RU2006126086A - METHODS FOR PRODUCING UNCLEANED PRODUCT AND HYDROGEN-CONTAINING GAS - Google Patents

METHODS FOR PRODUCING UNCLEANED PRODUCT AND HYDROGEN-CONTAINING GAS Download PDF

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RU2006126086A
RU2006126086A RU2006126086/15A RU2006126086A RU2006126086A RU 2006126086 A RU2006126086 A RU 2006126086A RU 2006126086/15 A RU2006126086/15 A RU 2006126086/15A RU 2006126086 A RU2006126086 A RU 2006126086A RU 2006126086 A RU2006126086 A RU 2006126086A
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crude feed
crude
crude product
feed
residue
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RU2379331C2 (en
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Томас Фэйрчайлд БРАУНСКОМБ (US)
Томас Фэйрчайлд Браунскомб
Скотт Ли ВЕЛЛИНГТОН (US)
Скотт Ли Веллингтон
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Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL)
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/043—Sulfides with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
    • C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1074—Vacuum distillates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1096—Aromatics or polyaromatics
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/301—Boiling range
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/305—Octane number, e.g. motor octane number [MON], research octane number [RON]

Claims (23)

1. Способ получения газообразного водорода, в котором неочищенное сырье контактирует с одним или несколькими углеводородами в присутствии неорганического солевого катализатора и водой, причем число атомов углерода в углеводороде находится в диапазоне от 1 до 6, неочищенное сырье имеет содержание остатка, по меньшей мере, 0,2 г остатка на 1 г неочищенного сырья, и для неорганического солевого катализатора наблюдается точка перегиба при выделении газа в температурном диапазоне между 50 и 500°С, что определяется по методу Временного анализа продуктов (ВАП), и получают газообразный водород.1. A method of producing gaseous hydrogen, in which the crude feed is contacted with one or more hydrocarbons in the presence of an inorganic salt catalyst and water, wherein the number of carbon atoms in the hydrocarbon is in the range from 1 to 6, the crude feed has a residue content of at least 0 , 2 g of residue per 1 g of crude feed, and for an inorganic salt catalyst, an inflection point is observed when gas is released in the temperature range between 50 and 500 ° C, which is determined by the method of Temporary analysis of uktov (VAP) to give hydrogen gas. 2. Способ по п.1, в котором углеводород, имеющий один или несколько атомов углерода в диапазоне от 1 до 6, включает в себя метан, этан, пропан, бутан, нафту или их смеси.2. The method according to claim 1, in which the hydrocarbon having one or more carbon atoms in the range from 1 to 6, includes methane, ethane, propane, butane, naphtha, or mixtures thereof. 3. Способ по п.1 или 2, в котором вода представляет собой водяной пар.3. The method according to claim 1 or 2, in which the water is water vapor. 4. Способ получения газового потока, в котором неочищенное сырье контактирует с неорганическим солевым катализатором в присутствии водяного пара, в котором неочищенное сырье имеет содержание остатка, по меньшей мере, 0,2 г остатка на 1 г неочищенного сырья, что определяется по методу ASTM 5307, и получают газовый поток, который содержит водород, монооксид углерода и диоксид углерода, причем молярное отношение монооксида углерода к диоксиду углерода составляет, по меньшей мере 0,3.4. A method of producing a gas stream in which the crude feed is contacted with an inorganic salt catalyst in the presence of water vapor, in which the crude feed has a residue content of at least 0.2 g of residue per 1 g of crude feed, as determined by ASTM 5307 and a gas stream is obtained which contains hydrogen, carbon monoxide and carbon dioxide, wherein the molar ratio of carbon monoxide to carbon dioxide is at least 0.3. 