NO862155L - Fremgangsmaate for fremstilling av katalyttiske spaltningskatalysatorer. - Google Patents
Fremgangsmaate for fremstilling av katalyttiske spaltningskatalysatorer.Info
- Publication number
- NO862155L NO862155L NO862155A NO862155A NO862155L NO 862155 L NO862155 L NO 862155L NO 862155 A NO862155 A NO 862155A NO 862155 A NO862155 A NO 862155A NO 862155 L NO862155 L NO 862155L
- Authority
- NO
- Norway
- Prior art keywords
- approx
- zeolite
- catalyst
- weight
- ammonium
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims description 140
- 238000000034 method Methods 0.000 title claims description 128
- 230000003197 catalytic effect Effects 0.000 title claims description 7
- 238000002360 preparation method Methods 0.000 title description 9
- 238000004090 dissolution Methods 0.000 title 1
- 239000010457 zeolite Substances 0.000 claims description 224
- 229910021536 Zeolite Inorganic materials 0.000 claims description 186
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 175
- 239000011159 matrix material Substances 0.000 claims description 62
- 239000000203 mixture Substances 0.000 claims description 60
- 239000011148 porous material Substances 0.000 claims description 59
- -1 rare earth metal cation Chemical class 0.000 claims description 55
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 51
- 150000002221 fluorine Chemical class 0.000 claims description 50
- 239000000047 product Substances 0.000 claims description 42
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 40
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 37
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 29
- 230000008569 process Effects 0.000 claims description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 26
- 238000001354 calcination Methods 0.000 claims description 24
- 239000004927 clay Substances 0.000 claims description 19
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 19
- 239000002994 raw material Substances 0.000 claims description 18
- 238000005336 cracking Methods 0.000 claims description 17
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 16
- 238000004523 catalytic cracking Methods 0.000 claims description 14
- 150000001768 cations Chemical class 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 239000005995 Aluminium silicate Substances 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 235000012211 aluminium silicate Nutrition 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 12
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical group [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims description 10
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 10
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 230000002378 acidificating effect Effects 0.000 claims description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 10
- 150000002910 rare earth metals Chemical class 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 239000004215 Carbon black (E152) Substances 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 239000010779 crude oil Substances 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052719 titanium Inorganic materials 0.000 claims description 7
- 229910052691 Erbium Inorganic materials 0.000 claims description 6
- 229910052689 Holmium Inorganic materials 0.000 claims description 6
- 229910052765 Lutetium Inorganic materials 0.000 claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052779 Neodymium Inorganic materials 0.000 claims description 6
- 229910052773 Promethium Inorganic materials 0.000 claims description 6
- 229910052775 Thulium Inorganic materials 0.000 claims description 6
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 6
- 229910052797 bismuth Inorganic materials 0.000 claims description 6
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 6
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 6
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims description 6
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052746 lanthanum Inorganic materials 0.000 claims description 6
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 6
- OHSVLFRHMCKCQY-UHFFFAOYSA-N lutetium atom Chemical compound [Lu] OHSVLFRHMCKCQY-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims description 6
- LXPCOISGJFXEJE-UHFFFAOYSA-N oxifentorex Chemical group C=1C=CC=CC=1C[N+](C)([O-])C(C)CC1=CC=CC=C1 LXPCOISGJFXEJE-UHFFFAOYSA-N 0.000 claims description 6
- VQMWBBYLQSCNPO-UHFFFAOYSA-N promethium atom Chemical compound [Pm] VQMWBBYLQSCNPO-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical group [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims description 6
- NAWDYIZEMPQZHO-UHFFFAOYSA-N ytterbium Chemical compound [Yb] NAWDYIZEMPQZHO-UHFFFAOYSA-N 0.000 claims description 6
- 229910052684 Cerium Inorganic materials 0.000 claims description 5
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 5
- 229910052693 Europium Inorganic materials 0.000 claims description 5
- 229910052688 Gadolinium Inorganic materials 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 5
- 229910052772 Samarium Inorganic materials 0.000 claims description 5
- 229910052771 Terbium Inorganic materials 0.000 claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims description 5
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 5
