NZ309676A - Coatable biocidal compositions comprising an acrylate emulsion polymer comprising acrylate or methacrylate and carboxylic acid monomers; and a metal salt complexing agent - Google Patents
Coatable biocidal compositions comprising an acrylate emulsion polymer comprising acrylate or methacrylate and carboxylic acid monomers; and a metal salt complexing agentInfo
- Publication number
- NZ309676A NZ309676A NZ309676A NZ30967696A NZ309676A NZ 309676 A NZ309676 A NZ 309676A NZ 309676 A NZ309676 A NZ 309676A NZ 30967696 A NZ30967696 A NZ 30967696A NZ 309676 A NZ309676 A NZ 309676A
- Authority
- NZ
- New Zealand
- Prior art keywords
- acrylate
- composition
- coating
- compositions
- group
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 134
- 230000003115 biocidal effect Effects 0.000 title claims description 50
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 title claims description 29
- 239000000178 monomer Substances 0.000 title claims description 21
- 150000003839 salts Chemical class 0.000 title claims description 17
- 239000004908 Emulsion polymer Substances 0.000 title claims description 16
- 229910052751 metal Inorganic materials 0.000 title claims description 14
- 239000002184 metal Substances 0.000 title claims description 14
- 239000008139 complexing agent Substances 0.000 title claims description 13
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 title claims description 8
- 150000001735 carboxylic acids Chemical class 0.000 title description 2
- 239000000758 substrate Substances 0.000 claims description 95
- 238000000576 coating method Methods 0.000 claims description 62
- 239000003139 biocide Substances 0.000 claims description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- 239000011248 coating agent Substances 0.000 claims description 41
- 239000000839 emulsion Substances 0.000 claims description 33
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 24
- 125000004122 cyclic group Chemical group 0.000 claims description 24
- 230000000052 comparative effect Effects 0.000 claims description 22
- 229910000077 silane Inorganic materials 0.000 claims description 22
- -1 tri- ethylene glycol ethers Chemical class 0.000 claims description 14
- 230000001464 adherent effect Effects 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 238000012360 testing method Methods 0.000 claims description 12
- 125000003178 carboxy group Chemical class [H]OC(*)=O 0.000 claims description 10
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 9
- 150000001875 compounds Chemical class 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 239000011701 zinc Substances 0.000 claims description 9
- 125000004103 aminoalkyl group Chemical group 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 230000000845 anti-microbial effect Effects 0.000 claims description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
- 230000002538 fungal effect Effects 0.000 claims description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 150000002989 phenols Chemical class 0.000 claims description 6
- ODIUACFRPDQOPA-UHFFFAOYSA-M C(C=C/C(=O)[O-])(=O)[O-].[Zn+].[NH4+] Chemical compound C(C=C/C(=O)[O-])(=O)[O-].[Zn+].[NH4+] ODIUACFRPDQOPA-UHFFFAOYSA-M 0.000 claims description 5
- RWPOLKFFARHZDK-UHFFFAOYSA-N NC1=CC=CC=C1.N.[Ca+2] Chemical compound NC1=CC=CC=C1.N.[Ca+2] RWPOLKFFARHZDK-UHFFFAOYSA-N 0.000 claims description 5
- MUHUIJPSGRCRFX-UHFFFAOYSA-M [Zn+].C([O-])([O-])=O.[NH4+] Chemical compound [Zn+].C([O-])([O-])=O.[NH4+] MUHUIJPSGRCRFX-UHFFFAOYSA-M 0.000 claims description 5
