RU2016116451A - METHOD FOR PRODUCING 6- [4-HYDROXY (THIO, CARBOXY) Phenyl] -1,11-DIOXA-4,8-DITIA-6-AZACYCLOTRIDECANES - Google Patents

METHOD FOR PRODUCING 6- [4-HYDROXY (THIO, CARBOXY) Phenyl] -1,11-DIOXA-4,8-DITIA-6-AZACYCLOTRIDECANES Download PDF

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RU2016116451A
RU2016116451A RU2016116451A RU2016116451A RU2016116451A RU 2016116451 A RU2016116451 A RU 2016116451A RU 2016116451 A RU2016116451 A RU 2016116451A RU 2016116451 A RU2016116451 A RU 2016116451A RU 2016116451 A RU2016116451 A RU 2016116451A
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dioxa
thio
carboxy
hydroxy
phenyl
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RU2016116451A
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RU2640211C2 (en
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Усеин Меметович Джемилев
Асхат Габдрахманович Ибрагимов
Елена Борисовна Рахимова
Инна Владимировна Васильева
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Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D291/00—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms
    • C07D291/02—Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms not condensed with other rings

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (3)

Способ получения 6-[4-гидрокси(тио,карбокси)фенил]-1,11-диокса-4,8-дитиа-6-азациклотридеканов общей формулы (1)The method of obtaining 6- [4-hydroxy (thio, carboxy) phenyl] -1,11-dioxa-4,8-dithia-6-azacyclotridecans of the general formula (1)
Figure 00000001
Figure 00000001
 отличающийся тем, что 4-аминофенол, или 4-аминотиофенол, или 4-аминобензойную кислоту подвергают взаимодействию с 1,6,9-триокса-3,12-дитиациклотридеканом в присутствии катализатора Sm(NO3)3·6H2O при мольном соотношении ароматический аминy:1,6,9-триокса-3,12-дитиациклотридекан:Sm(NO3)3·6H2O = 1:1:(0.03-0.07) при комнатной температуре (~20°C) в среде растворителей этанол-хлороформ (1:1, объемное соотношение) в течение 2.5-3.5 ч.characterized in that 4-aminophenol or 4-aminothiophenol or 4-aminobenzoic acid is reacted with 1,6,9-trioxa-3,12-dithiacyclotridecane in the presence of a Sm (NO 3 ) 3 · 6H 2 O catalyst in a molar ratio aromatic amine: 1,6,9-trioxa-3,12-dithiacyclotridecane: Sm (NO 3 ) 3 · 6H 2 O = 1: 1: (0.03-0.07) at room temperature (~ 20 ° C) in ethanol solvent -chloroform (1: 1, volume ratio) for 2.5-3.5 hours
RU2016116451A 2016-04-26 2016-04-26 Method of producing 6-[4-hydroxy(thio,carboxy)phenyl]-1,11-dioxa-4,8-dithia-6-azacyclotridecanes RU2640211C2 (en)

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RU2565786C1 (en) * 2014-05-30 2015-10-20 Федеральное государственное бюджетное учреждение науки Институт нефтехимии и катализа Российской академии наук METHOD OF OBTAINING 6-(m,n-HALOGENPHENYL)-1,11-DIOXA-4,8-DITHIA-6-AZACYCLOTRIDECANES

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