CN104130626A - Gold ink composition - Google Patents

Gold ink composition Download PDF

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Publication number
CN104130626A
CN104130626A CN201310756463.6A CN201310756463A CN104130626A CN 104130626 A CN104130626 A CN 104130626A CN 201310756463 A CN201310756463 A CN 201310756463A CN 104130626 A CN104130626 A CN 104130626A
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CN
China
Prior art keywords
composition
pigment
ink composition
pearlescence
additive
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CN201310756463.6A
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Chinese (zh)
Inventor
张鸿仁
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Lion Pencil Co Ltd
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Lion Pencil Co Ltd
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Publication of CN104130626A publication Critical patent/CN104130626A/en
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Abstract

The invention provides a gold ink composition. The gold ink composition comprises 80-95 parts by weight of an ink, 0.1-5 parts by weight of a first dispersant and 5-15 parts by weight of at least one additive, wherein the additive is a pearlescent pigment or a metallic pigment. The invention provides a gold ink composition suitable for writing on paper, which is a gold ink composition with higher variability, attracts more users to contact calligraphy, can enable the product to have higher economic benefit, and has positive significance for enterprises and consumers.

Description

Gold ink composition
Technical field
The invention relates to a kind of ink composition, and particularly relevant for a kind of golden ink composition.
Background technology
General common prepared Chinese ink be take black as main, although the prepared Chinese ink product of each family is still slightly different, is only deep or light difference, generally speaking still belongs to black, for user, have no attraction and interest not high.
Produce on the market a kind of gold lacquer, mostly be two bottled, one bottle is solvent, and another bottle is bronze, after solvent fully must being mixed with bronze, can use before use.Yet, because solvent-borne type is excessively strong to paper perviousness, result in that on paper, to write timeliness fruit not good.
In view of this, the utmost point needs a kind of golden ink composition in paper that is applicable to writing at present, and to improve above-mentioned problem, expectation can provide the golden ink composition that a variability is higher, attracts more user to contact calligraphy, to accord with the demands of the market.
Summary of the invention
For solving the problems of the technologies described above, the object of this invention is to provide a kind of golden ink composition.
For reaching above-mentioned purpose, the invention provides a kind of golden ink composition, one first dispersion agent of the prepared Chinese ink that its composition comprises 80 to 95 weight parts, 0.1 to 5 weight part and at least one additive of 5 to 15 weight parts, wherein, described additive is pearly pigment or metallic pigment.
According to the specific embodiment of the present invention, preferably, in above-mentioned golden ink composition, described pearly pigment is pearlescence or pearlite slurry.Pearlescence can be silver-coloured lustre powder, golden pearlescence, metallic color pearlescence, color pearl powder, variable color pearlescence or its combination.
According to the specific embodiment of the present invention, preferably, in above-mentioned golden ink composition, described metallic pigment can be the pigment after metal-powder or metal oxide processing.
According to the specific embodiment of the present invention, preferably, in above-mentioned golden ink composition, the particle size range of described additive is 2 to 2000 μ m.According to another embodiment of the present invention, preferably, the particle size range of described additive is 2 to 200 μ m.
According to the specific embodiment of the present invention, preferably, in above-mentioned golden ink composition, described the first dispersion agent is sodium sulfonate formaldehyde condensation products, the quaternary ammonium alkyl salt copolymer that contains acidic-group or multipolymer or its combination that contains pigment affinity group.
According to the specific embodiment of the present invention, preferably, in above-mentioned golden ink composition, described prepared Chinese ink comprises: one second dispersion agent of the water of 80 to 95 weight parts, 0.1 to 5 weight part and a black pigment of 5 to 15 weight parts.
According to the specific embodiment of the present invention, preferably, in above-mentioned golden ink composition, described the second dispersion agent is sodium sulfonate formaldehyde condensation products, the quaternary ammonium alkyl salt copolymer that contains acidic-group or multipolymer or its combination that contains pigment affinity group.
According to the specific embodiment of the present invention, preferably, in above-mentioned golden ink composition, described black pigment is carbon black pigment.
According to the specific embodiment of the present invention, preferably, above-mentioned golden ink composition more comprises sanitas, resin, defoamer, spices, dry preventing agent or its combination.
The present invention proposes a kind of golden ink composition in paper that is applicable to writing, it is the golden ink composition that a variability is higher, attracts more user to contact calligraphy, not only can make product possess higher economic benefit, for enterprise, human consumer, have more positive meaning.
Accompanying drawing explanation
For above and other objects of the present invention, feature, advantage and embodiment can be become apparent, appended graphic being described as follows:
Figure 1A is for to write the schematic diagram on a paper with the golden ink composition of an embodiment of the present invention.