5. Способ по любому из пп.1, 2 и 4, в котором газообразный водород или газовый поток используют в процессе с восходящим потоком.5. The method according to any one of claims 1, 2 and 4, in which gaseous hydrogen or a gas stream is used in the process with an upward flow. 6. Способ по любому из пп.1, 2 и 4, в котором газообразный водород или газовый поток используют в процессе получении синтез-газа.6. The method according to any one of claims 1, 2 and 4, in which gaseous hydrogen or a gas stream is used in the process of producing synthesis gas. 7. Способ по любому из пп.1, 2 и 4, в котором при контактировании неочищенного сырья с неорганическим солевым катализатором в присутствии воды образуется суммарный продукт, который включает в себя неочищенный продукт, который является жидкой смесью при 25°С и 0,101 МПа.7. The method according to any one of claims 1, 2 and 4, wherein upon contacting the crude feed with an inorganic salt catalyst in the presence of water, a total product is formed, which includes the crude product, which is a liquid mixture at 25 ° C and 0.101 MPa. 8. Способ получения неочищенного продукта, в котором первое неочищенное сырье контактирует с первым катализатором в присутствии водяного пара с целью получения газового потока, который включает в себя водород, при этом первое неочищенное сырье имеет содержание остатка по меньшей мере, 0,2 г остатка на 1 г первого неочищенного сырья, что определяется по методу ASTM D5307, и первый катализатор содержит неорганический солевой катализатор, который имеет точку перегиба при выделении газа в температурном диапазоне между 50°С и 500°С, что определяется по методу Временного анализа продуктов (ВАП), второе неочищенное сырье контактирует со вторым катализатором в присутствии, по меньшей мере, части образовавшегося газового потока, чтобы получить суммарный продукт, который включает неочищенный продукт, представляющий собой жидкую смесь при 25°С и 0,101 МПа, и регулируют условия контактирования таким образом, что одна или несколько характеристик неочищенного продукта изменяется, по меньшей мере, на 10% относительно одной или нескольких соответствующих характеристик второго неочищенного сырья.8. A method of obtaining a crude product, in which the first crude feed is contacted with the first catalyst in the presence of water vapor in order to obtain a gas stream that includes hydrogen, wherein the first crude feed has a residue content of at least 0.2 g of residue per 1 g of the first crude feed, as determined by ASTM D5307, and the first catalyst contains an inorganic salt catalyst that has an inflection point for gas evolution in the temperature range between 50 ° C and 500 ° C, which is determined by using the Temporary Product Analysis (VAP) method, the second crude feed is contacted with the second catalyst in the presence of at least a portion of the resulting gas stream to obtain a total product that includes the crude product, which is a liquid mixture at 25 ° C and 0.101 MPa, and adjust the contact conditions so that one or more characteristics of the crude product changes by at least 10% with respect to one or more corresponding characteristics of the second crude feed. 9. Способ по п.8, в котором условия контактирования регулируют таким образом, что температура контактирования лежит выше T1, где T1 на 30°С ниже ВАП температуры неорганического солевого катализатора, и ВАП температура представляет собой самую низкую температуру, при которой неорганический солевой катализатор имеет точку перегиба при выделении газа.9. The method of claim 8, in which the contact conditions are adjusted so that the contact temperature lies above T 1 , where T 1 is 30 ° C lower than the VAP temperature of the inorganic salt catalyst, and the VAP temperature is the lowest temperature at which the inorganic the salt catalyst has an inflection point in the evolution of gas. 10. Способ по п.8 или 9, в котором выделенный газ представляет собой водяной пар и/или диоксид углерода.10. The method of claim 8 or 9, in which the evolved gas is water vapor and / or carbon dioxide. 11. Способ по любому из п.8 или 9, в котором второй катализатор содержит неорганический солевой катализатор и/или катализатор, представляющий собой сульфид переходного металла.11. The method according to any one of claim 8 or 9, in which the second catalyst comprises an inorganic salt catalyst and / or a transition metal sulfide catalyst. 