PL23809B1 - A method of producing water-soluble dyes. - Google Patents
A method of producing water-soluble dyes. Download PDFInfo
- Publication number
- PL23809B1 PL23809B1 PL23809A PL2380933A PL23809B1 PL 23809 B1 PL23809 B1 PL 23809B1 PL 23809 A PL23809 A PL 23809A PL 2380933 A PL2380933 A PL 2380933A PL 23809 B1 PL23809 B1 PL 23809B1
- Authority
- PL
- Poland
- Prior art keywords
- soluble dyes
- producing water
- water
- molecule
- soluble
- Prior art date
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- 239000000975 dye Substances 0.000 title claims description 5
- 238000000034 method Methods 0.000 title claims 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QIDUHGHFWAMMPV-UHFFFAOYSA-N 1,1-diphenylethylbenzene Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)(C)C1=CC=CC=C1 QIDUHGHFWAMMPV-UHFFFAOYSA-N 0.000 description 1
- AGHYMXKKEXDUTA-UHFFFAOYSA-N 4-methyl-n-phenylaniline Chemical compound C1=CC(C)=CC=C1NC1=CC=CC=C1 AGHYMXKKEXDUTA-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Description
Wykryto, ze otrzymuje sie latwo roz¬ puszczalne w wodzie zasadowe barwniki trójfenyloinetanowe O' bardzo dobrej od¬ pornosci na dzialanie swiatla i dajace czy¬ ste zabarwienia, kondensujac w ilosciach czasteczkowych czterohydro - oksyalkylo - dwuaminobenzofenony, podstawione lub riiepodstawione, z p - alkoksy- lub p - al- kylo - dwufenyloaniina.Przyklad L Kondensujac w sposób zwykly jedna czasteczke 4,4* - czterohy- droksyetylodwuaminobenzofenonu z jedna czasteczika 4 - etoksydwufenyloaniiny w o- becnosci tlenochlorku fosforu, otrzymuje sie barwnik, bardzOi dobrze rozpuszczajacy sie w wodzie, który barwi bawelne, trak¬ towana tanina, welne i jedwab na jaskra¬ we odcienie niebieskie o wybitnej trwalo¬ sci na dzialanie swiatla i który posiada wzór nastepujacy:HOH4C^ HOH.C/ N: CMiOH / x N-C2H4OH CI C I I NH I I OCH, Przyklad II. Przez kondensacje jed¬ nej czasteczki 4,4' - czterohydroksyetylo- dwuamino - 2,2' - dwumetylo - benzofeno- nu z jedna czasteczka 4 - metylodwufeny- loaminy w obecnosci tlenochlorku fosforo¬ wego otrzymuje sie barwnik niebieski, bar¬ dzo dobrze rozpuszczajacy sie w wodzie, który posiada bardziej zielona barwe, niz barwnik, przytoczony w przykladzie I, i który, posiadajac taka sama odpornosc, odpowiada wzorowi nastepujacemu: HOHAC^ HOHtCo N- \ CH, C C2ff40r7 / N-CiHfili Cl CH2 NH CH.A — 2 — PLIt has been found that water-soluble basic triphenylethane dyes of very good light fastness and a pure color are obtained by condensing in molecular amounts tetrahydro - oxyalkyl - diaminobenzophenones, substituted or disubstituted, or with p - alkoxy p-Alkyl-diphenylanin. Example L Condensing in the usual manner one molecule of 4,4 * - tetrahydroxyethyl diaminobenzophenone with one molecule of 4-ethoxydiphenylanin in the presence of phosphorus oxychloride, a dye is obtained which is very and well soluble in water. cotton, treated tannin, wool and silk, bright blue shades with outstanding lightfastness and which has the following formula: HOH4C ^ HOH. C / N: CMiOH / x N-C2H4OHCII NH II OCH, Example II. By condensation of one molecule of 4,4'-tetrahydroxyethyl-diamino-2,2'-dimethyl-benzophenone with one molecule of 4-methyldiphenylamine in the presence of phosphorus oxychloride a blue dye is obtained, which dissolves very well in water, which has a greener color than the dye in example I, and which, while having the same resistance, corresponds to the formula: HOHAC ^ HOHtCo N- \ CH, C C2ff40r7 / N-CiHfil Cl CH2 NH CH.A - 2 - PL
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| PL23809B1 true PL23809B1 (en) | 1936-10-31 |
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