RU2003122063A - Способ охлаждения сжиженного газа и установка для осуществления способа - Google Patents
Способ охлаждения сжиженного газа и установка для осуществления способа Download PDFInfo
- Publication number
- RU2003122063A RU2003122063A RU2003122063/06A RU2003122063A RU2003122063A RU 2003122063 A RU2003122063 A RU 2003122063A RU 2003122063/06 A RU2003122063/06 A RU 2003122063/06A RU 2003122063 A RU2003122063 A RU 2003122063A RU 2003122063 A RU2003122063 A RU 2003122063A
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- Prior art keywords
- fraction
- compressed
- natural gas
- expanded
- during
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract 8
- 238000009434 installation Methods 0.000 title claims 9
- 239000003949 liquefied natural gas Substances 0.000 claims abstract 20
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 10
- 238000001816 cooling Methods 0.000 claims 4
- 238000004821 distillation Methods 0.000 claims 4
- 239000007789 gas Substances 0.000 claims 3
- 238000010438 heat treatment Methods 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 239000003345 natural gas Substances 0.000 claims 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims 1
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 230000004907 flux Effects 0.000 abstract 1
- 239000002737 fuel gas Substances 0.000 abstract 1
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
- F25J1/0279—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc.
- F25J1/0285—Combination of different types of drivers mechanically coupled to the same refrigerant compressor, possibly split on multiple compressor casings
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0022—Hydrocarbons, e.g. natural gas
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
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- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
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- F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
- F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
- F25J1/008—Hydrocarbons
- F25J1/0087—Propane; Propylene
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
- F25J1/0219—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. using a deep flash recycle loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
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- F25J1/0281—Compression of refrigerant or internal recycle fluid, e.g. kind of compressor, accumulator, suction drum etc. characterised by the type of prime driver, e.g. hot gas expander
- F25J1/0283—Gas turbine as the prime mechanical driver
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- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
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- F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
- F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
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- F25J2280/00—Control of the process or apparatus
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- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
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Claims (13)
1. Способ охлаждения сжиженного под давлением природного газа (1), содержащего метан и углеводороды с С2 и выше, содержащий первый этап (I), во время которого указанный сжиженный под давлением природный газ (1) расширяют (Ia) для получения потока расширенного сжиженного природного газа (2), во время которого указанный расширенный сжиженный природный газ (2) разделяют (Ib) на первую относительно более летучую головную фракцию (3) и на первую относительно менее летучую хвостовую фракцию (4), во время которого собирают (Ic) первую хвостовую фракцию (4), содержащую охлажденный сжиженный природный газ, во время которого (Id) первую головную фракцию (3) нагревают, сжимают в первом компрессоре (К1) и охлаждают для получения первой сжатой фракции (5) горючего газа, которую собирают, во время которого из первой сжатой фракции (5) извлекают (Ie) вторую сжатую фракцию (6), которую затем охлаждают и смешивают с потоком расширенного сжиженного природного газа (2), отличающийся тем, что содержит второй этап (II), во время которого вторую сжатую фракцию (6) сжимают (IIa) во втором компрессоре (ХК1), соединенном с расширительной турбиной (Х1), для получения третьей сжатой фракции (7), во время которого (IIb) третью сжатую фракцию (7) охлаждают, после чего разделяют на четвертую сжатую фракцию (8) и на пятую сжатую фракцию (9), во время которого (IIс) четвертую сжатую фракцию (8) охлаждают и расширяют в расширительной турбине (Х1), соединенной со вторым компрессором (ХК1), для получения расширенной фракции (10), которую нагревают, а затем вводят в первую ступень среднего давления (11) компрессора (К1), и во время которого (IId) пятую сжатую фракцию (9) охлаждают, затем смешивают с потоком расширенного сжиженного природного газа (2).
