RU2000129669A - METHOD FOR PAPER MANUFACTURE - Google Patents
METHOD FOR PAPER MANUFACTUREInfo
- Publication number
- RU2000129669A RU2000129669A RU2000129669/12A RU2000129669A RU2000129669A RU 2000129669 A RU2000129669 A RU 2000129669A RU 2000129669/12 A RU2000129669/12 A RU 2000129669/12A RU 2000129669 A RU2000129669 A RU 2000129669A RU 2000129669 A RU2000129669 A RU 2000129669A
- Authority
- RU
- Russia
- Prior art keywords
- carbon atoms
- cationic
- hydrophobic group
- polymer
- group
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims 3
- 125000004432 carbon atoms Chemical group C* 0.000 claims 32
- 125000002091 cationic group Chemical group 0.000 claims 26
- 125000001165 hydrophobic group Chemical group 0.000 claims 23
- 125000003118 aryl group Chemical group 0.000 claims 19
- 239000001257 hydrogen Substances 0.000 claims 17
- 229910052739 hydrogen Inorganic materials 0.000 claims 17
- 239000000178 monomer Substances 0.000 claims 17
- 125000000217 alkyl group Chemical group 0.000 claims 16
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 16
- 229920000642 polymer Polymers 0.000 claims 13
- 229910052760 oxygen Inorganic materials 0.000 claims 12
- 239000001301 oxygen Substances 0.000 claims 12
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims 12
- 229920000620 organic polymer Polymers 0.000 claims 11
- 125000002947 alkylene group Chemical group 0.000 claims 10
- 125000001424 substituent group Chemical group 0.000 claims 9
- 239000000725 suspension Substances 0.000 claims 9
- 229920002554 vinyl polymer Polymers 0.000 claims 8
- 125000000129 anionic group Chemical group 0.000 claims 7
- DOKHEARVIDLSFF-UHFFFAOYSA-N prop-1-en-1-ol Chemical group CC=CO DOKHEARVIDLSFF-UHFFFAOYSA-N 0.000 claims 7
- HRPVXLWXLXDGHG-UHFFFAOYSA-N acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 5
- 229910052757 nitrogen Inorganic materials 0.000 claims 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 238000006297 dehydration reaction Methods 0.000 claims 3
- 239000000835 fiber Substances 0.000 claims 3
- 230000014759 maintenance of location Effects 0.000 claims 3
- 239000000463 material Substances 0.000 claims 3
- 239000000203 mixture Substances 0.000 claims 3
- 125000004429 atoms Chemical group 0.000 claims 2
- 239000000945 filler Substances 0.000 claims 2
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 2
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims 2
- 238000000465 moulding Methods 0.000 claims 2
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 2
- HWKQNAWCHQMZHK-UHFFFAOYSA-N Trolnitrate Chemical compound [O-][N+](=O)OCCN(CCO[N+]([O-])=O)CCO[N+]([O-])=O HWKQNAWCHQMZHK-UHFFFAOYSA-N 0.000 claims 1
- 125000002029 aromatic hydrocarbon group Chemical group 0.000 claims 1
- 239000000440 bentonite Substances 0.000 claims 1
- 229910000278 bentonite Inorganic materials 0.000 claims 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- 239000002245 particle Substances 0.000 claims 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 claims 1
- 125000000286 phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 claims 1
- 238000004064 recycling Methods 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000012239 silicon dioxide Nutrition 0.000 claims 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
Claims (25)
где радикал R1 означает водород или СН3; каждый из радикалов R2 и R3 представляет собой водород или алкильную группу, содержащую от 1 до 3 атомов углерода; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 8 атомов углерода, или гидроксипропиленовую группу; R4 представляет собой заместитель, содержащий неароматическую гидрофобную группу, содержащую от 3 до 12 атомов углерода; и X- означает анионный противоион; (ii) неионного мономера, содержащего неароматическую гидрофобную группу, описываемого общей формулой (IV):
