CN107236356A - A kind of environment-friendly water-based printing-ink - Google Patents

A kind of environment-friendly water-based printing-ink Download PDF

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Publication number
CN107236356A
CN107236356A CN201710590708.0A CN201710590708A CN107236356A CN 107236356 A CN107236356 A CN 107236356A CN 201710590708 A CN201710590708 A CN 201710590708A CN 107236356 A CN107236356 A CN 107236356A
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CN
China
Prior art keywords
parts
water
environment
ink
based printing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710590708.0A
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Chinese (zh)
Inventor
蒋冬艳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Taicang Xin He Printing Packaging Co Ltd
Original Assignee
Taicang Xin He Printing Packaging Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Taicang Xin He Printing Packaging Co Ltd filed Critical Taicang Xin He Printing Packaging Co Ltd
Priority to CN201710590708.0A priority Critical patent/CN107236356A/en
Publication of CN107236356A publication Critical patent/CN107236356A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/08—Printing inks based on natural resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104—Polyesters
    • C09D11/105—Alkyd resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

Abstract

The invention discloses a kind of environment-friendly water-based printing-ink, including 20 30 parts of deionized water in parts by weight, 10 16 parts of polyalcohol, 8 12 parts of polyvinyl alcohol, 38 parts of aqueous rosin milk, 10 15 parts of aqueous alkide resin, 10 15 parts of water-based acrylic resin, 8 12 parts of water-compatible amino resin, 2 10 parts of aqueous polyamide resin, 0.1 2 parts of nano-aluminum hydroxide, 0.1 2 parts of sub-nano silica micro mist, 12 parts of defoamer, 24 parts of dispersant, 3 18 parts of pigment.The aqueous degree of the present patent application is high, and due to the reinforcing of nanometer and sub- nano material, is relatively specific for most behaviour in service, water-based ink printing quick-drying, coloring is good, preserves lasting, and than the more environmental protection of general water-based ink.

