NO980411L - Hetrogene katalysatorkomponenter for polymerisering av olefiner, samt fremstilling derav - Google Patents

Hetrogene katalysatorkomponenter for polymerisering av olefiner, samt fremstilling derav

Info

Publication number
NO980411L
NO980411L NO980411A NO980411A NO980411L NO 980411 L NO980411 L NO 980411L NO 980411 A NO980411 A NO 980411A NO 980411 A NO980411 A NO 980411A NO 980411 L NO980411 L NO 980411L
Authority
NO
Norway
Prior art keywords
olefins
polymerization
preparation
well
metallocenes
Prior art date
Application number
NO980411A
Other languages
English (en)
Other versions
NO980411D0 (no
Inventor
Luis Mendez Llatas
Antonio Munoz-Escalon Lafuente
Jose Sancho Royo
Pilar Lafuente Canas
Wilfried Michiels Vega
Begona Pena Garcya
Original Assignee
Repsol Quimica Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Repsol Quimica Sa filed Critical Repsol Quimica Sa
Publication of NO980411D0 publication Critical patent/NO980411D0/no
Publication of NO980411L publication Critical patent/NO980411L/no

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

Det er vist metallocener med en funksjonalisert bro i henhold til formelen. hvor M representerer et overgangsmetall i gruppe 3, 4, 5 eller 6, L representerer syklopentadienyl-type ligander, Y representerer et halogen som kan danne en eller flere broer mellom L-enhetene. Minst en av disse broene er funksjonalisert gjennom en gruppe som er dannet av forbindelsen mellom et ha-logenatom og et silisium-, germanium eller tin-natom. Det er også vist en metode for syntesen av disse metallocen-forbindelsene med utgangspunkt i det tilsvarende haluret og en forløper for liganden som har grupper som skai fjernes. Disse metallocen-forbindelsene brukes som katalyseforløpere ved homopolymerisasjonen og kopolymerisasjonen av olefiner. Det er også vist metoder for å feste disse metallocenene på inorganiske bærere for å få kata-lysatorsystemer med faste stoffer ved polymeri-sasjonsprosesser for olefiner i heterogen fase.
NO980411A 1997-02-01 1998-01-30 Hetrogene katalysatorkomponenter for polymerisering av olefiner, samt fremstilling derav NO980411L (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES9700201 1997-02-01

Publications (2)

Publication Number Publication Date
NO980411D0 NO980411D0 (no) 1998-01-30
NO980411L true NO980411L (no) 1998-08-03

Family

ID=8298076

Family Applications (1)

Application Number Title Priority Date Filing Date
NO980411A NO980411L (no) 1997-02-01 1998-01-30 Hetrogene katalysatorkomponenter for polymerisering av olefiner, samt fremstilling derav

Country Status (4)

Country Link
US (2) US6278009B1 (no)
EP (1) EP0856524A1 (no)
JP (1) JP3393985B2 (no)
NO (1) NO980411L (no)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0856524A1 (en) * 1997-02-01 1998-08-05 Repsol Quimica S.A. Heterogeneous catalyst components for olefins polymerization, preparation process and use thereof
DE19802753A1 (de) * 1998-01-26 1999-07-29 Merck Patent Gmbh Coreaktive Trägermaterialien zur Heterogenisierung von Katalysatoren, Cokatalysatoren und Liganden
CN1127522C (zh) * 1998-08-20 2003-11-12 出光石油化学株式会社 烯烃聚合物生产用催化剂、其生产方法、和烯烃聚合物的生产方法

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US323716A (en) * 1885-08-04 Cowitz
US426637A (en) * 1890-04-29 Metallic railway-tie
US260130A (en) * 1882-06-27 Eaele h
US206794A (en) * 1878-08-06 Improvement in curtain-fixtures
US277004A (en) * 1883-05-08 Knitting machine
US361866A (en) * 1887-04-26 Lewis clayton erwin
DE2608863A1 (de) 1976-03-04 1977-09-08 Basf Ag Verfahren zum herstellen von polyaethylen
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
IL85097A (en) 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
EP0314797B1 (en) 1987-04-20 1997-07-02 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for polymerizing olefin
DE3718888A1 (de) 1987-06-05 1988-12-22 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US4925821A (en) 1987-12-17 1990-05-15 Exxon Chemical Patents Inc. Method for utilizing triethyaluminum to prepare an alumoxane support for an active metallocene catalyst
US4937217A (en) 1987-12-17 1990-06-26 Exxon Chemical Patents Inc. Method for utilizing triethylaluminum to prepare an alumoxane support for an active metallocene catalyst
US4912075A (en) 1987-12-17 1990-03-27 Exxon Chemical Patents Inc. Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization
US4935397A (en) 1988-09-28 1990-06-19 Exxon Chemical Patents Inc. Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same
DE3840772A1 (de) 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
US5057475A (en) 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
DK0426637T4 (da) 1989-10-30 2002-01-14 Fina Technology Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner
EP0474391B1 (en) 1990-08-21 1995-10-25 Nippon Oil Co. Ltd. Polyolefins
US5466766A (en) * 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
TW294669B (no) * 1992-06-27 1997-01-01 Hoechst Ag
EP0721954B1 (en) * 1993-09-30 2006-12-13 Idemitsu Kosan Co., Ltd. Transition metal compound, olefin polymerization catalyst, and process for producing olefin polymer by using said catalyst
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US6391817B1 (en) * 1993-12-28 2002-05-21 Exxonmobil Chemical Patents Inc. Method for producing a prepolymerized catalyst
DE69511023T2 (de) 1994-04-11 2000-01-27 Mitsui Chemicals Inc Verfahren zur herstellung einer propylen-polymerzusammensetzung und propylen-polymerzusammensetzung
US5473020A (en) * 1994-06-30 1995-12-05 Phillips Petroleum Company Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use
SG64939A1 (en) * 1995-07-17 2002-02-19 Mitsui Chemicals Inc Olefin polymerization catalyst, process for preparing olefin polymer, and olefin polymer
DE19527652A1 (de) 1995-07-28 1997-01-30 Hoechst Ag Metallocenverbindung
US6583227B2 (en) * 1996-09-04 2003-06-24 Exxonmobil Chemical Patents Inc. Propylene polymers for films
US6136742A (en) * 1996-09-24 2000-10-24 Exxon Chemical Patents, Inc. Metallocene catalyst systems
JP3694371B2 (ja) * 1996-10-04 2005-09-14 関東化学株式会社 メタロセン化合物の新規な合成方法
ES2142140T3 (es) * 1996-10-30 2000-04-01 Repsol Quimica Sa Catalizadores organometalicos para la polimerizacion y copolimerizacion de alfa-olefinas.
EP0856524A1 (en) * 1997-02-01 1998-08-05 Repsol Quimica S.A. Heterogeneous catalyst components for olefins polymerization, preparation process and use thereof
DE69813058T2 (de) 1997-02-01 2004-02-19 Repsol Quimica S.A. Metallocene, deren Herstellung und Verwendung
US5997392A (en) * 1997-07-22 1999-12-07 International Business Machines Corporation Slurry injection technique for chemical-mechanical polishing
DE60102789T2 (de) * 2001-01-18 2005-05-12 Repsol Quimica S.A. Olefinpolymerisationskatalysatoren
EP2707408B1 (de) * 2011-05-10 2015-07-08 BASF Coatings GmbH Radsätze für schienengebundene fahrzeuge oder deren teile und verfahren zum beschichten

