CN107903710A - A kind of environmental protection black ink and preparation method thereof - Google Patents
A kind of environmental protection black ink and preparation method thereof Download PDFInfo
- Publication number
- CN107903710A CN107903710A CN201711422111.1A CN201711422111A CN107903710A CN 107903710 A CN107903710 A CN 107903710A CN 201711422111 A CN201711422111 A CN 201711422111A CN 107903710 A CN107903710 A CN 107903710A
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- parts
- ferrous
- black ink
- acid
- thickener
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/16—Writing inks
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A kind of environmental protection black ink, is made of the raw material of following parts by weight：Tannic acid is 2 10 parts ferrous, gallic acid is 0.5 5 parts ferrous, 15 parts of oxalic acid, 13 parts of glycerine, 10 20 parts of thickener, 16 parts of alkyl glycosides, 15 parts of citrus extracts, 15 parts of methyl sodiosul foaliphatate, 18 parts of polytetrafluoroethylene powder, 30 50 parts of deionized water.The invention also provides a kind of method for preparing above-mentioned ink.By above-mentioned technical proposal, the present invention provides safe and nontoxic, fluent writing environmentally friendly black ink.
Description
Technical field
The invention belongs to inks field, more particularly to a kind of environmentally friendly black ink.
Background technology
Containing some chemical substances to human injury in the formula of existing ink, and the ink marks of most of pigment catches clothing
Not easy cleaning after clothes.Carbon black ink is the most popular black ink of present fountain pen, and main colorant is carbon black, and carbon black is
Organic matter imperfect combustion or the product of cracking, main component are carbon, are a kind of not hydrophilic black powders, ink can not be made
Water, it is necessary to which, through handling or adding the auxiliary agent with specific function, and since water solid content is generally higher, its is not soluble in water not to have yet
There is self-dispersing, place easily produce layering and precipitation for a long time, written blocking is also be easy to cause, to solve the problems, such as such lead to
Dispersant, stabilizer, suspending agent, emulsifying agent etc. can be often added, carbon black disperseed in water steadily in the long term, suspended, adds work
The complexity and cost of skill.Carbon black ink generally there are writing it is not smooth, if interval write if be easy to block pen tool.In addition,
After black ink accidentally stays in color on clothes now, not easy cleaning.Pollution-free is basic demand of the modern society to ink,
Therefore poisonous and corrosive elements to be reduced to the greatest extent in the formula of ink.This major embodiment is from organic solvent type to more environmentally friendly
The water-based ink development of theory.Therefore, a kind of environmental protection of invention, be not easy to plug pen tool, catch clothes after easy cleaning and of low cost
New black ink be extremely necessary.
The content of the invention
It is an object of the present invention to overcome existing ink there are the defects of, there is provided a kind of environmental protection, green, fluent writing
Environment-friendlyink ink.
The object of the invention to solve the technical problems is realized using following technical scheme.According to proposed by the present invention
A kind of environmental protection black ink, is made of the raw material of following parts by weight：2-10 parts of tannic acid ferrous iron, 0.5-5 parts of gallic acid ferrous iron,
1-5 parts of oxalic acid, 1-3 parts of glycerine, 10-20 parts of thickener, 1-6 parts of alkyl glycosides, 1-5 parts of citrus extracts, fatty acid methyl ester
1-5 parts of sodium sulfonate, 1-8 parts of polytetrafluoroethylene powder, 30-50 parts of deionized water.
Preferably, a kind of environmentally friendly black ink includes the following raw material according to mass fraction meter：Tannic acid ferrous iron 8
Part, 3 parts of gallic acid ferrous iron, 3 parts of oxalic acid, 2 parts of glycerine, 15 parts of thickener, 5 parts of alkyl glycosides, 3 parts of citrus extracts, fat
4 parts of fatty acid methyl esters sodium sulfonate, 5 parts of polytetrafluoroethylene powder, 40 parts of deionized water.