- SXGBQDIIBBUDKN-UHFFFAOYSA-N acetic acid;azane;zinc Chemical compound [NH4+].[Zn].CC([O-])=O SXGBQDIIBBUDKN-UHFFFAOYSA-N 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- GIYDISLTIIILLG-UHFFFAOYSA-N azane;prop-2-enoic acid;zinc Chemical compound [NH4+].[Zn].[O-]C(=O)C=C GIYDISLTIIILLG-UHFFFAOYSA-N 0.000 claims description 5
- 239000006184 cosolvent Substances 0.000 claims description 5
- WJCNZQLZVWNLKY-UHFFFAOYSA-N thiabendazole Chemical compound S1C=NC(C=2NC3=CC=CC=C3N=2)=C1 WJCNZQLZVWNLKY-UHFFFAOYSA-N 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- BEZPOYJGECASSD-UHFFFAOYSA-N CC(ON)=O.N.[Zn+2] Chemical compound CC(ON)=O.N.[Zn+2] BEZPOYJGECASSD-UHFFFAOYSA-N 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims description 4
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 4
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 3
- JLHMJWHSBYZWJJ-UHFFFAOYSA-N 1,2-thiazole 1-oxide Chemical class O=S1C=CC=N1 JLHMJWHSBYZWJJ-UHFFFAOYSA-N 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 3
- 150000001346 alkyl aryl ethers Chemical class 0.000 claims description 3
- DIOLOCSXUMYFJN-UHFFFAOYSA-N calcium;azane Chemical compound N.[Ca+2] DIOLOCSXUMYFJN-UHFFFAOYSA-N 0.000 claims description 3
- 235000013985 cinnamic acid Nutrition 0.000 claims description 3
- WBYWAXJHAXSJNI-UHFFFAOYSA-N cinnamic acid group Chemical class C(C=CC1=CC=CC=C1)(=O)O WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 claims description 3
- 150000008056 dicarboxyimides Chemical class 0.000 claims description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 3
- 150000004053 quinones Chemical class 0.000 claims description 3
- 150000003457 sulfones Chemical class 0.000 claims description 3
- 150000004867 thiadiazoles Chemical class 0.000 claims description 3
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 claims description 3
- PNFOZEDBTQHPPH-UHFFFAOYSA-M C([O-])([O-])=O.C(CN)N.[Ca+].[NH4+] Chemical compound C([O-])([O-])=O.C(CN)N.[Ca+].[NH4+] PNFOZEDBTQHPPH-UHFFFAOYSA-M 0.000 claims description 2
- 150000004891 diazines Chemical class 0.000 claims description 2
- 125000004188 dichlorophenyl group Chemical group 0.000 claims description 2
- 239000012990 dithiocarbamate Substances 0.000 claims description 2
- 150000004659 dithiocarbamates Chemical class 0.000 claims description 2
- ZJXZSIYSNXKHEA-UHFFFAOYSA-N ethyl dihydrogen phosphate Chemical class CCOP(O)(O)=O ZJXZSIYSNXKHEA-UHFFFAOYSA-N 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 150000003567 thiocyanates Chemical class 0.000 claims description 2
- KEBUEWXZQBMCNB-UHFFFAOYSA-N 1h-benzimidazol-2-yl carbamate Chemical class C1=CC=C2NC(OC(=O)N)=NC2=C1 KEBUEWXZQBMCNB-UHFFFAOYSA-N 0.000 claims 2
- 229940099451 3-iodo-2-propynylbutylcarbamate Drugs 0.000 claims 2
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims 2
- GHEQMRDSHPGZIK-UHFFFAOYSA-N FC=1C(=C(C=CC1)N(C(=O)NC(C1=CC=CC=C1)=O)Cl)F Chemical compound FC=1C(=C(C=CC1)N(C(=O)NC(C1=CC=CC=C1)=O)Cl)F GHEQMRDSHPGZIK-UHFFFAOYSA-N 0.000 claims 2
- CRQQGFGUEAVUIL-UHFFFAOYSA-N chlorothalonil Chemical compound ClC1=C(Cl)C(C#N)=C(Cl)C(C#N)=C1Cl CRQQGFGUEAVUIL-UHFFFAOYSA-N 0.000 claims 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 2
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 claims 2
- 229920006395 saturated elastomer Polymers 0.000 claims 2
- 150000003852 triazoles Chemical class 0.000 claims 2
- UUIVKBHZENILKB-UHFFFAOYSA-N 2,2-dibromo-2-cyanoacetamide Chemical compound NC(=O)C(Br)(Br)C#N UUIVKBHZENILKB-UHFFFAOYSA-N 0.000 claims 1
