RU2016125132A - BINDING COMPOSITION FOR INSULATION PRODUCTS - Google Patents

BINDING COMPOSITION FOR INSULATION PRODUCTS Download PDF

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RU2016125132A
RU2016125132A RU2016125132A RU2016125132A RU2016125132A RU 2016125132 A RU2016125132 A RU 2016125132A RU 2016125132 A RU2016125132 A RU 2016125132A RU 2016125132 A RU2016125132 A RU 2016125132A RU 2016125132 A RU2016125132 A RU 2016125132A
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water
soluble
binder composition
group
based polymer
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RU2016125132A
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Russian (ru)
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RU2659965C1 (en
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Тяньцзянь ХУАН
Кристина ТОМПСОН
Дэниел УОСКИ
Крис ДЖЕТТИ
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ХЕНКЕЛЬ АйПи ЭНД ХОЛДИНГ ГМБХ
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J201/00—Adhesives based on unspecified macromolecular compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B32B29/002—Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B21/00—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board
    • B32B21/04—Layered products comprising a layer of wood, e.g. wood board, veneer, wood particle board comprising wood as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00—Layered products comprising a layer of paper or cardboard
    • B32B29/08—Corrugated paper or cardboard
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/16—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by features of a layer formed of particles, e.g. chips, powder or granules
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09J109/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • C09J123/04—Homopolymers or copolymers of ethene
    • C09J123/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
    • C09J125/02—Homopolymers or copolymers of hydrocarbons
    • C09J125/04—Homopolymers or copolymers of styrene
    • C09J125/08—Copolymers of styrene
    • C09J125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
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    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/062—Copolymers with monomers not covered by C09J133/06
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/10—Coatings without pigments
    • D21H19/12—Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/50—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by form
    • D21H21/52—Additives of definite length or shape
    • D21H21/54—Additives of definite length or shape being spherical, e.g. microcapsules, beads
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30—Multi-ply
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/08—Coating on the layer surface on wood layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/12—Coating on the layer surface on paper layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/51—Elastic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00—Containers; Receptacles
    • B32B2439/70—Food packaging
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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Claims (32)

1. Связующая композиция на водорастворимой основе, включающая:1. A binder composition on a water-soluble basis, including: (a) полимер на водной основе, изготовленный посредством эмульсионной полимеризации;(a) a water-based polymer made by emulsion polymerization; (b) множество расширяющихся микросфер; и(b) many expanding microspheres; and (c) необязательно добавку;(c) optionally an additive; в которой полимер на водной основе имеет (i) модуль упругости более чем 0,5 МПа в температурном интервале от 70°C до 110°C; (ii) абсолютное значение тангенса угла наклона кривой log(E)/T менее чем 0,05 в температурном интервале от 70°C до 110°C; и (iii) значение тангенса дельта менее чем 0,6 при 90°C.in which the water-based polymer has (i) an elastic modulus of more than 0.5 MPa in the temperature range from 70 ° C to 110 ° C; (ii) the absolute value of the slope of the log (E) / T curve is less than 0.05 in the temperature range from 70 ° C to 110 ° C; and (iii) a tangent delta value of less than 0.6 at 90 ° C. 2. Связующая композиция на водорастворимой основе по п. 1, в которой полимер на водной основе имеет (i) модуль упругости 5 МПа при температуре от 85°C до 100°C.2. The water-soluble binder composition according to claim 1, wherein the water-based polymer has (i) an elastic modulus of 5 MPa at a temperature