CN107760104A - A kind of colour flash ink and preparation method thereof - Google Patents
A kind of colour flash ink and preparation method thereof Download PDFInfo
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- CN107760104A CN107760104A CN201711199262.5A CN201711199262A CN107760104A CN 107760104 A CN107760104 A CN 107760104A CN 201711199262 A CN201711199262 A CN 201711199262A CN 107760104 A CN107760104 A CN 107760104A
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- ink
- agent
- settling
- colour flash
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
- C09D11/17—Writing inks characterised by colouring agents
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of colour flash ink and preparation method thereof, ink composition includes by weight percentage：Dyestuff 0.3~7%, pearl essence 0.1~5%, resin 10~35%, anti-settling agent 1~8%, anti-settling auxiliary agent 0.08~1%, dispersant 0.1~6%, bleeding agent 0.08~1%, preservative 0.08~1%, surfactant 0.05~2%, lubricant 5~14%, water 30~80%.Preparation process：(1) resin, anti-settling agent, anti-settling auxiliary agent, dispersant, bleeding agent, preservative, surfactant, lubricant are added in reaction vessel, being stirred at room temperature makes it well mixed, obtains product 1.；(2) dyestuff and pearl essence dissolving are dispersed in water, obtain product 2., and 2. 1. product is added to product, stirred；Place 13 days, after foam all disappears.Thus, the formula of ink and craft science are reasonable, write and glisten functional, and ink color is various, are particularly suitable for the use of children's Writing-painting.
Description
Technical field
The present invention relates to stationery and ink, more particularly to a kind of colour flash ink and preparation method thereof, it is specifically
Various colour flash ink of a kind of color and preparation method thereof.
Background technology
Ink can be divided into dye ink and paint ink according to manufacturing theory.Paint ink be usually it is not soluble in water,
Often occur that ink blocks up the phenomenon of nib.Dye ink simple production process, cost price is low, is complete composite solution, and
Dye ink is water miscible, and ink blocks up the probability very little of nib.
At present, it is thus proposed that the concept of shiny inks, but without the shiny inks technology of preparing of maturation, our seminars
Set about the research of this project and propose the scheme of relative maturity.In terms of the ink is mainly used in children's Writing-painting, this
Not only color is various for invention, easily causes the interest of children, develops its intelligence；And it is easily dry, the back of paper will not be penetrated into, is saved
Paper.Pearl essence moderate in grain size that shiny inks use, lower current are smooth, and after being combined with dyestuff, flash effect is obvious.
The content of the invention
The purpose of the present invention is the problem of can not realizing flash of light for existing color inks, there is provided a kind of colour flash ink
Water and preparation method thereof.The ink not only wants fluent writing, does not block up nib, and color is various；And the writing write with the ink
Flash of light and it will not penetrate into the back of paper.
A kind of colour flash ink provided by the invention, component include by weight percentage：
The dyestuff be N- (4- ((4- (dimethylamino) phenyl) phenylmethylene) -2,5- cyclohexadiene -1- subunits) -
N- methyl-oxalate, ((4- (double (4- ((sulfophenyl) amino) phenyl) methylene) -2,5- cyclohexadiene -1- subunits) ammonia
Base) disodium salt, 4,4'- (3H-2,1- benzothiazole alcohol -3- subunits) two (2- methyl)-S, S- dioxide, N- (4- (4- (diethyls
Base amino) -2 aminomethyl phenyls)), 6- dimethylaminos -3,3- double (4- dimethylaminophenyls) phthalide, (4- (4- aminophenyls)
(4- imido butylcyclohexyl -2,5- dienylidenes) methyl) -2-aminotoluene hydrochloride, (4- ((4- lignocaines) phenyl) is sub- by N-
Methyl) -2,5 cyclohexadiene-subunit-N- ethyl second ammoniums sulfate, 5- ((3- carboxyl -5- methyl -4- oxo -2,5- hexamethylenes two
Alkene -1- subunits) (the chloro- 3- sulfo groups phenyl of 2,6- bis-) methyl) -2- hydroxy-3-methyls, N, N- dimethyl -4- (2- (2- (octyl group oxygen
Base) phenyl) -6- phenylpyridine -4- bases) double (4- the dimethylamino phenyls) -6- Dimethylaminobenzene peptides of aniline or 3,3-.