2. Способ по п.1, отличающийся тем, что поток расширенного сжиженного природного газа (2) перед этапом (Ib) разделяют на вторую головную фракцию (12) и на вторую хвостовую фракцию (13) и тем, что вторую головную фракцию (12) нагревают, а затем вводят в первый компрессор (К1) во вторую ступень среднего давления (14), промежуточную между первой ступенью среднего давления (11) и ступенью низкого давления (15), и тем, что вторую хвостовую фракцию (13) разделяют на первую головную фракцию (3) и на первую хвостовую фракцию (4).
3. Способ по п.1 или 2, отличающийся тем, что после каждого этапа сжатия следует этап охлаждения.
4. Охлажденный сжиженный природный газ (4), полученный при помощи способа по любому из предыдущих пунктов.
5. Горючий газ (5), полученный при помощи способа по любому из пп.1-3.
6. Установка для охлаждения сжиженного под давлением природного газа (1), содержащего метан и углеводороды с С2 и выше, содержащая средства для осуществления первого этапа (I), во время которого указанный сжиженный под давлением природный газ (1) расширяют (Ia) для получения потока расширенного сжиженного природного газа (2), во время которого указанный расширенный сжиженный природный газ (2) разделяют (Ib) на первую относительно более летучую головную фракцию (3) и на первую относительно менее летучую хвостовую фракцию (4), во время которого собирают (Ic) первую хвостовую фракцию (4), содержащую охлажденный сжиженный природный газ, во время которого (Id) первую головную фракцию (3) нагревают, сжимают в первом компрессоре (К1) и охлаждают для получения первой сжатой фракции (5) горючего газа, которую собирают, во время которого из первой сжатой фракции (5) извлекают (Ie) вторую сжатую фракцию (6), которую затем охлаждают и смешивают с потоком расширенного сжиженного природного газа (2), отличающаяся тем, что она содержит средства для осуществления второго этапа (II), во время которого вторую сжатую фракцию (6) сжимают (IIa) во втором компрессоре (ХК1), соединенном с расширительной турбиной (Х1), для получения третьей сжатой фракции (7), во время которого (IIb) третью сжатую фракцию (7) охлаждают, после чего разделяют на четвертую сжатую фракцию (8) и на пятую сжатую фракцию (9), во время которого (IIс) четвертую сжатую фракцию (8) охлаждают и расширяют в расширительной турбине (Х1), соединенной со вторым компрессором (ХК1), для получения расширенной фракции (10), которую нагревают, а затем вводят в первую ступень среднего давления (11) компрессора (К1), и во время которого (IId) пятую сжатую фракцию (9) охлаждают, затем смешивают с потоком расширенного сжиженного природного газа (2).
7. Установка по п.6, отличающаяся тем, что содержит средства для разделения потока расширенного сжиженного природного газа (2) перед этапом (Ib) на вторую головную фракцию (12) и на вторую хвостовую фракцию (13), тем, что содержит средства для нагрева и последующей подачи второй головной фракции (12) в первый компрессор (К1) во вторую ступень среднего давления (14), промежуточную между первой ступенью среднего давления (11) и ступенью низкого давления (15), и тем, что содержит средства для разделения второй хвостовой фракции (13) на первую головную фракцию (3) и на первую хвостовую фракцию (4).
8. Установка по п.6 или п.7, отличающаяся тем, что первая головная фракция (3) и первая хвостовая фракция (4) разделяются в первой сепараторной колбе (V1).
9. Установка по п.6 или 7, отличающаяся тем, что первая головная фракция (3) и первая хвостовая фракция (4) разделяются в дистилляционной колонне (С1).
10. Установка по любому из пп.6-9, отличающаяся тем, что поток расширенного сжиженного природного газа (2) разделяются на вторую головную фракцию (12) и на вторую хвостовую фракцию (13) во второй сепараторной колбе (V2).
