RU2010118455A - Добавки для непрерывности и их применение в процессах полимеризации - Google Patents
Добавки для непрерывности и их применение в процессах полимеризации Download PDFInfo
- Publication number
- RU2010118455A RU2010118455A RU2010118455/04A RU2010118455A RU2010118455A RU 2010118455 A RU2010118455 A RU 2010118455A RU 2010118455/04 A RU2010118455/04 A RU 2010118455/04A RU 2010118455 A RU2010118455 A RU 2010118455A RU 2010118455 A RU2010118455 A RU 2010118455A
- Authority
- RU
- Russia
- Prior art keywords
- compound
- group
- polyoxometallocarboxylate
- catalytic
- catalyst
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/002—Scale prevention in a polymerisation reactor or its auxiliary parts
- C08F2/005—Scale prevention in a polymerisation reactor or its auxiliary parts by addition of a scale inhibitor to the polymerisation medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/20—Complexes comprising metals of Group II (IIA or IIB) as the central metal
- B01J2531/22—Magnesium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
- B01J2531/31—Aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/46—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/49—Hafnium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/50—Complexes comprising metals of Group V (VA or VB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0212—Alkoxylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/122—Metal aryl or alkyl compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Abstract
1. Каталитическая композиция, включающая: ! по меньшей мере одно каталитическое соединение и ! по меньшей мере одно полиоксометаллокарбоксилатное соединение, которое отвечает формуле ! (MQO)n, ! в которой М обозначает металл из групп со 2 по 14; Q обозначает карбоксилатную группу, содержащую от 2 до 24 углеродных атомов; О обозначает кислород; а n обозначает целое число от 3 до 25. ! 2. Каталитическая композиция по п.1, в которой ! полиоксометаллокарбоксилатное соединение представляет собой соединение, дополнительно связанное с Q' и Q”, где Q' обозначает Q или любую группу R, где R обозначает гидрокарбильный радикал, а Q” обозначает Н, R или -C(O)-R, где R обозначает гидрокарбильный радикал. ! 3. Каталитическая композиция по п.1, в которой ! полиоксометаллокарбоксилатное соединение представляет собой полиоксоалюмостеарат. ! 4. Каталитическая композиция по одному из пп.1-3, в которой по меньшей мере одно каталитическое соединение выбирают из группы, включающей обычный катализатор, металлоценовый катализатор, содержащий элемент группы 15 катализатор и их сочетание. ! 5. Каталитическая композиция по одному из пп.1-3, дополнительно включающая активатор, который выбирают из группы, включающей кислоту Льюиса, неионизирующий активатор, ионизирующий активатор, нанесенный на носитель активатор, алкилалюминиевое соединение, алюмоксан и их сочетание. ! 6. Способ полимеризации олефинов, включающий: контактирование олефинов и полиоксометаллокарбоксилатного соединения в присутствии по меньшей мере одного каталитического соединения. ! 7. Способ по п.6, в котором полиоксометаллокарбоксилатное соединение отвечает формуле ! (MQO)n, ! в которой М обозна
Claims (17)
1. Каталитическая композиция, включающая:
по меньшей мере одно каталитическое соединение и
по меньшей мере одно полиоксометаллокарбоксилатное соединение, которое отвечает формуле
(MQO)n,
в которой М обозначает металл из групп со 2 по 14; Q обозначает карбоксилатную группу, содержащую от 2 до 24 углеродных атомов; О обозначает кислород; а n обозначает целое число от 3 до 25.
2. Каталитическая композиция по п.1, в которой
полиоксометаллокарбоксилатное соединение представляет собой соединение, дополнительно связанное с Q' и Q”, где Q' обозначает Q или любую группу R, где R обозначает гидрокарбильный радикал, а Q” обозначает Н, R или -C(O)-R, где R обозначает гидрокарбильный радикал.
3. Каталитическая композиция по п.1, в которой
полиоксометаллокарбоксилатное соединение представляет собой полиоксоалюмостеарат.
4. Каталитическая композиция по одному из пп.1-3, в которой по меньшей мере одно каталитическое соединение выбирают из группы, включающей обычный катализатор, металлоценовый катализатор, содержащий элемент группы 15 катализатор и их сочетание.
5. Каталитическая композиция по одному из пп.1-3, дополнительно включающая активатор, который выбирают из группы, включающей кислоту Льюиса, неионизирующий активатор, ионизирующий активатор, нанесенный на носитель активатор, алкилалюминиевое соединение, алюмоксан и их сочетание.
6. Способ полимеризации олефинов, включающий: контактирование олефинов и полиоксометаллокарбоксилатного соединения в присутствии по меньшей мере одного каталитического соединения.
7. Способ по п.6, в котором полиоксометаллокарбоксилатное соединение отвечает формуле
(MQO)n,
в которой М обозначает металл из групп со 2 по 14; Q обозначает карбоксилатную группу, содержащую от 2 до 24 углеродных атомов; О обозначает кислород; а n обозначает целое число от 3 до 25.