Further：
Described resin is water soluble acrylic acid or aqueous polyurethane.
Described anti-settling agent is water-based anti-settling agent, bentonite anti-settling agent or anti-settling thickener.
Described anti-settling auxiliary agent is guar gum.
Described dispersant is water-based wetting dispersing agent.
Described surfactant is neopelex, dodecyl sodium sulfate, lauryl sodium sulfate, 16
Alkyl trimethyl ammonium bromide, tween or this Pan.
Described lubricant is dimethicone, n-butyl stearate, stearic acid, atoleine, the poly- methyl of polyoxyethylene
Siloxanes or polyoxyethylene polyoxypropylene polymethyl siloxane；
Described water is secondary water.
The preparation method of colour flash ink, comprises the following steps：
(1) resin, anti-settling agent, anti-settling auxiliary agent, dispersant, surfactant, lubricant are added in reaction vessel,
Stirring makes it well mixed at room temperature, obtains product 1.；
(2) dyestuff and pearl essence dissolving are dispersed in water, obtain product 2., and 2. 1. product is added to product,
Stir；Place 1-3 days, after foam all disappears.
Compared with the prior art, ink of the invention, using pearl essence as flash of light material, is equipped with anti-settling using dyestuff as colouring agent
Agent, anti-settling auxiliary agent, dispersant, bleeding agent, preservative, surfactant, lubricant are prepared.The colour flash ink of the present invention
Water, moderate in grain size, flash effect are obvious；Handwriting can realize rapid draing, and will not permeate paper；The ink will not
Nib is blocked, is long placed in and does not produce precipitation；The ink color is various, easily causes the interest of children；The ink formulation technique is simple, former
Material is easy to get, cheap.
Embodiment
In following examples：
The green colouring material is that (4- ((4- (dimethylamino) phenyl) phenylmethylene) -2,5- cyclohexadiene -1- is sub- by N-
Base)-N- methyl-oxalate；
The dark blue dyes are ((4- (double (4- ((sulfophenyl) amino) phenyl) methylene) -2,5- cyclohexadiene -1-
Subunit) amino) disodium salt；
The orchil is 4,4'- (3H-2,1- benzothiazole alcohol -3- subunits) two (2- methyl)-S, S- dioxide；
The light blue dyestuff is N- (4- (aminomethyl phenyl of 4- (diethylamino) -2))；
The cudbear is double (4- dimethylaminophenyls) phthalides of 6- dimethylaminos -3,3-；
The orange is (4- (4- aminophenyls) (4- imido butylcyclohexyl -2,5- dienylidenes) methyl) -2- first
Base anilinechloride；
The light green color dyestuff is N- (4- ((4- lignocaines) phenyl) methylene) -2,5 cyclohexadiene-subunit-N- second
Base second ammonium sulfate；
The blood cyan dye is 5- ((3- carboxyl -5- methyl -4- oxo -2,5- cyclohexadiene -1- subunits) (2,6- bis-
Chloro- 3- sulfo groups phenyl) methyl) -2- hydroxy-3-methyls；
The golden yellow dyestuff is N, N- dimethyl -4- (2- (2- (octyl group epoxide) phenyl) -6- phenylpyridine -4- bases) benzene
Amine；
The light yellow dyestuff is double (4- the dimethylamino phenyls) -6- Dimethylaminobenzene peptides of 3,3-.
Embodiment 1
1st, a kind of writing green ink formula smooth, with flash of light：
2nd, preparation technology：Green colouring material and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；Then
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio, dress pen can use.
