WO1998057743A3 - Conversion of synthesis gas to lower olefins using modified molecular sieves - Google Patents

Conversion of synthesis gas to lower olefins using modified molecular sieves Download PDF

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Publication number
WO1998057743A3
WO1998057743A3 PCT/US1998/012703 US9812703W WO9857743A3 WO 1998057743 A3 WO1998057743 A3 WO 1998057743A3 US 9812703 W US9812703 W US 9812703W WO 9857743 A3 WO9857743 A3 WO 9857743A3
Authority
WO
WIPO (PCT)
Prior art keywords
molecular sieves
conversion
complexes
synthesis gas
modified molecular
Prior art date
Application number
PCT/US1998/012703
Other languages
French (fr)
Other versions
WO1998057743A2 (en
Inventor
Hsiang-Ning Sun
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Priority to EP98931364A priority Critical patent/EP0989908A2/en
Priority to AU81512/98A priority patent/AU8151298A/en
Priority to CA002289993A priority patent/CA2289993A1/en
Publication of WO1998057743A2 publication Critical patent/WO1998057743A2/en
Publication of WO1998057743A3 publication Critical patent/WO1998057743A3/en
Priority to NO996308A priority patent/NO996308L/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/082—Decomposition and pyrolysis
    • B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

The present invention provides a method for incorporating one or more Fischer Tropsch catalysts into molecular sieves comprising contacting untreated molecular sieves with a catalyst precursor in an inert atmosphere under first conditions effective to form complexes comprising said catalyst precursor and said molecular sieves; and, exposing said complexes to an inert atmosphere and to second conditions effective to dissociate volatile components from said catalyst precursor and to evaporate solvent from said complexes, forming modified molecular sieves comprising a catalytically effective amount of a catalyst selected from the group consisting of iron, cobalt, nickel, chromium, manganese, and rhodium.
PCT/US1998/012703 1997-06-18 1998-06-18 Conversion of synthesis gas to lower olefins using modified molecular sieves WO1998057743A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP98931364A EP0989908A2 (en) 1997-06-18 1998-06-18 Conversion of synthesis gas to lower olefins using modified molecular sieves
AU81512/98A AU8151298A (en) 1997-06-18 1998-06-18 Conversion of synthesis gas to lower olefins using modified molecular sieves
CA002289993A CA2289993A1 (en) 1997-06-18 1998-06-18 Conversion of synthesis gas to lower olefins using modified molecular sieves
NO996308A NO996308L (en) 1997-06-18 1999-12-17 Conversion of synthesis gas to lower olefins using modified molecular sieves

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5014497P 1997-06-18 1997-06-18
US60/050,144 1997-06-18

Publications (2)

Publication Number Publication Date
WO1998057743A2 WO1998057743A2 (en) 1998-12-23
WO1998057743A3 true WO1998057743A3 (en) 1999-05-27

Family

ID=21963592

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/012703 WO1998057743A2 (en) 1997-06-18 1998-06-18 Conversion of synthesis gas to lower olefins using modified molecular sieves

Country Status (8)

Country Link
EP (1) EP0989908A2 (en)
CN (1) CN1260823A (en)
AR (1) AR013002A1 (en)
AU (1) AU8151298A (en)
CA (1) CA2289993A1 (en)
NO (1) NO996308L (en)
TW (1) TW482750B (en)
WO (1) WO1998057743A2 (en)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6331574B1 (en) 1999-10-08 2001-12-18 Exxonmobil Research And Engineering Company Process for the preparation of high activity carbon monoxide hydrogenation catalysts; the catalyst compositions, use of the catalysts for conducting such reactions, and the products of such reactions
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
BG109246A (en) * 2005-07-29 2005-11-30 АНГЕЛОВ Чавдар Method for producing hydrocarbons from hydrogen dioxide
EP1887071A1 (en) * 2006-07-31 2008-02-13 Edmund Dr.-Ing. Wagner Process for the production of synthetic hydrocarbons and derivatives from carbon dioxide and hydrogen used as synthesis gas
KR100903439B1 (en) * 2007-10-15 2009-06-18 한국화학연구원 Preparation method of direct synthesis of light hydrocarbons from natural gas
JP2010116328A (en) * 2008-11-11 2010-05-27 Nippon Oil Corp Method for producing unsaturated hydrocarbon and oxygen-containing compound, catalyst and method for producing the same
TWI473652B (en) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
CA2784860A1 (en) 2009-12-18 2011-06-23 Basf Se Ferrous zeolite, method for producing ferrous zeolites, and method for catalytically reducing nitrous oxides
BR112016000038B1 (en) 2013-07-04 2021-03-16 Total Research & Technology Feluy catalyst compositions comprising small size molecular sieve crystals deposited in a porous material
CN107774302B (en) * 2016-08-26 2020-08-14 中国科学院大连化学物理研究所 Method for preparing liquid fuel and co-producing low-carbon olefin by directly converting catalyst and synthesis gas
CN109701634B (en) * 2017-10-26 2021-09-03 中国石油化工股份有限公司 Catalyst composition for preparing low-carbon hydrocarbon from synthesis gas and application thereof
CN109704900B (en) * 2017-10-26 2021-11-30 中国石油化工股份有限公司 Method for preparing olefin by synthesis gas one-step method
CN109704899B (en) * 2017-10-26 2022-07-08 中国石油化工股份有限公司 Method for preparing olefin from synthesis gas
CN109701628A (en) * 2017-10-26 2019-05-03 中国石油化工股份有限公司 Composite catalyst containing phosphate aluminium molecular sieve and its application in one-step method from syngas alkene
CN109701631B (en) * 2017-10-26 2021-10-01 中国石油化工股份有限公司 Catalyst for directly preparing low-carbon hydrocarbon from synthetic gas and its use method
CN111111766A (en) * 2018-10-30 2020-05-08 中国石油化工股份有限公司 Method for utilizing carbon dioxide
CN111111760B (en) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 Catalyst for preparing low-carbon olefin by carbon dioxide hydrogenation and application thereof
CN111111763B (en) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 Catalyst for directly preparing low-carbon olefin by carbon dioxide hydrogenation and application method thereof
CN111111762B (en) * 2018-10-30 2022-10-11 中国石油化工股份有限公司 Catalyst composition for directly preparing low-carbon olefin by carbon dioxide hydrogenation and application thereof
CN111346671B (en) 2018-12-21 2023-03-24 中国科学院大连化学物理研究所 Catalyst and method for preparing low aromatic hydrocarbon liquid fuel by directly converting synthesis gas
US11643375B2 (en) 2019-03-28 2023-05-09 Exxonmobil Chemical Patents Inc. Processes for converting benzene and/or toluene via methylation
US11827579B2 (en) 2019-03-28 2023-11-28 ExxonMobil Technology and Engineering Company Processes for converting benzene and/or toluene via methylation
CN113574037A (en) 2019-03-28 2021-10-29 埃克森美孚化学专利公司 Method and system for converting benzene and/or toluene via methylation
WO2023044278A1 (en) 2021-09-16 2023-03-23 Exxonmobil Chemical Patents Inc. Xylene isomer separation processes
CN118159511A (en) 2021-10-12 2024-06-07 埃克森美孚化学专利公司 Staged alkylation to produce xylene product
WO2023204947A1 (en) 2022-04-19 2023-10-26 Exxonmobil Chemical Patents Inc. Processes for oxidizing p-xylene or p-xylene-containing mixtures

