RU2014149582A - Washing composition - Google Patents

Washing composition Download PDF

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RU2014149582A
RU2014149582A RU2014149582A RU2014149582A RU2014149582A RU 2014149582 A RU2014149582 A RU 2014149582A RU 2014149582 A RU2014149582 A RU 2014149582A RU 2014149582 A RU2014149582 A RU 2014149582A RU 2014149582 A RU2014149582 A RU 2014149582A
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detergent composition
composition according
mixtures
group
detergent
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RU2014149582A
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RU2612142C2 (en
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Стивен Джордж ПАТТЕРСОН
Филип Франк СОУТЕР
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Дзе Проктер Энд Гэмбл Компани
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246Silicates, e.g. diatomaceous earth
    • C11D3/1253Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
    • C11D3/126Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38672Granulated or coated enzymes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/06Phosphates, including polyphosphates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/386Preparations containing enzymes, e.g. protease or amylase
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395Bleaching agents

Abstract

1. Моющий состав, содержащий:(a) полиферментную согранулу, содержащую от 10 до 98 мас. % поглощающего влагу компонента;(b) менее чем 10 мас. % цеолита (в расчете на безводное вещество);(c) менее чем 10 мас. % фосфатной соли (в расчете на безводное вещество), при этом указанная ферментная согранула содержит от 10 до 98 мас. % поглощающего влагу компонента;(d) и состав дополнительно содержит от 20 до 80 мас. % моющего поглощающего влагу компонента.2. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит (а) один или более ферментов, выбранных из группы, состоящей из липаз первого цикла стирки, чистящих целлюлаз, ксилоглюканаз, пергидролаз, пероксидаз, липоксигеназ, лакказ и их смесей; и (b) один или более ферментов, выбранных из группы, состоящей из гемицеллюлаз, протеаз, целлюлаз для ухода, целлобиозодегидрогеназ, ксиланаз, фосфолипаз, эстераз, кутиназ, пектиназ, маннаназ, пектатлиаз, кератиназ, редуктаз, оксидаз, фенолоксидаз, лигниназ, пуллуланаз, танназ, пентозаназ, лихеназ глюканаз, арабинозидаз, гиалуронидазы, хондроитиназы, амилаз и их смесей.3. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит протеазный фермент.4. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит липазу.5. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит липазу и протеазу в массовом соотношении от 2:5 до 1:1.6. Моющий состав по п. 1, отличающийся тем, что моющий поглощающий влагу компонент содержит сульфат натрия.7. Моющий состав по п. 1, содержащий моющий поглощающий влагу компонент в количестве, по меньшей мере, 25 мас. %.8. Моющий состав по п. 1, отличающийся тем, что поглощающий влагу компонент и общий активный фермент присутствуют в полифермен1. A detergent composition containing: (a) a multi-enzyme co-granule containing from 10 to 98 wt. % moisture absorbing component; (b) less than 10 wt. % zeolite (calculated on an anhydrous substance); (c) less than 10 wt. % phosphate salt (calculated on an anhydrous substance), while the specified enzyme co-granule contains from 10 to 98 wt. % moisture absorbing component; (d) and the composition further comprises from 20 to 80 wt. % detergent absorbing moisture. 2. A detergent composition according to claim 1, characterized in that the polyenzyme co-granule contains (a) one or more enzymes selected from the group consisting of lipases of the first washing cycle, cleaning cellulases, xyloglucanases, perhydrolases, peroxidases, lipoxygenases, laccase and mixtures thereof; and (b) one or more enzymes selected from the group consisting of hemicellulases, proteases, cellulases for care, cellobiose dehydrogenases, xylanases, phospholipases, esterases, cutinases, pectinases, mannanases, pectatliases, keratinases, reductases, oxidases, phenol oxidases, , tannase, pentosanase, lichenase glucanases, arabinosidases, hyaluronidases, chondroitinases, amylases and mixtures thereof. 3. A detergent composition according to claim 1, characterized in that the polyenzymatic co-granule contains a protease enzyme. A detergent composition according to claim 1, characterized in that the polyenzymatic co-granule contains lipase. A detergent composition according to claim 1, characterized in that the polyenzymatic co-granule contains lipase and protease in a mass ratio of from 2: 5 to 1: 1.6. A detergent composition according to claim 1, characterized in that the detergent absorbing moisture contains sodium sulfate. A detergent composition according to claim 1, comprising a detergent absorbing moisture in an amount of at least 25 wt. %.8. A detergent composition according to claim 1, characterized in that the moisture absorbing component and the common active enzyme are present in the polyferman