- VDGRKHYRTPJTLO-UHFFFAOYSA-N ClOC(C(Cl)(Cl)Cl)(C1=CC=CC=C1)Cl Chemical compound ClOC(C(Cl)(Cl)Cl)(C1=CC=CC=C1)Cl VDGRKHYRTPJTLO-UHFFFAOYSA-N 0.000 claims 1
- NSEQHAPSDIEVCD-UHFFFAOYSA-N N.[Zn+2] Chemical compound N.[Zn+2] NSEQHAPSDIEVCD-UHFFFAOYSA-N 0.000 claims 1
- 230000000536 complexating effect Effects 0.000 claims 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 1
- 125000000232 haloalkynyl group Chemical group 0.000 claims 1
- 230000002035 prolonged effect Effects 0.000 claims 1
- 150000003918 triazines Chemical class 0.000 claims 1
- 229920000058 polyacrylate Polymers 0.000 description 24
- 239000011440 grout Substances 0.000 description 18
- 239000004014 plasticizer Substances 0.000 description 12
- 238000001035 drying Methods 0.000 description 11
- 239000000919 ceramic Substances 0.000 description 10
- 150000004756 silanes Chemical class 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- 239000001993 wax Substances 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000004816 latex Substances 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 230000028070 sporulation Effects 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 238000013270 controlled release Methods 0.000 description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000003755 preservative agent Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- 230000000813 microbial effect Effects 0.000 description 4
- 239000004209 oxidized polyethylene wax Substances 0.000 description 4
- 235000013873 oxidized polyethylene wax Nutrition 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 241000233866 Fungi Species 0.000 description 3
- 239000003619 algicide Substances 0.000 description 3
- 230000002421 anti-septic effect Effects 0.000 description 3
- 239000000645 desinfectant Substances 0.000 description 3
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 230000002070 germicidal effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000005065 mining Methods 0.000 description 3
- 230000002335 preservative effect Effects 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- WTLBZVNBAKMVDP-UHFFFAOYSA-N tris(2-butoxyethyl) phosphate Chemical compound CCCCOCCOP(=O)(OCCOCCCC)OCCOCCCC WTLBZVNBAKMVDP-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 2
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000004599 antimicrobial Substances 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 2
- SKKTUOZKZKCGTB-UHFFFAOYSA-N butyl carbamate Chemical compound CCCCOC(N)=O SKKTUOZKZKCGTB-UHFFFAOYSA-N 0.000 description 2
- 150000004657 carbamic acid derivatives Chemical class 0.000 description 2
- UHZZMRAGKVHANO-UHFFFAOYSA-M chlormequat chloride Chemical compound [Cl-].C[N+](C)(C)CCCl UHZZMRAGKVHANO-UHFFFAOYSA-M 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 230000005923 long-lasting effect Effects 0.000 description 2
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 description 2
- 150000001282 organosilanes Chemical class 0.000 description 2
- 239000002304 perfume Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000011115 styrene butadiene Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- YYDNBUBMBZRNQQ-UHFFFAOYSA-N 1-methyl-4-methylsulfonylbenzene Chemical compound CC1=CC=C(S(C)(=O)=O)C=C1 YYDNBUBMBZRNQQ-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- HFOCAQPWSXBFFN-UHFFFAOYSA-N 2-methylsulfonylbenzaldehyde Chemical compound CS(=O)(=O)C1=CC=CC=C1C=O HFOCAQPWSXBFFN-UHFFFAOYSA-N 0.000 description 1
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 1
