PL56400B1 - - Google Patents

Info

Publication number

PL56400B1

PL56400B1 PL105507A PL10550764A PL56400B1 PL 56400 B1 PL56400 B1 PL 56400B1 PL 105507 A PL105507 A PL 105507A PL 10550764 A PL10550764 A PL 10550764A PL 56400 B1 PL56400 B1 PL 56400B1

Authority

PL

Poland

Prior art keywords

molten metal

tank

bath

additives

auxiliary

Prior art date

1964-08-19

Links

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• 229910052751 metal Inorganic materials 0.000 claims description 157
• 239000002184 metal Substances 0.000 claims description 157
• 239000000654 additive Substances 0.000 claims description 113
• 238000005868 electrolysis reaction Methods 0.000 claims description 35
• 230000000996 additive effect Effects 0.000 claims description 34
• 238000000034 method Methods 0.000 claims description 31
• 150000001875 compounds Chemical class 0.000 claims description 24
• 239000011521 glass Substances 0.000 claims description 23
• 230000001105 regulatory effect Effects 0.000 claims description 22
• 239000005357 flat glass Substances 0.000 claims description 8
• 238000010438 heat treatment Methods 0.000 claims description 8
• 238000005192 partition Methods 0.000 claims description 7
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
• 238000004140 cleaning Methods 0.000 claims description 6
• 239000000203 mixture Substances 0.000 claims description 6
• DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
• ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 5
• ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
• 229910052788 barium Inorganic materials 0.000 claims description 5
• DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 5
• -1 calcium halides Chemical class 0.000 claims description 5
• 239000011591 potassium Substances 0.000 claims description 5
• 229910052700 potassium Inorganic materials 0.000 claims description 5
• WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 4
• RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
• 239000011575 calcium Substances 0.000 claims description 4
• 229910052791 calcium Inorganic materials 0.000 claims description 4
• 238000009792 diffusion process Methods 0.000 claims description 4
• 230000006698 induction Effects 0.000 claims description 4
• 229910052744 lithium Inorganic materials 0.000 claims description 4
• 238000004519 manufacturing process Methods 0.000 claims description 4
• 239000010936 titanium Substances 0.000 claims description 4
• 229910052719 titanium Inorganic materials 0.000 claims description 4
• FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
• XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
• HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
• QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
• 229910052782 aluminium Inorganic materials 0.000 claims description 3
• XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
• 238000006243 chemical reaction Methods 0.000 claims description 3
• 229910052742 iron Inorganic materials 0.000 claims description 3
• 239000011777 magnesium Substances 0.000 claims description 3
• 229910052749 magnesium Inorganic materials 0.000 claims description 3
• 229910052758 niobium Inorganic materials 0.000 claims description 3
• 239000010955 niobium Substances 0.000 claims description 3
• GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 3
• 229910052710 silicon Inorganic materials 0.000 claims description 3
• 239000010703 silicon Substances 0.000 claims description 3
• 229910052708 sodium Inorganic materials 0.000 claims description 3
• 239000011734 sodium Substances 0.000 claims description 3
• 229910052715 tantalum Inorganic materials 0.000 claims description 3
• GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 3
• 229910052725 zinc Inorganic materials 0.000 claims description 3
• 239000011701 zinc Substances 0.000 claims description 3
• 229910052726 zirconium Inorganic materials 0.000 claims description 3
• ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
• 229910052684 Cerium Inorganic materials 0.000 claims description 2
• 229910052796 boron Inorganic materials 0.000 claims description 2
• WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
• 239000000956 alloy Substances 0.000 claims 2
• 229910045601 alloy Inorganic materials 0.000 claims 2
• ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
• 230000001939 inductive effect Effects 0.000 claims 1
• 239000010410 layer Substances 0.000 description 51
• 150000003839 salts Chemical class 0.000 description 10
• 239000006060 molten glass Substances 0.000 description 8
• 239000007789 gas Substances 0.000 description 7
• 230000001681 protective effect Effects 0.000 description 7
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
• WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 6
• 229910052799 carbon Inorganic materials 0.000 description 5
• TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
• 229910021380 Manganese Chloride Inorganic materials 0.000 description 4
• GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 4
• KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 4
• 239000011565 manganese chloride Substances 0.000 description 4
• 235000002867 manganese chloride Nutrition 0.000 description 4
• 229940099607 manganese chloride Drugs 0.000 description 4
• 230000008018 melting Effects 0.000 description 4
• 238000002844 melting Methods 0.000 description 4
• 238000000746 purification Methods 0.000 description 4
• FAPWRFPIFSIZLT-UHFFFAOYSA-M sodium chloride Inorganic materials [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
• OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
• 238000007792 addition Methods 0.000 description 3
• WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 3
• 239000000460 chlorine Substances 0.000 description 3
• 229910052801 chlorine Inorganic materials 0.000 description 3
• 239000001103 potassium chloride Substances 0.000 description 3
• 235000011164 potassium chloride Nutrition 0.000 description 3
• 239000011780 sodium chloride Substances 0.000 description 3
• 239000000126 substance Substances 0.000 description 3
• UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
• 229910020261 KBF4 Inorganic materials 0.000 description 2
• 229910001128 Sn alloy Inorganic materials 0.000 description 2
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
• 229910001626 barium chloride Inorganic materials 0.000 description 2
• 230000015572 biosynthetic process Effects 0.000 description 2
• 239000001110 calcium chloride Substances 0.000 description 2
• 229910001628 calcium chloride Inorganic materials 0.000 description 2
• 239000000356 contaminant Substances 0.000 description 2
• 229910001610 cryolite Inorganic materials 0.000 description 2
• 238000010790 dilution Methods 0.000 description 2
• 239000012895 dilution Substances 0.000 description 2
• RXCBCUJUGULOGC-UHFFFAOYSA-H dipotassium;tetrafluorotitanium;difluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[K+].[K+].[Ti+4] RXCBCUJUGULOGC-UHFFFAOYSA-H 0.000 description 2
• 239000012535 impurity Substances 0.000 description 2
• 229910001629 magnesium chloride Inorganic materials 0.000 description 2
• 150000002739 metals Chemical class 0.000 description 2
• 229910052760 oxygen Inorganic materials 0.000 description 2
• 239000001301 oxygen Substances 0.000 description 2
• 238000009991 scouring Methods 0.000 description 2
• 229910052712 strontium Inorganic materials 0.000 description 2
• CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
• 239000011593 sulfur Substances 0.000 description 2
• 229910052717 sulfur Inorganic materials 0.000 description 2
• 229910052716 thallium Inorganic materials 0.000 description 2
• BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 2
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
• BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
• 238000013459 approach Methods 0.000 description 1
• 150000001805 chlorine compounds Chemical class 0.000 description 1
• 238000010276 construction Methods 0.000 description 1
• 238000013270 controlled release Methods 0.000 description 1
• 239000003599 detergent Substances 0.000 description 1
• 239000002019 doping agent Substances 0.000 description 1
• 230000002349 favourable effect Effects 0.000 description 1
• 150000004673 fluoride salts Chemical class 0.000 description 1
• 230000008014 freezing Effects 0.000 description 1
• 238000007710 freezing Methods 0.000 description 1
• 229910002804 graphite Inorganic materials 0.000 description 1
• 239000010439 graphite Substances 0.000 description 1
• 150000004820 halides Chemical class 0.000 description 1
• 238000010348 incorporation Methods 0.000 description 1
• 230000008595 infiltration Effects 0.000 description 1
• 238000001764 infiltration Methods 0.000 description 1
• 230000003993 interaction Effects 0.000 description 1
• NTIGMHLFJNXNBT-UHFFFAOYSA-N manganese tin Chemical compound [Mn].[Sn] NTIGMHLFJNXNBT-UHFFFAOYSA-N 0.000 description 1
• 239000011159 matrix material Substances 0.000 description 1
• 239000000155 melt Substances 0.000 description 1
• 150000002736 metal compounds Chemical class 0.000 description 1
• 229910001092 metal group alloy Inorganic materials 0.000 description 1
• 229910044991 metal oxide Inorganic materials 0.000 description 1
• 150000004706 metal oxides Chemical class 0.000 description 1
• 230000001590 oxidative effect Effects 0.000 description 1
• 239000008188 pellet Substances 0.000 description 1
• 230000000149 penetrating effect Effects 0.000 description 1
• 230000035515 penetration Effects 0.000 description 1
• 239000011241 protective layer Substances 0.000 description 1
• 239000012629 purifying agent Substances 0.000 description 1
• 239000011819 refractory material Substances 0.000 description 1
• 230000000284 resting effect Effects 0.000 description 1
• 238000003892 spreading Methods 0.000 description 1
• 230000002459 sustained effect Effects 0.000 description 1
• 238000011144 upstream manufacturing Methods 0.000 description 1