RU2001116591A - Composition of Metallic Ink for Fibrous Writing Instruments - Google Patents

Composition of Metallic Ink for Fibrous Writing Instruments

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Publication number
RU2001116591A
RU2001116591A RU2001116591/12A RU2001116591A RU2001116591A RU 2001116591 A RU2001116591 A RU 2001116591A RU 2001116591/12 A RU2001116591/12 A RU 2001116591/12A RU 2001116591 A RU2001116591 A RU 2001116591A RU 2001116591 A RU2001116591 A RU 2001116591A
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RU
Russia
Prior art keywords
writing instrument
ink composition
instrument according
aluminum
ink
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Application number
RU2001116591/12A
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Russian (ru)
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RU2224659C2 (en
Inventor
Чхман СУХНА
Чарлз РЕЙЧМАНН
Original Assignee
Дри Марк Продактс Инкорпорейтед
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Priority claimed from US09/416,359 external-priority patent/US6224284B1/en
Application filed by Дри Марк Продактс Инкорпорейтед filed Critical Дри Марк Продактс Инкорпорейтед
Publication of RU2001116591A publication Critical patent/RU2001116591A/en
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Publication of RU2224659C2 publication Critical patent/RU2224659C2/en

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Claims (20)

1. Пишущий инструмент, содержащий резервуар из плотноупакованного полиэфирного волокна и перо из пористого полиэфирного ориентированного волокна с каналами, обеспечивающими прохождение через него чернил, композицию чернил в резервуаре, которая включает цветную пигментированную дисперсию и алюминиевый пигмент с размерами частиц не более приблизительно 12 микрон, причем волокнистое перо соприкасается с резервуаром и способно поглощать алюминиевый пигмент в результате капиллярного действия.1. A writing instrument comprising a reservoir of close-packed polyester fiber and a feather of a porous oriented polyester fiber with channels to allow ink to pass through it, an ink composition in the reservoir, which includes a color pigmented dispersion and aluminum pigment with particle sizes of not more than about 12 microns, moreover the fiber pen is in contact with the reservoir and is capable of absorbing aluminum pigment as a result of capillary action. 2. Пишущий инструмент по п.1, содержащий вещество, препятствующее осаждению, для поддержания частиц алюминия во взвешенном состоянии, нелетучий увлажнитель, причем указанная цветная пигментированная дисперсия имеет частицы субмикронных размеров.2. The writing instrument according to claim 1, containing a substance that prevents deposition, to maintain aluminum particles in suspension, a non-volatile humidifier, and the specified color pigmented dispersion has particles of submicron sizes. 3. Пишущий инструмент по п.2, в котором указанная композиция чернил включает дистиллированную воду в качестве носителя в количестве примерно 40-70 вес.%, водорастворимый органический растворитель со скоростью испарения более 1,0 при температуре 25°С с использованием бутилацетата со скоростью испарения порядка 1,0 в качестве основного компонента; жидкий раствор акриловой смолы с содержанием сухого вещества порядка 40-50%, находящийся в композиции чернил в количестве примерно 10-20 вес.%, вышеупомянутый увлажнитель, выбранный из группы полигликолей с молекулярной массой 400-1025, в количестве примерно 5-15 вес.%, алюминиевую пигментированную дисперсию с содержанием сухого вещества примерно 10-15% с размерами частиц менее примерно 12 микрон в количестве 10-25 вес.% с рН приблизительно от 7,0 до 8,5, фтористое поверхностно-активное вещество с рН порядка 9,0 и поверхностным натяжением порядка 25 дин/см в количестве 0,25-1,0 вес.%, вещество, препятствующее осаждению, выбранное из ненасыщенных поликарбоновых кислот с низкой молекулярной массой и ионным зарядом, в количестве 0,25-1,25 вес.%, и аммиачное основание для регулирования рН композиции чернил до значений порядка 7,5-8,5 в количестве 0,25-1,5 вес.