RU2012103327A - Полиметаллический катализатор с сильным межметаллическим взаимодействием - Google Patents
Полиметаллический катализатор с сильным межметаллическим взаимодействием Download PDFInfo
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- RU2012103327A RU2012103327A RU2012103327/05A RU2012103327A RU2012103327A RU 2012103327 A RU2012103327 A RU 2012103327A RU 2012103327/05 A RU2012103327/05 A RU 2012103327/05A RU 2012103327 A RU2012103327 A RU 2012103327A RU 2012103327 A RU2012103327 A RU 2012103327A
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- Prior art keywords
- catalyst according
- catalyst
- halogen
- containing compound
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- 239000003054 catalyst Substances 0.000 title claims abstract 23
- 230000003993 interaction Effects 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims abstract 8
- 229910052736 halogen Inorganic materials 0.000 claims abstract 8
- 150000002367 halogens Chemical class 0.000 claims abstract 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract 6
- 229910052801 chlorine Inorganic materials 0.000 claims abstract 6
- 239000000460 chlorine Substances 0.000 claims abstract 6
- 229910052751 metal Inorganic materials 0.000 claims abstract 6
- 239000002184 metal Substances 0.000 claims abstract 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims abstract 4
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims abstract 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims abstract 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052787 antimony Inorganic materials 0.000 claims abstract 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052785 arsenic Inorganic materials 0.000 claims abstract 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052797 bismuth Inorganic materials 0.000 claims abstract 2
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052794 bromium Inorganic materials 0.000 claims abstract 2
- 229910052731 fluorine Inorganic materials 0.000 claims abstract 2
- 239000011737 fluorine Substances 0.000 claims abstract 2
- 229910052733 gallium Inorganic materials 0.000 claims abstract 2
- 229910052738 indium Inorganic materials 0.000 claims abstract 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052740 iodine Inorganic materials 0.000 claims abstract 2
- 239000011630 iodine Substances 0.000 claims abstract 2
- 239000011777 magnesium Substances 0.000 claims abstract 2
- 229910052749 magnesium Inorganic materials 0.000 claims abstract 2
- 229910052763 palladium Chemical group 0.000 claims abstract 2
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract 2
- 239000011574 phosphorus Substances 0.000 claims abstract 2
- 229910052697 platinum Inorganic materials 0.000 claims abstract 2
- 229910052710 silicon Inorganic materials 0.000 claims abstract 2
- 239000010703 silicon Substances 0.000 claims abstract 2
- 239000000126 substance Substances 0.000 claims abstract 2
- 239000000758 substrate Substances 0.000 claims abstract 2
- 229910052716 thallium Inorganic materials 0.000 claims abstract 2
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052719 titanium Inorganic materials 0.000 claims abstract 2
- 239000010936 titanium Substances 0.000 claims abstract 2
- 229910052726 zirconium Inorganic materials 0.000 claims abstract 2
- 238000003984 119Sn Moessbauer spectroscopy Methods 0.000 claims 1
- 238000004813 Moessbauer spectroscopy Methods 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
- B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
- B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
- B01J37/24—Chlorinating
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/644—Arsenic, antimony or bismuth
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/644—Arsenic, antimony or bismuth
- B01J23/6445—Antimony
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
- B01J27/1856—Phosphorus; Compounds thereof with iron group metals or platinum group metals with platinum group metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0207—Pretreatment of the support
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/085—Catalytic reforming characterised by the catalyst used containing platinum group metals or compounds thereof
- C10G35/09—Bimetallic catalysts in which at least one of the metals is a platinum group metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/28—Phosphorising
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
1. Катализатор, содержащий по меньшей мере один металл M группы платины, олово, фосфорный промотор, галогенсодержащее соединение, пористую подложку и по меньшей мере один промотор X1, выбранный из группы, состоящей из галлия, индия, таллия, мышьяка, сурьмы и висмута, причем указанный катализатор в восстановленной форме демонстрирует, согласно мессбауэровской спектроскопииSn, сигнал, имеющий величину квадрупольного расщепления от 0 до 0,45 мм/с и химический сдвиг IS от 1,5 до 2,4 мм/с относительно CaSnO, причем площадь указанного сигнала составляет от 1% до 30% общей площади сигналов.2. Катализатор по п.1, в котором атомное отношение Sn/M составляет от 0,5 до 4,0.3. Катализатор по п.1, в котором отношение X1/M составляет от 0,1 до 5,0.4. Катализатор по п.1, в котором отношение P/M составляет от 0,2 до 30,0.5. Катализатор по одному из пп.1-4, в котором содержание металла M составляет от 0,01 до 5 вес.%.6. Катализатор по п.5, в котором металл M является платиной или палладием.7. Катализатор по п.1, в котором галогенсодержащее соединение выбрано из группы, состоящей из фтора, хлора, брома и йода.8. Катализатор по п.7, в котором содержание галогенсодержащего соединения составляет от 0,1 до 15,0 вес.%.9. Катализатор по п.8, в котором галогенсодержащее соединение является хлором, и содержание хлора составляет от 0,1 до 5,0 вес.%.10. Катализатор по п.1, в котором подложка содержит по меньшей мере один оксид, выбранный из группы, состоящей из оксидов магния, титана, циркония, алюминия, кремния.