12. Способ по любому из пп.1, 2, 4, 8, в котором неорганический солевой катализатор включает, по меньшей мере, один карбонат щелочных металлов, по меньшей мере, один карбонат щелочно-земельных металлов, по меньшей мере, один гидроксид щелочных металлов, по меньшей мере, один гидроксид щелочно-земельных металлов, по меньшей мере, один гидрид щелочных металлов, по меньшей мере, один гидрид щелочно-земельных металлов, по меньшей мере, один сульфид одного или нескольких щелочных металлов, по меньшей мере, один сульфид одного или нескольких щелочно-земельных металлов, по меньшей мере, один амид одного или нескольких щелочных металлов, по меньшей мере, один амид одного или нескольких щелочно-земельных металлов, по меньшей мере, или их смеси.12. The method according to any one of claims 1, 2, 4, 8, wherein the inorganic salt catalyst comprises at least one alkali metal carbonate, at least one alkaline earth metal carbonate, at least one alkaline hydroxide metals, at least one alkaline earth metal hydroxide, at least one alkali metal hydride, at least one alkaline earth metal hydride, at least one sulfide of one or more alkali metals, at least one sulfide of one or more alkaline earth earth metals, at least one amide of one or more alkali metals, at least one amide of one or more alkaline earth metals, at least, or mixtures thereof. 13. Способ по п.12, в котором, по меньшей мере, один щелочной металл представляет собой натрий, калий, рубидий, цезий или их смеси, и/или, по меньшей мере, один щелочно-земельный металл представляет собой кальций, магний или их смеси.13. The method according to item 12, in which at least one alkali metal is sodium, potassium, rubidium, cesium or mixtures thereof, and / or at least one alkaline earth metal is calcium, magnesium or mixtures thereof. 14. Способ по любому из пп.1, 2, 4, 8, в котором неочищенное сырье, первое неочищенное сырье или второе неочищенное сырье имеет от 0,2 до 0,99 г или от 0,3 до 0,8 г остатка на 1 г неочищенного сырья, первого неочищенного сырья или второго неочищенного сырья.14. The method according to any one of claims 1, 2, 4, 8, in which the crude feed, the first crude feed or the second raw feed has from 0.2 to 0.99 g or from 0.3 to 0.8 g of residue 1 g of crude feed, a first crude feed or a second raw feed. 15. Способ по любому из п.8 или 9, в котором условия контактирования регулируют таким образом, что в ходе контактирования образуется, на 1 г неочищенного сырья, по большей мере 0,2 г, по большей мере 0,15 г, по большей мере, 0,1 г, или по большей мере, 0,05 г углеводородов, которые не конденсируются при 25°С и 0,101 МПа, что определяется с помощью материального баланса.15. The method according to any one of p. 8 or 9, in which the contact conditions are regulated so that during contact is formed, per 1 g of crude feed, at least 0.2 g, at most 0.15 g, at most at least 0.1 g, or at least 0.05 g of hydrocarbons that do not condense at 25 ° C and 0.101 MPa, which is determined using the material balance. 16. Способ по любому из п.8 или 9, в котором одна или несколько характеристик включает в себя содержание остатка, содержание Ni/V/Fe, содержание гетероатомов, и условия контактирования регулируют таким образом, что неочищенный продукт имеет суммарное кислотное число (СКЧ), суммарное содержание Ni/V/Fe, и/или суммарное содержание гетероатомов, по большей мере 90%, от величин СКЧ, суммарного содержания Ni/V/Fe, и/или суммарного содержания гетероатомов в неочищенном сырье или втором неочищенном сырье.16. The method according to any one of claims 8 or 9, in which one or more of the characteristics includes the residue content, the content of Ni / V / Fe, the content of heteroatoms, and the contacting conditions are controlled so that the crude product has a total acid number (SKH ), the total content of Ni / V / Fe, and / or the total content of heteroatoms, at least 90% of the values of SKH, the total content of Ni / V / Fe, and / or the total content of heteroatoms in the crude feed or the second crude feed. 17. Способ по любому из п.8 или 9, в котором неочищенный продукт также имеет, на 1 г неочищенного продукта, от 0,001 до 0,05 г нафты, от 0,001 до 0,05 г дистиллята, от 0,001 до 0,3 г ВГО, или их смесей.17. The method according to any one of claim 8 or 9, in which the crude product also has, per 1 g of the crude product, from 0.001 to 0.05 g of naphtha, from 0.001 to 0.05 g of distillate, from 0.001 to 0.3 g VGO, or mixtures thereof. 