PL50185B1 - - Google Patents
Download PDFInfo
- Publication number
- PL50185B1 PL50185B1 PL105831A PL10583164A PL50185B1 PL 50185 B1 PL50185 B1 PL 50185B1 PL 105831 A PL105831 A PL 105831A PL 10583164 A PL10583164 A PL 10583164A PL 50185 B1 PL50185 B1 PL 50185B1
- Authority
- PL
- Poland
- Prior art keywords
- solution
- glycoerisoline
- water
- glycerisoline
- lead
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 24
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 3
- 238000001704 evaporation Methods 0.000 claims description 3
- 239000000284 extract Substances 0.000 claims description 3
- 229910021514 lead(II) hydroxide Inorganic materials 0.000 claims description 3
- 239000003208 petroleum Substances 0.000 claims description 3
- 239000003495 polar organic solvent Substances 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 230000001476 alcoholic effect Effects 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims description 2
- 229910052939 potassium sulfate Inorganic materials 0.000 claims description 2
- 235000011151 potassium sulphates Nutrition 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- 239000002002 slurry Substances 0.000 claims 2
- 238000007865 diluting Methods 0.000 claims 1
- 230000008020 evaporation Effects 0.000 claims 1
- 238000002955 isolation Methods 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- WNCZPWWLBZOFJL-UHFFFAOYSA-N SJ000287139 Natural products CS(=O)(=O)CCCCN=C=S WNCZPWWLBZOFJL-UHFFFAOYSA-N 0.000 description 4
- HBCNXWUNPXIERK-UHFFFAOYSA-N erysoline Natural products C1C=C2C=CC(O)CC32N1CCC1=C3C=C(O)C(OC)=C1 HBCNXWUNPXIERK-UHFFFAOYSA-N 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 229930182470 glycoside Natural products 0.000 description 3
- 150000002338 glycosides Chemical class 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 241000146985 Erysimum perofskianum Species 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229940046892 lead acetate Drugs 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- UCSJYZPVAKXKNQ-HZYVHMACSA-N streptomycin Chemical compound CN[C@H]1[C@H](O)[C@@H](O)[C@H](CO)O[C@H]1O[C@@H]1[C@](C=O)(O)[C@H](C)O[C@H]1O[C@@H]1[C@@H](NC(N)=N)[C@H](O)[C@@H](NC(N)=N)[C@H](O)[C@H]1O UCSJYZPVAKXKNQ-HZYVHMACSA-N 0.000 description 2
- -1 4-methylsulfobutyl Chemical group 0.000 description 1
- TWCMVXMQHSVIOJ-UHFFFAOYSA-N Aglycone of yadanzioside D Natural products COC(=O)C12OCC34C(CC5C(=CC(O)C(O)C5(C)C3C(O)C1O)C)OC(=O)C(OC(=O)C)C24 TWCMVXMQHSVIOJ-UHFFFAOYSA-N 0.000 description 1
- PLMKQQMDOMTZGG-UHFFFAOYSA-N Astrantiagenin E-methylester Natural products CC12CCC(O)C(C)(CO)C1CCC1(C)C2CC=C2C3CC(C)(C)CCC3(C(=O)OC)CCC21C PLMKQQMDOMTZGG-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229930182555 Penicillin Natural products 0.000 description 1
- JGSARLDLIJGVTE-MBNYWOFBSA-N Penicillin G Chemical compound N([C@H]1[C@H]2SC([C@@H](N2C1=O)C(O)=O)(C)C)C(=O)CC1=CC=CC=C1 JGSARLDLIJGVTE-MBNYWOFBSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 239000000469 ethanolic extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- PFOARMALXZGCHY-UHFFFAOYSA-N homoegonol Natural products C1=C(OC)C(OC)=CC=C1C1=CC2=CC(CCCO)=CC(OC)=C2O1 PFOARMALXZGCHY-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 238000000338 in vitro Methods 0.000 description 1
- 238000001727 in vivo Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 125000004425 isosulfocyanate group Chemical group 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229940049954 penicillin Drugs 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229960005322 streptomycin Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000006188 syrup Substances 0.000 description 1
- 235000020357 syrup Nutrition 0.000 description 1
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL50185B1 true PL50185B1 (enExample) | 1965-08-15 |
Family
ID=
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| El Khadem et al. | 675. Constituents of the leaves of Psidium guaijava, L. Part II. Quercetin, avicularin, and guaijaverin | |
| SU628822A3 (ru) | Способ получени хлоргидрата 4 -эпи-6 оксиадриамицина | |
| US2746960A (en) | New chemotherapeutic nitrofurans | |
| DE1134086B (de) | Verfahren zur Herstellung von analeptisch wirksamen alpha-Aminoisobutyrophenonen und deren Säureadditionssalzen | |
| DE3111428A1 (de) | Oxazaphosphorin-4-thio-alkansulfonsaeuren und deren neutrale salze, verfahren zu ihrer herstellung und diese enthaltende pharmazeutische zubereitungen | |
| CN104557967A (zh) | 一种高纯度米尔贝霉素的生产方法 | |
| CZ20004775A3 (en) | Process for preparing aloin by extraction | |
| Kaneta et al. | The Constituents of Arthraxon hispidus Makino, Miscanthus tinctorius Hackel, Miscanthus sinensis Anderss, and Phragmites communis Trinius | |
| US6147228A (en) | Convenient method for the large scale isolation of garcinia acid | |
| CN100395253C (zh) | 一种由亚麻籽制备开环异落叶松树脂酚二葡萄糖苷的方法 | |
| CN101486730A (zh) | 一种磷酸肌酸钠化合物及其合成方法 | |
| Jones et al. | 247. Synthesis of some derivatives of D-and L-arabinose | |
| CH419113A (de) | Verfahren zur Herstellung von D-Homo-androstan-18-säuren | |
| ACREE Jr et al. | Amorphin, a glycoside in Amorpha fruticosa L. | |
| US2483137A (en) | Synthesis of vitamin b6 | |
| Wiggins | 143. The conversion of galactose into derivatives of d-idose | |
| ONODERA et al. | Debenzyloxycarbonylation of 1, 3, 4, 6-Tetra-O-acetyl-2-benzyloxycarbonylamino-2-deoxy-D-hexopyranoses in the Conversion of α, β-Acetoxy to Glycosyl Bromide | |
| Adams et al. | A Synthesis of 6-Hydroxy-4-quinolizones | |
| Gregory et al. | 446. The conversion of sucrose into pyridazine derivatives. Part V. Experiments on the synthesis of 3-amino-6-methylpyridazine and of its sulphanilamido-derivative | |
| Bell et al. | 360. A new reaction of 4: 6-ethylidene β-methylglucoside derivatives: 4: 6-dimethyl glucose | |
| Haworth et al. | LXXXVI.—Crystalline α-methylmannofuranoside (γ-methylmannoside). Part I | |
| US3147246A (en) | Obtention of an alkaloid from nuphar luteum | |
| US20020137950A1 (en) | Novel chiral derivatives of garcinia acid bearing lactone ring moiety and process for preparing the same | |
| AT218531B (de) | Verfahren zur Herstellung des neuen N- (4-Sulfonamidophenyl)-butansultam | |
| CN107445984B (zh) | 一种磷酸肌肉醇的制备方法 |