NO996308L - Conversion of synthesis gas to lower olefins using modified molecular sieves - Google Patents

Conversion of synthesis gas to lower olefins using modified molecular sieves

Info

Publication number
NO996308L
NO996308L NO996308A NO996308A NO996308L NO 996308 L NO996308 L NO 996308L NO 996308 A NO996308 A NO 996308A NO 996308 A NO996308 A NO 996308A NO 996308 L NO996308 L NO 996308L
Authority
NO
Norway
Prior art keywords
molecular sieves
conversion
complexes
catalyst precursor
modified molecular
Prior art date
Application number
NO996308A
Other languages
Norwegian (no)
Other versions
NO996308D0 (en
Inventor
Hsiang-Ning Sun
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of NO996308D0 publication Critical patent/NO996308D0/en
Publication of NO996308L publication Critical patent/NO996308L/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Fremgangsmåte for inkorporering av en eller flere Fischer-Tropsch-katalysatorer i molekylsikter, omfattende anbringelse av ubehandlede molekylsikter i kontakt med en ¿ katalysatorforløper i en inert atmosfære under første betingelser som er effektive med hensyn til dannelse av komplekser omfattende nevnte katalysatorforløper og nevnte molekylsikter; og eksponering av nevnte komplekser for en inert atmosfære og for andre betingelser som er effektive med hensyn til å dissosiere flyktige komponenter fra nevnte katalysatorforløper og til å fordampe oppløsningsmiddel fra nevnte komplekser, under dannelse av modifiserte molekylsikter omfattende en katalytisk effektiv mengde av en katalysator valgt fra gruppen bestående av j em, kobolt, nikkel, krom, mangan og rhodium.A method of incorporating one or more Fischer-Tropsch catalysts into molecular sieves, comprising placing untreated molecular sieves in contact with a catalyst precursor in an inert atmosphere under initial conditions effective in forming complexes comprising said catalyst precursor and said molecular sieves; and exposing said complexes to an inert atmosphere and to other conditions effective for dissociating volatile components from said catalyst precursor and for evaporating solvent from said complexes, to produce modified molecular sieves comprising a catalytically effective amount of a catalyst selected from the group consisting of em, cobalt, nickel, chromium, manganese and rhodium.

NO996308A 1997-06-18 1999-12-17 Conversion of synthesis gas to lower olefins using modified molecular sieves NO996308L (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5014497P 1997-06-18 1997-06-18
PCT/US1998/012703 WO1998057743A2 (en) 1997-06-18 1998-06-18 Conversion of synthesis gas to lower olefins using modified molecular sieves

Publications (2)

Publication Number Publication Date
NO996308D0 NO996308D0 (en) 1999-12-17
NO996308L true NO996308L (en) 2000-02-07

Family

ID=21963592

Family Applications (1)

Application Number Title Priority Date Filing Date
NO996308A NO996308L (en) 1997-06-18 1999-12-17 Conversion of synthesis gas to lower olefins using modified molecular sieves

Country Status (8)

Country Link
EP (1) EP0989908A2 (en)
CN (1) CN1260823A (en)
AR (1) AR013002A1 (en)
AU (1) AU8151298A (en)
CA (1) CA2289993A1 (en)
NO (1) NO996308L (en)
TW (1) TW482750B (en)
WO (1) WO1998057743A2 (en)

