RU2012105418A - Способ изготовления стержня и его применение - Google Patents

Способ изготовления стержня и его применение Download PDF

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RU2012105418A
RU2012105418A RU2012105418/04A RU2012105418A RU2012105418A RU 2012105418 A RU2012105418 A RU 2012105418A RU 2012105418/04 A RU2012105418/04 A RU 2012105418/04A RU 2012105418 A RU2012105418 A RU 2012105418A RU 2012105418 A RU2012105418 A RU 2012105418A
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synthetic material
rod
molding
profile
extruded
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RU2012105418/04A
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RU2598851C2 (ru
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Райнер Геринг
Маркус ХАРТМАНН
Карл КУХМАНН
Бернфрид КАЛЬТХОФ
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Эвоник Дегусса Гмбх
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/34Auxiliary operations
    • B29C44/60Measuring, controlling or regulating
    • B29C44/605Calibration following a shaping operation, e.g. extrusion
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C69/00Combinations of shaping techniques not provided for in a single one of main groups B29C39/00 - B29C67/00, e.g. associations of moulding and joining techniques; Apparatus therefore
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61BDIAGNOSIS; SURGERY; IDENTIFICATION
    • A61B17/00Surgical instruments, devices or methods, e.g. tourniquets
    • A61B17/56Surgical instruments or methods for treatment of bones or joints; Devices specially adapted therefor
    • A61B17/58Surgical instruments or methods for treatment of bones or joints; Devices specially adapted therefor for osteosynthesis, e.g. bone plates, screws, setting implements or the like
    • A61B17/68Internal fixation devices, including fasteners and spinal fixators, even if a part thereof projects from the skin
    • A61B17/84Fasteners therefor or fasteners being internal fixation devices
    • A61B17/86Pins or screws or threaded wires; nuts therefor
    • A61B17/866Material or manufacture
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/20Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of indefinite length
    • B29C44/32Incorporating or moulding on preformed parts, e.g. linings, inserts or reinforcements
    • B29C44/322Incorporating or moulding on preformed parts, e.g. linings, inserts or reinforcements the preformed parts being elongated inserts, e.g. cables
    • B29C44/324Incorporating or moulding on preformed parts, e.g. linings, inserts or reinforcements the preformed parts being elongated inserts, e.g. cables the preformed parts being tubular or folded to a tubular shape
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/022Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/06Rod-shaped
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    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F2/00Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
    • A61F2/02Prostheses implantable into the body
    • A61F2/30Joints
    • A61F2002/30001Additional features of subject-matter classified in A61F2/28, A61F2/30 and subgroups thereof
    • A61F2002/30003Material related properties of the prosthesis or of a coating on the prosthesis
    • A61F2002/30004Material related properties of the prosthesis or of a coating on the prosthesis the prosthesis being made from materials having different values of a given property at different locations within the same prosthesis
    • A61F2002/30011Material related properties of the prosthesis or of a coating on the prosthesis the prosthesis being made from materials having different values of a given property at different locations within the same prosthesis differing in porosity
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F2/00Filters implantable into blood vessels; Prostheses, i.e. artificial substitutes or replacements for parts of the body; Appliances for connecting them with the body; Devices providing patency to, or preventing collapsing of, tubular structures of the body, e.g. stents
    • A61F2/02Prostheses implantable into the body
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    • A61F2/30767Special external or bone-contacting surface, e.g. coating for improving bone ingrowth
    • A61F2002/3092Special external or bone-contacting surface, e.g. coating for improving bone ingrowth having an open-celled or open-pored structure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
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    • B29C48/151Coating hollow articles
    • B29C48/152Coating hollow articles the inner surfaces thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
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    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
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    • B29C48/907Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article using adjustable calibrators, e.g. the dimensions of the calibrator being changeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
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    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/90Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article
    • B29C48/908Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article characterised by calibrator surface, e.g. structure or holes for lubrication, cooling or venting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
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    • B29C48/911Cooling
    • B29C48/9115Cooling of hollow articles
    • B29C48/912Cooling of hollow articles of tubular films
    • B29C48/913Cooling of hollow articles of tubular films externally
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/88Thermal treatment of the stream of extruded material, e.g. cooling
    • B29C48/911Cooling
    • B29C48/9135Cooling of flat articles, e.g. using specially adapted supporting means
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2071/00Use of polyethers, e.g. PEEK, i.e. polyether-etherketone or PEK, i.e. polyetherketone or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/00Stock material or miscellaneous articles
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  • Molding Of Porous Articles (AREA)