Claims (15)

1. Моющий состав, содержащий:1. A detergent composition containing: (a) полиферментную согранулу, содержащую от 10 до 98 мас. % поглощающего влагу компонента;(a) a polyenzymatic co-granule containing from 10 to 98 wt. % moisture absorbing component; (b) менее чем 10 мас. % цеолита (в расчете на безводное вещество);(b) less than 10 wt. % zeolite (calculated on anhydrous substance); (c) менее чем 10 мас. % фосфатной соли (в расчете на безводное вещество), при этом указанная ферментная согранула содержит от 10 до 98 мас. % поглощающего влагу компонента;(c) less than 10 wt. % phosphate salt (calculated on an anhydrous substance), while the specified enzyme co-granule contains from 10 to 98 wt. % moisture absorbing component; (d) и состав дополнительно содержит от 20 до 80 мас. % моющего поглощающего влагу компонента.(d) and the composition further comprises from 20 to 80 wt. % detergent absorbing moisture. 2. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит (а) один или более ферментов, выбранных из группы, состоящей из липаз первого цикла стирки, чистящих целлюлаз, ксилоглюканаз, пергидролаз, пероксидаз, липоксигеназ, лакказ и их смесей; и (b) один или более ферментов, выбранных из группы, состоящей из гемицеллюлаз, протеаз, целлюлаз для ухода, целлобиозодегидрогеназ, ксиланаз, фосфолипаз, эстераз, кутиназ, пектиназ, маннаназ, пектатлиаз, кератиназ, редуктаз, оксидаз, фенолоксидаз, лигниназ, пуллуланаз, танназ, пентозаназ, лихеназ глюканаз, арабинозидаз, гиалуронидазы, хондроитиназы, амилаз и их смесей.2. The detergent composition according to claim 1, characterized in that the polyenzyme co-granule contains (a) one or more enzymes selected from the group consisting of lipases of the first washing cycle, cleaning cellulases, xyloglucanases, perhydrolases, peroxidases, lipoxygenases, laccase and mixtures thereof ; and (b) one or more enzymes selected from the group consisting of hemicellulases, proteases, cellulases for care, cellobiose dehydrogenases, xylanases, phospholipases, esterases, cutinases, pectinases, mannanases, pectatliases, keratinases, reductases, oxidases, phenol oxidases, , tannase, pentosanase, lichenase glucanases, arabinosidases, hyaluronidases, chondroitinases, amylases and mixtures thereof. 3. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит протеазный фермент.3. The detergent composition according to claim 1, characterized in that the polyenzymatic co-granule contains a protease enzyme. 4. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит липазу.4. The detergent composition according to claim 1, characterized in that the polyenzymatic co-granule contains a lipase. 5. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит липазу и протеазу в массовом соотношении от 2:5 до 1:1.5. The detergent composition according to claim 1, characterized in that the polyenzymatic co-granule contains lipase and protease in a mass ratio of from 2: 5 to 1: 1. 6. Моющий состав по п. 1, отличающийся тем, что моющий поглощающий влагу компонент содержит сульфат натрия.6. The detergent composition according to claim 1, characterized in that the moisture-absorbing detergent component contains sodium sulfate. 7. Моющий состав по п. 1, содержащий моющий поглощающий влагу компонент в количестве, по меньшей мере, 25 мас. %.7. The detergent composition according to claim 1, containing a detergent absorbing moisture in an amount of at least 25 wt. % 8. Моющий состав по п. 1, отличающийся тем, что поглощающий влагу компонент и общий активный фермент присутствуют в полиферментной согрануле в массовом соотношении от 4:1 до 40:1.8. The detergent composition according to claim 1, characterized in that the moisture absorbing component and the common active enzyme are present in the polyenzyme co-granule in a mass ratio of 4: 1 to 40: 1. 