RO87143B - Procedeu pentru prepararea unor saruri de mono-si di-n-fosfonometilglicibamino - Google Patents
Procedeu pentru prepararea unor saruri de mono-si di-n-fosfonometilglicibaminoInfo
- Publication number
- RO87143B RO87143B RO110775A RO11077583A RO87143B RO 87143 B RO87143 B RO 87143B RO 110775 A RO110775 A RO 110775A RO 11077583 A RO11077583 A RO 11077583A RO 87143 B RO87143 B RO 87143B
- Authority
- RO
- Romania
- Prior art keywords
- mono
- salt
- phosphonomethylglycine
- moles
- general formula
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 abstract 3
- 125000001841 imino group Chemical group [H]N=* 0.000 abstract 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 abstract 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 2
- 150000001447 alkali salts Chemical class 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- FQQQSNAVVZSYMB-UHFFFAOYSA-N 1,1-diaminoguanidine Chemical compound NN(N)C(N)=N FQQQSNAVVZSYMB-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 abstract 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 150000003973 alkyl amines Chemical class 0.000 abstract 1
- 125000003282 alkyl amino group Chemical group 0.000 abstract 1
- 125000005037 alkyl phenyl group Chemical group 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- HAMNKKUPIHEESI-UHFFFAOYSA-N aminoguanidine Chemical compound NNC(N)=N HAMNKKUPIHEESI-UHFFFAOYSA-N 0.000 abstract 1
- 125000005265 dialkylamine group Chemical group 0.000 abstract 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 abstract 1
- 125000005059 halophenyl group Chemical group 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- -1 hydroxy, guanidino, aminoguanidino Chemical group 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000243 solution Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/44—Amides thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
- A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Molecular Biology (AREA)
- Biochemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Abstract
Procedeul de preparare a unor saruri de mono- si di-N-fosfonometilglicinamino sau iminouree cu formula generala I: (vezi formula) în care R1, R2 si R3 independent unul de altul sunt hidrogen, fara a putea fi toti 3 concomitent hidrogen, alchilamino în care grupa alchil este liniara sau ramificata si are 1...6 atomi de carbon, putînd fi substituita cu o grupa hidroxi, guanidino, aminoguanidino, diamonoguanidino, alchil inferiordiguanidino consta în aceea ca se oxideaza o sare de iminouree de acidcu formula generala II: (vezi formula) în care Ar1 si Ar2, fiecare independent, este ales din grupul constînd din fenil, alchilfenil si halofenil, în solutie apoasa prin tratare cu cel putin 2 mol de apa oxigenata pentru fiecare mol de acid fosfonicla 80 degree C, obtinînd sarea de iminouree a N-fosfonometilglicinei cu formula generala III: (vezi formula) în care Ar1 si Ar2 au semnificatiile de mai sus, 1 mol din aceasta sare se trateaza cu 2 mol de alchilamina sau dialchilamina în care radicalii alchil au 1...6 atomi de carbon si sunt liniari cu 2 mol de guanidina, di(aminoguanidina) mono-si di (diaminoguanidina), mono- si di (alchilinferiorguanidina), mono- si di(alchileninferiordiguanidina) în solutie apoasa la 25 degree C si separînd acilaminoureeainsolubila în apa în care arezultat de sarea bazica a N-fosfonometilglicinei solubila în apa si în final se trateaza aceasta sare bazica cu 1 mol de N-fosfonometilgilina, în solutie apoasa la 25 degree C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IL66137A IL66137A (en) | 1982-06-25 | 1982-06-25 | Process for producing n-phosphonomethylglycine isopropyl amine salt and herbicidal compositions prepared therewith |
IL66824A IL66824A0 (en) | 1982-06-25 | 1982-09-17 | Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby |
Publications (2)
Publication Number | Publication Date |
---|---|
RO87143B true RO87143B (ro) | 1985-10-31 |