The preparation method of the environmentally friendly black ink is as follows：The deionized water for accounting for total amount half of preparation is added
In reaction kettle, water temperature in kettle is set to be maintained at 50~60 DEG C, stirring lower ferrous tannic acid, gallic acid ferrous iron, the oxalic acid of adding makes its complete
After fully dissolved, glycerine, methyl sodiosul foaliphatate, alkyl glycosides, polytetrafluoroethylene powder are sequentially added, stirring homogeneous 30~
50min, is eventually adding deionized water, citrus extracts and the thickener of surplus, is further continued for 10~20min of stirring, is down to room temperature,
Stand, filtering, that is, obtain product.
By above-mentioned technical proposal, the present invention does not have toxicity and corrosivity compared with prior art, using rear degradable.This
The invention thickener comes from one kind in starch, gelatin, agar, guar gum, sodium alginate, and thickener used is natural
Thickener, to human body and environmentally friendly.The alkyl glycosides of the present invention is synthesized by renewable resource natural fat alcohol and glucose
, it is a kind of more comprehensive new non-ionic surfactants of performance.It has conventional nonionic and anion surfactant concurrently
Characteristic, there is high surface, good ecological security and intermiscibility, be internationally recognized preferred " green " feature table
Face activating agent, therefore when ink stays in clothing accidentally, be readily cleaned, and its waste water will not pollute water quality.It is of the present invention
Citrus extracts have the function that anti-oxidant, antisepsis and sterilization.Methyl sodiosul foaliphatate is synthesized from natural plant grease, temperature
With it is safe and non-toxic, be a kind of excellent novel environment friendly surfactant of scourability, have good dispersiveness, emulsibility, increasing
Dissolubility.The polytetrafluoroethylene powder of the present invention has excellent chemical stability, corrosion resistance, leakproofness, high lubrication non-stick, electricity
Insulating properties and good anti-aging endurance, polytetrafluoroethylene (PTFE) is nonhygroscopic, non-ignitable, to oxygen, the equal stabilizer pole of ultraviolet, so with excellent
Different weatherability, and nonhazardous, the raw material as ink so that ink fluent writing is durable, and performance is stablized, and will not block pen
Head.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, and
It can be practiced according to the content of specification, and to allow the above and other objects, features and advantages of the present invention can be brighter
It is aobvious understandable, described in detail below especially exemplified by preferred embodiment.
Embodiment
Further to illustrate the present invention to reach the technological means and effect that predetermined goal of the invention is taken, below in conjunction with
Preferred embodiment, to according to a kind of its embodiment of environmentally friendly black ink, structure, feature and its work(proposed by the present invention
Effect, describes in detail as after.
A kind of environmental protection black ink, is made of the raw material of following parts by weight：2-10 parts of tannic acid ferrous iron, gallic acid are ferrous
0.5-5 parts, 1-5 parts of oxalic acid, 1-3 parts of glycerine, 10-20 parts of thickener, 1-6 parts of alkyl glycosides, 1-5 parts of citrus extracts, fat
1-5 parts of fatty acid methyl esters sodium sulfonate, 1-8 parts of polytetrafluoroethylene powder, 30-50 parts of deionized water.
Preferably, a kind of environmentally friendly black ink includes the following raw material according to mass fraction meter：Tannic acid ferrous iron 8
Part, 3 parts of gallic acid ferrous iron, 3 parts of oxalic acid, 2 parts of glycerine, 15 parts of thickener, 5 parts of alkyl glycosides, 3 parts of citrus extracts, fat
4 parts of fatty acid methyl esters sodium sulfonate, 5 parts of polytetrafluoroethylene powder, 40 parts of deionized water.
The preparation method of the environmentally friendly black ink is as follows：The deionized water for accounting for total amount half of preparation is added
In reaction kettle, water temperature in kettle is set to be maintained at 50~60 DEG C, stirring lower ferrous tannic acid, gallic acid ferrous iron, the oxalic acid of adding makes its complete
After fully dissolved, glycerine, methyl sodiosul foaliphatate, alkyl glycosides, polytetrafluoroethylene powder are sequentially added, stirring homogeneous 30~
50min, is eventually adding deionized water, citrus extracts and the thickener of surplus, is further continued for 10~20min of stirring, is down to room temperature,
Stand, filtering, that is, obtain product.