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 5
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 5
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052741 iridium Inorganic materials 0.000 claims description 5
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 230000000737 periodic effect Effects 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Substances 0.000 claims description 5
- 229910052697 platinum Inorganic materials 0.000 claims description 5
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 5
- 229910052702 rhenium Inorganic materials 0.000 claims description 5
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims description 5
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims description 5
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 claims description 5
- 229910052715 tantalum Inorganic materials 0.000 claims description 5
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 5
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 4
- 229910052796 boron Inorganic materials 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 229910052733 gallium Inorganic materials 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- NMGYKLMMQCTUGI-UHFFFAOYSA-J diazanium;titanium(4+);hexafluoride Chemical compound [NH4+].[NH4+].[F-].[F-].[F-].[F-].[F-].[F-].[Ti+4] NMGYKLMMQCTUGI-UHFFFAOYSA-J 0.000 claims description 3
- 229910052681 coesite Inorganic materials 0.000 claims description 2
- 229910052906 cristobalite Inorganic materials 0.000 claims description 2
- 239000013078 crystal Substances 0.000 claims description 2
- 238000004321 preservation Methods 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910052682 stishovite Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- 241000158147 Sator Species 0.000 claims 1
- VIJYFGMFEVJQHU-UHFFFAOYSA-N aluminum oxosilicon(2+) oxygen(2-) Chemical class [O-2].[Al+3].[Si+2]=O VIJYFGMFEVJQHU-UHFFFAOYSA-N 0.000 claims 1
- QMABZEWAQYHYST-UHFFFAOYSA-N europium samarium Chemical compound [Sm][Eu] QMABZEWAQYHYST-UHFFFAOYSA-N 0.000 claims 1
- HQWUQSSKOBTIHZ-UHFFFAOYSA-N gadolinium terbium Chemical compound [Gd][Tb] HQWUQSSKOBTIHZ-UHFFFAOYSA-N 0.000 claims 1
- 239000002002 slurry Substances 0.000 description 46
- 239000000243 solution Substances 0.000 description 37
- 239000011734 sodium Substances 0.000 description 27
- 238000011282 treatment Methods 0.000 description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 150000004673 fluoride salts Chemical class 0.000 description 15
- 239000012265 solid product Substances 0.000 description 13
- 239000007864 aqueous solution Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 239000012266 salt solution Substances 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
- 238000005342 ion exchange Methods 0.000 description 9
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 8
- 238000009835 boiling Methods 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000003921 oil Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 7
- 150000003863 ammonium salts Chemical group 0.000 description 6
- 238000003776 cleavage reaction Methods 0.000 description 6
- 230000007017 scission Effects 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 239000000571 coke Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 229910052783 alkali metal Inorganic materials 0.000 description 4
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 4
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 4
- 235000011130 ammonium sulphate Nutrition 0.000 description 4
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 239000000017 hydrogel Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 229910015900 BF3 Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000002222 fluorine compounds Chemical class 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000000499 gel Substances 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 229910052680 mordenite Inorganic materials 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 238000000634 powder X-ray diffraction Methods 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 238000005341 cation exchange Methods 0.000 description 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 230000000593 degrading effect Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000011363 dried mixture Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 239000012013 faujasite Substances 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical group S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- COWQHZHWEJJEFQ-UHFFFAOYSA-A O[Sb](O)(F)=O.O[Sb](O)(F)=O.O[Sb](O)(F)=O.O[Sb](O)(F)=O.O[Sb](O)(F)=O.N.N.N.N.N.N.N.N.N.N Chemical compound O[Sb](O)(F)=O.O[Sb](O)(F)=O.O[Sb](O)(F)=O.O[Sb](O)(F)=O.O[Sb](O)(F)=O.N.N.N.N.N.N.N.N.N.N COWQHZHWEJJEFQ-UHFFFAOYSA-A 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 238000010306 acid treatment Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000002156 adsorbate Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910001515 alkali metal fluoride Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical class O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000011959 amorphous silica alumina Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- KVBCYCWRDBDGBG-UHFFFAOYSA-N azane;dihydrofluoride Chemical compound [NH4+].F.