015/000083 WO2015145478A2 (en) | 2014-03-28 | 2015-03-26 | Vinyl polymers having a flame-retardant function |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| RU2016136648A true RU2016136648A (ru) | 2018-04-28 |
| RU2016136648A3 RU2016136648A3 (ru) | 2018-08-28 |
| RU2678442C2 RU2678442C2 (ru) | 2019-01-29 |
Family
ID=50897724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2016136648A RU2678442C2 (ru) | 2014-03-28 | 2015-03-26 | Огнестойкие виниловые полимеры |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10662380B2 (ru) |
| EP (1) | EP3122792B1 (ru) |
| JP (1) | JP6653259B2 (ru) |
| CN (1) | CN105873962B (ru) |
| BR (1) | BR112016013773B1 (ru) |
| ES (1) | ES2705424T3 (ru) |
| IL (1) | IL248091B (ru) |
| MX (1) | MX2016012459A (ru) |
| MY (1) | MY178792A (ru) |
| PL (1) | PL3122792T3 (ru) |
| RU (1) | RU2678442C2 (ru) |
| TR (1) | TR201900374T4 (ru) |
| WO (1) | WO2015145478A2 (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020139111A1 (en) * | 2018-12-27 | 2020-07-02 | Public Joint Stock Company "Sibur Holding" | Modified diene-containing (co)polymer, method for producing the same and use of the same as a flame retardant |
| RU2741967C1 (ru) * | 2019-12-26 | 2021-02-01 | Публичное акционерное общество «СИБУР Холдинг» | Способ получения модифицированного диенсодержащего (со)полимера и его применение в качестве антипирена |
| CN113372518B (zh) * | 2021-05-27 | 2022-10-11 | 理工清科(重庆)先进材料研究院有限公司 | 一种阻燃抑烟聚丙烯腈材料及其制备方法 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3624012A (en) | 1969-11-21 | 1971-11-30 | Leslie C Case | Process for preparing halogenated copolymers of olefinically unsaturated cycloaliphatic monoanhydrides with cyclic monoethers |
| US3880957A (en) * | 1973-04-12 | 1975-04-29 | Goodrich Co B F | Graft copolymers of vinylidene monomers onto trihalomethyl hydrocarbon glycidyl ether polymers |
| JPS5756481B2 (ru) * | 1974-06-13 | 1982-11-30 | ||
| JPS5458791A (en) * | 1977-10-19 | 1979-05-11 | Somar Mfg | Posiitype resist material |
| JPS61115078A (ja) * | 1984-11-08 | 1986-06-02 | Sanyo Kokusaku Pulp Co Ltd | 臭素化ビスフエノ−ルｆ型エポキシおよびその製造法 |
| JPS62133189A (ja) * | 1985-12-02 | 1987-06-16 | Bando Chem Ind Ltd | ゴム製床カバ−材 |
| EP0519097B1 (en) * | 1991-06-19 | 1994-03-16 | GE Plastics ABS Europe B.V. | Process for the preparation of copolymers with units derived from glycidyl esters or glycidylethers |
| EP2410015B1 (en) * | 2008-02-26 | 2013-09-18 | Dow Global Technologies LLC | Brominated polymers as flame retardant additives and polymer systems containing same |
| FR2943073B1 (fr) * | 2009-03-16 | 2012-12-14 | Astrium Sas | Utilisation de resines durcissables contenant un prepolymere a base de (meth)acrylate de glycidyle pour la fabrication de materiaux composites a usage spatial |
| CN102471397B (zh) * | 2009-06-30 | 2013-11-06 | 陶氏环球技术有限责任公司 | 溴化并环氧化的阻燃剂 |
| US8440748B2 (en) | 2010-09-28 | 2013-05-14 | Toray Industries, Inc. | Thermoplastic resin composition and molded item formed from same |
| US8568958B2 (en) * | 2011-06-21 | 2013-10-29 | Az Electronic Materials Usa Corp. | Underlayer composition and process thereof |
-
2015
- 2015-03-26 MY MYPI2016703152A patent/MY178792A/en unknown
- 2015-03-26 WO PCT/IT2015/000083 patent/WO2015145478A2/en active Application Filing
- 2015-03-26 RU RU2016136648A patent/RU2678442C2/ru active
- 2015-03-26 BR BR112016013773-6A patent/BR112016013773B1/pt active IP Right Grant
- 2015-03-26 ES ES15734246T patent/ES2705424T3/es active Active
- 2015-03-26 CN CN201580003513.0A patent/CN105873962B/zh active Active
- 2015-03-26 PL PL15734246T patent/PL3122792T3/pl unknown
- 2015-03-26 JP JP2016553559A patent/JP6653259B2/ja not_active Expired - Fee Related
- 2015-03-26 US US15/119,564 patent/US10662380B2/en active Active
- 2015-03-26 TR TR2019/00374T patent/TR201900374T4/tr unknown
- 2015-03-26 EP EP15734246.0A patent/EP3122792B1/en active Active
- 2015-03-26 MX MX2016012459A patent/MX2016012459A/es unknown
-
2016
- 2016-09-27 IL IL24809116A patent/IL248091B/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CN105873962B (zh) | 2018-01-30 |
| WO2015145478A2 (en) | 2015-10-01 |
| RU2016136648A3 (ru) | 2018-08-28 |
| JP6653259B2 (ja) | 2020-02-26 |
| EP3122792A2 (en) | 2017-02-01 |
| MX2016012459A (es) | 2016-12-20 |
| EP3122792B1 (en) | 2018-10-17 |
| MY178792A (en) | 2020-10-20 |
| IL248091A0 (en) | 2016-11-30 |
| US10662380B2 (en) | 2020-05-26 |
| TR201900374T4 (tr) | 2019-02-21 |
| CN105873962A (zh) | 2016-08-17 |
| JP2017508842A (ja) | 2017-03-30 |
| BR112016013773B1 (pt) | 2021-06-08 |
| US20170051209A1 (en) | 2017-02-23 |
| PL3122792T3 (pl) | 2019-06-28 |
| ES2705424T3 (es) | 2019-03-25 |
| RU2678442C2 (ru) | 2019-01-29 |
| IL248091B (en) | 2019-10-31 |
| WO2015145478A3 (en) | 2015-11-19 |
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