RU1838317C - Способ получени силанового соединени - Google Patents
Способ получени силанового соединениInfo
- Publication number
- RU1838317C RU1838317C SU884355285A SU4355285A RU1838317C RU 1838317 C RU1838317 C RU 1838317C SU 884355285 A SU884355285 A SU 884355285A SU 4355285 A SU4355285 A SU 4355285A RU 1838317 C RU1838317 C RU 1838317C
- Authority
- RU
- Russia
- Prior art keywords
- silane compound
- compound synthesis
- reagent
- organic solvent
- alkylcyclohexyl
- Prior art date
Links
- 238000000034 method Methods 0.000 title description 3
- 229910000077 silane Inorganic materials 0.000 title description 2
- -1 silane compound Chemical class 0.000 title description 2
- 230000015572 biosynthetic process Effects 0.000 title 1
- 238000003786 synthesis reaction Methods 0.000 title 1
- 239000003960 organic solvent Substances 0.000 abstract description 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000005037 alkyl phenyl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 229910052759 nickel Inorganic materials 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N hexane Substances CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/0801—General processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/18—Compounds having one or more C—Si linkages as well as one or more C—O—Si linkages
- C07F7/1804—Compounds having Si-O-C linkages
- C07F7/1872—Preparation; Treatments not provided for in C07F7/20
- C07F7/1892—Preparation; Treatments not provided for in C07F7/20 by reactions not provided for in C07F7/1876 - C07F7/1888
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Сущность изобретени : продукт-Х- SlRi,R2,R3, где Х-циклогексил, алкилцикло- гексил, содержащий от 6 до 20 атомов углерода. Р1Р2-одинаковые или разные ал- кил Ci-Cao Ra-X, RL Реагент 1: соединение Y-SIRi.Ra.Ra, где RiRa - как указано выше, , Y; Y-фенил, алкилфенил Се-С20. Реагент 2: Н2. Услови реакции: NIRe, модифицированный Сг в количестве 2-5 мас.% относительно NI. Органический растворитель , 84-107°С. 10-60 бао. 2 табл.
Description
/ X - S-J- R,
.
R-,ю
где X - циклогексил, Се-С20-алкилциклогек- сил;
RI и R2 - одинаковые или разные Ci- 15 Сао-алкил, С1-С20-алкоксил;
или RI,
путем гидрировани соответствующего силанового соединени общей формулы20
где Ri, R2 - как указано выше;
Ra RI или Y;
Y - фенил, Сб-Сго-элкилфенил, водородом в присутствии никелевого катализатора Рене в среде органического растворител при повышенной температуре и давлении, отличающийс тем, что, с целью увеличени выхода целевого продукта, в качестве никелевого катализатора Рене используют никель Рене , модифицированный хромом, в количестве 2-5 мас.% относительно никел .
2. Способ по п.1, отличающийс тем, что процесс ведут при температуре 84- 107°С, давлении 10-60 бар ив качестве органического растворител используют Н-гексан или циклогексан.