%, цветную пигментированную дисперсию на водной основе с содержанием сухого вещества порядка 35-45% и размерами частиц менее примерно 0,5 микрон в количестве 10-20 вес.%.3. The writing instrument according to claim 2, in which the specified ink composition includes distilled water as a carrier in an amount of about 40-70 wt.%, A water-soluble organic solvent with an evaporation rate of more than 1.0 at a temperature of 25 ° C using butyl acetate with a speed evaporation of the order of 1.0 as the main component; a liquid solution of acrylic resin with a dry matter content of about 40-50%, which is in the ink composition in an amount of about 10-20 wt.%, the aforementioned moisturizer selected from the group of polyglycols with a molecular weight of 400-1025, in an amount of about 5-15 weight. %, aluminum pigmented dispersion with a dry matter content of about 10-15% with particle sizes less than about 12 microns in an amount of 10-25 wt.% with a pH of from about 7.0 to 8.5, a fluoride surfactant with a pH of about 9 , 0 and surface tension of the order of 25 dyne / cm per count 0.25-1.0 wt.%, anti-precipitation substance selected from unsaturated polycarboxylic acids with a low molecular weight and ionic charge, in an amount of 0.25-1.25 wt.%, and an ammonia base for adjusting the pH of the composition ink up to values of the order of 7.5-8.5 in an amount of 0.25-1.5 wt.%, a water-based color pigmented dispersion with a dry matter content of about 35-45% and particle sizes less than about 0.5 microns in an amount 10-20 wt.%. 4. Пишущий инструмент по п.2, в котором указанная композиция чернил содержит одну фазу с вязкостью 5-10 сП, рН порядка 8-8,5 и поверхностным натяжением порядка 37 дин/см и обеспечивает нанесение плавной непрерывной непрозрачной "металлической" линии.4. The writing instrument according to claim 2, wherein said ink composition contains a single phase with a viscosity of 5-10 cP, a pH of about 8-8.5, and a surface tension of about 37 dyne / cm and provides a smooth, continuous, opaque "metallic" line. 5. Пишущий инструмент по п.2, в котором указанная композиция чернил включает связующее, представляющее собой раствор акриловой смолы в количестве порядка 10-25 вес.%, выбранный из группы или класса растворов акриловых смол с температурой стеклования -16-30°С, MFFT°С<25°С, вязкостью порядка 50-150 сП и содержанием сухого вещества 40-50%.5. The writing instrument according to claim 2, in which the specified ink composition includes a binder, which is a solution of acrylic resin in an amount of about 10-25 wt.%, Selected from the group or class of solutions of acrylic resins with a glass transition temperature of -16-30 ° C, MFFT ° C <25 ° C, a viscosity of about 50-150 cP and a dry matter content of 40-50%. 6. Пишущий инструмент по п.5, в котором указанное связующее образует при комнатной температуре светлую пленку и остается устойчивым при температурах 100-125°F в течение продолжительного времени, обеспечивая большую долговечность композиции чернил при хранении.6. The writing instrument according to claim 5, in which the specified binder forms a light film at room temperature and remains stable at temperatures of 100-125 ° F for a long time, providing greater durability of the ink composition during storage. 7. Пишущий инструмент по п.2, включающий связующее, содержащее поливинилпирролидоновый полимер в количестве порядка 1-2 вес.% для получения композиции металлосодержащих смываемых чернил с мокрым и/или сухим способом стирания, обеспечивающей возможность письма на черном и белом меламине, фарфоре и всевозможных непористых панелях.7. The writing instrument according to claim 2, comprising a binder containing polyvinylpyrrolidone polymer in an amount of about 1-2 wt.% To obtain a composition of metal-containing washable ink with a wet and / or dry erasure method, which allows writing on black and white melamine, porcelain and all kinds of non-porous panels. 8. Пишущий инструмент по п.2, в котором указанная композиция чернил содержит дисперсию на водной основе с алюминиевым пигментом, размеры частиц которой не превышают 12 микрон, полученную из блестящих чешуйчатых хлопьев алюминия.8. The writing instrument according to claim 2, in which said ink composition contains a water-based dispersion with aluminum pigment, the particle size of which does not exceed 12 microns, obtained from shiny flake aluminum flakes. 