RU2001135572A - Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа - Google Patents

Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа

Info

Publication number
RU2001135572A
RU2001135572A RU2001135572/04A RU2001135572A RU2001135572A RU 2001135572 A RU2001135572 A RU 2001135572A RU 2001135572/04 A RU2001135572/04 A RU 2001135572/04A RU 2001135572 A RU2001135572 A RU 2001135572A RU 2001135572 A RU2001135572 A RU 2001135572A
Authority
RU
Russia
Prior art keywords
catalyst
phase
gas
synthesis gas
catalyst according
Prior art date
Application number
RU2001135572/04A
Other languages
English (en)
Other versions
RU2210432C1 (ru
Inventor
Изабелла Шендеровна Итенберг
Валерий Александрович Кириллов
Николай Алексеевич Кузин
Валентин Николаевич Пармон
Анатолий Геннадьевич Сипатров
Александр Александрович Хасин
Галина Константиновна Чермашенцева
Тамара Михайловна Юрьева
Original Assignee
Институт катализа им. Г.К. Борескова СО РАН
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Институт катализа им. Г.К. Борескова СО РАН filed Critical Институт катализа им. Г.К. Борескова СО РАН
Priority to RU2001135572/04A priority Critical patent/RU2210432C1/ru
Priority to EP02783882A priority patent/EP1457258A4/en
Priority to AU2002349609A priority patent/AU2002349609A1/en
Priority to EA200400652A priority patent/EA006414B1/ru
Priority to US10/498,894 priority patent/US20050032921A1/en
Priority to PCT/RU2002/000507 priority patent/WO2003053568A1/ru
Application granted granted Critical
Publication of RU2210432C1 publication Critical patent/RU2210432C1/ru
Publication of RU2001135572A publication Critical patent/RU2001135572A/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B01J35/59—Membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Claims (13)

1. Катализатор получения углеводородов и/или их кислородсодержащих производных из синтез-газа, содержащий не менее 0,4 г/см3 совокупности фаз, представляющей собой фазу каталитически активного металла, закрепленную на фазе подложки оксидной природы, оказывающей значительное влияние на дисперсность фазы активного металла или другие ее физико-химические свойства, при этом тело катализатора имеет проницаемость не менее 5·10-15 м2.
2. Катализатор по п.1, в котором в качестве каталитически активного металла используют один из металлов VIII группы или интерметаллическое соединение с их содержанием.
3. Катализатор по пп.1 и 2, в котором содержание фазы каталитически активного металла в совокупности фаз составляет не менее 5 мас.%.
4. Катализатор по пп.1-3, в котором объем пор с размером менее 70 мкм составляет не менее 90% от общего объема пор тела катализатора.
5. Катализатор по пп.1-4, в котором в его состав входит фаза инертного по отношению к синтез-газу металла и/или графитоподобная фаза.
6. Катализатор по п.5, в котором в качестве инертного по отношению к синтез-газу металла используют медь, и/или цинк, и/или алюминий, и/или их сплавы.
7. Катализатор по пп.1-6, в котором его тело имеет теплопроводность не менее 1 Вт м-1 К-1.
8. Катализатор по пп.1-7, в котором хотя бы часть объема его пор заполнена углеводородами и/или их кислородсодержащими производными в жидком или твердом агрегатном состоянии.
9. Способ получения углеводородов и/или их кислородсодержащих производных, включающий в качестве одной из стадий пропускание газового потока, содержащего синтез-газ, через одно или несколько тел концентрированного проницаемого катализатора по любому из пп.1-8.
10. Способ по п.9, в котором один из линейных размеров тел концентрированного проницаемого катализатора составляет не менее 20% от наименьшего линейного размера реактора.
11. Способ по пп.9-10, в котором тела концентрированного проницаемого катализатора полностью перекрывают газовый поток.
12. Способ по пп.9-11, в котором через тела концентрированного проницаемого катализатора спутно пропускаемому газовому потоку пропускают поток жидкой фазы, образующей с ним единый газо-жидкостный поток.
13. Способ по пп.9-12, в котором стадию пропускания газового либо газо-жидкостного потока через тела концентрированного проницаемого катализатора повторяют многократно.
RU2001135572/04A 2001-12-21 2001-12-21 Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа RU2210432C1 (ru)

Priority Applications (6)