Description

A kind of environment-friendly water-based printing-ink
Technical field
The present invention relates to printing-ink field, more particularly to a kind of environment-friendly water-based printing-ink.
Background technology
Ink is to ensure one of very crucial factor of printing quality.The existing ink for being used to print always has various The problem of：Some ink contains benzene, ketones derivant, and environmental pollution is larger；Some ink adaptability is poor, for different Paper adhesive force it cannot be guaranteed that, or total adhesive force is not strong enough；Some ink combination properties are good, but composition toxicity is too big, to print Dataller people has chronic body harm.
For problem above, the characteristics of water-based ink has environmental protection in itself, and for the current water-based ink of retention property Beneficial environmental properties can decline, and in order to continue the beneficial environmental properties for strengthening water-based ink, constantly develop new raw material formula, more lumping weight Will.
The content of the invention
It is an object of the invention to provide a kind of environment-friendly water-based printing-ink, have on the basis of basic performance is kept, use Material is degradable all using environmentally friendly raw material, and pigment is also environmentally friendly composition, overcomes problems of the prior art.
In order to realize the above object the technical scheme is that：
A kind of environment-friendly water-based printing-ink, includes the component of following parts by weight：
20-30 parts of deionized water
10-16 parts of polyalcohol
8-12 parts of polyvinyl alcohol
Aqueous rosin milk 3-8 parts
10-15 parts of aqueous alkide resin
10-15 parts of water-based acrylic resin
8-12 parts of water-compatible amino resin
2-10 parts of aqueous polyamide resin
0.1-2 parts of nano-aluminum hydroxide
0.1-2 parts of sub-nano silica micro mist
1-2 parts of defoamer
2-4 parts of dispersant
3-18 parts of pigment.
Preferably, the polyalcohol is the composition of ethylene glycol and glycerine, and its ratio is 2 ~ 3:1.
Preferably, ratio of the sub-nano silica grain size of micropowder in the range of 100 ~ 400nm of interval is more than 95%.
Preferably, the particle diameter of the nano-aluminum hydroxide is in 60 ~ 200nm.
Preferably, the molecular weight of the polyvinyl alcohol is in 20000-80000.
Preferably, the pigment is carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, iron oxide red In one kind or its combination.
The beneficial effects of the present invention are：Environmental protection of the invention, high-performance.Formula all components be it is aqueous, without phenyl ring, The noxious materials such as ketone；Nano-aluminum hydroxide and sub-nano silica micro mist have special effect, make ink colorant finer and smoother, are difficult Scatter, overcome the weakness of water-based ink；Pigment is also environmental protection, and black, white, blue, green, red cooperation can meet most of printings The use requirement of color.The aqueous degree of the present patent application is high, and due to the reinforcing of nanometer and sub- nano material, is relatively specific for big Most behaviours in service, water-based ink printing quick-drying, coloring is good, preserves lasting and more more green than general water-based ink Environmental protection.
Embodiment
In order to illustrate more clearly of the embodiment of the present application or technical scheme of the prior art, letter will be made to embodiment below Singly introduce.
Embodiment 1
A kind of environment-friendly water-based printing-ink, includes the component of following parts by weight：
25 parts of deionized water
10 parts of polyalcohol
8 parts of polyvinyl alcohol
Aqueous 3 parts of rosin milk
12 parts of aqueous alkide resin
11 parts of water-based acrylic resin
10 parts of water-compatible amino resin
2 parts of aqueous polyamide resin
2 parts of nano-aluminum hydroxide
0.9 part of sub-nano silica micro mist
1.5 parts of defoamer
2 parts of dispersant
3 parts of pigment；
The polyalcohol is the composition of ethylene glycol and glycerine, and its ratio is 2:1；The sub-nano silica grain size of micropowder is in area Between ratio in the range of 100 ~ 400nm more than 95%；The particle diameter of the nano-aluminum hydroxide is in 60 ~ 200nm；The polyvinyl alcohol Molecular weight in 20000-80000；The pigment is carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, oxygen Change one kind in iron oxide red or its combination.
Experiment shows that the water-based ink quick-drying, coloring are good, and attachment fastness is high and for a long time colour-fast.
Embodiment 2
A kind of environment-friendly water-based printing-ink, includes the component of following parts by weight：
20 parts of deionized water
12 parts of polyalcohol
12 parts of polyvinyl alcohol
Aqueous 8 parts of rosin milk
15 parts of aqueous alkide resin
10 parts of water-based acrylic resin
8 parts of water-compatible amino resin
10 parts of aqueous polyamide resin
0.1 part of nano-aluminum hydroxide
2 parts of sub-nano silica micro mist
2 parts of defoamer
3 parts of dispersant
18 parts of pigment；
The polyalcohol is the composition of ethylene glycol and glycerine, and its ratio is 3:1；The sub-nano silica grain size of micropowder is in area Between ratio in the range of 100 ~ 400nm more than 95%；The particle diameter of the nano-aluminum hydroxide is in 60 ~ 200nm；The polyvinyl alcohol Molecular weight in 20000-80000；The pigment is carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, oxygen Change one kind in iron oxide red or its combination.
Experiment shows that the water-based ink quick-drying, coloring are good, and attachment fastness is high and for a long time colour-fast.
Embodiment 3
A kind of environment-friendly water-based printing-ink, includes the component of following parts by weight：
30 parts of deionized water
16 parts of polyalcohol
11 parts of polyvinyl alcohol
Aqueous 6 parts of rosin milk
10 parts of aqueous alkide resin
15 parts of water-based acrylic resin
12 parts of water-compatible amino resin
6 parts of aqueous polyamide resin
0.7 part of nano-aluminum hydroxide
0.1 part of sub-nano silica micro mist
1 part of defoamer
4 parts of dispersant
12 parts of pigment；
The polyalcohol is the composition of ethylene glycol and glycerine, and its ratio is 2:1；The sub-nano silica grain size of micropowder is in area Between ratio in the range of 100 ~ 400nm more than 95%；The particle diameter of the nano-aluminum hydroxide is in 60 ~ 200nm；The polyvinyl alcohol Molecular weight in 20000-80000；The pigment is carbon black, titanium dioxide, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, oxygen Change one kind in iron oxide red or its combination.
Experiment shows that the water-based ink quick-drying, coloring are good, and attachment fastness is high and for a long time colour-fast.
Above example is only to illustrate the preferred technical solution of the present invention, it is noted that for the general of the art For logical technical staff, under the premise without departing from the principles of the invention, some improvement made or equivalent substitution are accordingly to be regarded as this The protection domain of invention, should cover in scope of the presently claimed invention.