RO87143A RO87143A (ro) | 1985-11-30 |
Family
ID=26321054
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
RO83110775A RO87143A (ro) | 1982-06-25 | 1983-04-25 | Procedeu pentru prepararea unor saruri de mono-si di-n-fosfonometilglicibamino |
Country Status (13)
Country | Link |
---|---|
US (1) | US4486356A (ro) |
EP (1) | EP0098034A3 (ro) |
KR (1) | KR840005155A (ro) |
AU (1) | AU1350283A (ro) |
BR (1) | BR8303513A (ro) |
DK (1) | DK157683A (ro) |
FI (1) | FI831204L (ro) |
GR (1) | GR81421B (ro) |
IL (1) | IL66824A0 (ro) |
NO (1) | NO831287L (ro) |
PL (1) | PL242678A1 (ro) |
PT (1) | PT76635B (ro) |
RO (1) | RO87143A (ro) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL68716A (en) * | 1983-05-17 | 1987-03-31 | Geshuri Lab Ltd | Process for producing n-phosphonomethylglycine |
US4579689A (en) * | 1985-02-11 | 1986-04-01 | Monsanto Company | Oxidation with coated catalyst |
US4582650A (en) * | 1985-02-11 | 1986-04-15 | Monsanto Company | Oxidation with encapsulated co-catalyst |
HU204533B (en) * | 1988-11-02 | 1992-01-28 | Nitrokemia Ipartelepek | Process for producing n-phosphono-methyl-glycine |
US5023369A (en) * | 1990-06-25 | 1991-06-11 | Monsanto Company | Process for producing N-phosphonomethylglycine |
IL101539A (en) * | 1991-04-16 | 1998-09-24 | Monsanto Europe Sa | Mono-ammonium salts of the history of N phosphonomethyl glycyl which are not hygroscopes, their preparations and pesticides containing |
US5948938A (en) * | 1995-03-07 | 1999-09-07 | Sankyo Company, Limited | Process for preparing N-phosphonomethylglycine |
ITTO980048A1 (it) * | 1998-01-20 | 1999-07-20 | Ipici Spa | Composizioni erbicide, procedimenti per la loro preparazione ed impieghi |
US6417133B1 (en) | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
DE69905894T2 (de) * | 1998-07-06 | 2003-12-04 | Syngenta Participations Ag | Herstellung von n-phosphonomethylglycin salzen |
DE60115019T2 (de) * | 2000-05-22 | 2006-08-03 | Monsanto Technology Llc. | Reaktionssysteme zur herstellung von n-(phosphonomethyl)glyzin verbindungen |
TW200624171A (en) * | 2004-09-15 | 2006-07-16 | Monsanto Technology Llc | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
US9615463B2 (en) * | 2006-09-22 | 2017-04-04 | Oscar Khaselev | Method for producing a high-aspect ratio conductive pattern on a substrate |
US8252953B2 (en) | 2008-05-01 | 2012-08-28 | Monsanto Technology Llc | Metal utilization in supported, metal-containing catalysts |
WO2010048164A2 (en) * | 2008-10-20 | 2010-04-29 | University Of South Florida | N,n'-di-p-bromophenyl guanidine treatment for stroke at delayed timepoints |
CN104854117B (zh) * | 2012-07-17 | 2018-12-25 | 孟山都技术有限责任公司 | 用于合成n-膦酰基甲基亚氨基二乙酸的方法 |
US11109591B2 (en) * | 2017-04-24 | 2021-09-07 | Taminco Bvba | Single phase liquids of alkanolamine salts of dicamba |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3853530A (en) * | 1971-03-10 | 1974-12-10 | Monsanto Co | Regulating plants with n-phosphonomethylglycine and derivatives thereof |
US3977860A (en) * | 1971-08-09 | 1976-08-31 | Monsanto Company | Herbicidal compositions and methods employing esters of N-phosphonomethylglycine |
US3954848A (en) * | 1972-05-31 | 1976-05-04 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
US3950402A (en) * | 1972-05-31 | 1976-04-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
US3969398A (en) * | 1974-05-01 | 1976-07-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
US3957431A (en) * | 1975-03-28 | 1976-05-18 | Basf Aktiengesellschaft | Process for easy-care finishing cellulosics |
MX4703E (es) * | 1976-12-20 | 1982-08-04 | Monsanto Co | Procedimiento mejorado para la preparacion de mono y disales de n-fosfonometilglicina |
CH634968A5 (de) * | 1977-04-01 | 1983-03-15 | Ciba Geigy Ag | Herbizides und pflanzenwuchsregulierendes mittel enthaltend eine neue phosphinsaeure oder deren salze, ester, amide oder hydrazide sowie verwendung derselben. |