Application Number Priority Date Filing Date Title
RU2001135572/04A RU2210432C1 (ru) 2001-12-21 2001-12-21 Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа
EP02783882A EP1457258A4 (en) 2001-12-21 2002-11-25 CATALYST AND METHOD FOR THE PRODUCTION OF HYDROCARBONS AND OXYGEN-DERIVATIVES DERIVED FROM SYNGAS
AU2002349609A AU2002349609A1 (en) 2001-12-21 2002-11-25 Catalyst and method for producing hydrocarbons and the oxygen-containing derivatives thereof obtained from syngas
EA200400652A EA006414B1 (ru) 2001-12-21 2002-11-25 Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа
US10/498,894 US20050032921A1 (en) 2001-12-21 2002-11-25 Catalyst and method for producing hydrocarbons and the oxygen-containing derivatives thereof obtained from syngas
PCT/RU2002/000507 WO2003053568A1 (fr) 2001-12-21 2002-11-25 Catalyseur et procede de fabrication d'hydrocarbures et de leurs derives contenant l'oxygene a partir du gaz de synthese

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RU2001135572/04A RU2210432C1 (ru) 2001-12-21 2001-12-21 Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа

Publications (2)

Publication Number Publication Date
RU2210432C1 RU2210432C1 (ru) 2003-08-20
RU2001135572A true RU2001135572A (ru) 2004-02-27

Family

ID=20254993

Family Applications (1)

Application Number Title Priority Date Filing Date
RU2001135572/04A RU2210432C1 (ru) 2001-12-21 2001-12-21 Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа

Country Status (6)

Country Link
US (1) US20050032921A1 (ru)
EP (1) EP1457258A4 (ru)
AU (1) AU2002349609A1 (ru)
EA (1) EA006414B1 (ru)
RU (1) RU2210432C1 (ru)
WO (1) WO2003053568A1 (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101747160B (zh) * 2008-11-28 2013-06-05 中国石油化工股份有限公司 一种由合成气制备甲醇、二甲醚和低碳烯烃的方法
GB201018152D0 (en) 2010-10-27 2010-12-08 Johnson Matthey Plc Catalyst preparation method
GB201105571D0 (en) 2011-04-01 2011-05-18 Gas2 Ltd High pressure gas to liquid process
RU2455065C1 (ru) * 2011-06-02 2012-07-10 Федеральное государственное бюджетное учреждение науки Институт структурной макрокинетики и проблем материаловедения Российской академии наук Способ получения катализатора для синтеза высших углеводородов из со и н2 и катализатор, полученный этим способом
GB201112028D0 (en) 2011-07-13 2011-08-31 Gas2 Ltd Fixed bed fischer tropsch reactor

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2947609A (en) * 1958-01-06 1960-08-02 Gen Electric Diamond synthesis
US3317035A (en) * 1963-09-03 1967-05-02 Gen Electric Graphite-catalyst charge assembly for the preparation of diamond
US3697447A (en) * 1969-05-07 1972-10-10 Johns Manville Catalytic oxidation unit comprising a fluid permeable body of fibrous admixture
US4605679A (en) * 1981-10-13 1986-08-12 Chevron Research Company Activated cobalt catalyst and synthesis gas conversion using same
US4409131A (en) * 1982-02-22 1983-10-11 Maine Preparation of CoMo and NiMo catalyst using cobalt or nickel complexes that are stable in basic solution
NL8201696A (nl) * 1982-04-23 1983-11-16 Unilever Nv Werkwijze ter bereiding van methaneringskatalysatoren.
ZA848604B (en) * 1983-11-04 1985-06-26 Veg Gasinstituut Nv Process for the production of hydrogen
EP0148358B1 (de) * 1983-11-10 1991-04-03 KAT-TEC Gesellschaft für Katalysatortechnik mbH Katalysator zur Verbrennung und Umwandlung von Gasen und höheren Kohlenwasserstoffen, sowie Vorrichtung zur Reduktion von Stickoxiden und Abgasnachverbrenner mit einem solchen Katalysator
FR2556235A1 (fr) * 1983-12-09 1985-06-14 Pro Catalyse Procede de fabrication d'un catalyseur a base d'alumine
US4670475A (en) * 1984-06-29 1987-06-02 Exxon Research And Engineering Company Improved cobalt catalysts, and use thereof for Fischer-Tropsch synthesis
US5168219A (en) * 1988-10-31 1992-12-01 Fujitsu Limited Integrated circuit device having signal discrimination circuit and method of testing the same
GB9108657D0 (en) * 1991-04-23 1991-06-12 Shell Int Research Process for the preparation of hydrocarbons
US5169821A (en) * 1991-11-14 1992-12-08 Exxon Research And Engineering Company Method for stabilizing titania supported cobalt catalyst and the catalyst for use in Fischer-Tropsch process
GB9415554D0 (en) * 1994-08-02 1994-09-21 Unilever Plc Cobalt on alumina catalysts
FR2736650B1 (fr) * 1995-07-13 1997-09-05 Inst Francais Du Petrole Procede de conversion du gaz de synthese en phase liquide
NO313086B1 (no) * 1995-08-04 2002-08-12 Inst Francais Du Petrole Fremgangsmåte for fremstilling av en katalysator, katalysator som kan oppnås derved, katalysatorblanding oppnådd derved samtfremgangsmåte for syntese av hydrokarboner
IT1289579B1 (it) * 1997-01-30 1998-10-15 Agip Petroli Composizione catalitica utile nella reazione di fischer tropsch
GB2322633A (en) * 1997-02-28 1998-09-02 Norske Stats Oljeselskap Fischer-Tropsch reactor
AU2043400A (en) * 1998-12-07 2000-06-26 Syntroleum Corporation Structured fischer-tropsch catalyst system and method for its application

