RO71465B1 - Metoda si electrod suma pentru determinarea concentratiei totale de ioni liberi din solutii - Google Patents

Metoda si electrod suma pentru determinarea concentratiei totale de ioni liberi din solutii

Info

Publication number
RO71465B1
RO71465B1 RO95520A RO9552078A RO71465B1 RO 71465 B1 RO71465 B1 RO 71465B1 RO 95520 A RO95520 A RO 95520A RO 9552078 A RO9552078 A RO 9552078A RO 71465 B1 RO71465 B1 RO 71465B1
Authority
RO
Romania
Prior art keywords
sum
test solution
concentration
free ions
electrode
Prior art date
Application number
RO95520A
Other languages
English (en)
Other versions
RO71465A2 (ro
Inventor
Nicolae Ulpiu Bonciocat
Mircea Stefan Borda
Sergiu Borca
Alexandru Leibovici
Liliana Ivanov
Original Assignee
Institutul De Cercetari Chimice
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Institutul De Cercetari Chimice filed Critical Institutul De Cercetari Chimice
Priority to RO7895520A priority Critical patent/RO71465A2/ro
Priority to DE19792943382 priority patent/DE2943382A1/de
Priority to FR7926697A priority patent/FR2439994A1/fr
Priority to GB7937437A priority patent/GB2036977A/en
Publication of RO71465B1 publication Critical patent/RO71465B1/ro
Publication of RO71465A2 publication Critical patent/RO71465A2/ro

Links

Classifications

    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N27/00Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
    • G01N27/26Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
    • G01N27/28Electrolytic cell components
    • G01N27/30Electrodes, e.g. test electrodes; Half-cells
    • G01N27/301Reference electrodes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Molecular Biology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analyzing Materials By The Use Of Electric Means (AREA)
  • Investigating Or Analysing Biological Materials (AREA)

Abstract

Metoda pentru determinarea concentratiei totale de ioni liberi din solutii, caracterizata prin aceea ca se determina suma produselor concentratie-mobilitate, (vezi form. în desc.) a tuturor ionilor liberi din solutia test indiferent de natura lor, pebaza masurarii tensiunii electrice U a pilei de concentratie cu transport, alcatuita din solutia test în contact electrochimic prin doua joctiuni lichide cu doi electrozi, dintre care cel putin unul este un electrod suma cel de al doilea putînd fi tot un electrod suma (15 II) sau un electrod de referinta, tensiune electrica a carei valoare creste odata cu dilutia solutiei test, avand expresia generala (vezi form. în desc.) în care valorile distantei la origine si pantei B sînt constante independente de compozitia solutiei test pentru o alcatuire data a pilei de concentratie si pentru temperatura si presiunea de lucru alese, aceste valori determinîndu-se experimental prin trasarea dreptei de variatie (vezi form. în desc.) pentru solutii decompozitie si pH cunoscute, într-un domeniu astfel încît suma concentratiilor cationilor (anionilor) sa fie speciale.
RO7895520A 1978-10-27 1978-10-27 Metoda si electrod suma pentru determinarea concentratiei totale de ioni liberi din solutii RO71465A2 (ro)

Priority Applications (4)

Application Number Priority Date Filing Date Title
RO7895520A RO71465A2 (ro) 1978-10-27 1978-10-27 Metoda si electrod suma pentru determinarea concentratiei totale de ioni liberi din solutii
DE19792943382 DE2943382A1 (de) 1978-10-27 1979-10-26 Summenelektrode, methode und vorrichtung zur bestimmung der gesamtkonzentration der freien ionen in loesungen
FR7926697A FR2439994A1 (fr) 1978-10-27 1979-10-26 Electrode sommatrice, procede et dispositif pour la determination de la concentration totale en ions libres des solutions
GB7937437A GB2036977A (en) 1978-10-27 1979-10-29 Unselective electrode for determination of ionic concentrations in solution

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
RO7895520A RO71465A2 (ro) 1978-10-27 1978-10-27 Metoda si electrod suma pentru determinarea concentratiei totale de ioni liberi din solutii