Abstract

1. Способ изготовления стержня, при которомa) из первой формовочной массы из синтетического материала, которая образует самый внешний слой, и которая по меньшей мере на 50% масс. состоит из частично кристалличного термопласта, экструзией получают профиль из синтетического материала,b) внутри калибратора этот свежеэкструдированный профиль заполняется второй формовочной массой из синтетического материала, иc) образовавшийся новый стержень калибруют, отводят и охлаждают,отличающийся тем,что первая формовочная масса из синтетического материала имеет следующие характеристики:- температуру плавления кристаллитов Tв соответствии со стандартом ISO 11357 по меньшей мере 170°С,- температуру кристаллизации Tв соответствии со стандартомISO 11357 максимум на 70 K ниже T, и- энтальпию плавления ΔH в соответствии со стандартом ISO 11357 по меньшей мере 20 Дж/г.2. Способ по п.1,отличающийся тем,что стержень представляет собой круглый стержень.3. Способ по п.1 или 2,отличающийся тем,что термопласт первой формовочной массы из синтетического материала выбирается из группы, включающей полиамид, частично ароматический сложный полиэфир, фторполимер, полифениленсульфид и простой полиариленэфиркетон.4. Способ по п.1 или 2,отличающийся тем,что термопласт второй формовочной массы из синтетического материала выбирается из группы, включающей полиамид, частично ароматический сложный полиэфир, фторполимер, полифениленсульфид и простой полиариленэфиркетон, прозрачный полиамид, полипропилен, полиэтилентерефталат, поликарбонат, полностью ароматический сложный полиэфир, сложный полиэфиркарбонат, полисульфон, простой полиэфирсульфон, полифенилсульфон, �

Claims (13)

1. Способ изготовления стержня, при котором
a) из первой формовочной массы из синтетического материала, которая образует самый внешний слой, и которая по меньшей мере на 50% масс. состоит из частично кристалличного термопласта, экструзией получают профиль из синтетического материала,
b) внутри калибратора этот свежеэкструдированный профиль заполняется второй формовочной массой из синтетического материала, и
c) образовавшийся новый стержень калибруют, отводят и охлаждают,
отличающийся тем,
что первая формовочная масса из синтетического материала имеет следующие характеристики:
- температуру плавления кристаллитов Tm в соответствии со стандартом ISO 11357 по меньшей мере 170°С,
- температуру кристаллизации Tk в соответствии со стандартом
ISO 11357 максимум на 70 K ниже Tm, и
- энтальпию плавления ΔH в соответствии со стандартом ISO 11357 по меньшей мере 20 Дж/г.
2. Способ по п.1,
отличающийся тем,
что стержень представляет собой круглый стержень.
3. Способ по п.1 или 2,
отличающийся тем,
что термопласт первой формовочной массы из синтетического материала выбирается из группы, включающей полиамид, частично ароматический сложный полиэфир, фторполимер, полифениленсульфид и простой полиариленэфиркетон.
4. Способ по п.1 или 2,
отличающийся тем,
что термопласт второй формовочной массы из синтетического материала выбирается из группы, включающей полиамид, частично ароматический сложный полиэфир, фторполимер, полифениленсульфид и простой полиариленэфиркетон, прозрачный полиамид, полипропилен, полиэтилентерефталат, поликарбонат, полностью ароматический сложный полиэфир, сложный полиэфиркарбонат, полисульфон, простой полиэфирсульфон, полифенилсульфон, простой полифениленовый эфир, простой полиэфиримид, полиимид и смеси из простого полиариленэфиркетона с полисульфоном, простым полиэфирсульфоном, полифенилсульфоном, простым полиэфиримидом и/или полиимидом.
5. Способ по п.1 или 2,
отличающийся тем,
что первая и вторая формовочные массы из синтетического материала являются идентичными.
6. Способ по п.1 или 2,
отличающийся тем,
что профиль из синтетического материала, экструдированный на стадии а), является вспененным.
7. Способ по п. 1 или 2,
отличающийся тем,
что вторая формовочная масса из синтетического материала, вводимая на стадии b), является вспененной.
8. Способ по п.1 или 2,
отличающийся тем,
что профиль из синтетического материала, экструдированный на стадии а), является многослойным, причем самый внутренний слой состоит из усилителя сцепления.
9. Способ по п.1 или 2,
отличающийся тем,
что диаметр или соответственно наименьший поперечный размер стержня лежит в интервале от 15 до 500 мм.
10. Способ по п.1 или 2,
отличающийся тем,
что толщина стенки профиля из синтетического материала, экструдированного на стадии а), лежит в области от 0,4 до 20% от диаметра или соответственно наименьшего поперечного размера.
11. Применение стержня, полученного согласно одному из пп.1-10, для изготовления готовых деталей резкой.
12. Применение по п.11,
отличающееся тем,
что стержень состоит из одной или нескольких формовочных масс из простого полиэфирэфиркетона, а готовая деталь представляет собой имплантат.
13. Применение стержня, полученного по одному из пп.1-10, для изготовления имплантата, который включает невспененную сердцевину и вспененный внешний слой с открытыми порами со среднечисленным размером пор от 1 до 700 мкм.
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