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0099715A1 (en) * 1982-07-14 1984-02-01 The British Petroleum Company p.l.c. Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas
US4431746A (en) * 1981-06-26 1984-02-14 Mobil Oil Corporation Preparing metal-exchanged highly siliceous porous crystalline materials
US4502945A (en) * 1982-06-09 1985-03-05 Chevron Research Company Process for preparing olefins at high pressure
US4552855A (en) * 1982-12-30 1985-11-12 Ozin Geoffrey A Metal zeolite catalyst preparation
DD233555A1 (en) * 1984-12-29 1986-03-05 Akad Wissenschaften Ddr PREPARATION OF LOW OLEFINE FROM SYNTHESEGAS MIXTURES
EP0188898A2 (en) * 1984-12-21 1986-07-30 Mobil Oil Corporation Cascade dewaxing process
EP0318282A2 (en) * 1987-11-25 1989-05-31 Uop Olefins production process
US4962269A (en) * 1982-05-18 1990-10-09 Mobil Oil Corporation Isomerization process
EP0447005A2 (en) * 1990-03-16 1991-09-18 Shell Internationale Researchmaatschappij B.V. Catalyst preparation process
WO1993015836A1 (en) * 1992-02-18 1993-08-19 The Broken Hill Proprietary Company Limited Praseodymium containing cobalt catalysts for the fischer-tropsch process

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4431746A (en) * 1981-06-26 1984-02-14 Mobil Oil Corporation Preparing metal-exchanged highly siliceous porous crystalline materials
US4962269A (en) * 1982-05-18 1990-10-09 Mobil Oil Corporation Isomerization process
US4502945A (en) * 1982-06-09 1985-03-05 Chevron Research Company Process for preparing olefins at high pressure
EP0099715A1 (en) * 1982-07-14 1984-02-01 The British Petroleum Company p.l.c. Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas
US4552855A (en) * 1982-12-30 1985-11-12 Ozin Geoffrey A Metal zeolite catalyst preparation
EP0188898A2 (en) * 1984-12-21 1986-07-30 Mobil Oil Corporation Cascade dewaxing process
DD233555A1 (en) * 1984-12-29 1986-03-05 Akad Wissenschaften Ddr PREPARATION OF LOW OLEFINE FROM SYNTHESEGAS MIXTURES
EP0318282A2 (en) * 1987-11-25 1989-05-31 Uop Olefins production process
EP0447005A2 (en) * 1990-03-16 1991-09-18 Shell Internationale Researchmaatschappij B.V. Catalyst preparation process
WO1993015836A1 (en) * 1992-02-18 1993-08-19 The Broken Hill Proprietary Company Limited Praseodymium containing cobalt catalysts for the fischer-tropsch process

Also Published As

Publication number Publication date
CA2289993A1 (en) 1998-12-23
TW482750B (en) 2002-04-11
WO1998057743A2 (en) 1998-12-23
AR013002A1 (en) 2000-11-22
CN1260823A (en) 2000-07-19
NO996308L (en) 2000-02-07
AU8151298A (en) 1999-01-04
EP0989908A2 (en) 2000-04-05
NO996308D0 (en) 1999-12-17

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