Publications (2)

Publication Number Publication Date
RO71465B1 true RO71465B1 (ro) 1983-07-30
RO71465A2 RO71465A2 (ro) 1983-08-03

Family

ID=20103037

Family Applications (1)

Application Number Title Priority Date Filing Date
RO7895520A RO71465A2 (ro) 1978-10-27 1978-10-27 Metoda si electrod suma pentru determinarea concentratiei totale de ioni liberi din solutii

Country Status (4)

Country Link
DE (1) DE2943382A1 (ro)
FR (1) FR2439994A1 (ro)
GB (1) GB2036977A (ro)
RO (1) RO71465A2 (ro)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4438524C5 (de) * 1994-10-31 2004-07-15 Schott-Geräte GmbH pH-Doppelmeßkette
EP2293052B1 (de) * 2009-09-03 2014-03-12 Hach Lange GmbH Wasseranalyse-Messanordnung
FR2950972A1 (fr) * 2009-10-02 2011-04-08 Commissariat Energie Atomique Procede et cellule de mesure de la concentration globale en ions d'un fluide corporel

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3455793A (en) * 1965-06-18 1969-07-15 Beckman Instruments Inc Method of providing for liquid junction
US3505196A (en) * 1966-07-15 1970-04-07 Ibm Reference electrode
US3598713A (en) * 1969-06-03 1971-08-10 Corning Glass Works Potassium ion sensitive electrode

Also Published As

Publication number Publication date
DE2943382A1 (de) 1980-06-26
RO71465A2 (ro) 1983-08-03
GB2036977A (en) 1980-07-02
FR2439994A1 (fr) 1980-05-23

Similar Documents

Publication Publication Date Title
GB1131574A (en) Fluoride sensitive electrode
Papeschi et al. Use of an iridium electrode for direct measurement of pI of proteins after isoelectric focusing in polyacrylamide gel
Brown et al. Operational amplifier potentiostats employing positive feedback for IR compensation. II. Application to ac polarography
RO71465B1 (ro) Metoda si electrod suma pentru determinarea concentratiei totale de ioni liberi din solutii
GB2013895A (en) Electroanalytical cell and amperometric measurement method
Estee et al. Reduction of neodymium at the dropping mercury electrode
US3528778A (en) Method for the determination of acid concentrations
Pungor et al. Voltammetric studies on graphite impregnated silicone rubber electrodes
KR970070254A (ko) 연속 주행물질의 전해 처리를 위한 공정 및 디바이스
Tallant et al. Voltammetry at the lead dioxide electrode: Anodic EDTA currents
FR2425064B1 (ro)
Gunasingham et al. Effect of pH on the response of glassy carbon electrodes
Bordl et al. Adsorption behaviour of quinoline, 2-and 4-methyl-quinoline at mercury-solution and at air-solution interfaces: I. Electrocapillary curves, surface tension and surface potential
SU1702283A1 (ru) Способ определени концентрации ионов в растворах
Palm et al. Kinetics of hydrogen evolution and double layer structure on bismuth
Koczorowski et al. Effect of constant polarization on the alternating voltage generated by a vibrating interface separating immiscible electrolyte solutions in water and nitrobenzene
SU901891A1 (ru) Способ определени концентрации ионов хлора на твердом электроде
JP4141098B2 (ja) ガスセンサ
SU1179195A1 (ru) Способ определени концентрации ионов в растворах
Schram et al. Effect of Amines on Polarization of Iron Electrodes
Crowell et al. The Electromotive Force of the Mercurous Bromide Electrode
Zhang et al. Properties and applications of carbon fiber dual‐cylinder microelectrodes
Itami et al. Thermoelectric power of ionic crystals—IV. Thermoelectric power and ionic conductivity of potassium iodide containing cadmium iodide
Shamim et al. The transient response of a two-terminal solion to a stepcrrent input
Foraison et al. Electrochemical study of sodium conductive glass/sodium amalgam interface