Embodiment 2
1st, a kind of writing navy blue ink set smooth, with flash of light：
2nd, preparation technology：Dark blue dyes and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；So
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio afterwards, dress pen can use.
Embodiment 3
1st, a kind of writing red ink formula smooth, with flash of light：
2nd, preparation technology：Orchil and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；Then
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio, dress pen can use.
Embodiment 4
1st, a kind of writing light blue ink set smooth, with flash of light：
2nd, preparation technology：Light blue dyestuff and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；Then
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio, dress pen can use.
Embodiment 5
1st, a kind of writing purple ink formula smooth, with flash of light：
2nd, preparation technology：Cudbear and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；Press again
Formula ratio adds other components, stirring, placement 2 day uniform to system in 1 hour, and dress pen can use.
Embodiment 6
1st, a kind of writing orange ink set smooth, with flash of light：
2nd, preparation technology：Orange and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；Then
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio, dress pen can use.
Embodiment 7
1st, a kind of writing light green ink formula smooth, with flash of light：
2nd, preparation technology：Light green color dyestuff and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；So
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio afterwards, dress pen can use.
Embodiment 8
1st, a kind of writing blood cyan formula smooth, with flash of light：
2nd, preparation technology：Blood cyan dye and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；So
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio afterwards, dress pen can use.
Embodiment 9
1st, a kind of writing golden yellow ink set smooth, with flash of light：
2nd, preparation technology：Golden yellow dyestuff and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；So
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio afterwards, dress pen can use.
Embodiment 10
1st, a kind of writing faint yellow ink set smooth, with flash of light：
2nd, preparation technology：Faint yellow dyestuff and pearl essence dissolving are scattered in secondary water, are placed in reaction vessel；So
Other components, stirring, placement 2 day uniform to system in 1 hour are added by formula ratio afterwards, dress pen can use.
Colour flash ink prepared by embodiment 1~10, moderate in grain size, flicker effect are obvious；Handwriting can be realized
Rapid draing, and paper will not be permeated；The ink will not block nib, be long placed in and do not produce precipitation；The ink color is various, easily
Cause the interest of children；The ink formulation technique is simple, and raw material is easy to get, cheap.
Claims (9)
1. a kind of colour flash ink, it is characterised in that component includes by weight percentage：
The dyestuff is N- (4- ((4- (dimethylamino) phenyl) phenylmethylene) -2,5- cyclohexadiene -1- subunits)-N- first
Base-oxalate, ((4- (double (4- ((sulfophenyl) amino) phenyl) methylene) -2,5- cyclohexadiene -1- subunits) amino) two
Sodium salt, 4,4'- (3H-2,1- benzothiazole alcohol -3- subunits) two (2- methyl)-S, S- dioxide, N- (4- (4- (diethyl aminos
Base) -2 aminomethyl phenyls)), double (4- dimethylaminophenyls) phthalides of 6- dimethylaminos -3,3-, ((4- is sub- by 4- (4- aminophenyls)
Aminocyclohexyl -2,5- dienylidenes) methyl) -2-aminotoluene hydrochloride, N- (4- ((4- lignocaines) phenyl) methylenes
Base) -2,5 cyclohexadiene-subunit-N- ethyl second ammoniums sulfate, 5- ((3- carboxyl -5- methyl -4- oxo -2,5- cyclohexadiene -
1- subunits) (the chloro- 3- sulfo groups phenyl of 2,6- bis-) methyl) -2- hydroxy-3-methyls, N, N- dimethyl -4- (2- (2- (octyl group epoxide)
Phenyl) -6- phenylpyridine -4- bases) double (4- the dimethylamino phenyls) -6- Dimethylaminobenzene peptides of aniline or 3,3-.
2. a kind of colour flash ink as claimed in claim 1, it is characterised in that described resin is water soluble acrylic acid, water
Property polyurethane.
A kind of 3. colour flash ink as claimed in claim 1, it is characterised in that described anti-settling agent be water-based anti-settling agent,
Bentonite anti-settling agent, anti-settling thickener.