Claims (10)
1. Катализатор, содержащий по меньшей мере один металл M группы платины, олово, фосфорный промотор, галогенсодержащее соединение, пористую подложку и по меньшей мере один промотор X1, выбранный из группы, состоящей из галлия, индия, таллия, мышьяка, сурьмы и висмута, причем указанный катализатор в восстановленной форме демонстрирует, согласно мессбауэровской спектроскопии 119Sn, сигнал, имеющий величину квадрупольного расщепления от 0 до 0,45 мм/с и химический сдвиг IS от 1,5 до 2,4 мм/с относительно CaSnO3, причем площадь указанного сигнала составляет от 1% до 30% общей площади сигналов.
2. Катализатор по п.1, в котором атомное отношение Sn/M составляет от 0,5 до 4,0.
3. Катализатор по п.1, в котором отношение X1/M составляет от 0,1 до 5,0.
4. Катализатор по п.1, в котором отношение P/M составляет от 0,2 до 30,0.
5. Катализатор по одному из пп.1-4, в котором содержание металла M составляет от 0,01 до 5 вес.%.
6. Катализатор по п.5, в котором металл M является платиной или палладием.
7. Катализатор по п.1, в котором галогенсодержащее соединение выбрано из группы, состоящей из фтора, хлора, брома и йода.
8. Катализатор по п.7, в котором содержание галогенсодержащего соединения составляет от 0,1 до 15,0 вес.%.
9. Катализатор по п.8, в котором галогенсодержащее соединение является хлором, и содержание хлора составляет от 0,1 до 5,0 вес.%.
10. Катализатор по п.1, в котором подложка содержит по меньшей мере один оксид, выбранный из группы, состоящей из оксидов магния, титана, циркония, алюминия, кремния.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0903225A FR2947464B1 (fr) | 2009-07-01 | 2009-07-01 | Catalyseur multi-metallique presentant une forte interaction metallique |
| FR0903225 | 2009-07-01 | ||
| PCT/FR2010/000444 WO2011001042A2 (fr) | 2009-07-01 | 2010-06-15 | Catalyseur multi-metallique presentant une forte interaction metallique |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2012103327A true RU2012103327A (ru) | 2013-08-10 |
| RU2533586C2 RU2533586C2 (ru) | 2014-11-20 |
Family
ID=41467018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2012103327/04A RU2533586C2 (ru) | 2009-07-01 | 2010-06-15 | Полиметаллический катализатор с сильным межметаллическим взаимодействием |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20120122665A1 (ru) |
| EP (1) | EP2448671B1 (ru) |
| JP (1) | JP5599881B2 (ru) |
| CN (2) | CN107020084A (ru) |
| DK (1) | DK2448671T3 (ru) |
| FR (1) | FR2947464B1 (ru) |
| RU (1) | RU2533586C2 (ru) |
| WO (1) | WO2011001042A2 (ru) |
| ZA (1) | ZA201109267B (ru) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR3039082B1 (fr) | 2015-07-24 | 2017-07-21 | Ifp Energies Now | Catalyseur multi-metallique dope par du phosphore et un lanthanide |
| FR3074062B1 (fr) | 2017-11-30 | 2020-06-26 | IFP Energies Nouvelles | Catalyseur multi-metallique dope par du phosphore et de l'yttrium |
| FR3074063B1 (fr) * | 2017-11-30 | 2019-11-01 | IFP Energies Nouvelles | Catalyseur multi-metallique dope par du phosphore et de l'ytterbium |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2814599A (en) | 1953-04-17 | 1957-11-26 | Kellogg M W Co | Group iii metal compound promoted platinum or palladium catalyst |
| US2890167A (en) | 1953-11-16 | 1959-06-09 | Universal Oil Prod Co | Conversion process using a phosphoruscontaining platinum group metal catalyst |
| US3706815A (en) | 1971-05-24 | 1972-12-19 | Union Oil Co | Chelated metal-polyphosphoric acid catalysts,method of preparation and isomerization process utilizing the same |