Claims (6)

1. a kind of environment-friendly water-based printing-ink, it is characterised in that include the component of following parts by weight：
20-30 parts of deionized water
10-16 parts of polyalcohol
8-12 parts of polyvinyl alcohol
Aqueous rosin milk 3-8 parts
10-15 parts of aqueous alkide resin
10-15 parts of water-based acrylic resin
8-12 parts of water-compatible amino resin
2-10 parts of aqueous polyamide resin
0.1-2 parts of nano-aluminum hydroxide
0.1-2 parts of sub-nano silica micro mist
1-2 parts of defoamer
2-4 parts of dispersant
3-18 parts of pigment.
2. a kind of environment-friendly water-based printing-ink according to claim 1, it is characterised in that the polyalcohol be ethylene glycol and The composition of glycerine, and its ratio is 2 ~ 3:1.
3. a kind of environment-friendly water-based printing-ink according to claim 1, it is characterised in that the sub-nano silica grain size of micropowder Ratio in the range of 100 ~ 400nm of interval is more than 95%.
4. a kind of environment-friendly water-based printing-ink according to claim 1, it is characterised in that the grain of the nano-aluminum hydroxide Footpath is in 60 ~ 200nm.
5. a kind of environment-friendly water-based printing-ink according to claim 1, it is characterised in that the molecular weight of the polyvinyl alcohol In 20000-80000.
6. a kind of environment-friendly water-based printing-ink according to claim 1, it is characterised in that the pigment is carbon black, titanium white Powder, ferric tannate, tannic acid ferrous iron, cobalt green, copper naphthenate, one kind in iron oxide red or its combination.
CN201710590708.0A 2017-07-19 2017-07-19 A kind of environment-friendly water-based printing-ink Pending CN107236356A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710590708.0A CN107236356A (en) 2017-07-19 2017-07-19 A kind of environment-friendly water-based printing-ink

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CN107236356A true CN107236356A (en) 2017-10-10

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107903710A (en) * 2017-12-25 2018-04-13 洛阳名力科技开发有限公司 A kind of environmental protection black ink and preparation method thereof
CN108102494A (en) * 2017-12-28 2018-06-01 安徽鑫铂铝业股份有限公司 A kind of aluminium section bar of corrosion resistant anti-pollution
CN109135420A (en) * 2018-06-25 2019-01-04 太原理工大学 A kind of rapid-curing cutback direct-liquid type water-based ink
CN110204958A (en) * 2019-07-08 2019-09-06 东莞职业技术学院 Environment-friendly water-based printing ink of one kind and preparation method thereof
CN111785157A (en) * 2020-07-17 2020-10-16 武汉世帝牧文化传媒有限公司 Anti-counterfeit label
CN112409841A (en) * 2020-08-03 2021-02-26 南通旭浩数码科技有限公司 Environment-friendly antibacterial thermal transfer ink

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104312287A (en) * 2014-10-13 2015-01-28 北京印刷学院 Pure water type plastic gravure white printing oil and preparation method thereof
CN105400285A (en) * 2015-12-29 2016-03-16 广东天龙油墨集团股份有限公司 High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104312287A (en) * 2014-10-13 2015-01-28 北京印刷学院 Pure water type plastic gravure white printing oil and preparation method thereof
CN105400285A (en) * 2015-12-29 2016-03-16 广东天龙油墨集团股份有限公司 High-weatherability water-borne printing ink for PVC wallpaper and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107903710A (en) * 2017-12-25 2018-04-13 洛阳名力科技开发有限公司 A kind of environmental protection black ink and preparation method thereof
CN108102494A (en) * 2017-12-28 2018-06-01 安徽鑫铂铝业股份有限公司 A kind of aluminium section bar of corrosion resistant anti-pollution
CN108102494B (en) * 2017-12-28 2020-08-21 安徽鑫铂铝业股份有限公司 Corrosion-resistant anti-fouling aluminum profile
CN109135420A (en) * 2018-06-25 2019-01-04 太原理工大学 A kind of rapid-curing cutback direct-liquid type water-based ink
CN109135420B (en) * 2018-06-25 2021-11-19 太原理工大学 Quick-drying direct-liquid type water-based ink
CN110204958A (en) * 2019-07-08 2019-09-06 东莞职业技术学院 Environment-friendly water-based printing ink of one kind and preparation method thereof
CN111785157A (en) * 2020-07-17 2020-10-16 武汉世帝牧文化传媒有限公司 Anti-counterfeit label
CN112409841A (en) * 2020-08-03 2021-02-26 南通旭浩数码科技有限公司 Environment-friendly antibacterial thermal transfer ink

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Application publication date: 20171010

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