где R1 представляет собой водород или СН3; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 8 атомов углерода, или гидроксипропиленовую группу, или А и В не имеют никаких значений, при этом между С и N находится простая связь (O= С-NR8R9); каждый из радикалов R8 и R9 означает водород или заместитель, содержащий неароматическую гидрофобную группу, содержащую от 1 до 6 атомов углерода, по крайней мере, один из радикалов R8 и R9, является заместителем, содержащим гидрофобную группу, имеющую от 2 до 6 атомов углерода; и (iii) неионного мономера, содержащего неароматическую гидрофобную группу, описываемого общей формулой (V):
где R1 представляет водород или СН3; А означает кислород или NH; В представляет собой алкиленовую группу, содержащую от 2 до 4 атомов углерода; n - целое число не меньше 1; R10 представляет собой заместитель, содержащий гидрофобную группу, имеющую не менее 2 атомов углерода.2. A method of manufacturing paper from a suspension containing cellulosic fibers and optional excipients, comprising adding dehydration and retention agents to this suspension, including a cationic organic polymer and anionic micronized material, molding and dewatering the suspension on a grid, characterized in that the cationic organic polymer contains in the polymerized form, one or more monomers comprising at least one monomer containing a non-aromatic hydrophobic group selected from (i) a cation monomer containing a non-aromatic hydrophobic group and described by the general formula (I):
where the radical R 1 means hydrogen or CH 3 ; each of the radicals R 2 and R 3 represents hydrogen or an alkyl group containing from 1 to 3 carbon atoms; A means oxygen or NH; B represents an alkylene group containing from 2 to 8 carbon atoms, or a hydroxypropylene group; R 4 is a substituent containing a non-aromatic hydrophobic group containing from 3 to 12 carbon atoms; and X is an anionic counterion; (ii) a non-ionic monomer containing a non-aromatic hydrophobic group described by the general formula (IV):
where R 1 represents hydrogen or CH 3 ; A means oxygen or NH; B represents an alkylene group containing from 2 to 8 carbon atoms, or a hydroxypropylene group, or A and B have no meaning, while there is a simple bond between C and N (O = C — NR 8 R 9 ); each of the radicals R 8 and R 9 means hydrogen or a substituent containing a non-aromatic hydrophobic group containing from 1 to 6 carbon atoms, at least one of the radicals R 8 and R 9 is a substituent containing a hydrophobic group having from 2 to 6 carbon atoms; and (iii) a non-ionic monomer containing a non-aromatic hydrophobic group described by the general formula (V):
where R 1 represents hydrogen or CH 3 ; A means oxygen or NH; B represents an alkylene group containing from 2 to 4 carbon atoms; n is an integer of at least 1; R 10 is a substituent containing a hydrophobic group having at least 2 carbon atoms.
где радикал R1 представляет собой водород или СН3; каждый из радикалов R2 и R3 представляет алкильную группу, содержащую от 1 до 2 атомов углерода; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 4 атомов углерода, или гидроксипропиленовую группу; R4 означает заместитель, содержащий алкильную группу, содержащую от 4 до 8 атомов углерода; и Х- означает анионный противоион.7. The method according to any one of the preceding paragraphs, characterized in that the cationic organic polymer includes in a polymerized form a cationic monomer containing a non-aromatic hydrophobic group described by the general formula (1):
where the radical R 1 represents hydrogen or CH 3 ; each of the radicals R 2 and R 3 represents an alkyl group containing from 1 to 2 carbon atoms; A means oxygen or NH; B represents an alkylene group containing from 2 to 4 carbon atoms, or a hydroxypropylene group; R 4 means a substituent containing an alkyl group containing from 4 to 8 carbon atoms; and X - means anionic counterion.
