RU2008132395A - METHOD FOR PRODUCING 1-AMINOMETHYL-2-PHENYLACETHYLENES - Google Patents

METHOD FOR PRODUCING 1-AMINOMETHYL-2-PHENYLACETHYLENES Download PDF

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RU2008132395A
RU2008132395A RU2008132395/04A RU2008132395A RU2008132395A RU 2008132395 A RU2008132395 A RU 2008132395A RU 2008132395/04 A RU2008132395/04 A RU 2008132395/04A RU 2008132395 A RU2008132395 A RU 2008132395A RU 2008132395 A RU2008132395 A RU 2008132395A
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Russia
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phenylacetylene
aminomethyl
phenylacethylenes
producing
reacted
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RU2008132395/04A
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Russian (ru)
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RU2391335C2 (en
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Усеин Меметович Джемилев (RU)
Усеин Меметович Джемилев
Мария Геннадьевна Шайбакова (RU)
Мария Геннадьевна Шайбакова
Ирина Геннадьевна Титова (RU)
Ирина Геннадьевна Титова
Асхат Габдрахманович Ибрагимов (RU)
Асхат Габдрахманович Ибрагимов
Гилемдар Адыхамович Махмудияров (RU)
Гилемдар Адыхамович Махмудияров
Ильфир Рифович Рамазанов (RU)
Ильфир Рифович Рамазанов
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Учреждение Российской академии наук ИНСТИТУТ НЕФТЕХИМИИ И КАТАЛИЗА Российской Академии Наук (RU)
Учреждение Российской Академии Наук Институт Нефтехимии И Катализа Российской Академии Наук
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  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Способ получения 1-аминометил-2-фенилацетиленов общей формулы (1): ! где ! ! характеризующийся тем, что фенилацетилен (Ph-C=CH) подвергают взаимодействию с гем-диаминами R2NCH2NR2, где R2N такое же, как определено выше, в присутствии катализатора Sm(NО3)2*6H2O, при мольном соотношении фенилацетилен:гем-диамин:Sm(NО3)2*6H2О=10:(8-12):(0.2-0.6) при температуре 80°С и атмосферном давлении в течение 3-5 ч.The method of obtaining 1-aminomethyl-2-phenylacetylene of the general formula (1):! where! ! characterized in that phenylacetylene (Ph-C = CH) is reacted with hemi-diamines R2NCH2NR2, where R2N is the same as defined above, in the presence of a catalyst Sm (NO3) 2 * 6H2O, with a molar ratio of phenylacetylene: heme diamine: Sm (NO3) 2 * 6H2O = 10: (8-12) :( 0.2-0.6) at a temperature of 80 ° C and atmospheric pressure for 3-5 hours.

Claims (1)

Способ получения 1-аминометил-2-фенилацетиленов общей формулы (1):The method of obtaining 1-aminomethyl-2-phenylacetylene of the General formula (1):
Figure 00000001
где
Figure 00000001
Where
Figure 00000002
Figure 00000002
 характеризующийся тем, что фенилацетилен (Ph-C=CH) подвергают взаимодействию с гем-диаминами R2NCH2NR2, где R2N такое же, как определено выше, в присутствии катализатора Sm(NО3)2*6H2O, при мольном соотношении фенилацетилен:гем-диамин:Sm(NО3)2*6H2О=10:(8-12):(0.2-0.6) при температуре 80°С и атмосферном давлении в течение 3-5 ч. characterized in that phenylacetylene (Ph-C = CH) is reacted with gemdiamines R 2 NCH 2 NR 2 , where R 2 N is the same as defined above, in the presence of a catalyst Sm (NO 3 ) 2 * 6H 2 O, at a molar ratio of phenylacetylene: gemdiamine: Sm (NO 3 ) 2 * 6H 2 O = 10: (8-12) :( 0.2-0.6) at a temperature of 80 ° C and atmospheric pressure for 3-5 hours
RU2008132395/04A 2008-08-05 2008-08-05 Method for synthesis of 1-aminomethyl-2-phenylacetylenes RU2391335C2 (en)

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