PL83201B1 - - Google Patents
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- Publication number
- PL83201B1 PL83201B1 PL1971147457A PL14745771A PL83201B1 PL 83201 B1 PL83201 B1 PL 83201B1 PL 1971147457 A PL1971147457 A PL 1971147457A PL 14745771 A PL14745771 A PL 14745771A PL 83201 B1 PL83201 B1 PL 83201B1
- Authority
- PL
- Poland
- Prior art keywords
- catalyst
- propylene
- uranium
- mixture
- tellurium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 claims description 47
- 238000000034 method Methods 0.000 claims description 29
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 26
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 26
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 24
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000000203 mixture Substances 0.000 claims description 14
- 229910021529 ammonia Inorganic materials 0.000 claims description 13
- 229910052714 tellurium Inorganic materials 0.000 claims description 13
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 229910052770 Uranium Inorganic materials 0.000 claims description 11
- 150000002825 nitriles Chemical class 0.000 claims description 11
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 239000000377 silicon dioxide Substances 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 4
- 238000002360 preparation method Methods 0.000 claims description 4
- FXADMRZICBQPQY-UHFFFAOYSA-N orthotelluric acid Chemical compound O[Te](O)(O)(O)(O)O FXADMRZICBQPQY-UHFFFAOYSA-N 0.000 claims description 2
- 150000003498 tellurium compounds Chemical class 0.000 claims 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical group C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 10
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 description 5
- 229910000439 uranium oxide Inorganic materials 0.000 description 5
- 229910052787 antimony Inorganic materials 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- -1 lanthanum and cerium Chemical class 0.000 description 3
- 229910052750 molybdenum Inorganic materials 0.000 description 3
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- LAJZODKXOMJMPK-UHFFFAOYSA-N tellurium dioxide Chemical compound O=[Te]=O LAJZODKXOMJMPK-UHFFFAOYSA-N 0.000 description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910017835 Sb—Sn Inorganic materials 0.000 description 1
- 229910020935 Sn-Sb Inorganic materials 0.000 description 1
- 229910008757 Sn—Sb Inorganic materials 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- JNAHSTZIPLLKBQ-UHFFFAOYSA-N [O].CC=C Chemical group [O].CC=C JNAHSTZIPLLKBQ-UHFFFAOYSA-N 0.000 description 1
- BYHYQBROBOIDAB-UHFFFAOYSA-N [U].C(C=C)#N Chemical compound [U].C(C=C)#N BYHYQBROBOIDAB-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052768 actinide Inorganic materials 0.000 description 1
- 150000001255 actinides Chemical class 0.000 description 1
- 238000001994 activation Methods 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 238000009739 binding Methods 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011964 heteropoly acid Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000002603 lanthanum Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000001603 reducing effect Effects 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical group [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
- B01J27/057—Selenium or tellurium; Compounds thereof
- B01J27/0576—Tellurium; Compounds thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2327070 | 1970-04-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL83201B1 true PL83201B1 (enExample) | 1975-12-31 |
Family
ID=11205495
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1971147457A PL83201B1 (enExample) | 1970-04-14 | 1971-04-13 | |