Figure 1B is the cross-sectional view according to the a-a ' tangent line in Figure 1A.
Primary clustering nomenclature:
110: prepared Chinese ink
120: additive
A-a ': tangent line
Embodiment
In order to make the narration of disclosure of the present invention more detailed and complete, below for embodiments of the present invention and specific embodiment illustrative description has been proposed; But this not implements or uses unique form of the specific embodiment of the invention.In embodiment, contained the feature of a plurality of specific embodiments and method steps and its order with these specific embodiments of operation in order to construction.Yet, also can utilize other specific embodiment to reach identical or impartial function and step order.
In the following description, many specific detail will be described in detail so that reader can fully understand following embodiment.Yet, can without this type of specific detail in the situation that, put into practice embodiments of the invention.In other cases, be simplicity of illustration, the structure of knowing is only schematically illustrated in figure.
A prepared Chinese ink, one first dispersion agent of 0.1 to 5 weight part and at least one additive of 5 to 15 weight parts that gold ink composition comprises 80 to 95 weight parts, wherein additive is pearly pigment or metallic pigment.
For develop the golden ink composition that can write on paper, therefore adopt prepared Chinese ink as substrate.Because prepared Chinese ink belongs to water-based, different from solvent type gold lacquer, therefore cannot write on various surfaces, for example: stone material or metal, to write object be stationery to golden ink composition of the present invention.
Water, one second dispersion agent of 0.1 to 5 weight part and a black pigment of 5 to 15 weight parts that the composition of the prepared Chinese ink in gold ink composition comprises 80 to 95 weight parts.
The second above-mentioned dispersion agent can be sodium sulfonate formaldehyde condensation products, containing the quaternary ammonium alkyl salt copolymer of acidic-group or containing multipolymer or its combination of pigment affinity group.Black pigment can be carbon black pigment or other known black pigment.
Additive in gold ink composition can be pearly pigment or metallic pigment.Pearly pigment is that a kind of mica sheet is outer coated with metal oxide, can produce nacreous pigment, and outward appearance is powder transparent, flats, has the characteristics such as larger diameter, more smooth plane and higher refractive index than general pigment.Pearly pigment can be pearlescence or pearlite slurry.For instance, pearlescence can be silver-coloured lustre powder, golden pearlescence, metallic color pearlescence, color pearl powder, variable color pearlescence or its combination.
Metallic pigment can be the pigment after metal-powder or metal oxide processing.For instance, metallic pigment are aluminium powder or copper powder.Yet the kind of additive is not limited to pearly pigment and metallic pigment, the additive that allows this golden ink composition have more variability, interest of other kind all can be applicable to this.
The particle size range of additive is unsuitable excessive, and the feel while easily causing writing is not good, and in one embodiment, the particle size range of additive is 2 to 2000 μ m; In another embodiment, the particle size range of additive is 2 to 200 μ m.
Above-mentioned prepared Chinese ink can be considered a traditional prepared Chinese ink, and it comprises the second dispersion agent, has been a stable dispersion system, if additionally add other additive, will certainly destroy its balance, causes and assembles or the curing phenomenon generation of precipitation.Therefore add after other additive, need to select the first suitable dispersion agent, this first dispersion agent can carry out dissemination to the carbon black of prepared Chinese ink and other additive simultaneously, avoids gathering or precipitation to solidify phenomenon and produces.
In one embodiment, the first dispersion agent and the second dispersion agent are sodium sulfonate formaldehyde condensation products, the quaternary ammonium alkyl salt copolymer that contains acidic-group or multipolymer or its combination that contains pigment affinity group.The first above-mentioned dispersion agent and the kind of the second dispersion agent can be identical or different.
In another embodiment, golden ink composition more comprises sanitas, resin, defoamer, spices, dry preventing agent or its combination.When interpolation resin contributes to write, golden ink composition is attached on paper.After gold ink composition is loaded in container, easily rocked and produced bubble, making writing effect not good, therefore add defoamer to avoid Bubble formation.Spices kind is unrestricted, can add according to actual demand.
Use above-mentioned golden ink composition to try to write, write in paper such as writing paper made from bamboo, rice paper, cotton papers, please refer to Figure 1A, it writes the schematic diagram on a paper for the golden ink composition of an embodiment of the present invention.As shown in Figure 1A, according to golden ink composition of the present invention, this composition be take prepared Chinese ink 110 end of as, therefore can set off obviously eye-catching additive 120 colors.Figure 1B is the cross-sectional view according to the a-a ' tangent line in Figure 1A, and as shown in Figure 1B, prepared Chinese ink 110 is the end, and additive 120 close-packed arrays, on prepared Chinese ink 110, but are not limit by this; That is, can make additive 120 parts disperse to be sunken in prepared Chinese ink 110 according to kind and the ratio of dispersion agent, build specific grisaille painting effect.
Embodiment 1-3: golden ink composition