| US4367137A (en) | 1980-12-04 | 1983-01-04 | Uop Inc. | Hydrocarbon conversion with an acidic multimetallic catalytic composite |
| US4416804A (en) * | 1981-11-23 | 1983-11-22 | Uop Inc. | Acidic multimetallic catalytic composite |
| US4426279A (en) | 1981-11-23 | 1984-01-17 | Uop Inc. | Reforming hydrocarbons with a platinum group- and phosphorus-containing catalyst |
| US4463104A (en) | 1981-11-23 | 1984-07-31 | Uop Inc. | Platinum group and phosphorus containing catalyst composition for hydrocarbon conversion |
| US4522935A (en) * | 1983-06-02 | 1985-06-11 | Uop Inc. | Platinum and indium-containing catalyst for reforming hydrocarbons |
| ZA873090B (en) * | 1987-04-29 | 1987-12-30 | Uop Inc | Catalytic composition for the isomerization of paraffinic hydrocarbons |
| US5858908A (en) * | 1997-04-17 | 1999-01-12 | Uop Llc | Selective multimetallic-multigradient reforming catalyst |
| CN1655867A (zh) * | 2002-05-22 | 2005-08-17 | 国际壳牌研究有限公司 | 含铋和磷的重整催化剂、其制备方法和石脑油重整方法 |
| US6667270B2 (en) | 2002-05-22 | 2003-12-23 | Shell Oil Company | Bismuth-and phosphorus-containing catalyst support, reforming catalysts made from same, method of making and naphtha reforming process |
| FR2840548B1 (fr) | 2002-06-07 | 2005-03-18 | Inst Francais Du Petrole | Lit homogene de catalyseur et procede de transformation d'hydrocarbures en composes aromatiques avec ledit lit |
| US20070215523A1 (en) | 2002-12-10 | 2007-09-20 | Moser Mark D | Dilute phosphorus incorporation into a naphtha reforming catalyst |
| US20060102520A1 (en) * | 2004-11-12 | 2006-05-18 | Lapinski Mark P | Reforming process using high density catalyst |
| US7449423B2 (en) * | 2005-01-14 | 2008-11-11 | Headwaters Technology Innovation, Llc | Heat treatment of anchored nanocatalysts in a non-zero oxidation state and catalysts made by such method |
| FR2910347B1 (fr) * | 2006-12-22 | 2009-12-04 | Inst Francais Du Petrole | Catalyseur bimetallique ou multi-metallique presentant un indice de bimetallicite et une capacite d'adsorption d'hydrogene optimises |
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2009
- 2009-07-01 FR FR0903225A patent/FR2947464B1/fr active Active
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2010
- 2010-06-15 CN CN201710095799.0A patent/CN107020084A/zh active Pending
- 2010-06-15 US US13/381,394 patent/US20120122665A1/en not_active Abandoned
- 2010-06-15 EP EP10734171.1A patent/EP2448671B1/fr active Active
- 2010-06-15 JP JP2012518104A patent/JP5599881B2/ja active Active
- 2010-06-15 DK DK10734171.1T patent/DK2448671T3/en active
- 2010-06-15 CN CN2010800301193A patent/CN102470347A/zh active Pending
- 2010-06-15 WO PCT/FR2010/000444 patent/WO2011001042A2/fr active Application Filing
- 2010-06-15 RU RU2012103327/04A patent/RU2533586C2/ru active
-
2011
- 2011-12-15 ZA ZA2011/09267A patent/ZA201109267B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2533586C2 (ru) | 2014-11-20 |
| EP2448671A2 (fr) | 2012-05-09 |
| CN102470347A (zh) | 2012-05-23 |
| JP5599881B2 (ja) | 2014-10-01 |
| DK2448671T3 (en) | 2016-01-11 |
| CN107020084A (zh) | 2017-08-08 |
| FR2947464A1 (fr) | 2011-01-07 |
| US20120122665A1 (en) | 2012-05-17 |
| FR2947464B1 (fr) | 2011-07-22 |
| ZA201109267B (en) | 2012-08-29 |
| WO2011001042A2 (fr) | 2011-01-06 |
| JP2012531307A (ja) | 2012-12-10 |
| WO2011001042A3 (fr) | 2011-10-06 |
| EP2448671B1 (fr) | 2015-09-23 |
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