RU2005137698A - Совмещенный способ получения дифенола а из гидропероксида - Google Patents
Совмещенный способ получения дифенола а из гидропероксида Download PDFInfo
- Publication number
- RU2005137698A RU2005137698A RU2005137698/04A RU2005137698A RU2005137698A RU 2005137698 A RU2005137698 A RU 2005137698A RU 2005137698/04 A RU2005137698/04 A RU 2005137698/04A RU 2005137698 A RU2005137698 A RU 2005137698A RU 2005137698 A RU2005137698 A RU 2005137698A
- Authority
- RU
- Russia
- Prior art keywords
- decomposition
- mass
- stage
- acetone
- phenol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/08—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by decomposition of hydroperoxides, e.g. cumene hydroperoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
- C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
- C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
- C07C45/53—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition of hydroperoxides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Claims (10)
1. Способ получения дифенола А, включающий стадии:
(a) разложение гидропероксида кумена в присутствии кислотного катализатора из сульфатированного оксида металла для превращения гидропероксида кумена в массу после разложения, содержащую, главным образом, фенол и ацетон; и
(b) реакции массы после разложения, предпочтительно без промежуточной очистки, в присутствии катионитного катализатора, состоящего из катионообменной смолы и меркаптанового промотора или промотора в виде меркаптоалкановой кислоты для превращения фенола и ацетона в массе после разложения главным образом в дифенол А.
2. Способ по п.1, при котором массу после разложения, полученную на стадии (а), приводят во взаимодействие на стадии (b) без промежуточной очистки.
3. Способ по п.1 или 2, при котором стадию разложения гидропероксида кумена выполняют при температуре от 55 до 65°С.
4. Способ по п.1 или 2, дополнительно включающий стадию добавления фенола к массе или удаления ацетона из массы после разложения, образовавшейся на стадии (а), для достижения мольного отношения ацетон : фенол от 1:20 до 1:10.
5. Способ по п.4, при котором полученное мольное отношение ацетон : фенол равно 1:13.
6. Способ по любому одному из пп.1, 2 или 5, при котором стадию (b) выполняют при температуре от 40 до 100°С.
7. Способ по любому одному из пп.1, 2 или 5, при котором катионитный катализатор включает в качестве промотора пиридилэтилмеркаптан.
8. Способ по п.7, при котором пиридилэтилмеркаптан нагружают на катионообменную смолу в количестве от 20 до 70% по весу.
9. Способ по п.8, при котором пиридилэтилмеркаптан нагружают на катионообменную смолу в количестве 40% по весу.
10. Способ по любому одному из пп.1, 2, 5, 8 или 9, при котором катализатор является сульфатированным диоксидом циркония.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/250,107 | 2003-06-04 | ||
| US10/250,107 US7154010B2 (en) | 2003-06-04 | 2003-06-04 | Integrated process for the production of bisphenol A from cumene hydroperoxide |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2005137698A true RU2005137698A (ru) | 2007-06-10 |
| RU2339608C2 RU2339608C2 (ru) | 2008-11-27 |
Family
ID=33489121
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2005137698/04A RU2339608C2 (ru) | 2003-06-04 | 2004-04-14 | Совмещенный способ получения дифенола а из гидропероксида кумена |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7154010B2 (ru) |
| EP (1) | EP1636156A1 (ru) |
| JP (1) | JP4790602B2 (ru) |
| KR (1) | KR20060021338A (ru) |
| CN (1) | CN100369877C (ru) |
| RU (1) | RU2339608C2 (ru) |
| TW (1) | TWI344456B (ru) |
| WO (1) | WO2004108641A1 (ru) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007137021A2 (en) * | 2006-05-16 | 2007-11-29 | Shell Oil Company | Catalysts comprising a combination of oxidized metals and a method for cleaving phenylalkyl hydroperoxides using the catalysts |
| US7417003B2 (en) * | 2006-12-29 | 2008-08-26 | Uop Llc | Solid acid catalyst and process for decomposition of cumene hydroperoxide |
| US7902408B2 (en) * | 2007-05-09 | 2011-03-08 | Stone & Webster, Inc. | BPA process improvement |
| US8803966B2 (en) | 2008-04-24 | 2014-08-12 | GM Global Technology Operations LLC | Clear path detection using an example-based approach |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3172916A (en) | 1965-03-09 | Bisphenol axpreparation u using ion ex- change resin containing mercapto and sulfonic acid groups | ||
| US2923744A (en) | 1960-02-02 | Preparation of bis-z | ||
| US2468982A (en) | 1946-10-19 | 1949-05-03 | Goodrich Co B F | Preparation of bis-phenols |
| US3394089A (en) | 1964-12-02 | 1968-07-23 | Dow Chemical Co | Ion exchange catalyst for the preparation of bisphenols |