- 241000228212 Aspergillus Species 0.000 description 1
- 241000223678 Aureobasidium pullulans Species 0.000 description 1
- XNCOSPRUTUOJCJ-UHFFFAOYSA-N Biguanide Chemical compound NC(N)=NC(N)=N XNCOSPRUTUOJCJ-UHFFFAOYSA-N 0.000 description 1
- 229910001369 Brass Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 241000221955 Chaetomium Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- 102100020746 Dolichol-phosphate mannosyltransferase subunit 1 Human genes 0.000 description 1
- 101000932202 Homo sapiens Dolichol-phosphate mannosyltransferase subunit 1 Proteins 0.000 description 1
- PWKSKIMOESPYIA-BYPYZUCNSA-N L-N-acetyl-Cysteine Chemical compound CC(=O)N[C@@H](CS)C(O)=O PWKSKIMOESPYIA-BYPYZUCNSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 241000606507 Talaromyces pinophilus Species 0.000 description 1
- 241001149558 Trichoderma virens Species 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000003609 aryl vinyl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000008047 benzoylureas Chemical class 0.000 description 1
- 239000010951 brass Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- NLCKLZIHJQEMCU-UHFFFAOYSA-N cyano prop-2-enoate Chemical class C=CC(=O)OC#N NLCKLZIHJQEMCU-UHFFFAOYSA-N 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- HHICRQHZPBOQPI-UHFFFAOYSA-L diazanium;zinc;dicarbonate Chemical compound [NH4+].[NH4+].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O HHICRQHZPBOQPI-UHFFFAOYSA-L 0.000 description 1
- 229960002380 dibutyl phthalate Drugs 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 239000000539 dimer Chemical class 0.000 description 1
- 238000004851 dishwashing Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 150000001469 hydantoins Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000011534 incubation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- PQIOSYKVBBWRRI-UHFFFAOYSA-N methylphosphonyl difluoride Chemical group CP(F)(F)=O PQIOSYKVBBWRRI-UHFFFAOYSA-N 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 230000003641 microbiacidal effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- XJTVQSAAHBCSBG-UHFFFAOYSA-N n-[chloro(phenyl)carbamoyl]benzamide Chemical compound C=1C=CC=CC=1N(Cl)C(=O)NC(=O)C1=CC=CC=C1 XJTVQSAAHBCSBG-UHFFFAOYSA-N 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- OSIVISXRDMXJQR-UHFFFAOYSA-M potassium;2-[ethyl(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctylsulfonyl)amino]acetate Chemical compound [K+].[O-]C(=O)CN(CC)S(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F OSIVISXRDMXJQR-UHFFFAOYSA-M 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/502,166 US5585407A (en) | 1995-07-13 | 1995-07-13 | Water-based coatable compositions comprising reaction products of acrylic emulsion polymers with organoalkoxysilanes |
| PCT/US1996/009540 WO1997003135A1 (en) | 1995-07-13 | 1996-06-07 | Coatable biocidal compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NZ309676A true NZ309676A (en) | 1999-09-29 |
Family
ID=23996644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NZ309676A NZ309676A (en) | 1995-07-13 | 1996-06-07 | Coatable biocidal compositions comprising an acrylate emulsion polymer comprising acrylate or methacrylate and carboxylic acid monomers; and a metal salt complexing agent |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5585407A (enExample) |
| EP (1) | EP0861302B1 (enExample) |
| JP (1) | JPH11508941A (enExample) |
| KR (1) | KR100433867B1 (enExample) |
| CN (1) | CN1148424C (enExample) |