11. Установка по п.9, отличающаяся тем, что дистилляционная колонна (С1) содержит, по меньшей мере, один боковой и/или донный ребойлер (16), тем, что жидкость, собираемая на тарелке (17) дистилляционной колонны (С1), циркулирующая в указанном ребойлере (16), нагревается в теплообменнике (Е2), затем опять поступает в дистилляционную колонну (С1) в нижнюю ступень указанной тарелки (17), и тем, что поток расширенного сжиженного природного газа (2) охлаждается в указанном теплообменнике (Е2).
12. Установка по любому из пп.6-11, отличающаяся тем, что охлаждение первой головной фракции (3) и расширенной фракции (10) и нагрев четвертой сжатой фракции (8) и пятой сжатой фракции (9) осуществляется только в первом теплообменнике (Е1).
13. Установка по любому из пп.6-12 в комбинации с п.7, отличающаяся тем, что вторая головная фракция (12) нагревается в первом теплообменнике (Е1).
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Application Number | Priority Date | Filing Date | Title |
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FR0016495A FR2818365B1 (fr) | 2000-12-18 | 2000-12-18 | Procede de refrigeration d'un gaz liquefie, gaz obtenus par ce procede, et installation mettant en oeuvre celui-ci |
FR0016495 | 2000-12-18 |
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RU2003122063A true RU2003122063A (ru) | 2005-01-10 |
RU2270408C2 RU2270408C2 (ru) | 2006-02-20 |
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RU2003122063/06A RU2270408C2 (ru) | 2000-12-18 | 2001-12-13 | Способ охлаждения сжиженного газа и установка для осуществления способа |
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EP (1) | EP1352203B1 (ru) |
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NO (1) | NO335843B1 (ru) |
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US6742357B1 (en) * | 2003-03-18 | 2004-06-01 | Air Products And Chemicals, Inc. | Integrated multiple-loop refrigeration process for gas liquefaction |
EP1613909B1 (en) * | 2003-03-18 | 2013-03-06 | Air Products And Chemicals, Inc. | Integrated multiple-loop refrigeration process for gas liquefaction |
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MY140540A (en) * | 2004-07-12 | 2009-12-31 | Shell Int Research | Treating liquefied natural gas |
AU2005290036B2 (en) * | 2004-09-22 | 2008-06-12 | Fluor Technologies Corporation | Configurations and methods for LPG and power cogeneration |
KR20070111531A (ko) * | 2005-02-17 | 2007-11-21 | 쉘 인터내셔날 리써취 마트샤피지 비.브이. | 천연 가스 액화 설비 및 액화 방법 |
FR2891900B1 (fr) | 2005-10-10 | 2008-01-04 | Technip France Sa | Procede de traitement d'un courant de gnl obtenu par refroidissement au moyen d'un premier cycle de refrigeration et installation associee. |
RU2423653C2 (ru) | 2006-05-15 | 2011-07-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ для сжижения потока углеводородов и установка для его осуществления |
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US9400134B2 (en) * | 2006-08-02 | 2016-07-26 | Shell Oil Company | Method and apparatus for liquefying a hydrocarbon stream |
AU2007286291B2 (en) * | 2006-08-14 | 2010-08-12 | Shell Internationale Research Maatschappij B.V. | Method and apparatus for cooling a hydrocarbon stream |
US7967036B2 (en) * | 2007-02-16 | 2011-06-28 | Clean Energy Fuels Corp. | Recipicating compressor with inlet booster for CNG station and refueling motor vehicles |
