CN102391722A - Ink with metal luster - Google Patents
Ink with metal luster Download PDFInfo
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- CN102391722A CN102391722A CN2011102978994A CN201110297899A CN102391722A CN 102391722 A CN102391722 A CN 102391722A CN 2011102978994 A CN2011102978994 A CN 2011102978994A CN 201110297899 A CN201110297899 A CN 201110297899A CN 102391722 A CN102391722 A CN 102391722A
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Abstract
The invention discloses ink with metal luster. The ink consists of the following components in percentage by weight: 2.0 to 15 percent of nano-scale metal pigment (D 90<200nm), 5 to 10 percent of dispersing agent, 10 to 20 percent of adhesion promoter, 5 to 20 percent of adhesive, 0.5 to 2 percent of surface tension regulator, 0.2 to 0.5 percent of fungicide, 0.2 to 0.5 percent of pH value regulator and the balance of deionized water. The ink with the metal luster is suitable for printing on a non-absorbing medium, and has excellent color fastness and quick drying property after printing; meanwhile, technical performance such as the stability, printing property and the like of the ink can meet the requirement of a light industry standard of China, namely QB/T 2730-2005.
Description
Technical field
The present invention relates to a kind of ink, more precisely, relate to the metalluster water-based jet ink of non-absorbent media such as a kind of suitable PVC, PP, PET, PU.
Background technology
Printed design person's writing space has been expanded in the appearance of metal ink, for printing industry has been opened up new thinking, is being applied in aspects such as tobacco bale, wine mark, industrial packaging, daily chemical products label, soft packaging at present, has improved the ornamental and aesthetics of product.But because the density of metallic pigment is big, so the metal ink particle precipitates gathering easily, particularly be applied on the digital ink-jet printing press, serious problems such as shower nozzle easily result in blockage.In addition; Water-based jet ink generally prints on the absorbency medium; Printing is inappropriate on non-absorbent media, and the metalluster ink is applied in the Printing industry, and the stability of ink, printing flexibility and colour fastness all should satisfy higher requirement.
Summary of the invention
The objective of the invention is to provides a kind of metalluster ink to deficiency of the prior art, has solved the metal ink particle effectively and has precipitated the accumulative problem easily, and be applicable to the printing on the non-absorbent media.
Technical scheme of the present invention is: a kind of metalluster ink, composed of the following components by weight percentage:
Nano level metal pigment 2.0-15%;
Dispersion agent 5-10%;
Adhesion promoter 10-20%;
Tackiness agent 5-20%;
Surface tension modifier 0.5-2%;
Sterilant 0.2-0.5%;
PH value regulator 0.2-0.5%;
Its surplus of deionized water;
Wherein, the D90＜200nm of nano-level pigment and ultraviolet isolating agent.
Preferably: said nano level metal pigment is selected from least a in argent, copper, aluminium, the zinc.
Preferably: said dispersion agent is the polyacrylate dispersant of modification.
Preferably: said adhesion promoter is one or more in diethylene glycol dimethyl ether, diethylene glycol ether, propylene glycol monomethyl ether, the n-propyl alcohol.
Preferably: said tackiness agent is at least a in urethane, the vinyl resin.
Preferably: said surface tension modifier is polyether-modified dimethyl silicone polymer surface promoting agent.
Preferably: said sterilant is a benzisothiazole ketone.
Preferably: said pH value regulator is one or more in sodium hydroxide, volatile caustic, the trolamine.
Metalluster ink of the present invention; Be applicable to the printing on the non-absorbent media; And having excellent colour fastness and quick-drying after the printing, technical features such as the stability of ink, printing meet the requirement of the light industry standard QB/T 2730-2005 of the People's Republic of China simultaneously.
Embodiment
Embodiment 1
A kind of metalluster ink; Composed of the following components according to weight percent: (D 90＜200nm) 15%, EFKA4800 (vapour Bagong department) 10%, diethylene glycol dimethyl ether 10%, vinyl resin 20%, BYK-348 (Bi Ke chemistry) 0.5%, benzisothiazole ketone 0.2%, trolamine 0.5%, all the other are deionized water to argent.After above component mixed,, can make a kind of metalluster ink through filtering.
Embodiment 2
A kind of metalluster ink; Composed of the following components according to weight percent: (D 90＜200nm) 10%, EFKA 4800 (vapour Bagong department) 8%, diethylene glycol ether 10%, vinyl resin 15%, BYK-348 (Bi Ke chemistry) 0.5%, benzisothiazole ketone 0.5%, trolamine 0.5%, all the other are deionized water to metallic copper.After above component mixed,, can make a kind of metalluster ink through filtering.
Embodiment 3
A kind of metalluster ink; Composed of the following components according to weight percent: (D 90＜200nm) 12%, EFKA 4800 (vapour Bagong department) 8%, diethylene glycol ether 10%, vinyl resin 15%, BYK-348 (Bi Ke chemistry) 0.5%, benzisothiazole ketone 0.4%, trolamine 0.4%, all the other are deionized water to metallic aluminium.After above component mixed,, can make a kind of metalluster ink through filtering.
Embodiment 4
A kind of metalluster ink; Composed of the following components according to weight percent: ((D 90＜200nm) 1%, EFKA4800 (vapour Bagong department) 5%, diethylene glycol ether 20%, urethane resin 5%, BYK-348 (Bi Ke chemistry) 0.2%, benzisothiazole ketone 0.2%, volatile caustic 0.2%, all the other are deionized water to metallic zinc for D 90＜200nm) 1%, metallic aluminium.After above component mixed,, can make a kind of metalluster ink through filtering.