Also Published As

Publication number Publication date
EA006414B1 (ru) 2005-12-29
EA200400652A1 (ru) 2004-12-30
EP1457258A1 (en) 2004-09-15
US20050032921A1 (en) 2005-02-10
EP1457258A4 (en) 2009-12-23
AU2002349609A1 (en) 2003-07-09
WO2003053568A1 (fr) 2003-07-03
RU2210432C1 (ru) 2003-08-20

Similar Documents

Publication Publication Date Title
Lee et al. ZIF-8: A comparison of synthesis methods
Allahyari et al. Ultrasound assisted co-precipitation of nanostructured CuO–ZnO–Al2O3 over HZSM-5: effect of precursor and irradiation power on nanocatalyst properties and catalytic performance for direct syngas to DME
Zhu et al. Catalysis opportunities of atomically precise gold nanoclusters
CN104209021A (zh) 一种zif-8型金属-有机骨架材料改性的芳香族聚酰胺膜的制备方法
ATE469697T1 (de) Verfahren zur selektiven hydrierung von alkinen und dafür geeigneter katalysator
Schäferhans et al. Novel and effective copper–aluminum propane dehydrogenation catalysts
RU2003105236A (ru) Корочковый металлический катализатор и его предшественник, способ их получения, и применение катализатора
EP2343123A3 (en) METHOD FOR PREPARATION of a COMPOSITE OXIDE CATALYST
Baskaran et al. Catalytic mechanism and bonding analyses of Au-Pd single atom alloy (SAA): CO oxidation reaction
Agarwal et al. Selective hydrogenation of monoterpenes on Rhodium (0) nanoparticles stabilized in Montmorillonite K-10 clay
JP6855073B2 (ja) 多元系固溶体微粒子及びその製造方法並びに触媒
RU2001135572A (ru) Катализатор и способ получения углеводородов и их кислородсодержащих производных из синтез-газа
Du et al. Facile preparation of hierarchical titanium silicalite-1 (TS-1) with efficient oxidation of cyclic alkenes using PVA modified MWCNTs as templates
Pazos-Perez et al. Ultrasound driven formation of metal-supported nanocatalysts
WO2013114667A1 (ja) パラフィンの製造方法およびパラフィン製造装置
CN108079991A (zh) 一种准单分散的负载型纳米铜催化剂的制备方法及其应用
JP2008514420A5 (ru)
CA2828585C (en) Hydrogen production catalyst containing ni3si-based intermetallic compound, method for activating the catalyst, and hydrogen production method and device using the catalyst
Maheswari et al. Copper containing TUD-1: synthesis, characterization and catalytic behavior in liquid-phase oxidation of ethylbenzene
CN1164553C (zh) 一种醇类脱氢的工艺方法
Uysal et al. Catalytic activity of SBA-15-grafted indium tri-isopropoxide in chemoselective MPV reductions
Chen et al. Sonochemical fabrication and characterization of ceria (CeO2) nanowires
JPH0459048A (ja) 水蒸気改質用の触媒
Ballivet-Tkatchenko et al. High-temperature oxidation of LnCu2 intermetallics and their catalytic behavior in 4-methyl-2-pentanol decomposition
SU870393A1 (ru) Способ одновременного получени циклопентена и камфары

Legal Events

Date Code Title Description
MM4A The patent is invalid due to non-payment of fees

Effective date: 20111222