Also Published As

Publication number Publication date
JP3393985B2 (ja) 2003-04-07
JPH10231315A (ja) 1998-09-02
US20020032294A1 (en) 2002-03-14
EP0856524A1 (en) 1998-08-05
NO980411D0 (no) 1998-01-30
US6278009B1 (en) 2001-08-21

Similar Documents

Publication Publication Date Title
EP0975644B1 (en) Substituted metallocene compounds for olefin polymerization catalyst systems, their intermediates and methods for preparing them
Rieger et al. Unsymmetric ansa-zirconocene complexes with chiral ethylene bridges: Influence of bridge conformation and monomer concentration on the stereoselectivity of the propene polymerization reaction
FI114798B (fi) Indenyyliyhdisteitä ja katalyyttiainesosia olefiinien polymeroimiseksi
RU93057745A (ru) Металлоцены с лигандами флуоренильного типа, способ их получения, промежуточное соединение для их получения, катализатор полимеризации олефинов, содержащий эти металлоцены, способ полимеризации олефинов
EP0472741A4 (en) Olefin polymerization catalyst
WO2005005496A3 (en) Process for the production of a polymer comprising monomeric units of ethylene, an a-olefin and a vinyl norbornene
EP0842939A4 (en) TRANSITION METAL COMPLEX, METHOD FOR THE PRODUCTION THEREOF, THE COMPLEX CONTAINING POLYMERIZATION CATALYST, AND METHOD FOR THE PRODUCTION OF OLEFIN POLYMERS
EP0969010A3 (en) Transition metal compound and catalyst containing the same for polymerization of olefins
HUP0001331A2 (hu) Metallocének, áthidalt ligandumok, olefinpolimerizációs katalizátorok és eljárás olefinek polimerizálására
EP1304319A3 (en) Metallocenes and processes therefor and therewith
KR940014423A (ko) 플루오레닐형 리간드를 갖는 메탈로센 화합물
CA2204803A1 (en) Process to prepare bridged phosphole-cyclopentadienyl compounds
DK0955304T3 (da) Metallocenkomplekser med bro til (co)polymerisation af olefiner
EP0864577A3 (en) Optically active phosphine derivative having at least two vinyl groups, polymer produced using the same as monomer and transition metal complexes of these
EP0877029A3 (en) Optically active phosphine derivative having vinyl group, polymer produced using the same as monomer and transition metal complexes of these
WO2003014166A1 (en) Process for producing polymer
EP1026177A4 (en) SUPPORTED METALLOCENE CATALYST, METHOD FOR THE PRODUCTION THEREOF AND METHOD FOR PRODUCING OLEFIN POLYMERS
ATE480547T1 (de) Übergangsmetallkomplexe, liganden, katalysatoren für die polymerisation von olefinen und verfahren zur herstellung von olefinpolymeren
JP2004507553A (ja) アルキル架橋の配位子系及び遷移金属化合物の製造方法
CA2295874A1 (fr) Complexes metalliques avec un ligand tridentate comme catalyseurs de polymerisation
NO980411L (no) Hetrogene katalysatorkomponenter for polymerisering av olefiner, samt fremstilling derav
WO2004060942A3 (en) Group iii bridged metallocene based on cyclopentadienyl-fluorenyl ligands
ATE361323T1 (de) Katalysatorzusammensetzung für die polymerisation von olefinen und polymerisationsverfahren unter dessen verwendung
CN101824110B (zh) [n^n^s]型三齿配体与钛金属配位的烯烃聚合催化剂及其制备方法
NO903292D0 (no) Fremgangsmaate for fremstilling av katalysatorkomponenter for polymerisasjon av etylen med en relativt trang molekylvektsfordeling.

Legal Events

Date Code Title Description
FC2A Withdrawal, rejection or dismissal of laid open patent application