of from 85 ° C to 100 ° C. 3. Связующая композиция на водорастворимой основе по п. 1, в которой полимер на водной основе выбирается из группы, включающей полимер полученный полимеризацией в эмульсии, выбранный из группы, включающей дисперсию сополимера этилена и винилацетата, поливинилацетат, сополимер винилацетата и винилового спирта, стабилизированный декстрином поливинилацетат, поливинилацетатные сополимеры, сополимеры винилацетата и этилена, винилакриловый, стиролакриловый, акриловый, стиролбутиловый каучук, полиуретан и их смеси.3. The water-soluble based binder composition according to claim 1, wherein the water-based polymer is selected from the group consisting of an emulsion polymerized polymer selected from the group consisting of a dispersion of a copolymer of ethylene and vinyl acetate, polyvinyl acetate, a dextrin stabilized vinyl acetate-vinyl alcohol copolymer polyvinyl acetate, polyvinyl acetate copolymers, copolymers of vinyl acetate and ethylene, vinyl acrylic, styrene acrylic, acrylic, styrene butyl rubber, polyurethane and mixtures thereof. 4. Связующая композиция на водорастворимой основе по п. 1, в которой расширяющиеся микросферы имеют углеводородную сердцевину и полиакрилонитрильную оболочку.4. The water-soluble binder composition according to claim 1, wherein the expanding microspheres have a hydrocarbon core and a polyacrylonitrile shell. 5. Связующая композиция на водорастворимой основе, по п. 1, в которой расширяющиеся микросферы начинают расширяться при температуре от приблизительно 80°C до приблизительно 100°C.5. The binder composition on a water-soluble basis, according to claim 1, in which the expanding microspheres begin to expand at a temperature of from about 80 ° C to about 100 ° C. 6. Связующая композиция на водорастворимой основе по п. 1, в которой расширяющиеся микросферы имеют максимальную температуру расширения от приблизительно 120°C до приблизительно 130°C.6. The water-soluble binder composition of claim 1, wherein the expandable microspheres have a maximum expansion temperature of from about 120 ° C to about 130 ° C. 7. Связующая композиция на водорастворимой основе по п. 1, в которой добавка выбирается из группы, включающей придающие клейкость вещества, пластификаторы, сшивающие вещества и их смеси.7. The binder composition on a water-soluble basis according to claim 1, in which the additive is selected from the group comprising tackifying substances, plasticizers, crosslinking agents and mixtures thereof. 8. Связующая композиция на водорастворимой основе по п. 7, в которой сшивающее вещество выбирается из группы, включающей нитрат алюминия, ацетат циркония, цирконилкарбонат аммония и их смеси.8. The water-soluble binder composition according to claim 7, wherein the crosslinking agent is selected from the group consisting of aluminum nitrate, zirconium acetate, ammonium zirconyl carbonate, and mixtures thereof. 9. Связующая композиция на водорастворимой основе по п. 1, дополнительно включающая сшивающее вещество, пеногаситель, консервант, поверхностно-активное вещество, реологический модификатор, наполнитель, пигмент, краситель, стабилизатор, поливиниловый спирт, увлажняющее вещество и их смеси.9. The binder composition on a water-soluble basis according to claim 1, further comprising a crosslinking agent, antifoam, preservative, surfactant, rheological modifier, filler, pigment, dye, stabilizer, polyvinyl alcohol, moisturizer and mixtures thereof. 10. Связующая композиция на водорастворимой основе по п. 1, где данная связующая композиция дополнительно включает ускоритель, который представляет собой водорастворимую соль многозарядного катиона.10. The binder composition on a water-soluble basis according to claim 1, where the binder composition further includes an accelerator, which is a water-soluble salt of a multiply charged cation. 11. Связующая композиция на водорастворимой основе по п. 10, в котором водорастворимая соль многозарядного катиона выбирается из группы, включающей нитрат алюминия, ацетат циркония, цирконилкарбонат аммония и их смеси.11. The water-soluble-based binder composition according to claim 10, wherein the water-soluble salt of the multiply charged cation is selected from the group consisting of aluminum nitrate, zirconium acetate, ammonium zirconyl carbonate, and mixtures thereof. 