First prepare prepared Chinese ink, because prepared Chinese ink is long placed in, can produce precipitation, therefore need stir with stirrer before preparing golden ink composition.Above-mentioned prepared Chinese ink can be commercially available prepared Chinese ink, or with the recipe configuration prepared Chinese ink of table 1, in the present embodiment, uses commercially available prepared Chinese ink.
Table 1
Ink formulation Addition (weight part)
Water 78.500
Carbon black 5.850
Sodium sulfonate formaldehyde condensation products 0.500
Sanitas 0.085
Resin 2.550
Defoamer 0.018
Spices 0.003
Dry preventing agent 2.000
Then, please refer to the formula of the golden ink composition of the embodiment 1 to 3 shown in table 2, first get prepared Chinese ink 89.5g, slowly add pearly-lustre bronze 10g, finally add again dispersion agent 0.5g, wherein the dispersion agent in embodiment 1 is sodium sulfonate formaldehyde condensation products (model: Demol N, flower king (KAO Corporation)), dispersion agent in embodiment 2 is the quaternary ammonium alkyl salt copolymer (model: DISPERBYK180 containing acidic-group, BYK company) dispersion agent and in embodiment 3 is the multipolymer (model: DISPERBYK192 containing pigment affinity group, BYK company), then continue to stir the mixture approximately 30 minutes, can write in writing paper made from bamboo, on the paper such as rice paper or cotton paper.
Table 2
The golden ink composition of above-described embodiment 1 to 3 is carried out to viscosity, particle diameter test and rocks and stir rear sample state observation, and test result is as shown in table 3.The number of days that wherein circulates represents that golden ink composition makes the circulation weathering process institute that changes by a series of envrionment conditionss through number of days, and each circulation represents that golden ink composition is through 50 ℃ 6 hours, 23 ℃ 6 hours, 4 ℃ 6 hours ,-20 ℃ 6 hours, 23 ℃ 6 hours and 50 ℃ of envrionment conditionss of 6 hours.
Table 3
The viscosity test of gold ink composition is the viscosity of the upper clear solution of test, uses a viscosmeter, and imposing a condition is 25 ℃ and 3rpm, and after 3 minutes the value of reading, test result is as shown in table 3.Consider to write the comfort level of feel, the viscosity scope that is suitable for writing is 5 to 20cps, and too thick or too rare all can to cause writing feel not good, and it is not good to write rear effect yet.As shown in table 3, embodiment 1 to 3 circulate in the 0th day time, viscosity is respectively 8.07,9.7 and 9.4cps; The viscosity circulating after aging 45 days is respectively 9.15,10.6 and 11cps, shows that the viscosity of golden ink composition of the present invention all drops in the scope that is applicable to writing.
The test of particle diameter is to use particle size analyzer, grain diameter measurement result is depicted as after the integral distribution curve of particle diameter, gets the 10th, 50 and the particle diameter of 90 per-cents, and the median size of getting its whole particles.Wherein take be less than 40 μ m granular size as good.As shown in table 3, circulate the 0th day time, particle diameter is on average about 12 to 19 μ m; After circulation in 30 days, median size is approximately 18 to 20 μ m.This can show, the particle size range of golden ink composition of the present invention all falls within normal range, because causing particle obviously to assemble and precipitation after aging.
One superior in quality Jin Moqi must easily stir, and stirs or to rock rear foam too much unsuitable; And prolonged postpone, should not have the phenomenon of obvious multiviscosisty, and significantly particle accumulation produces.As shown in table 3, all there is not multiviscosisty in the aging front and back of golden ink composition of embodiments of the invention 1 to 3, and without obviously particle accumulation generation.Difference is that embodiment 1 easily stirs and foam is few, after aging 30 days, only become and be slightly difficult for stirring, but still foam is few; The aging front and back of embodiment 2 are all difficult for stirring, but foam is few; And embodiment 3 is difficult for stirring and foam is many.The golden ink composition of comparing embodiment 1 to 3, better with the effect of embodiment 1.
In addition, by embodiment 1 and 2, respectively at envrionment conditions, be in 50 ℃, 4 ℃ ,-20 ℃, 50 ℃ humidity 60% standing 45 days respectively, then analyze viscosity, the particle diameter of the golden ink composition under above-mentioned envrionment conditions and rock the sample state after stirring.Wherein the measuring result of embodiment 1 is as shown in table 4, and the measuring result of embodiment 2 is as shown in table 5.
Table 4
Table 5
Known via above-mentioned table 4 and table 5, embodiment 1 and 2 is in 50 ℃, 4 ℃ ,-20 ℃, 50 ℃ humidity 60% after standing 45 days respectively at envrionment conditions, the upper clear liquid body viscosity of embodiment 2 is a bit larger tham embodiment 1, the particle diameter of embodiment 1 is a bit larger tham embodiment 2, after embodiment 1 rocks and stirs, sample state is that easily stirring and foam are few, and embodiment 2 is difficult for stirring and foam volume increase after rocking stirring.Generally, after golden ink composition of the present invention is long placed under varying environment, its physical properties is not obviously affected.
The present invention proposes a kind of golden ink composition in paper that is applicable to writing, it is the golden ink composition that a variability is higher, attracts more user to contact calligraphy, not only can make product possess higher economic benefit, for enterprise, human consumer, have more positive meaning.
Although the present invention discloses as above with embodiment; so it is not in order to limit the present invention; without departing from the spirit and scope of the present invention, when being used for a variety of modifications and variations, so the scope that protection scope of the present invention is worked as with claims is as the criterion persons skilled in the art.