| AU (1) | AU709129B2 (enExample) |
| BR (1) | BR9609609A (enExample) |
| NZ (1) | NZ309676A (enExample) |
| WO (1) | WO1997003135A1 (enExample) |
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1248268A (zh) * | 1997-01-15 | 2000-03-22 | 伊斯曼化学公司 | 水性氢化硅可交联胶乳组合物和其制备方法 |
| US5891966A (en) * | 1997-12-11 | 1999-04-06 | Eastman Chemical Company | Waterborne silicon hydride crosslinkable latex compositions and methods of preparing the same |
| US5786282A (en) * | 1997-02-25 | 1998-07-28 | Barnhardt Manufacturing Company | Opened wet processed intermediate natural fiber product suitable for formation into end use fiber products with long-lasting antimicrobial properties and method |
| ES2327369T3 (es) | 1998-02-12 | 2009-10-28 | Surfacine Development Company, Llc | Compuestos desinfectantes que proporcionan accion biocida prolongada. |
| DE19814133A1 (de) * | 1998-03-30 | 1999-10-07 | Espe Dental Ag | Selbstdesinfizierende Kunststoffe und ihre Verwendung im dentalen und dentaltechnischen Bereich |
| US6042877A (en) * | 1998-07-28 | 2000-03-28 | 3M Innovative Properties Company | Method for the manufacture of anti-microbial articles |
| JP2000119587A (ja) * | 1998-10-20 | 2000-04-25 | Clariant Polymer Kk | コーティング組成物 |
| US6221976B1 (en) | 1999-01-25 | 2001-04-24 | The Dow Chemical Company | Polymers containing partially neutralized silanols |
| US6420455B1 (en) | 1999-06-18 | 2002-07-16 | 3M Innovative Properties Company | Antimicrobial composition containing photosensitizers articles, and methods of use |
| US6432396B1 (en) | 2000-07-06 | 2002-08-13 | 3M Innovative Properties Company | Limiting the presence of microorganisms using polymer-bound metal-containing compositions |
| US7459167B1 (en) | 2000-07-27 | 2008-12-02 | 3M Innovative Properties Company | Biocidal polyurethane compositions and methods of use |
| US20030108700A1 (en) * | 2001-11-21 | 2003-06-12 | 3M Innovative Properties Company | Plastic shipping and storage containers and composition and method therefore |
| US20100160445A1 (en) * | 2002-01-17 | 2010-06-24 | Carlson Paul E | Synergistic Mixtures of OPP and DGH |
| US7262222B2 (en) * | 2002-01-17 | 2007-08-28 | Verichem, Inc. | Synergistic mixtures of o-phenylphenol and other nitrogen and aldehyde microbiocides |
| KR20040038041A (ko) * | 2002-10-31 | 2004-05-08 | 에스케이케미칼주식회사 | 살균제 조성물 및 이를 이용한 살균방법 |
| US6897191B2 (en) | 2003-04-30 | 2005-05-24 | Specialty Construction Brands, Inc. | Disinfecting, antimicrobial sealing compositions and methods of using the same |
| EP1667741B1 (en) * | 2003-09-08 | 2009-10-07 | Ethicon, Inc. | Cyanoacrylate monomer formulation containing diiodomethyl-p-tolylsulfone |
| US7902140B1 (en) | 2003-10-21 | 2011-03-08 | Bissell Homecare, Inc. | Carpet cleaning with fungicide |
| WO2006028491A1 (en) * | 2004-02-13 | 2006-03-16 | University Of Florida | Biocides based on silanol terminated silanes and siloxanes |
| WO2006031736A2 (en) * | 2004-09-13 | 2006-03-23 | Horsehead Corp. | Bacteria and mold resistant wallboard |
| US7484261B2 (en) | 2004-09-30 | 2009-02-03 | Kimberly-Clark Worldwide, Inc. | Spot cleaner |
| US20070009695A1 (en) * | 2005-07-07 | 2007-01-11 | Lancer Partnership, Ltd. | Method and apparatus for a mold barrier |
| US8124169B2 (en) | 2005-12-14 | 2012-02-28 | 3M Innovative Properties Company | Antimicrobial coating system |
| US9247736B2 (en) | 2005-12-14 | 2016-02-02 | 3M Innovative Properties Company | Antimicrobial adhesive films |