12. Способ получения изделия, включающий следующие стадии:12. The method of obtaining the product, comprising the following stages: (a) получение композиции, включающей:(a) obtaining a composition comprising: (1) полимер на водной основе, изготовленный посредством эмульсионной полимеризации, который имеет (i) модуль упругости более чем 0,5 МПа в температурном интервале от 70°C до 110°C; (ii) абсолютное значение тангенса угла наклона кривой log(E)/T менее чем 0,05 в температурном интервале от 70°C до 110°C; и (iii) значение тангенса дельта менее чем 0,6 при 90°C; и(1) a water-based polymer made by emulsion polymerization, which has (i) an elastic modulus of more than 0.5 MPa in the temperature range from 70 ° C to 110 ° C; (ii) the absolute value of the slope of the log (E) / T curve is less than 0.05 in the temperature range from 70 ° C to 110 ° C; and (iii) a tangent delta value of less than 0.6 at 90 ° C; and (2) множество расширяющихся микросфер;(2) many expanding microspheres; (b) нанесение композиции на подложку, которая представляет собой бумагу, картон или древесину;(b) applying the composition to a substrate, which is paper, cardboard or wood; (c) высушивание композиции до практически полного удаления воды; и(c) drying the composition until the water is almost completely removed; and (d) расширение композиции.(d) expanding the composition. 13. Способ по п. 12, в котором композиция наносится на трафарет.13. The method according to p. 12, in which the composition is applied to the stencil. 14. Способ по п. 13, в котором трафарет представляет собой ряд точек, полос, волн, клеток или многогранная форма, которая имеет практически плоское основание.14. The method according to p. 13, in which the stencil is a series of points, stripes, waves, cells or a multifaceted shape that has an almost flat base. 15. Способ по п. 12, в котором стадии (c) и (d) объединяются и осуществляются одновременно.15. The method according to p. 12, in which stage (c) and (d) are combined and carried out simultaneously. 16. Изделие, включающее целлюлозную подложку и композицию, включающую:16. An article comprising a cellulosic substrate and a composition comprising: (a) полимер на водной основе, изготовленный посредством эмульсионной полимеризации, который имеет (i) модуль упругости более чем 0,5 МПа в температурном интервале от 70°C до 110°C; (ii) абсолютное значение тангенса угла наклона кривой log(E)/T менее чем 0,05 в температурном интервале от 70°C до 110°C; и (iii) значение тангенса дельта менее чем 0,6 при 90°C; и(a) a water-based polymer made by emulsion polymerization, which has (i) an elastic modulus of more than 0.5 MPa in a temperature range from 70 ° C to 110 ° C; (ii) the absolute value of the slope of the log (E) / T curve is less than 0.05 in the temperature range from 70 ° C to 110 ° C; and (iii) a tangent delta value of less than 0.6 at 90 ° C; and (b) множество расширяющихся микросфер.(b) many expanding microspheres. 17. Изделие по п. 16, в котором полимер на водной основе выбирается из группы, включающей полимер, полученный полимеризацией в эмульсии, выбранный из группы, включающей дисперсию сополимера этилена и винилацетата, поливинилацетат, сополимер винилацетата и винилового спирта, стабилизированный декстрином поливинилацетат, поливинилацетатные сополимеры, сополимеры винилацетата и этилена, винилакриловый, стиролакриловый, акриловый, стиролбутиловый каучук, полиуретан и их смеси.17. The product of claim 16, wherein the water-based polymer is selected from the group comprising a polymer obtained by emulsion polymerization selected from the group comprising a dispersion of a copolymer of ethylene and vinyl acetate, polyvinyl acetate, a copolymer of vinyl acetate and vinyl alcohol, stabilized with dextrin polyvinyl acetate, polyvinyl acetate copolymers, copolymers of vinyl acetate and ethylene, vinyl acrylic, styrene acrylic, acrylic, styrene butyl rubber, polyurethane and mixtures thereof. 18. Изделие по п. 17, в котором целлюлозная подложка представляет собой древесноволокнистую плиту, гофрированный картон, твердый беленый картон, крафт-бумагу или мелованную бумагу.18. The product of claim 17, wherein the cellulosic substrate is a fiberboard, corrugated board, hard bleached board, kraft paper, or coated paper. 19. Изделие по п. 16, которое представляет собой многослойную подложку.19. The product according to p. 16, which is a multilayer substrate. 20. Многослойная подложка по п. 19, которая представляет собой стакан, пищевой контейнер, футляр, картонную упаковку, пакет, ящик, крышку, оболочку, обертку или ковш. 20. The multilayer substrate according to claim 19, which is a glass, food container, case, cardboard packaging, bag, box, lid, shell, wrapper or bucket.
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