9. Моющий состав по п. 1, отличающийся тем, что полиферментная согранула содержит покрытие, выбранное из группы, включающей диоксид титана, поливиниловый спирт, гидроксипропилметилцеллюлозу, метилцеллюлозу, поликарбоксилаты, каолин, полиэтиленгликоли и их смеси.9. The detergent composition according to claim 1, characterized in that the polyenzymatic co-granule contains a coating selected from the group consisting of titanium dioxide, polyvinyl alcohol, hydroxypropyl methyl cellulose, methyl cellulose, polycarboxylates, kaolin, polyethylene glycols and mixtures thereof. 10. Моющий состав по п. 1, отличающийся тем, что поглощающий влагу компонент выбран из группы, состоящей из: безводного карбоната натрия, осушенной глины, безводного сульфата натрия; безводного хлорида натрия; бионаполнителя, содержащего от 0 до 10% свободной влаги, и их смесей.10. The detergent composition according to claim 1, characterized in that the moisture absorbing component is selected from the group consisting of: anhydrous sodium carbonate, dried clay, anhydrous sodium sulfate; anhydrous sodium chloride; bio-filler containing from 0 to 10% free moisture, and mixtures thereof. 11. Моющий состав по п. 1, отличающийся тем, что дополнительно содержит агент, ингибирующий перенос красителя.11. A detergent composition according to claim 1, characterized in that it further comprises an agent that inhibits dye transfer. 12. Моющий состав по п. 1, отличающийся тем, что дополнительно содержит оттеночный краситель для ткани, выбранный из растворителя, красителей, дисперсных красителей, кислотных красителей и прямых красителей, или их смесей и/или пигмента или их смесей.12. The detergent composition according to claim 1, characterized in that it further comprises a hue dye for the fabric selected from a solvent, dyes, dispersed dyes, acid dyes and direct dyes, or mixtures thereof and / or pigment or mixtures thereof. 13. Моющий состав по п. 1, отличающийся тем, что содержит одно или более из следующих вспомогательных веществ:13. A detergent composition according to claim 1, characterized in that it contains one or more of the following excipients: (a) инкапсулят, содержащий отдушку;(a) an encapsulate containing fragrance; (b) систему поверхностно-активных веществ, содержащую анионное поверхностно-активное вещество и неионное поверхностно-активное вещество в массовом соотношении от 20:1 до 1:10;(b) a surfactant system comprising an anionic surfactant and a nonionic surfactant in a weight ratio of from 20: 1 to 1:10; (c) силикатную соль, выбранную из группы, состоящей из силиката натрия, силиката калия и их смесей;(c) a silicate salt selected from the group consisting of sodium silicate, potassium silicate and mixtures thereof; (d) карбоксилатный полимер, выбранный из группы, состоящей из малеатного/акрилатного статистического сополимера или полиакрилатного гомополимера и их смесей;(d) a carboxylate polymer selected from the group consisting of a maleate / acrylate random copolymer or polyacrylate homopolymer and mixtures thereof; (e) грязеотталкивающий полимер, выбранный из группы, состоящей из терефталатных сополимеров и их смесей;(e) a dirt-repellent polymer selected from the group consisting of terephthalate copolymers and mixtures thereof; (f) целлюлозный полимер, выбранный из группы, состоящей из алкилцеллюлозы, алкилалкоксиалкилцеллюлозы, карбоксиалкилцеллюлозы, алкилкарбоксиалкилцеллюлозы и их смесей;(f) a cellulosic polymer selected from the group consisting of alkyl cellulose, alkyl alkoxyalkyl cellulose, carboxyalkyl cellulose, alkyl