18. Способ по любому из п.8 или 9, в котором неочищенный продукт имеет, на 1 г неочищенного продукта, от 0,000001 до 0,1 г, от 0,00001 до 0,05 г, 0,0001-0,03 г или от 0,005 до 0,04 г, остатка.18. The method according to any one of claim 8 or 9, in which the crude product has, per g of crude product, from 0.000001 to 0.1 g, from 0.00001 to 0.05 g, 0.0001-0, 03 g or from 0.005 to 0.04 g, residue. 19. Способ по любому из п.8 или 9, в котором смешивают неочищенный продукт с сырьем, которое является таким же или отличается от неочищенного сырья, чтобы получить смесь.19. The method according to any one of claim 8 or 9, in which the crude product is mixed with a raw material that is the same or different from the raw material, to obtain a mixture. 20. Неочищенный продукт или смесь, которые получают способом по любому из пп.8-19.20. The crude product or mixture, which is obtained by the method according to any one of paragraphs.8-19. 21. Способ получения транспортного топлива, котельного топлива, смазочных средств или химикалий, который включает в себя переработку неочищенного продукта или смеси по п.20.21. A method of obtaining a transport fuel, boiler fuel, lubricants or chemicals, which includes the processing of the crude product or mixture according to claim 20. 22. Способ по п.21, в котором переработка включает в себя дистилляцию неочищенного продукта или смеси, чтобы получить одну или несколько дистиллятных фракций.22. The method according to item 21, in which the processing includes distillation of the crude product or mixture to obtain one or more distillate fractions. 23. Способ по п.21 или 22, в котором переработка включает в себя гидроочистку.23. The method according to item 21 or 22, in which the processing includes hydrotreating.
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WO2005066308A2 (en) 2005-07-21
EA200601185A1 (en) 2006-10-27
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NL1027780A1 (en) 2005-06-22
MXPA06006743A (en) 2006-08-18
RU2006126084A (en) 2008-02-10
EP1702023A2 (en) 2006-09-20
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EP1702024A2 (en) 2006-09-20
RU2379331C2 (en) 2010-01-20
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EP1704207A2 (en) 2006-09-27
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BRPI0405583A (en) 2005-09-20
TW200535231A (en) 2005-11-01
EP1702048A2 (en) 2006-09-20
AU2004312366A1 (en) 2005-07-21
WO2005061671A2 (en) 2005-07-07
WO2005066308A3 (en) 2006-03-30
MXPA06006742A (en) 2006-08-18
EA200601183A1 (en) 2006-10-27
RU2006126091A (en) 2008-02-10
NL1027773C2 (en) 2006-08-24
CA2559798A1 (en) 2005-07-14
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JP2007516330A (en) 2007-06-21
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JP2007518846A (en) 2007-07-12
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MXPA06006900A (en) 2006-12-19
AU2004312366B2 (en) 2008-07-10
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AU2004312368A1 (en) 2005-07-21
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WO2005066305A3 (en) 2006-01-19
EP1704209A2 (en) 2006-09-27
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EA200601184A1 (en) 2006-12-29
MXPA06006791A (en) 2006-12-19
JP2007514844A (en) 2007-06-07
WO2005066316A2 (en) 2005-07-21
BRPI0405723A (en) 2005-10-04
AU2004309352A1 (en) 2005-07-14
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AU2004303865A1 (en) 2005-07-07
CA2549405C (en) 2013-07-23
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JP2007514535A (en) 2007-06-07
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KR20060130112A (en) 2006-12-18
JP4712723B2 (en) 2011-06-29
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