9. Пишущий инструмент по п.8, в котором указанный алюминий диспергирован в крахмально-водной среде для предотвращения осаждения, имеющей рН от 8,0 до 8,5 для предотвращения накопления газообразного водорода, причем дисперсия алюминия является устойчивой при температуре 100-125°F, обеспечивая предотвращение высыхания пишущего инструмента.9. The writing instrument of claim 8, wherein said aluminum is dispersed in a starch-aqueous medium to prevent precipitation having a pH of 8.0 to 8.5 to prevent the accumulation of hydrogen gas, wherein the aluminum dispersion is stable at a temperature of 100-125 ° F, providing prevention of drying of the writing instrument. 10. Пишущий инструмент по п.3, в котором указанная композиция чернил устойчива в слабощелочной среде и не взаимодействует с газообразным водородом, а указанное поверхностно-активное вещество обеспечивает уменьшение поверхностного натяжения и способствует протеканию чернил.10. The writing instrument according to claim 3, wherein said ink composition is stable in a slightly alkaline environment and does not interact with hydrogen gas, and said surfactant provides a reduction in surface tension and promotes ink flow. 11. Пишущий инструмент по п.2, в котором указанная композиция чернил включает в качестве вещества, препятствующего осаждению благодаря низкой молекулярной массе, ненасыщенную поликарбоновую кислоту с ионной активностью, которая связывается с алюминиевыми пигментами, удерживая их во взвешенном состоянии в течение длительного времени в композиции чернил низкой вязкости.11. The writing instrument according to claim 2, in which the ink composition includes, as a substance that prevents deposition due to low molecular weight, unsaturated polycarboxylic acid with ionic activity, which binds to aluminum pigments, keeping them suspended for a long time in the composition low viscosity ink. 12. Пишущий инструмент по п.2, в котором указанное вещество, препятствующее осаждению, повышает интенсивность цвета и предотвращает существенное осаждение алюминиевых пигментов.12. The writing instrument according to claim 2, in which the specified substance, preventing deposition, increases the color intensity and prevents substantial precipitation of aluminum pigments. 13. Пишущий инструмент по п.2, в котором указанная композиция чернил включает увлажнитель, выбранный из группы полигликолей с молекулярной массой от 400 до 1025.13. The writing instrument according to claim 2, wherein said ink composition includes a humectant selected from the group of polyglycols with a molecular weight of from 400 to 1025. 14. Пишущий инструмент по п.2, в котором указанная композиция чернил включает консервант для предотвращения появления грибов и бактерий в чернилах на водной основе, содержащий диазолидинил-мочевину, метилпарабен и пропилпарабен.14. The writing instrument of claim 2, wherein said ink composition includes a preservative to prevent the formation of fungi and bacteria in water-based inks containing diazolidinyl urea, methyl paraben and propyl paraben. 15. Пишущий инструмент по п.2, в котором указанная композиция чернил включает вещество, регулирующее рН в форме основания, обеспечивающий стабилизацию рН указанной композиции в пределах от 8,0 до 8,5.15. The writing instrument according to claim 2, in which the specified ink composition includes a substance that regulates the pH in the form of a base, providing stabilization of the pH of the specified composition in the range from 8.0 to 8.5. 