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US6331574B1 (en) * 1999-10-08 2001-12-18 Exxonmobil Research And Engineering Company Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst compositions, use of the catalysts for conducting such reactions, and the products of such reactions
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
BG109246A (en) * 2005-07-29 2005-11-30 АНГЕЛОВ Чавдар Method for producing hydrocarbons from hydrogen dioxide
EP1887071A1 (en) * 2006-07-31 2008-02-13 Edmund Dr.-Ing. Wagner Process for the production of synthetic hydrocarbons and derivatives from carbon dioxide and hydrogen used as synthesis gas
KR100903439B1 (en) * 2007-10-15 2009-06-18 한국화학연구원 Preparation method of direct synthesis of light hydrocarbons from natural gas
JP2010116328A (en) * 2008-11-11 2010-05-27 Nippon Oil Corp Method for producing unsaturated hydrocarbon and oxygen-containing compound, catalyst and method for producing the same
TWI473652B (en) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
ES2655323T3 (en) * 2009-12-18 2018-02-19 Basf Se Zeolite containing iron, process for the preparation of zeolites containing iron and process for catalytic reduction of nitrogen oxides
JP6436495B2 (en) 2013-07-04 2018-12-12 トタル リサーチ アンド テクノロジー フエリユイ Catalyst composition comprising small size molecular sieve crystals deposited on a porous material
CN107774302B (en) * 2016-08-26 2020-08-14 中国科学院大连化学物理研究所 Method for preparing liquid fuel and co-producing low-carbon olefin by directly converting catalyst and synthesis gas
CN109704900B (en) * 2017-10-26 2021-11-30 中国石油化工股份有限公司 Method for preparing olefin by synthesis gas one-step method
CN109701634B (en) * 2017-10-26 2021-09-03 中国石油化工股份有限公司 Catalyst composition for preparing low-carbon hydrocarbon from synthesis gas and application thereof
CN109704899B (en) * 2017-10-26 2022-07-08 中国石油化工股份有限公司 Method for preparing olefin from synthesis gas
CN109701631B (en) * 2017-10-26 2021-10-01 中国石油化工股份有限公司 Catalyst for directly preparing low-carbon hydrocarbon from synthetic gas and its use method
CN109701628A (en) * 2017-10-26 2019-05-03 中国石油化工股份有限公司 Composite catalyst containing phosphate aluminium molecular sieve and its application in one-step method from syngas alkene
CN111111762B (en) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 Catalyst composition for directly preparing low-carbon olefin by carbon dioxide hydrogenation and application thereof
CN111111760B (en) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 Catalyst for preparing low-carbon olefin by carbon dioxide hydrogenation and application thereof
CN111111766A (en) * 2018-10-30 2020-05-08 中国石油化工股份有限公司 Method for utilizing carbon dioxide
CN111111763B (en) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 Catalyst for directly preparing low-carbon olefin by carbon dioxide hydrogenation and application method thereof
CN111346671B (en) * 2018-12-21 2023-03-24 中国科学院大连化学物理研究所 Catalyst and method for preparing low aromatic hydrocarbon liquid fuel by directly converting synthesis gas
WO2020197890A1 (en) 2019-03-28 2020-10-01 Exxonmobil Chemical Patents Inc. Processes for converting benzene and/or toluene via methylation
CN113574037A (en) 2019-03-28 2021-10-29 埃克森美孚化学专利公司 Method and system for converting benzene and/or toluene via methylation
US11643375B2 (en) 2019-03-28 2023-05-09 Exxonmobil Chemical Patents Inc. Processes for converting benzene and/or toluene via methylation
WO2023044278A1 (en) 2021-09-16 2023-03-23 Exxonmobil Chemical Patents Inc. Xylene isomer separation processes
WO2023064684A1 (en) 2021-10-12 2023-04-20 Exxonmobil Chemical Patents Inc. Staged alkylation for producing xylene products
WO2023204947A1 (en) 2022-04-19 2023-10-26 Exxonmobil Chemical Patents Inc. Processes for oxidizing p-xylene or p-xylene-containing mixtures

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4431746A (en) * 1981-06-26 1984-02-14 Mobil Oil Corporation Preparing metal-exchanged highly siliceous porous crystalline materials
US4962269A (en) * 1982-05-18 1990-10-09 Mobil Oil Corporation Isomerization process
US4502945A (en) * 1982-06-09 1985-03-05 Chevron Research Company Process for preparing olefins at high pressure
CA1196617A (en) * 1982-07-14 1985-11-12 George E. Morris Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas
US4552855A (en) * 1982-12-30 1985-11-12 Ozin Geoffrey A Metal zeolite catalyst preparation
DE3579802D1 (en) * 1984-12-21 1990-10-25 Mobil Oil Corp CASCADE DEWLING PROCESS.
DD233555A1 (en) * 1984-12-29 1986-03-05 Akad Wissenschaften Ddr PREPARATION OF LOW OLEFINE FROM SYNTHESEGAS MIXTURES
US4849575A (en) * 1987-11-25 1989-07-18 Uop Production of olefins
GB9005964D0 (en) * 1990-03-16 1990-05-09 Shell Int Research Catalyst preparation process
WO1993015836A1 (en) * 1992-02-18 1993-08-19 The Broken Hill Proprietary Company Limited Praseodymium containing cobalt catalysts for the fischer-tropsch process

Also Published As

Publication number Publication date
CN1260823A (en) 2000-07-19
TW482750B (en) 2002-04-11
AU8151298A (en) 1999-01-04
NO996308D0 (en) 1999-12-17
AR013002A1 (en) 2000-11-22
WO1998057743A2 (en) 1998-12-23
CA2289993A1 (en) 1998-12-23
EP0989908A2 (en) 2000-04-05
WO1998057743A3 (en) 1999-05-27

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