где радикал R1 представляет собой водород или СН3; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 4 атомов углерода, или гидроксипропиленовую группу или, наоборот, А и В не означают ничего, при этом между С и N расположена простая связь (O= С-NR8R9); каждый из радикалов R8 и R9 представляет собой водород или заместитель, содержащий алкильную группу, содержащую от 1 до 6 атомов углерода, по крайней мере, один из радикалов R8 и R9 является заместителем, содержащим алкильную группу, имеющую от 3 до 4 атомов углерода.8. The method according to any one of the preceding paragraphs, characterized in that the cationic organic polymer comprises in a polymerized form a non-ionic monomer containing a non-aromatic hydrophobic group described by the general formula (IV):
where the radical R 1 represents hydrogen or CH 3 ; A means oxygen or NH; B represents an alkylene group containing from 2 to 4 carbon atoms, or a hydroxypropylene group, or, conversely, A and B do not mean anything, while there is a simple bond between C and N (O = C-NR 8 R 9 ); each of the radicals R 8 and R 9 represents hydrogen or a substituent containing an alkyl group containing from 1 to 6 carbon atoms, at least one of the radicals R 8 and R 9 is a substituent containing an alkyl group having from 3 to 4 carbon atoms.
где радикал R1 представляет собой водород или СН3; А означает кислород; В представляет алкиленовую группу, содержащую от 2 до 4 атомов углерода; n - целое число не меньше 1; радикал R10 представляет собой алкил, имеющий не менее 2 атомов углерода.9. The method according to any one of the preceding paragraphs, characterized in that the cationic organic polymer comprises in a polymerized form a non-ionic monomer containing a non-aromatic hydrophobic group described by the general formula (V):
where the radical R 1 represents hydrogen or CH 3 ; A means oxygen; B represents an alkylene group containing from 2 to 4 carbon atoms; n is an integer of at least 1; the radical R 10 represents alkyl having at least 2 carbon atoms.
где радикал R1 представляет собой водород или СН3; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 4 атомов углерода, или гидроксипропиленовую группу или, наоборот, А и В не означают ничего, при этом между С и N расположена простая связь (O= С-NR8R9) ; каждый из радикалов R8 и R9 представляет собой водород или заместитель, содержащий алкильную группу, имеющую от 1 до 6 атомов углерода, и, по меньшей мере, один из радикалов R8 и R9 представляет собой заместитель, содержащий алкильную группу, имеющую от 2 до 6 атомов углерода.20. The cationic vinyl polymer accession according to any one of paragraphs. 16-19, characterized in that the cationic vinyl addition polymer includes in a polymerized form a non-ionic monomer containing a non-aromatic hydrophobic group described by the general formula (IV):
where the radical R 1 represents hydrogen or CH 3 ; A means oxygen or NH; B represents an alkylene group containing from 2 to 4 carbon atoms, or a hydroxypropylene group, or, conversely, A and B do not mean anything, while there is a simple bond between C and N (O = C-NR 8 R 9 ); each of the radicals R 8 and R 9 represents hydrogen or a substituent containing an alkyl group having from 1 to 6 carbon atoms, and at least one of the radicals R 8 and R 9 represents a substituent containing an alkyl group having from 2 to 6 carbon atoms.
где радикал R1 представляет собой водород или СН3; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 4 атомов углерода; n - целое число не меньше 1; радикал R10 представляет собой алкил, содержащий не меньше 2 атомов углерода.21. Cationic vinyl polymer accession according to any one of paragraphs. 16-20, characterized in that the cationic vinyl addition polymer includes in a polymerized form a nonionic monomer containing a non-aromatic hydrophobic group described by the general formula (V):
where the radical R 1 represents hydrogen or CH 3 ; A means oxygen or NH; B represents an alkylene group containing from 2 to 4 carbon atoms; n is an integer of at least 1; the radical R 10 is an alkyl containing at least 2 carbon atoms.