Таблице 1
Таблица 2
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT8741003A IT1210319B (it) | 1987-03-06 | 1987-03-06 | Composto silanico o silossanico con processo per la produzione di untenente almeno un anello cicloalchilico |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| RU1838317C true RU1838317C (ru) | 1993-08-30 |
Family
ID=11250015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU884355285A RU1838317C (ru) | 1987-03-06 | 1988-03-04 | Способ получени силанового соединени |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4956484A (ru) |
| EP (1) | EP0281425A3 (ru) |
| JP (1) | JPS63230694A (ru) |
| KR (1) | KR880011053A (ru) |
| AU (1) | AU602196B2 (ru) |
| BR (1) | BR8800934A (ru) |
| CA (1) | CA1305716C (ru) |
| FI (1) | FI87788C (ru) |
| IL (1) | IL85610A (ru) |
| IT (1) | IT1210319B (ru) |
| NO (1) | NO880993L (ru) |
| RU (1) | RU1838317C (ru) |
| ZA (1) | ZA881455B (ru) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1341025C (en) * | 1987-05-08 | 2000-06-13 | Daniel Schirlin | Substituted silyl alkylene amines |
| IT1210321B (it) * | 1987-06-05 | 1989-09-14 | Donegani Guido Ist | Processo per la produzione di un composto silanico o silossanico contenente almeno un anello cicloalchilico |
| JPH03115335A (ja) * | 1989-09-28 | 1991-05-16 | Shin Etsu Chem Co Ltd | 複合材料用改質剤 |
| JP2530512B2 (ja) * | 1990-06-18 | 1996-09-04 | 信越化学工業株式会社 | 有機珪素化合物の製造方法 |
| JP3115064B2 (ja) * | 1990-11-16 | 2000-12-04 | 東燃株式会社 | 新規シラン化合物の製造方法 |
| JP2938726B2 (ja) * | 1993-09-10 | 1999-08-25 | 信越化学工業株式会社 | 第３級ブチルシクロアルキルジアルコキシシラン化合物の製造方法 |
| US5670688A (en) * | 1996-12-19 | 1997-09-23 | Dow Corning Corporation | Process for the industrial manufacture of a cycloalkylsilane or polyorganosiloxane |
| US6235863B1 (en) * | 1998-12-03 | 2001-05-22 | Shell Oil Company | Production of saturated siloxane polymers from aromatic monomers |
| JP2023088718A (ja) * | 2021-12-15 | 2023-06-27 | 国立大学法人 東京大学 | オルガノシロキサン系水素貯蔵用組成物 |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU245057A1 (ru) * | 1967-11-15 | 1975-12-25 | Казахский Химико-Технологический Институт | Способ получени циклогексана |
-
1987
- 1987-03-06 IT IT8741003A patent/IT1210319B/it active
-
1988
- 1988-03-01 ZA ZA881455A patent/ZA881455B/xx unknown
- 1988-03-01 CA CA000560254A patent/CA1305716C/en not_active Expired - Fee Related
- 1988-03-02 IL IL85610A patent/IL85610A/xx unknown
- 1988-03-02 AU AU12581/88A patent/AU602196B2/en not_active Ceased
- 1988-03-03 US US07/163,948 patent/US4956484A/en not_active Expired - Fee Related
- 1988-03-04 NO NO880993A patent/NO880993L/no unknown
- 1988-03-04 JP JP63051443A patent/JPS63230694A/ja active Pending
- 1988-03-04 FI FI881013A patent/FI87788C/fi not_active IP Right Cessation
- 1988-03-04 RU SU884355285A patent/RU1838317C/ru active
- 1988-03-04 BR BR8800934A patent/BR8800934A/pt not_active Application Discontinuation
- 1988-03-04 EP EP88301944A patent/EP0281425A3/en not_active Withdrawn
- 1988-03-05 KR KR1019880002315A patent/KR880011053A/ko not_active Application Discontinuation
Non-Patent Citations (1)
| Title |
|---|
| J. am Chem. Soc., 1962, v 84, p. 1856-1868. * |
Also Published As
| Publication number | Publication date |
|---|---|
| IT8741003A0 (it) | 1987-03-06 |
| AU1258188A (en) | 1988-09-08 |
| NO880993L (no) | 1988-09-07 |
| AU602196B2 (en) | 1990-10-04 |
| EP0281425A3 (en) | 1990-01-10 |
| ZA881455B (en) | 1988-08-23 |
| US4956484A (en) | 1990-09-11 |
| IL85610A (en) | 1992-05-25 |
| FI881013A (fi) | 1988-09-07 |
| NO880993D0 (no) | 1988-03-04 |
| BR8800934A (pt) | 1988-10-11 |
| IT1210319B (it) | 1989-09-14 |
| IL85610A0 (en) | 1988-08-31 |
| EP0281425A2 (en) | 1988-09-07 |
| FI87788B (fi) | 1992-11-13 |
| KR880011053A (ko) | 1988-10-26 |
| JPS63230694A (ja) | 1988-09-27 |
| CA1305716C (en) | 1992-07-28 |
| FI881013A0 (fi) | 1988-03-04 |
| FI87788C (fi) | 1993-02-25 |
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