8. Способ по п.6, в котором полиоксометаллокарбоксилатное соединение представляет собой соединение, дополнительно связанное с Q' и Q”, где Q' обозначает Q или любую группу R, где R обозначает гидрокарбильный радикал, а Q” обозначает Н, R или -C(O)-R, где R обозначает гидрокарбильный радикал.
9. Способ по п.6, в котором полиоксометаллокарбоксилатное соединение представляет собой полиоксоалюмостеарат.
10. Способ по одному из пп.6-9, в котором каталитическая композиция включает катализатор, выбранный из группы, включающей катализаторы обычного типа с переходными металлами, металлоценовые катализаторы, содержащий элемент группы 15 катализатор и их сочетание.
11. Способ по одному из пп.6-9, в котором каталитическая композиция включает активатор, который выбирают из группы, включающей кислоту Льюиса, неионизирующий активатор, ионизирующий активатор, нанесенный на носитель активатор, алкилалюминиевое соединение и алюмоксан.
12. Способ по одному из пп.6-9, в котором олефины выбирают из группы, включающей этилен, пропилен, бутен, гексен и их сочетание.
13. Способ приготовления каталитической композиции, включающий следующие стадии:
обеспечение наличия по меньшей мере одного каталитического соединения;
контактирование каталитического соединения с полиоксометаллокарбоксилатным соединением с получением каталитической композиции.
14. Способ по п.13, в котором полиоксометаллокарбоксилатное соединение отвечает формуле
(MQO)n,
в которой М обозначает металл из групп со 2 по 14; Q обозначает карбоксилатную группу, содержащую от 2 до 24 углеродных атомов; О обозначает кислород; а n обозначает целое число от 3 до 25.
15. Способ по п.13, в котором полиоксометаллическое соединение представляет собой соединение, дополнительно связанное с Q' и Q”, из которых Q' обозначает Q или любую группу R, где R обозначает гидрокарбильный радикал, а Q” обозначает Н, R или -C(O)-R, где R обозначает гидрокарбильный радикал.
16. Способ по одному из пп.13-15, в котором по меньшей мере одно каталитическое соединение выбирают из группы, включающей обычный катализатор, металлоценовый катализатор, содержащий элемент группы 15 катализатор и их сочетание.
17. Способ по одному из пп.13-15, в котором полиоксометаллокарбоксилатное соединение уменьшает сплавление полимерных частиц в полимеризационном реакторе.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US99849707P | 2007-10-11 | 2007-10-11 | |
US60/998,497 | 2007-10-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
RU2010118455A true RU2010118455A (ru) | 2011-11-20 |
RU2454430C2 RU2454430C2 (ru) | 2012-06-27 |
Family
ID=40193494
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RU2010118455/04A RU2454430C2 (ru) | 2007-10-11 | 2008-10-09 | Добавки для непрерывности и их применение в процессах полимеризации |
Country Status (7)
Country | Link |
---|---|
US (1) | US8962510B2 (ru) |
EP (1) | EP2197920B1 (ru) |
CN (1) | CN101821296B (ru) |
BR (1) | BRPI0818563B1 (ru) |
ES (1) | ES2529433T3 (ru) |
RU (1) | RU2454430C2 (ru) |
WO (1) | WO2009048625A1 (ru) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9809656B2 (en) | 2013-12-09 | 2017-11-07 | Univation Technologies, Llc | Feeding polymerization additives to polymerization processes |
RU2677897C2 (ru) * | 2014-04-02 | 2019-01-22 | ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи | Композиции обеспечения непрерывности и способы изготовления и использования таковых |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1143799B (de) | 1956-08-15 | 1963-02-21 | Hardman & Holden Ltd | Verfahren zum Herstellen organischer Aluminiumverbindungen |
AU7031674A (en) | 1973-06-25 | 1976-01-08 | Ici Ltd | Novel compounds |
US4142991A (en) * | 1975-12-22 | 1979-03-06 | Stauffer Chemical Company | Substantially agglomeration-free catalyst component |
WO1982004271A1 (en) | 1981-06-03 | 1982-12-09 | Holbek Kjeld | A method for treating a fibrous material and a plant for carrying out the method |
TW218884B (ru) | 1991-05-01 | 1994-01-11 | Mitsubishi Kakoki Kk | |
ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
CA2127822A1 (en) | 1993-07-13 | 1995-01-14 | Yoshinori Morita | Process for gas phase polymerization of olefin |
US5648310A (en) | 1993-12-23 | 1997-07-15 | Union Carbide Chemicals & Plastics Technology Corporation | Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture |
US5770755A (en) | 1994-11-15 | 1998-06-23 | Phillips Petroleum Company | Process to prepare polymeric metallocenes |
US5565395A (en) * | 1995-05-26 | 1996-10-15 | Albemarle Corporation | Aluminoxanate compositions |