4. a kind of colour flash ink as claimed in claim 1, it is characterised in that described anti-settling auxiliary agent is guar gum.
5. a kind of colour flash ink as claimed in claim 1, it is characterised in that described dispersant is water-based wetting and dispersing
Agent.
6. a kind of colour flash ink as claimed in claim 1, it is characterised in that described surfactant is dodecyl
Benzene sulfonic acid sodium salt, dodecyl sodium sulfate, lauryl sodium sulfate, cetyl trimethylammonium bromide, tween or this Pan.
A kind of 7. colour flash ink as claimed in claim 1, it is characterised in that described lubricant be dimethicone,
N-butyl stearate, stearic acid, atoleine, polyoxyethylene polymethyl siloxane or polyoxyethylene polyoxypropylene methyl polysilicone
Alkane.
8. a kind of colour flash ink as claimed in claim 1, it is characterised in that described water is secondary water.
9. a kind of preparation method of colour flash ink as claimed in claim 1, it is characterised in that comprise the following steps：(1)
Resin, anti-settling agent, anti-settling auxiliary agent, dispersant, bleeding agent, preservative, surfactant, lubricant are added to reaction vessel
In, being stirred at room temperature makes it well mixed, obtains product 1.；(2) dyestuff and pearl essence are dissolved and disperses in a solvent, to obtain
2. 2. 1. product, and is added to product by product, stir；Place 1-3 days, after foam all disappears.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711199262.5A CN107760104A (en) | 2017-11-26 | 2017-11-26 | A kind of colour flash ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711199262.5A CN107760104A (en) | 2017-11-26 | 2017-11-26 | A kind of colour flash ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107760104A true CN107760104A (en) | 2018-03-06 |
Family
ID=61275268
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711199262.5A Pending CN107760104A (en) | 2017-11-26 | 2017-11-26 | A kind of colour flash ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107760104A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504166A (en) * | 2018-12-29 | 2019-03-22 | 惠州市立美特环保油墨有限公司 | A kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink and preparation method thereof |
| CN111393904A (en) * | 2020-04-13 | 2020-07-10 | 肇庆斯塔文化用品有限公司 | Strongly flashing water-based paint ink for pens and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11193362A (en) * | 1997-12-29 | 1999-07-21 | Pentel Kk | Water-base glossy ink composition |
| CN1327418A (en) * | 1999-10-12 | 2001-12-19 | 德里马克产品股份有限公司 | Metallic ink composition for wick type writing instruments |
| CN104130626A (en) * | 2013-04-30 | 2014-11-05 | 雄狮铅笔厂股份有限公司 | Gold ink composition |
| CN104893420A (en) * | 2015-06-09 | 2015-09-09 | 山西大学 | Colored ink for light-colored teaching board and preparation method of colored ink |
-
2017
- 2017-11-26 CN CN201711199262.5A patent/CN107760104A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11193362A (en) * | 1997-12-29 | 1999-07-21 | Pentel Kk | Water-base glossy ink composition |
| CN1327418A (en) * | 1999-10-12 | 2001-12-19 | 德里马克产品股份有限公司 | Metallic ink composition for wick type writing instruments |
| CN104130626A (en) * | 2013-04-30 | 2014-11-05 | 雄狮铅笔厂股份有限公司 | Gold ink composition |
| CN104893420A (en) * | 2015-06-09 | 2015-09-09 | 山西大学 | Colored ink for light-colored teaching board and preparation method of colored ink |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109504166A (en) * | 2018-12-29 | 2019-03-22 | 惠州市立美特环保油墨有限公司 | A kind of cigarette-brand solidified by ultraviolet ray radiation pearly-lustre gold ink and preparation method thereof |
| CN111393904A (en) * | 2020-04-13 | 2020-07-10 | 肇庆斯塔文化用品有限公司 | Strongly flashing water-based paint ink for pens and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20180306 |