| PL1972153372A PL88981B1 (enExample) | 1970-04-14 | 1972-02-08 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PL1972153372A PL88981B1 (enExample) | 1970-04-14 | 1972-02-08 |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US3850975A (enExample) |
| JP (1) | JPS5140557B1 (enExample) |
| AT (1) | AT313866B (enExample) |
| BE (1) | BE765621A (enExample) |
| CA (1) | CA981241A (enExample) |
| CH (1) | CH530378A (enExample) |
| CS (1) | CS174813B2 (enExample) |
| DE (2) | DE2117351A1 (enExample) |
| DK (1) | DK132605C (enExample) |
| ES (1) | ES390536A1 (enExample) |
| FR (1) | FR2093436A5 (enExample) |
| GB (2) | GB1354153A (enExample) |
| HU (1) | HU165998B (enExample) |
| LU (1) | LU62980A1 (enExample) |
| NL (1) | NL7104954A (enExample) |
| NO (1) | NO130042B (enExample) |
| PL (2) | PL83201B1 (enExample) |
| RO (1) | RO56406A (enExample) |
| SE (2) | SE399704B (enExample) |
| SU (1) | SU425380A3 (enExample) |
| ZA (1) | ZA712388B (enExample) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3983054A (en) * | 1970-04-14 | 1976-09-28 | Snam Progetti S.P.A. | Catalytic composition and its applications to the production of unsaturated nitriles and to the oxidation of olefines |
-
1971
- 1971-04-05 NO NO01299/71A patent/NO130042B/no unknown
- 1971-04-07 DK DK170871A patent/DK132605C/da active
- 1971-04-08 DE DE19712117351 patent/DE2117351A1/de active Pending
- 1971-04-08 DE DE19712165978 patent/DE2165978A1/de active Pending
- 1971-04-09 FR FR7112678A patent/FR2093436A5/fr not_active Expired
- 1971-04-13 PL PL1971147457A patent/PL83201B1/pl unknown
- 1971-04-13 CS CS2630A patent/CS174813B2/cs unknown
- 1971-04-13 CH CH536771A patent/CH530378A/fr not_active IP Right Cessation
- 1971-04-13 BE BE765621A patent/BE765621A/xx unknown
- 1971-04-13 LU LU62980D patent/LU62980A1/xx unknown
- 1971-04-13 AT AT03114/71A patent/AT313866B/de not_active IP Right Cessation
- 1971-04-13 CA CA110,230A patent/CA981241A/en not_active Expired
- 1971-04-13 HU HUSA2187A patent/HU165998B/hu unknown
- 1971-04-14 RO RO66575A patent/RO56406A/ro unknown
- 1971-04-14 JP JP46023209A patent/JPS5140557B1/ja active Pending
- 1971-04-14 ES ES390536A patent/ES390536A1/es not_active Expired
- 1971-04-14 ZA ZA712388A patent/ZA712388B/xx unknown
- 1971-04-14 US US00133886A patent/US3850975A/en not_active Expired - Lifetime
- 1971-04-14 SE SE7104859A patent/SE399704B/xx unknown
- 1971-04-14 NL NL7104954A patent/NL7104954A/xx unknown
- 1971-04-14 SU SU1641109A patent/SU425380A3/ru active
- 1971-04-19 GB GB3909673A patent/GB1354153A/en not_active Expired
- 1971-04-19 GB GB2669371*A patent/GB1354152A/en not_active Expired
-
1972
- 1972-02-08 PL PL1972153372A patent/PL88981B1/pl unknown
-
1976
- 1976-09-03 SE SE7609779A patent/SE7609779L/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CH530378A (fr) | 1972-11-15 |
| DE2165978A1 (de) | 1972-06-22 |
| RO56406A (enExample) | 1974-09-01 |
| GB1354152A (en) | 1974-06-05 |
| BE765621A (fr) | 1971-08-30 |
| HU165998B (enExample) | 1974-12-28 |
| NO130042B (enExample) | 1974-07-01 |
| DK132605B (da) | 1976-01-12 |
| NL7104954A (enExample) | 1971-10-18 |
| ES390536A1 (es) | 1974-04-01 |
| CS174813B2 (enExample) | 1977-04-29 |
| GB1354153A (en) | 1974-06-05 |
| US3850975A (en) | 1974-11-26 |
| SE399704B (sv) | 1978-02-27 |
| AT313866B (de) | 1974-02-15 |
| SE7609779L (sv) | 1976-09-03 |
| CA981241A (en) | 1976-01-06 |
| SU425380A3 (ru) | 1974-04-25 |
| ZA712388B (en) | 1972-01-26 |
| DE2117351A1 (de) | 1971-11-04 |
| FR2093436A5 (enExample) | 1972-01-28 |
| DK132605C (da) | 1976-06-08 |
| JPS5140557B1 (enExample) | 1976-11-04 |
| LU62980A1 (enExample) | 1971-08-26 |
| PL88981B1 (enExample) | 1976-10-30 |
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