где радикал R1 представляет собой водород или СН3; каждый из радикалов R2 и R3 означает водород или алкильную группу, содержащую от 1 до 3 атомов углерода; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 4 атомов углерода, или гидроксипропиленовую группу; R4 представляет собой неароматическую углеводородную группу, содержащую от 4 до 8 атомов углерода; и X- представляет собой анионный противоион.23. Cationic vinyl polymer accession according to any one of paragraphs. 16-22, characterized in that the cationic vinyl addition polymer includes, in a polymerized form, a cationic monomer described by the general formula (I):
where the radical R 1 represents hydrogen or CH 3 ; each of the radicals R 2 and R 3 means hydrogen or an alkyl group containing from 1 to 3 carbon atoms; A means oxygen or NH; B represents an alkylene group containing from 2 to 4 carbon atoms, or a hydroxypropylene group; R 4 represents a non-aromatic hydrocarbon group containing from 4 to 8 carbon atoms; and X - represents an anionic counterion.
где радикал R1 представляет собой водород или СН3; каждый из радикалов R2 и R3 представляет собой водород или алкильную группу, содержащую от 1 до 3 атомов углерода, приемлемо от 1 до 2 атомов углерода; А означает кислород или NH; В представляет алкиленовую группу, содержащую от 2 до 8 атомов углерода, приемлемо от 2 до 4 атомов углерода, или гидроксипропиленовую группу; радикал R7 представляет собой водород, алкильную группу, содержащую от 1 до 3 атомов углерода, бензильную группу или фенилэтильную группу; и X- означает анионный противоион.24. Cationic vinyl polymer accession according to any one of paragraphs. 16-23, characterized in that the cationic vinyl addition polymer includes, in a polymerized form, a cationic monomer described by the general formula (III):
where the radical R 1 represents hydrogen or CH 3 ; each of the radicals R 2 and R 3 represents hydrogen or an alkyl group containing from 1 to 3 carbon atoms, suitably from 1 to 2 carbon atoms; A means oxygen or NH; B represents an alkylene group containing from 2 to 8 carbon atoms, suitably from 2 to 4 carbon atoms, or a hydroxypropylene group; the radical R 7 represents hydrogen, an alkyl group containing from 1 to 3 carbon atoms, a benzyl group or a phenylethyl group; and X - means anionic counterion.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US8325398P | 1998-04-27 | 1998-04-27 | |
| US60/083,253 | 1998-04-27 | ||
| EP98850067.4 | 1998-04-27 | ||
| EP98850067A EP0953680A1 (en) | 1998-04-27 | 1998-04-27 | A process for the production of paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2194818C2 RU2194818C2 (en) | 2002-12-20 |
| RU2000129669A true RU2000129669A (en) | 2003-01-10 |
Family
ID=8236970
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2000129670/12A RU2185470C1 (en) | 1998-04-27 | 1999-04-26 | Paper manufacture process |
| RU2000129668/12A RU2194106C2 (en) | 1998-04-27 | 1999-04-26 | Paper manufacturing process |
| RU2000129669/12A RU2194818C2 (en) | 1998-04-27 | 1999-04-26 | Paper manufacture process |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2000129670/12A RU2185470C1 (en) | 1998-04-27 | 1999-04-26 | Paper manufacture process |
| RU2000129668/12A RU2194106C2 (en) | 1998-04-27 | 1999-04-26 | Paper manufacturing process |
Country Status (18)
| Country | Link |
|---|---|
| EP (4) | EP0953680A1 (en) |
| JP (3) | JP4307721B2 (en) |
| CN (3) | CN1155754C (en) |
| AT (3) | ATE257530T1 (en) |
| AU (3) | AU750335B2 (en) |
| BR (3) | BR9909945B1 (en) |
| CA (3) | CA2329027C (en) |
| CZ (3) | CZ20003937A3 (en) |
| DE (3) | DE69914078T2 (en) |
| DK (3) | DK1084295T3 (en) |
| ES (3) | ES2196815T3 (en) |
| ID (3) | ID27307A (en) |