Embodiment 5 (comparative example)
A kind of metalluster ink; Composed of the following components according to weight percent: plain metal copper 10%, EFKA 4800 (vapour Bagong department) 8%, diethylene glycol ether 10%, vinyl resin 15%, BYK-348 (Bi Ke chemistry) 0.5%, benzisothiazole ketone 0.5%, trolamine 0.5%, all the other are deionized water.After above component mixed,, can make a kind of metalluster ink through filtering.
Embodiment 6 (comparative example)
A kind of metalluster ink; Composed of the following components according to weight percent: plain metal aluminium 12%, EFKA 4800 (vapour Bagong department) 8%, diethylene glycol ether 10%, vinyl resin 15%, BYK-348 (Bi Ke chemistry) 0.5%, benzisothiazole ketone 0.4%, trolamine 0.4%, all the other are deionized water.After above component mixed,, can make a kind of metalluster ink through filtering.
Wherein EFKA 4800 (vapour Bagong department) is the polyacrylic ester of modification, uses as macromolecule dispersing agent; BYK-348 and BYK-345 (Bi Ke chemistry) are polyether-modified dimethyl silicone polymer surface promoting agent.
The digital printing water-based jet ink of gained is printed on EPSON 4880, and the printed product on different media is tested through each item colour fastness, result such as following table:
The test of printing fluency:
The metalluster ink of case study on implementation 1-4 and embodiment 5-6 is respectively printed 5 square metres of monochromatic color lumps on EPSON 4880 stamping machines, the printing test page or leaf is seen initial broken string situation; Room temperature condition is shut down after 7 days down, and the printing test page or leaf is seen the intermittent printing performance again.Print result such as following table:
Annotate: " ◎ " expression test sheets broken string is below 5, and fluency/intermittent printing performance is qualified.
" ● " expression test sheets breaks more than 5 fluency/intermittent printing performance inconsistency lattice.
Claims (8)
1. metalluster ink is characterized in that: composed of the following components by weight percentage:
Nano level metal pigment 2.0-15%;
Dispersion agent 5-10%;
Adhesion promoter 10-20%;
Tackiness agent 5-20%;
Surface tension modifier 0.5-2%;
Sterilant 0.2-0.5%;
PH value regulator 0.2-0.5%;
Its surplus of deionized water;
Wherein, the D90＜200nm of nano-level pigment and ultraviolet isolating agent.
2. metalluster ink according to claim 1 is characterized in that: said nano level metal pigment is selected from least a in argent, copper, aluminium, the zinc.
3. metalluster ink according to claim 1 is characterized in that: said dispersion agent is the polyacrylate dispersant of modification.
4. metalluster ink according to claim 1 is characterized in that: said adhesion promoter is one or more in diethylene glycol dimethyl ether, diethylene glycol ether, propylene glycol monomethyl ether, the n-propyl alcohol.
5. metalluster ink according to claim 1 is characterized in that: said tackiness agent is at least a in urethane, the vinyl resin.
6. metalluster ink according to claim 1 is characterized in that: said surface tension modifier is polyether-modified dimethyl silicone polymer surface promoting agent.
7. metalluster ink according to claim 1 is characterized in that: said sterilant is a benzisothiazole ketone.
8. metalluster ink according to claim 1 is characterized in that: said pH value regulator is one or more in sodium hydroxide, volatile caustic, the trolamine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102978994A CN102391722A (en) | 2011-09-30 | 2011-09-30 | Ink with metal luster |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102978994A CN102391722A (en) | 2011-09-30 | 2011-09-30 | Ink with metal luster |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102391722A true CN102391722A (en) | 2012-03-28 |
Family
ID=45859111
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102978994A Pending CN102391722A (en) | 2011-09-30 | 2011-09-30 | Ink with metal luster |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102391722A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694778A (en) * | 2013-12-11 | 2014-04-02 | 苏州谊恒印务有限公司 | Silver nano ink |
| CN104130626A (en) * | 2013-04-30 | 2014-11-05 | 雄狮铅笔厂股份有限公司 | Gold ink composition |
| CN104341855A (en) * | 2014-10-28 | 2015-02-11 | 成都纳硕科技有限公司 | High-toughness modified ultraviolet-curing water-based ink and manufacturing method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851445A (en) * | 2009-04-03 | 2010-10-06 | 陈祥 | Water-based jet ink composition |
| CN102108641A (en) * | 2011-01-12 | 2011-06-29 | 郑州鸿盛数码科技股份有限公司 | Digital printing active dye jet ink |
-
2011
- 2011-09-30 CN CN2011102978994A patent/CN102391722A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851445A (en) * | 2009-04-03 | 2010-10-06 | 陈祥 | Water-based jet ink composition |
| CN102108641A (en) * | 2011-01-12 | 2011-06-29 | 郑州鸿盛数码科技股份有限公司 | Digital printing active dye jet ink |
Non-Patent Citations (1)
| Title |
|---|
| 凌云星等: "《实用油墨技术指标南》", 30 November 2007 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130626A (en) * | 2013-04-30 | 2014-11-05 | 雄狮铅笔厂股份有限公司 | Gold ink composition |
| CN103694778A (en) * | 2013-12-11 | 2014-04-02 | 苏州谊恒印务有限公司 | Silver nano ink |
| CN104341855A (en) * | 2014-10-28 | 2015-02-11 | 成都纳硕科技有限公司 | High-toughness modified ultraviolet-curing water-based ink and manufacturing method thereof |
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| PB01 | Publication | ||
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| C12 | Rejection of a patent application after its publication | ||
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Application publication date: 20120328 |