IL65187A (en) * | 1982-03-08 | 1985-03-31 | Geshuri Lab Ltd | N-phosphonomethylglycine derivatives,processes for their preparation and herbicidal compositions containing them |
-
1982
- 1982-09-17 IL IL66824A patent/IL66824A0/xx unknown
-
1983
- 1983-04-11 DK DK157683A patent/DK157683A/da not_active IP Right Cessation
- 1983-04-11 FI FI831204A patent/FI831204L/fi not_active Application Discontinuation
- 1983-04-12 NO NO831287A patent/NO831287L/no unknown
- 1983-04-13 AU AU13502/83A patent/AU1350283A/en not_active Abandoned
- 1983-04-15 GR GR71101A patent/GR81421B/el unknown
- 1983-04-15 US US06/485,501 patent/US4486356A/en not_active Expired - Fee Related
- 1983-04-21 KR KR1019830001694A patent/KR840005155A/ko not_active Application Discontinuation
- 1983-04-22 EP EP83302314A patent/EP0098034A3/en not_active Withdrawn
- 1983-04-25 RO RO83110775A patent/RO87143A/ro unknown
- 1983-05-04 PT PT76635A patent/PT76635B/pt unknown
- 1983-06-24 BR BR8303513A patent/BR8303513A/pt unknown
- 1983-06-24 PL PL24267883A patent/PL242678A1/xx unknown
Also Published As
Publication number | Publication date |
---|---|
FI831204A0 (fi) | 1983-04-11 |
NO831287L (no) | 1983-12-27 |
FI831204L (fi) | 1983-12-26 |
US4486356A (en) | 1984-12-04 |
PL242678A1 (en) | 1984-07-02 |
PT76635A (en) | 1983-06-01 |
EP0098034A3 (en) | 1984-03-28 |
AU1350283A (en) | 1984-01-05 |
DK157683A (da) | 1983-12-26 |
EP0098034A2 (en) | 1984-01-11 |
BR8303513A (pt) | 1984-02-07 |
KR840005155A (ko) | 1984-11-03 |
RO87143A (ro) | 1985-11-30 |
IL66824A0 (en) | 1982-12-31 |
DK157683D0 (da) | 1983-04-11 |
GR81421B (ro) | 1984-12-11 |
PT76635B (en) | 1985-12-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
RO87143B (ro) | Procedeu pentru prepararea unor saruri de mono-si di-n-fosfonometilglicibamino | |
ES8507320A1 (es) | Procedimiento de producir acido n-fosfonometilglicinico | |
DK0767609T3 (da) | Herbicidsammensætning | |
TR199701141T1 (xx) | Eteramin s�rfaktanlar ihtiva eden glifosat form�lasyonlar�. | |
ES429540A1 (es) | Procedimiento para la obtencion de acidos fosfonicos. | |
MY106103A (en) | Glyphosate compositions and their use. | |
HUT35629A (en) | Preparations of plant growth controlling effect and containing 1-methyl-amino-cylopropane-1-carboxylic acid-derivatives as agent and process for the production of the agents | |
PT87352A (pt) | Process for preparing improved glyphosate formulations | |
ATE51858T1 (de) | Verfahren zur herstellung von (2,2)-paracyclophan und dessen derivaten. | |
DE3751821D1 (de) | Oberflächenaktive laktame | |
GB1440847A (en) | Carboxyethyl ester of n-phosphonomethyl glycine salts thereof and their use as herbicides | |
RO86850B (ro) | Procedeu pentru prepararea unor 2-fenilimidazo [4,5 c] piridine | |
RO84317B (ro) | Procedeu de preparare a unor derivati de difenileter cu activitate erbicida | |
RO84661B (ro) | Procedeu pentru prepararea acidului oxazafosforin/4-tioalcan-sulfonic sau a sarurilor neutre ale acestuia | |
DE69818709D1 (en) | Derivatives of aminoalkane sulphonic, phosphonic and phosphinic acids, their preparation and their use as medicaments | |
RO88128B (ro) | Procedeu pentru prepararea n-fosfanometilglicinei | |
US2794818A (en) | Germicidally active phenolic copper chelate compounds | |
ATE45951T1 (de) | Phosphonsaeureester in haarbehandlungsmitteln. | |
DE3882623T2 (de) | Phosphorsaeurediester und salze davon. | |
GB1274350A (en) | 2-chloroethane-(thiono)-phosphonic acid derivatives, process for their preparation, and their use for the regulation of plant growth | |
ATE50557T1 (de) | Verfahren zur herstellung von 8- und 9-formyltricyclo-(5,2,1,0, 2,6)-decen-3. | |
ES8505973A1 (es) | Un procedimiento para la preparacion de derivados de pirimidinatriona | |
GB1437055A (en) | Thiono phosphoric phosphonic acid esters their preparation and their use as insecticides and acaricides | |
DE3662039D1 (de) | Novel diamine derivatives | |
DE59004266D1 (de) | Bad zur galvanischen Abscheidung von Feingoldüberzügen. |