| NZ (3) | NZ507604A (en) |
| PL (3) | PL200673B1 (en) |
| PT (3) | PT1080271E (en) |
| RU (3) | RU2185470C1 (en) |
| WO (3) | WO1999055965A1 (en) |
| ZA (3) | ZA200005552B (en) |
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|---|---|---|---|---|
| KR100403840B1 (en) * | 1998-04-27 | 2003-11-01 | 악조 노벨 엔.브이. | A process for the production of paper |
| US6417268B1 (en) | 1999-12-06 | 2002-07-09 | Hercules Incorporated | Method for making hydrophobically associative polymers, methods of use and compositions |
| MX255774B (en) † | 2000-08-07 | 2008-03-31 | Akzo Nobel Nv | A process for the production of paper. |
| US6918995B2 (en) | 2000-08-07 | 2005-07-19 | Akzo Nobel N.V. | Process for the production of paper |
| GB0019415D0 (en) * | 2000-08-09 | 2000-09-27 | Ciba Spec Chem Water Treat Ltd | Noval monomers, polymers thereof and the use of the polymers |
| WO2002025013A1 (en) | 2000-09-20 | 2002-03-28 | Akzo Nobel N.V. | A process for the production of paper |
| DE10113998A1 (en) * | 2001-03-22 | 2002-09-26 | Voith Paper Patent Gmbh | Method for loading fibers contained in a fiber suspension with an auxiliary |
| MXPA04005533A (en) * | 2001-12-21 | 2004-09-13 | Akzo Nobel Nv | Aqueous silica-containing composition and process for production of paper. |
| US7156955B2 (en) * | 2001-12-21 | 2007-01-02 | Akzo Nobel N.V. | Papermaking process using a specified NSF to silica-based particle ratio |
| PL214002B1 (en) * | 2002-01-31 | 2013-06-28 | Akzo Nobel Nv | Process for manufacturing paper |
| CA2500545A1 (en) * | 2002-10-01 | 2004-04-15 | Akzo Nobel N.V. | Cationised polysaccharide product |
| US20040084162A1 (en) | 2002-11-06 | 2004-05-06 | Shannon Thomas Gerard | Low slough tissue products and method for making same |
| US7303654B2 (en) | 2002-11-19 | 2007-12-04 | Akzo Nobel N.V. | Cellulosic product and process for its production |
| BR0316393A (en) * | 2002-11-19 | 2005-09-27 | Akzo Nobel Nv | Cellulosic product and process for its production |
| JP4179913B2 (en) * | 2003-03-31 | 2008-11-12 | ソマール株式会社 | Paper manufacturing method |
| KR20050058785A (en) * | 2003-12-12 | 2005-06-17 | 김재봉 | Introduction and manufacturing method of bentonite involving dispersion polymer |
| AU2005231671B2 (en) * | 2004-04-07 | 2008-08-07 | Akzo Nobel Chemicals International B.V. | Silica-based sols and their production and use |
| GB0425101D0 (en) * | 2004-11-15 | 2004-12-15 | Ciba Spec Chem Water Treat Ltd | Papermaking process |
| BRPI0515831B1 (en) * | 2004-12-22 | 2017-03-28 | Akzo Nobel Nv | process for paper production |
| US7955473B2 (en) | 2004-12-22 | 2011-06-07 | Akzo Nobel N.V. | Process for the production of paper |
| US20060254464A1 (en) | 2005-05-16 | 2006-11-16 | Akzo Nobel N.V. | Process for the production of paper |
| US8273216B2 (en) | 2005-12-30 | 2012-09-25 | Akzo Nobel N.V. | Process for the production of paper |
| PT1969183E (en) | 2005-12-30 | 2015-03-06 | Akzo Nobel Nv | A process for the production of paper |
| CA2581898A1 (en) * | 2006-03-17 | 2007-09-17 | Weyerhaeuser Company | Method for making a low density multi-ply paperboard with high internal bond strength |
| EP1936032A1 (en) | 2006-12-18 | 2008-06-25 | Akzo Nobel N.V. | Method of producing a paper product |
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| WO2011113119A1 (en) | 2010-03-19 | 2011-09-22 | Fibria Celulose S/A | Process for the treatment of cellulose pulps, cellulose pulp thus obtained and use of biopolymer for treating cellulose pulps |
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1998
- 1998-04-27 EP EP98850067A patent/EP0953680A1/en not_active Withdrawn
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1999
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