The above described is only a preferred embodiment of the present invention, any person skilled in the art is not departing from
In the range of technical solution of the present invention, the technical spirit according to the present invention is to any simple modification made for any of the above embodiments, equivalent
Change and modification, in the range of still falling within technical solution of the present invention.
Claims (3)
1. a kind of environmental protection black ink, it is characterised in that be made of the raw material of following parts by weight：2-10 parts of tannic acid ferrous iron, nutgall
Sour 0.5-5 parts of ferrous iron, 1-5 parts of oxalic acid, 1-3 parts of glycerine, 10-20 parts of thickener, 1-6 parts of alkyl glycosides, citrus extracts 1-5
Part, 1-5 parts of methyl sodiosul foaliphatate, 1-8 parts of polytetrafluoroethylene powder, 30-50 parts of deionized water.
2. a kind of environmentally friendly black ink according to claim 1, it is characterised in that including according to the as follows of mass fraction meter
Raw material：Tannic acid is 8 parts ferrous, gallic acid is 3 parts ferrous, 3 parts of oxalic acid, 2 parts of glycerine, 15 parts of thickener, 5 parts of alkyl glycosides, mandarin orange
3 parts of tangerine extract, 4 parts of methyl sodiosul foaliphatate, 5 parts of polytetrafluoroethylene powder, 40 parts of deionized water.
3. the preparation method of environmental protection black ink as claimed in claim 1 is as follows：Preparation is accounted for into going for total amount half
Ionized water is added in reaction kettle, water temperature in kettle is maintained at 50~60 DEG C, addition tannic acid is ferrous under stirring, gallic acid is ferrous,
After oxalic acid is completely dissolved it, glycerine, methyl sodiosul foaliphatate, alkyl glycosides, polytetrafluoroethylene powder are sequentially added, is stirred
Homogeneous 30~50mi n are mixed, deionized water, citrus extracts and the thickener of surplus is eventually adding, is further continued for 10~20mi of stirring
N, is down to room temperature, stands, and filtering, that is, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711422111.1A CN107903710A (en) | 2017-12-25 | 2017-12-25 | A kind of environmental protection black ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711422111.1A CN107903710A (en) | 2017-12-25 | 2017-12-25 | A kind of environmental protection black ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107903710A true CN107903710A (en) | 2018-04-13 |
Family
ID=61871164
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711422111.1A Pending CN107903710A (en) | 2017-12-25 | 2017-12-25 | A kind of environmental protection black ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107903710A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102268206A (en) * | 2011-06-17 | 2011-12-07 | 杭州华大海天科技有限公司 | Black ink for gel-ink pen and preparation method thereof |
| CN102925006A (en) * | 2012-11-23 | 2013-02-13 | 重庆市秀峰教学设备有限公司 | Ink and preparation method thereof |
| CN104592811A (en) * | 2015-02-04 | 2015-05-06 | 韦棋 | Environment-friendly black ink |
| CN107236356A (en) * | 2017-07-19 | 2017-10-10 | 太仓市鑫鹤印刷包装有限公司 | A kind of environment-friendly water-based printing-ink |
-
2017
- 2017-12-25 CN CN201711422111.1A patent/CN107903710A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102268206A (en) * | 2011-06-17 | 2011-12-07 | 杭州华大海天科技有限公司 | Black ink for gel-ink pen and preparation method thereof |
| CN102925006A (en) * | 2012-11-23 | 2013-02-13 | 重庆市秀峰教学设备有限公司 | Ink and preparation method thereof |
| CN104592811A (en) * | 2015-02-04 | 2015-05-06 | 韦棋 | Environment-friendly black ink |
| CN107236356A (en) * | 2017-07-19 | 2017-10-10 | 太仓市鑫鹤印刷包装有限公司 | A kind of environment-friendly water-based printing-ink |
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180413 |
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| WD01 | Invention patent application deemed withdrawn after publication |