| US9668476B2 (en) * | 2006-02-23 | 2017-06-06 | Lanxess Corporation | Removable antimicrobial coating compositions and methods of use |
| EP1991624A2 (en) * | 2006-02-23 | 2008-11-19 | E.I. Du Pont De Nemours And Company | Removable antimicrobial coating compositions and methods of use |
| US7585919B2 (en) * | 2006-09-26 | 2009-09-08 | 3M Innovative Properties Company | Polymer derived from monomers with long-chain aliphatic, poly(oxyalkylene) and substrate-reactive groups |
| EP2342282B1 (en) * | 2008-09-26 | 2016-12-28 | 3M Innovative Properties Company | Antimicrobial and antifouling polymeric materials |
| US20110177146A1 (en) * | 2009-07-27 | 2011-07-21 | E. I. Du Pont De Nemours And Company | Removable antimicrobial coating compositions containing cationic rheology agent and methods of use |
| US20110182959A1 (en) | 2009-07-27 | 2011-07-28 | E.I. Du Pont De Nemours And Company. | Removable antimicrobial coating compositions containing acid-activated rheology agent and methods of use |
| US20120148751A1 (en) | 2010-12-14 | 2012-06-14 | Ecolab Usa Inc. | Wear resistant antimicrobial compositions and methods of use |
| EP2468825A1 (en) | 2010-12-21 | 2012-06-27 | Akzo Nobel Coatings International B.V. | Antifouling coating composition |
| US9580574B2 (en) | 2012-12-12 | 2017-02-28 | Galata Chemicals Llc | Bio-based biocide compositions and methods of preserving therewith |
| CN104893380A (zh) * | 2015-05-18 | 2015-09-09 | 苏州市贝克生物科技有限公司 | 一种医用防霉涂料及其制备方法 |
| CN104893379A (zh) * | 2015-05-18 | 2015-09-09 | 苏州市贝克生物科技有限公司 | 一种医用快干杀菌防霉涂料及其制备方法 |
| CN104893456A (zh) * | 2015-05-18 | 2015-09-09 | 苏州市贝克生物科技有限公司 | 一种医用杀菌防霉涂料及其制备方法 |
| CN110114453A (zh) * | 2016-09-08 | 2019-08-09 | 莫尔豪斯医学院 | 清洁组合物,其制造方法和使用 |
| GB201708025D0 (en) * | 2017-05-18 | 2017-07-05 | Clearstream Tech Ltd | A laminate membrane, an implant comprising the laminate membrane and a method of manufacturing the same |
| US20190230929A1 (en) * | 2018-01-30 | 2019-08-01 | W.M. Barr & Company, Inc. | Composition for residual sanitization |
| RU2687356C1 (ru) * | 2018-04-13 | 2019-05-13 | Общество С Ограниченной Ответственностью "Лаборатория Био Зет" | Состав для придания антимикробных свойств продуктам или материалам |
| JP7324720B2 (ja) * | 2020-01-27 | 2023-08-10 | 三菱鉛筆株式会社 | 抗菌粒子水分散体 |
| US12342824B2 (en) | 2020-04-28 | 2025-07-01 | Apex Biomaterials Inc. | Metal-infused antimicrobial material and method of preparation thereof |
| WO2023075664A1 (en) | 2021-10-26 | 2023-05-04 | Rise Research Institutes of Sweden AB | A disinfectant film-forming composition and a dry disinfectant film formed on a surface from the film forming composition |
| CN116535914A (zh) * | 2023-04-26 | 2023-08-04 | 广东美涂士建材股份有限公司 | 一种耐磨抗菌涂料及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL139174B (nl) * | 1963-12-31 | 1973-06-15 | Geigy Ag J R | Werkwijze voor het bereiden van triamino-s-triazinederivaten, geschikt voor het bereiden van oppervlakteveredelingsmiddelen en werkwijze voor het bereiden van oppervlakteveredelingsmiddelen die deze verbindingen bevatten, alsmede voorwerpen die met deze oppervlakteveredelingsmiddelen behandeld zijn. |
| US3666698A (en) * | 1970-12-14 | 1972-05-30 | Sherwin Williams Co | Water-soluble polyester resin containing phenylindan dicarboxylic acid |
| US3837875A (en) * | 1973-01-19 | 1974-09-24 | J Murphy | Composition for cleaning, sealing, preserving, protecting and beautifying host materials |
| JPS5319345B2 (enExample) * | 1974-05-17 | 1978-06-20 | ||
| US3976501A (en) * | 1974-09-18 | 1976-08-24 | Blue Maurice R | Process for cleaning and polishing a floor |
