NO951943L - Fremgangsmåte for fremstilling av alifatiske karboksylsyrer, samt blanding og katalysator - Google Patents

Fremgangsmåte for fremstilling av alifatiske karboksylsyrer, samt blanding og katalysator

Info

Publication number
NO951943L
NO951943L NO951943A NO951943A NO951943L NO 951943 L NO951943 L NO 951943L NO 951943 A NO951943 A NO 951943A NO 951943 A NO951943 A NO 951943A NO 951943 L NO951943 L NO 951943L
Authority
NO
Norway
Prior art keywords
catalyst
mixture
carboxylic acids
aliphatic carboxylic
relates
Prior art date
Application number
NO951943A
Other languages
English (en)
Other versions
NO951943D0 (no
Inventor
Elisabeth Bordes
Michel Gubelmann
Laurent Tessier
Original Assignee
Rhone Poulenc Chimie
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhone Poulenc Chimie filed Critical Rhone Poulenc Chimie
Publication of NO951943D0 publication Critical patent/NO951943D0/no
Publication of NO951943L publication Critical patent/NO951943L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Foreliggende oppfinnelse vedrører en fremgangsmåte for fremstilling av alifatiske karboksylsyrer ved kontrollert oksydasjon av korresponderende alkaner, med en oksygenkilde, i nærvær av en katalysator der den aktive fase er dannet fra en heteropolysyre med formel (1) : [AaBb] ([CcDaE.OJ*" hvor A representerer minst et monovalent kation valgt blant hydrogen, et alkalimetall eller ammoniumion; B representerer VO2*, VO3*, eller et jordalkalimetallion eller et av metallene i gruppe VII A, VIII, I B, IV B og V B etter klassifiseringen i elementenes periodiske system; C representerer W og/eller Mo; D representerer fosfor, arsenikk, antimon, silisium, germanium og/eller bor; E representerer et element valgt blant vanadium, eventuelt i kombinasjon med minst et av metallene i gruppe V A, VII A, VIII eller krom; f = a + ab; der a er avhengig av ladningen på ion B, som er lik 2,3 eller 4; c varierer fra 5 til 20; d varierer fra l til 5; e varierer fra l til 9. Oppfinnelsen vedrører også en blanding dannet fra titandioksyd som bærer og en heteropolysyre med formel(l) som gitt ovenfor. Oppfinnelsen vedrører endelig en katalysator der den aktive fase er den ovennevnte blanding.
NO951943A 1994-05-20 1995-05-16 Fremgangsmåte for fremstilling av alifatiske karboksylsyrer, samt blanding og katalysator NO951943L (no)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9406168A FR2720063B1 (fr) 1994-05-20 1994-05-20 Catalyseur à base d'hétéropolyacide et son utilisation pour la préparation d'acide acétique par oxydation ménagée de l'éthane.

Publications (2)

Publication Number Publication Date
NO951943D0 NO951943D0 (no) 1995-05-16
NO951943L true NO951943L (no) 1995-11-21

Family

ID=9463379

Family Applications (1)

Application Number Title Priority Date Filing Date
NO951943A NO951943L (no) 1994-05-20 1995-05-16 Fremgangsmåte for fremstilling av alifatiske karboksylsyrer, samt blanding og katalysator

Country Status (7)

Country Link
US (1) US6114274A (no)
EP (1) EP0683153A1 (no)
JP (1) JPH0852359A (no)
CN (1) CN1117039A (no)
CA (1) CA2149994A1 (no)
FR (1) FR2720063B1 (no)
NO (1) NO951943L (no)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2766818B1 (fr) * 1997-08-01 1999-09-10 Rhodia Chimie Sa Procede d'oxydation menagee de derives hydrocarbones substitues et compositions heteropolyacides utiles comme catalyseurs d'oxydation menagee
CN1102863C (zh) * 1998-05-28 2003-03-12 中国石油天然气股份有限公司抚顺石化分公司 环氧乙烷水合制备乙二醇的催化剂及过程
GB9828020D0 (en) * 1998-12-18 1999-02-10 Bp Chem Int Ltd Synthesis of heteropolyacids
US6660681B1 (en) * 1999-04-15 2003-12-09 E. I. Du Pont De Nemours And Company Vanadium phosphorus oxide catalyst having a thermally conductive support
US7514577B2 (en) * 2006-05-31 2009-04-07 Exxonmobil Chemical Patents Inc. Pd- and Pt-substituted polyoxometalates and process for their preparation
US7417008B2 (en) * 2006-05-31 2008-08-26 Exxonmobil Chemical Patents Inc. Supported polyoxometalates and process for their preparation
US7820868B2 (en) * 2007-01-19 2010-10-26 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
US7645907B2 (en) * 2007-03-23 2010-01-12 Exxonmobil Chemical Patents Inc. Transition metal substituted polyoxometalates and process for their preparation
CN101786008B (zh) * 2010-02-10 2012-10-24 东南大学 一种缩醛反应用负载型杂多酸催化剂及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2625519A (en) * 1950-03-07 1953-01-13 Du Pont Oxidation catalysts
US4192951A (en) * 1975-08-11 1980-03-11 Celanese Corporation Hydrocarbon oxidation process
US4250346A (en) * 1980-04-14 1981-02-10 Union Carbide Corporation Low temperature oxydehydrogenation of ethane to ethylene
US4410752A (en) * 1980-07-10 1983-10-18 The Standard Oil Company Process for the oxydehydrogenation of ethane to ethylene
JPS5936546A (ja) * 1982-08-20 1984-02-28 Showa Denko Kk ブタンの気相酸化用触媒
JPS61280439A (ja) * 1985-05-13 1986-12-11 Idemitsu Kosan Co Ltd アルケニル芳香族炭化水素誘導体の製造方法
US5162578A (en) * 1987-06-12 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Acetic acid from ethane, ethylene and oxygen
US5091354A (en) * 1988-10-07 1992-02-25 Sun Refining And Marketing Company Alkane oxidation catalysts
US5260250A (en) * 1989-07-05 1993-11-09 Bp Chemicals Limited Catalyst for the production of ethylene and acetic acid
US5300682A (en) * 1991-06-10 1994-04-05 The Standard Oil Co. Catalytic oxidation of ethane to acetic acid
US5300684A (en) * 1991-12-09 1994-04-05 The Standard Oil Company Process for the fluidized bed oxidation of ethane to acetic acid
FR2705668B1 (fr) * 1993-05-28 1995-08-25 Rhone Poulenc Chimie Procédé de préparation d'acide acétique par oxydation ménagée de l'éthane.
US5393922A (en) * 1993-07-22 1995-02-28 Gas Research Institute Catalytic direct oxidation of hydrocarbons to acids
US5334780A (en) * 1993-07-30 1994-08-02 Sun Company, Inc. Oxidation of hydrocarbons over ordered arrays of heteropolyacids and polyoxoanions on graphite
US5510308A (en) * 1994-10-19 1996-04-23 E. I. Du Pont De Nemours And Company Cation and vanadium substituted heteropolyacid catalysts for vapor phase oxidation

Also Published As

Publication number Publication date
CA2149994A1 (fr) 1995-11-21
CN1117039A (zh) 1996-02-21
NO951943D0 (no) 1995-05-16
FR2720063B1 (fr) 1996-10-25
FR2720063A1 (fr) 1995-11-24
JPH0852359A (ja) 1996-02-27
US6114274A (en) 2000-09-05
EP0683153A1 (fr) 1995-11-22

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