US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
US5688880A (en) | 1995-12-11 | 1997-11-18 | The Dow Chemical Company | Readily supportable metal complexes |
US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
ES2129323B1 (es) | 1996-04-18 | 2000-09-16 | Repsol Quimica Sa | Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas |
US6239235B1 (en) | 1997-07-15 | 2001-05-29 | Phillips Petroleum Company | High solids slurry polymerization |
US6322890B1 (en) * | 1998-03-30 | 2001-11-27 | Wm. Marsh Rice University | Supra-molecular alkylalumoxanes |
US7354880B2 (en) * | 1998-07-10 | 2008-04-08 | Univation Technologies, Llc | Catalyst composition and methods for its preparation and use in a polymerization process |
US6472903B1 (en) * | 1999-01-08 | 2002-10-29 | Altera Corporation | Programmable logic device input/output architecture with power bus segmentation for multiple I/O standards |
US6482903B1 (en) * | 1999-12-15 | 2002-11-19 | Univation Technologies, Llc | Method for preparing a supported catalyst system and its use in a polymerization process |
US6933258B2 (en) * | 2000-12-19 | 2005-08-23 | Univation Technologies, L.L.C. | Catalyst composition and methods for its preparation and use in a polymerization process |
EP1611169B1 (en) * | 2003-03-21 | 2010-06-02 | Dow Global Technologies Inc. | Morphology controlled olefin polymerization process |
-
2008
- 2008-10-09 ES ES08838441.7T patent/ES2529433T3/es active Active
- 2008-10-09 CN CN200880111155.5A patent/CN101821296B/zh active Active
- 2008-10-09 WO PCT/US2008/011687 patent/WO2009048625A1/en active Application Filing
- 2008-10-09 BR BRPI0818563-8A patent/BRPI0818563B1/pt active IP Right Grant
- 2008-10-09 EP EP08838441.7A patent/EP2197920B1/en active Active
- 2008-10-09 RU RU2010118455/04A patent/RU2454430C2/ru active
- 2008-10-09 US US12/682,148 patent/US8962510B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US8962510B2 (en) | 2015-02-24 |
US20110077370A1 (en) | 2011-03-31 |
BRPI0818563A8 (pt) | 2018-09-25 |
EP2197920B1 (en) | 2014-11-19 |
CN101821296B (zh) | 2015-12-02 |
RU2454430C2 (ru) | 2012-06-27 |
WO2009048625A1 (en) | 2009-04-16 |
EP2197920A1 (en) | 2010-06-23 |
CN101821296A (zh) | 2010-09-01 |
ES2529433T3 (es) | 2015-02-20 |
BRPI0818563A2 (pt) | 2015-04-22 |
BRPI0818563B1 (pt) | 2019-10-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
ATE400591T1 (de) | Polymerisationsverfahren | |
JP2019508227A5 (ru) | ||
HUP0004538A2 (hu) | Nikkel-diimin katalizátorok metil-alumoxán kokatalizátorral, eljárás ezen katalizátorokkal történő olefin polimerizációra és az előállított polimerek | |
WO2004099269A3 (en) | Process for polymerizing 1-butene | |
ATE355308T1 (de) | Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation | |
RU2008125137A (ru) | Каталитический способ олигомеризации олефиновых мономеров | |
RU2010153869A (ru) | Способ получения бимодальнего полиэтилена и изделий из него | |
JP6175192B2 (ja) | 触媒組成物およびエチレンのオリゴマ化のための方法 | |
MX347382B (es) | Activadores de catalizador de aluminoxano derivados de agentes precursores de cation dialquilaluminio, procesos para su elaboracion, y su uso en catalizadores y polimerizacion de olefinas. | |
RU2001101489A (ru) | Компоненты и катализаторы полимеризации олефинов | |
RU2009136640A (ru) | Способ полимеризации олефинов | |
JP2015503643A5 (ru) | ||
DE602005023844D1 (de) | Verfahren zur polymerisation von 1-hexen oder höheren alpha-olefinen | |
RU2010120469A (ru) | Металлоценовые катализаторы и их применение в процессах полимеризации | |
RU2013128495A (ru) | Композиции активатора, их получение и их использование в катализе | |
PT955304E (pt) | Complexo de metaloceno com pontes para a (co) polimerizacao de olefinas | |
RU2759004C1 (ru) | Способ получения катализатора олигомеризации этилена и его олигомеризация | |
KR950704365A (ko) | 지에글러 중합화 촉매 및 그 제조 방법(catalyst and process for a ziegler polymerisati0n) | |
RU2011129234A (ru) | Способ обработки зародышевого слоя реакции полимеризации | |
RU2019113132A (ru) | Композиция прокатализатора, полученная с комбинацией внутренних доноров электронов | |
KR930006060A (ko) | 올레핀폴리머의 제조방법 및 이에 사용되는 촉매 | |
DE60224205D1 (de) | Komponenten und katalysatoren für die polymerisation von olefinen | |
RU2010118455A (ru) | Добавки для непрерывности и их применение в процессах полимеризации | |
DK1171479T3 (da) | Bimetalkatalysatorer til (co)polymerisationen af $g(a)-olefiner | |
EA201200289A1 (ru) | Каталитическая система и способ получения полиэтилена |