| US4340520A (en) * | 1980-06-27 | 1982-07-20 | Union Carbide Corporation | Polyester aminoorganosilane salt/polyalkylene oxide compositions for improved glass fiber treatment |
| US4340524A (en) * | 1980-06-30 | 1982-07-20 | Union Carbide Corporation | Water-resistant latex sealants |
| US4500337A (en) * | 1980-09-03 | 1985-02-19 | Young Robert W | Adherent controlled release microbiocides containing hydrolyzable silanes and organic titanium compounds |
| US4500339A (en) * | 1980-09-03 | 1985-02-19 | Young Robert W | Adherent controlled release microbiocides containing hydrolyzable silanes |
| US4601954A (en) * | 1984-03-30 | 1986-07-22 | Servicemaster Industries, Inc. | Disinfectant formulation |
| JPS6172071A (ja) * | 1984-09-17 | 1986-04-14 | Yuuhoo Chem Kk | 被覆剤組成物 |
| US5154920A (en) * | 1985-03-13 | 1992-10-13 | Ecolab Inc. | Disinfectant polymeric coatings for hard surfaces |
| US4818536A (en) * | 1986-06-05 | 1989-04-04 | The Dow Chemical Company | Emulsfiable polymer concentrate controlled delivery and release system |
| US5061485A (en) * | 1987-05-12 | 1991-10-29 | Ecolab Inc. | Disinfectant polymeric coatings for hard surfaces |
| JP2600343B2 (ja) * | 1988-10-28 | 1997-04-16 | ダイキン工業株式会社 | 防菌防黴剤組成物 |
| US5089205A (en) * | 1989-09-25 | 1992-02-18 | Becton, Dickinson And Company | Process for producing medical devices having antimicrobial properties |
| US5234974A (en) * | 1990-07-26 | 1993-08-10 | S. C. Johnson & Son, Inc. | Alkali-soluble hydrophilic polymer coatings |
| JP2517785B2 (ja) * | 1990-08-02 | 1996-07-24 | 信越化学工業株式会社 | 含浸性防水剤組成物 |
| US5118534A (en) * | 1991-02-07 | 1992-06-02 | The Dow Chemical Company | Alkylthioethanamine carbamic acid derivatives and their use in biocidal compositions |
| FR2684107B1 (fr) * | 1991-11-27 | 1995-06-23 | Rhone Poulenc Chimie | Dispersions aqueuses de polymeres styrene-acrylate carboxyle et leurs utilisations comme liant dans des compositions adhesives et de revetement. |
| KR950018342A (ko) * | 1993-12-15 | 1995-07-22 | 윌리엄 이. 램버트 3세 | 백악질 기질에 대한 코팅제의 접착력을 개선시키는 혼합조성물 |
-
1995
- 1995-07-13 US US08/502,166 patent/US5585407A/en not_active Expired - Lifetime
-
1996
- 1996-06-07 AU AU59902/96A patent/AU709129B2/en not_active Ceased
- 1996-06-07 WO PCT/US1996/009540 patent/WO1997003135A1/en not_active Ceased
- 1996-06-07 EP EP96917266A patent/EP0861302B1/en not_active Expired - Lifetime
- 1996-06-07 BR BR9609609A patent/BR9609609A/pt not_active IP Right Cessation
- 1996-06-07 CN CNB961954426A patent/CN1148424C/zh not_active Expired - Fee Related
- 1996-06-07 KR KR10-1998-0700207A patent/KR100433867B1/ko not_active Expired - Fee Related
- 1996-06-07 NZ NZ309676A patent/NZ309676A/en unknown
- 1996-06-07 JP JP9505806A patent/JPH11508941A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| AU5990296A (en) | 1997-02-10 |
| MX9800314A (es) | 1998-07-31 |
| US5585407A (en) | 1996-12-17 |
| KR19990028905A (ko) | 1999-04-15 |
| HK1015816A1 (en) | 1999-10-22 |
| KR100433867B1 (ko) | 2004-12-17 |
| BR9609609A (pt) | 1999-05-25 |
| CN1190422A (zh) | 1998-08-12 |
| EP0861302A1 (en) | 1998-09-02 |
| EP0861302B1 (en) | 2001-11-07 |
| AU709129B2 (en) | 1999-08-19 |
| CN1148424C (zh) | 2004-05-05 |
| WO1997003135A1 (en) | 1997-01-30 |
| JPH11508941A (ja) | 1999-08-03 |
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Legal Events
| Date | Code | Title | Description |
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| RENW | Renewal (renewal fees accepted) | ||
| RENW | Renewal (renewal fees accepted) |