| DE2931036A1 (de) | 1979-07-31 | 1981-02-26 | Bayer Ag | Katalysator fuer die herstellung von bisphenolen |
| DE2935316A1 (de) | 1979-08-31 | 1981-03-26 | Bayer Ag, 51373 Leverkusen | Verfahren zur herstellung reiner 4,4'-dihydroxydiphenylalkane bzw. -cycloalkane |
| US4294995A (en) | 1979-12-13 | 1981-10-13 | General Electric Company | Method and catalyst for making bisphenol |
| US4423252A (en) | 1980-08-07 | 1983-12-27 | Mitsubishi Chemical Industries Limited | Process for preparing bisphenols |
| US4396728A (en) | 1980-09-30 | 1983-08-02 | General Electric Company | Method and catalyst for making bisphenol |
| US4455409A (en) | 1982-12-02 | 1984-06-19 | General Electric Company | Method for making bisphenol catalysts |
| US4490565A (en) | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
| US4490566A (en) | 1983-05-06 | 1984-12-25 | Mobil Oil Corporation | Production of phenol |
| US5212206A (en) | 1986-06-10 | 1993-05-18 | Bayer Aktiengesellschaft | Ion exchange modified with mercapto amines |
| DE3736814A1 (de) | 1987-10-30 | 1989-05-11 | Roehm Gmbh | Verfahren zur herstellung von bisphenolaromaten |
| DE3835204A1 (de) | 1988-10-15 | 1990-04-19 | Bayer Ag | Verfahren zur herstellung von dihydroxidiarylalkanen |
| US4870217A (en) | 1988-10-24 | 1989-09-26 | Texaco Chemical Company | Method for production of phenol/acetone from cumene hydroperoxide |
| US4898987A (en) | 1989-03-17 | 1990-02-06 | Texaco Chemical Company | Method for production of phenol/acetone from cumene hydroperoxide |
| US4898995A (en) | 1988-10-24 | 1990-02-06 | Texaco Chemical Company | Method for production of phenol/acetone from cumene hydroperoxide |
| US5113034A (en) | 1991-08-05 | 1992-05-12 | Exxon Research And Engineering Company | Dimerization catalyst and process therefor |
| DE4227520A1 (de) | 1992-08-20 | 1994-02-24 | Bayer Ag | Verfahren zur Herstellung von Bisphenolen |
| US5315042A (en) | 1993-03-22 | 1994-05-24 | General Electric Company | Use of partial acetone conversion for capacity increase and quality/yield improvement in the bisphenol-A reaction |
| US5824622A (en) | 1994-01-12 | 1998-10-20 | E. I. Du Pont De Nemours And Company | Porous microcomposite of perfluorinated ion-exchange polymer and metal oxide, a network of silica, or a network of metal oxide and silica derived via a sol-gel process |
| EP0725771A1 (en) | 1994-08-31 | 1996-08-14 | The Dow Chemical Company | Process for making polyphenols from ketones or aldehydes and phenols |
| PL328002A1 (en) * | 1995-12-19 | 1999-01-04 | Shell Int Research | Improved method of obtaining bisphenols |
| ZA972382B (en) * | 1996-03-21 | 1997-09-25 | Shell Int Research | Fixed bed reactor packing. |
| US6169215B1 (en) | 1999-03-25 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
| US6169216B1 (en) | 1999-04-22 | 2001-01-02 | Mobil Oil Corporation | Production of phenol |
| US6297406B1 (en) | 1999-08-03 | 2001-10-02 | Mobil Oil Corporation | Production of phenol |
| JP2002069023A (ja) * | 2000-08-30 | 2002-03-08 | Mitsubishi Chemicals Corp | ビスフェノールの製造方法 |
| JP2002316962A (ja) * | 2001-04-17 | 2002-10-31 | Idemitsu Petrochem Co Ltd | ビスフェノールａの製造方法 |
| US6586640B2 (en) * | 2001-06-26 | 2003-07-01 | E. I. Du Pont De Nemours And Company | Decomposition of organic hydroperoxides in the presence of a particulate catalyst containing highly fluorinated polymer having sulfonic acid groups and process for the manufacture of bisphenol A |
-
2003
- 2003-06-04 US US10/250,107 patent/US7154010B2/en not_active Expired - Fee Related
-
2004
- 2004-04-14 WO PCT/US2004/011504 patent/WO2004108641A1/en active Application Filing
- 2004-04-14 CN CNB2004800155577A patent/CN100369877C/zh not_active Expired - Fee Related
- 2004-04-14 JP JP2006510029A patent/JP4790602B2/ja not_active Expired - Fee Related
- 2004-04-14 EP EP04785676A patent/EP1636156A1/en not_active Withdrawn
- 2004-04-14 KR KR1020057023166A patent/KR20060021338A/ko not_active Application Discontinuation
- 2004-04-14 RU RU2005137698/04A patent/RU2339608C2/ru not_active IP Right Cessation
- 2004-05-20 TW TW093114308A patent/TWI344456B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TWI344456B (en) | 2011-07-01 |
| JP4790602B2 (ja) | 2011-10-12 |
| RU2339608C2 (ru) | 2008-11-27 |
| KR20060021338A (ko) | 2006-03-07 |
| JP2006526627A (ja) | 2006-11-24 |
| EP1636156A1 (en) | 2006-03-22 |
| CN100369877C (zh) | 2008-02-20 |
| US20040249223A1 (en) | 2004-12-09 |
| TW200504001A (en) | 2005-02-01 |
| CN1798718A (zh) | 2006-07-05 |
| US7154010B2 (en) | 2006-12-26 |
| WO2004108641A1 (en) | 2004-12-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PC4A | Invention patent assignment |
Effective date: 20081202 |
|
| MM4A | The patent is invalid due to non-payment of fees |
Effective date: 20160415 |