16. Пишущий инструмент по п.2, включающий резервуар из полиэфирного волокна, который прочно связан со свернутой полипропиленовой пленкой, находящейся в тесном контакте с многоканальным пером из высокопористого ориентированного волокна, содержащим указанную композицию чернил, при этом указанная композиция чернил имеет вязкость 5-10 сП при температуре 25°С, поверхностное натяжение менее 40 дин/см при температуре 25°С и рН порядка 7,0-8,5, получения несмываемых и смываемых "металлических" линий на черных и белых поверхностях.16. The writing instrument according to claim 2, comprising a reservoir of polyester fiber, which is firmly bonded to a rolled polypropylene film in close contact with a multichannel pen of highly porous oriented fiber containing the specified ink composition, while the specified ink composition has a viscosity of 5-10 cP at a temperature of 25 ° C, a surface tension of less than 40 dyne / cm at a temperature of 25 ° C and a pH of about 7.0-8.5, to obtain indelible and washable "metal" lines on black and white surfaces. 17. Пишущий инструмент по п.2, обеспечивающий выполнение непрозрачных "металлических" линий на коже и ногтях человека, напоминающих временную татуировку, которые могут смываться мыльной водой.17. The writing instrument according to claim 2, providing the implementation of opaque "metallic" lines on the skin and nails of a person resembling a temporary tattoo that can be washed off with soapy water. 18. Пишущий инструмент, содержащий корпус неклапанного действия, образующий резервуар для чернил с отверстием, перекрываемым пером из волокнистого материала, композицию чернил в резервуаре, которая содержит дисперсию из алюминиевого пигмента с размерами частиц не более приблизительно 12 микрон, субмикронную пигментированную цветную водную дисперсию для придания цветового оттенка, вещество, препятствующее осаждению, для предотвращения осаждения частиц алюминия и связующее для обеспечения сцепления друг с другом алюминиевых пигментов.18. A writing instrument comprising a non-valve body, forming an ink tank with an opening covered by a pen of fibrous material, an ink composition in the tank that contains an aluminum pigment dispersion with a particle size of not more than about 12 microns, a submicron pigmented color aqueous dispersion to give hue, anti-precipitation agent to prevent the deposition of aluminum particles and a binder to adhere aluminum pigments to each other. 19. Пишущий инструмент по п.18, содержащий дополнительно консервант, поверхностно-активное вещество для уменьшения поверхностного натяжения и вещество, регулирующее рН.19. The writing instrument of claim 18, further comprising a preservative, a surfactant to reduce surface tension, and a pH adjusting agent. 20. Способ получения временных татуировок на коже человека, включающий этапы создания пишущего инструмента, содержащего резервуар из плотноупакованного полиэфирного волокна и перо из пористого полиэфирного ориентированного волокна с каналами, обеспечивающими прохождение через него чернил, а также композицию чернил в резервуаре, которая включает алюминиевый пигмент с размерами частиц не более приблизительно 12 микрон, причем волокнистое перо соприкасается с резервуаром и способно поглощать алюминиевый пигмент в результате капиллярного действия, и нажатия перемещаемым пишущим инструментом на кожу человека с целью получения временных татуировок, представляющих собой смываемые непрозрачные " металлические" линии.20. A method of obtaining temporary tattoos on human skin, which includes the steps of creating a writing instrument comprising a reservoir of close-packed polyester fiber and a feather made of porous oriented polyester fiber with channels allowing ink to pass through it, as well as an ink composition in the reservoir, which includes aluminum pigment with particle sizes of not more than about 12 microns, and the fibrous pen is in contact with the tank and is able to absorb aluminum pigment as a result of capillary of action, and pressing the movable writing instrument on human skin in order to obtain temporary tattoos, which are washed off by non-transparent 'metallic' line.
RU2001116591/12A 1999-10-12 2000-03-20 Recording instrument with fibrous rod containing a composition of metal-containing ink and its application RU2224659C2 (en)

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US09/416,359 US6224284B1 (en) 1999-10-12 1999-10-12 Metallic ink composition for wick type writing instruments
US09/416359 1999-10-12

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EP (1) EP1137545A1 (en)
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