Claims (11)

1. a golden ink composition, comprises:
One prepared Chinese ink of 80 to 95 weight parts;
One first dispersion agent of 0.1 to 5 weight part; And
At least one additive of 5 to 15 weight parts, wherein, described additive is pearly pigment or metallic pigment.
2. composition as claimed in claim 1, wherein, described pearly pigment is pearlescence or pearlite slurry.
3. composition as claimed in claim 2, wherein, described pearlescence is silver-coloured lustre powder, golden pearlescence, metallic color pearlescence, color pearl powder, variable color pearlescence or its combination.
4. composition as claimed in claim 1, wherein, described metallic pigment are the pigment after metal-powder or metal oxide processing.
5. composition as claimed in claim 1, wherein, described the first dispersion agent is sodium sulfonate formaldehyde condensation products, containing the quaternary ammonium alkyl salt copolymer of acidic-group or containing multipolymer or its combination of pigment affinity group.
6. composition as claimed in claim 1, wherein, the particle size range of described additive is 2 to 2000 μ m.
7. composition as claimed in claim 6, wherein, the particle size range of described additive is 2 to 200 μ m.
8. composition as claimed in claim 1, wherein, described prepared Chinese ink comprises:
The water of 80 to 95 weight parts;
One second dispersion agent of 0.1 to 5 weight part; And
One black pigment of 5 to 15 weight parts.
9. composition as claimed in claim 8, wherein, described the second dispersion agent is sodium sulfonate formaldehyde condensation products, containing the quaternary ammonium alkyl salt copolymer of acidic-group or containing multipolymer or its combination of pigment affinity group.
10. composition as claimed in claim 8, wherein, described black pigment is carbon black pigment.
11. compositions as claimed in claim 1, it more comprises sanitas, resin, defoamer, spices, dry preventing agent or its combination.
CN201310756463.6A 2013-04-30 2013-12-31 Gold ink composition Pending CN104130626A (en)

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TW102115435A TW201441321A (en) 2013-04-30 2013-04-30 Gold ink composition

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107760104A (en) * 2017-11-26 2018-03-06 山西大学 A kind of colour flash ink and preparation method thereof
CN108297611A (en) * 2018-01-03 2018-07-20 张金忠 A method of on pure silk face fabric calligraphy is write with bronze silver powder
CN114574034A (en) * 2021-08-30 2022-06-03 廖双涛 Antioxidant and corrosion-resistant ink after writing

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CN102618121A (en) * 2012-03-23 2012-08-01 西安理工大学 Golden ball pen ink composition and preparation method thereof

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CN102391722A (en) * 2011-09-30 2012-03-28 郑州鸿盛数码科技股份有限公司 Ink with metal luster
CN102558961A (en) * 2011-12-22 2012-07-11 河南科技大学 Scrape-removable water-based ink for flexographic printing and preparation method thereof
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107760104A (en) * 2017-11-26 2018-03-06 山西大学 A kind of colour flash ink and preparation method thereof
CN108297611A (en) * 2018-01-03 2018-07-20 张金忠 A method of on pure silk face fabric calligraphy is write with bronze silver powder
CN114574034A (en) * 2021-08-30 2022-06-03 廖双涛 Antioxidant and corrosion-resistant ink after writing

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Application publication date: 20141105