US20110036120A1 (en) * | 2007-07-19 | 2011-02-17 | Marco Dick Jager | Method and apparatus for recovering and fractionating a mixed hydrocarbon feed stream |
US20090095153A1 (en) * | 2007-10-12 | 2009-04-16 | Paul Roper | Natural gas recovery system and method |
CA2708154A1 (en) * | 2007-12-07 | 2009-06-11 | Dresser-Rand Company | Compressor system and method for gas liquefaction system |
CN102265104B (zh) * | 2008-09-19 | 2013-11-06 | 国际壳牌研究有限公司 | 冷却烃物流的方法及其设备 |
WO2010054434A1 (en) * | 2008-11-17 | 2010-05-20 | Woodside Energy Limited | Power matched mixed refrigerant compression circuit |
FR2943683B1 (fr) * | 2009-03-25 | 2012-12-14 | Technip France | Procede de traitement d'un gaz naturel de charge pour obtenir un gaz naturel traite et une coupe d'hydrocarbures en c5+, et installation associee |
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-
2000
- 2000-12-18 FR FR0016495A patent/FR2818365B1/fr not_active Expired - Fee Related
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2001
- 2001-12-13 DZ DZ013483A patent/DZ3483A1/fr active
- 2001-12-13 AT AT01271522T patent/ATE528602T1/de not_active IP Right Cessation
- 2001-12-13 KR KR1020037007947A patent/KR100825827B1/ko active IP Right Grant
- 2001-12-13 ES ES01271522T patent/ES2373218T3/es not_active Expired - Lifetime
- 2001-12-13 PT PT01271522T patent/PT1352203E/pt unknown
- 2001-12-13 EG EG20011346A patent/EG23286A/xx active
- 2001-12-13 JP JP2002551337A patent/JP3993102B2/ja not_active Expired - Lifetime
- 2001-12-13 WO PCT/FR2001/003983 patent/WO2002050483A1/fr active Application Filing
- 2001-12-13 US US10/451,712 patent/US6898949B2/en not_active Expired - Lifetime
- 2001-12-13 RU RU2003122063/06A patent/RU2270408C2/ru active
- 2001-12-13 AU AU1930102A patent/AU1930102A/xx active Pending
- 2001-12-13 MX MXPA03005213A patent/MXPA03005213A/es active IP Right Grant
- 2001-12-13 CN CNB018207480A patent/CN1266445C/zh not_active Expired - Lifetime
- 2001-12-13 BR BRPI0116288-8A patent/BR0116288B1/pt not_active IP Right Cessation
- 2001-12-13 EP EP01271522A patent/EP1352203B1/fr not_active Expired - Lifetime
- 2001-12-13 AU AU2002219301A patent/AU2002219301B2/en not_active Expired
- 2001-12-22 GC GCP20011775 patent/GC0000378A/en active
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Publication number | Publication date |
---|---|
KR20030081349A (ko) | 2003-10-17 |
EG23286A (en) | 2004-10-31 |
EP1352203B1 (fr) | 2011-10-12 |
JP2004527716A (ja) | 2004-09-09 |
CN1266445C (zh) | 2006-07-26 |
RU2270408C2 (ru) | 2006-02-20 |
NO20032543D0 (no) | 2003-06-05 |
ES2373218T3 (es) | 2012-02-01 |
FR2818365A1 (fr) | 2002-06-21 |
KR100825827B1 (ko) | 2008-04-28 |
US20040065113A1 (en) | 2004-04-08 |
PT1352203E (pt) | 2011-10-20 |
CN1481495A (zh) | 2004-03-10 |
DZ3483A1 (fr) | 2002-06-27 |
NO20032543L (no) | 2003-08-07 |
NO335843B1 (no) | 2015-03-02 |
MXPA03005213A (es) | 2005-06-20 |
AU1930102A (en) | 2002-07-01 |
GC0000378A (en) | 2007-03-31 |
CY1112363T1 (el) | 2015-12-09 |
FR2818365B1 (fr) | 2003-02-07 |
BR0116288B1 (pt) | 2010-03-09 |
JP3993102B2 (ja) | 2007-10-17 |
ATE528602T1 (de) | 2011-10-15 |
BR0116288A (pt) | 2004-03-09 |
US6898949B2 (en) | 2005-05-31 |
WO2002050483A1 (fr) | 2002-06-27 |
EP1352203A1 (fr) | 2003-10-15 |
AU2002219301B2 (en) | 2006-10-12 |
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