carboxyalkyl cellulose and mixtures thereof; (g) хелатирующий агент, выбранный из группы, состоящей из DTPA (диэтилентриаминпентауксусной кислоты), HEDP (гидроксиэтандифосфоновой кислоты), DTPMP (диэтилентриаминпента(метиленфосфоновой кислоты)), этилендиаминдиянтарной кислоты (EDDS), гидрата динатриевой соли 1,2-дигидроксибензол-3,5-дисульфоновой кислоты, производных указанных хелатирующих агентов; и(g) a chelating agent selected from the group consisting of DTPA (diethylene triamine pentaacetic acid), HEDP (hydroxyethane diphosphonic acid), DTPMP (diethylene triamine penta (methylene phosphonic acid), ethylene diamindi succinic acid (EDDS), 1,2-disodium dihydroxy disodium salt 5-disulfonic acid, derivatives of these chelating agents; and (h) их смеси.(h) mixtures thereof. 14. Моющий состав по п. 1, отличающийся тем, что дополнительно содержит от 5 мас. % до 35 мас. % перкарбоната натрия.14. The detergent composition according to claim 1, characterized in that it further comprises from 5 wt. % up to 35 wt. % sodium percarbonate. 15. Моющий состав по п. 1, отличающийся тем, что дополнительно содержит одну или более отбеливающих частиц, выбранных из группы, состоящей из:15. The detergent composition according to claim 1, characterized in that it further comprises one or more whitening particles selected from the group consisting of: (a) катализатора отбеливания, предпочтительно включающего вещество, выбранное из группы, состоящей из: иминных катионов, иминных полиионов; иминных цвитерионов; модифицированных аминов; модифицированных аминоксидов; N-сульфонилиминов; N-фосфонилиминов; N-ацилиминов; тиадиазольных диоксидов; перфториминов; циклических сахарных кетонов и катализаторов на основе переходного металла или лигандов для их образования, или их смесей;(a) a whitening catalyst, preferably comprising a substance selected from the group consisting of: imine cations, imine polyion; imine zwitterions; modified amines; modified amine oxides; N-sulfonylimines; N-phosphonylimines; N-acylimines; thiadiazole dioxides; perfluorimines; cyclic sugar ketones and transition metal catalysts or ligands for their formation, or mixtures thereof; (b) активатора отбеливания, предпочтительно включающего вещество, выбранное из группы, состоящей из додеканоилоксибензолсульфоната, деканоилоксибензолсульфоната, деканоилоксибензойной кислоты или ее солей, 3,5,5-триметилгексаноилоксибензолсульфоната, тетраацетилэтилендиамина (TAED), нонаноилоксибензолсульфоната (NOBS) и их смесей;(b) a whitening activator, preferably comprising a substance selected from the group consisting of dodecanoyloxybenzenesulfonate, decanoyloxybenzenesulfonate, decanoyloxybenzoic acid or its salts, 3,5,5-trimethylhexanoyloxybenzenesulfonate, tetraacetylethylenediamine (TAED) and n-mixture of (OBED) nobenone; (c) катализатора на основе металла;(c) a metal based catalyst; (d) фотоотбеливателя, предпочтительно цинковых и/или алюминиевых фталоцианиновых соединений, пищевого красного, эритрозина и/или бенгальского розового; и(d) a photobleach, preferably zinc and / or aluminum phthalocyanine compounds, food red, erythrosine and / or Bengal pink; and (e) их смесей. (e) mixtures thereof.
RU2014149582A 2012-06-11 2013-06-11 Detergent composition RU2612142C2 (en)

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EP12171551.0A EP2674475A1 (en) 2012-06-11 2012-06-11 Detergent composition
EP12171551.0 2012-06-11
PCT/US2013/045070 WO2013188331A1 (en) 2012-06-11 2013-06-11 Detergent composition

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RU2014149582A true RU2014149582A (en) 2016-07-10
RU2612142C2 RU2612142C2 (en) 2017-03-02

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