[F-] KVBCYCWRDBDGBG-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- BUACSMWVFUNQET-UHFFFAOYSA-H dialuminum;trisulfate;hydrate Chemical compound O.[Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O BUACSMWVFUNQET-UHFFFAOYSA-H 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- MDQRDWAGHRLBPA-UHFFFAOYSA-N fluoroamine Chemical group FN MDQRDWAGHRLBPA-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000004761 hexafluorosilicates Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- OTUXRAAQAFDEQT-UHFFFAOYSA-N magnesium oxosilicon(2+) oxygen(2-) Chemical compound [O-2].[Mg+2].[Si+2]=O.[O-2] OTUXRAAQAFDEQT-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- LNDHQUDDOUZKQV-UHFFFAOYSA-J molybdenum tetrafluoride Chemical compound F[Mo](F)(F)F LNDHQUDDOUZKQV-UHFFFAOYSA-J 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- AXFLWPUWMOTLEY-UHFFFAOYSA-N oxosilicon(2+) oxygen(2-) zirconium(4+) Chemical compound [Si+2]=O.[O-2].[Zr+4].[O-2].[O-2] AXFLWPUWMOTLEY-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000011271 tar pitch Substances 0.000 description 1
- JBXWMZTZQQGLAG-UHFFFAOYSA-H tetrafluoroplatinum(2+) difluoride Chemical compound F[Pt](F)(F)(F)(F)F JBXWMZTZQQGLAG-UHFFFAOYSA-H 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
- B01J29/084—Y-type faujasite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/30—After treatment, characterised by the means used
- B01J2229/42—Addition of matrix or binder particles
Landscapes
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/659,641 US4591576A (en) | 1984-10-03 | 1984-10-03 | Process for preparing catalytic cracking catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| NO862155L true NO862155L (no) | 1986-05-30 |
Family
ID=24646192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO862155A NO862155L (no) | 1984-10-03 | 1986-05-30 | Fremgangsmaate for fremstilling av katalyttiske spaltningskatalysatorer. |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4591576A (de) |
| EP (1) | EP0197995B1 (de) |
| JP (1) | JPS62500502A (de) |
| CN (1) | CN1006525B (de) |
| AU (1) | AU585548B2 (de) |
| BR (1) | BR8506963A (de) |
| CA (1) | CA1255283A (de) |
| DE (1) | DE3566501D1 (de) |
| DK (1) | DK261186A (de) |
| FI (1) | FI862366A7 (de) |
| NO (1) | NO862155L (de) |
| WO (1) | WO1986002019A1 (de) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU562665B2 (en) * | 1982-05-04 | 1987-06-18 | Cosmo Oil Company Ltd | Crystalline metal silicates |
| US4855036A (en) * | 1984-10-03 | 1989-08-08 | Uop | Catalytic cracking process |
| FR2582665B1 (fr) * | 1985-06-04 | 1988-08-05 | Inst Francais Du Petrole | Procede de craquage catalytique |
| EP0206871B1 (de) * | 1985-06-19 | 1989-02-01 | Institut Français du Pétrole | Stabilisiertes und entaluminiertes Zeolith-Omega |
| DE3661990D1 (en) * | 1985-09-04 | 1989-03-09 | Inst Francais Du Petrole | Omega structure zeolite |
| NZ219327A (en) * | 1986-03-05 | 1989-02-24 | Mobil Oil Corp | Process for removing aluminium from aluminosilicate zeolites |
| US4814316A (en) * | 1987-06-04 | 1989-03-21 | Uop | Novel catalyst composition, and processes for making and using same |
| US4861739A (en) * | 1987-06-04 | 1989-08-29 | Uop | Microporous crystalline composite compositions |
| US4803185A (en) * | 1987-06-04 | 1989-02-07 | Uop | Octane boosting catalyst |
| US4826804A (en) * | 1987-06-04 | 1989-05-02 | Uop | Catalyst for oligomerization process |
| US4853202A (en) * | 1987-09-08 | 1989-08-01 | Engelhard Corporation | Large-pored crystalline titanium molecular sieve zeolites |
| US5080778A (en) * | 1988-12-27 | 1992-01-14 | Uop | Hydrocarbon conversion process using novel silica-substituted aluminas |
| US5259948A (en) * | 1991-04-29 | 1993-11-09 | Uop | Hydrocarbon conversion process using a novel silicon enhanced amorphous silica-alumina |
| US5160493A (en) * | 1991-04-29 | 1992-11-03 | Uop | Silicon enhanced amorphous silica-alumina |
| JP3665069B2 (ja) * | 1993-10-08 | 2005-06-29 | アクゾ ノーベル ナムローゼ フェンノートシャップ | 水素化分解及び水素化脱ロウ方法 |
| WO1998026870A1 (en) * | 1996-12-18 | 1998-06-25 | Bp Amoco Corporation | Preparation of uniformly impregnated extrudate catalyst |
| CA2597881C (en) | 2007-08-17 | 2012-05-01 | Imperial Oil Resources Limited | Method and system integrating thermal oil recovery and bitumen mining for thermal efficiency |
| US20120261310A1 (en) * | 2010-10-11 | 2012-10-18 | Shell Oil Company | Process for catalytic cracking a fischer-tropsch derived feedstock with heat balanced operation of the catalytic cracking system |
| CN109718832A (zh) * | 2017-10-31 | 2019-05-07 | 中国石油化工股份有限公司 | 制备裂化催化剂的方法及裂化催化剂 |
| US11237067B2 (en) * | 2019-08-20 | 2022-02-01 | Kidde Technologies, Inc. | Uncertainty diagnosis for temperature detection systems |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3835030A (en) * | 1965-07-06 | 1974-09-10 | Exxon Research Engineering Co | Crystalline alumino-silicate catalysts for catalytic cracking |
| FR1553934A (de) * | 1967-12-05 | 1969-01-17 | ||
| US3575887A (en) * | 1968-03-19 | 1971-04-20 | Shell Oil Co | Fluoride-containing crystalline alumino-silicates |
| GB1217968A (en) * | 1968-03-19 | 1971-01-06 | Shell Int Research | Process for the preparation of a catalytically active aluminosilicate |
| JPS4945477B1 (de) * | 1969-03-05 | 1974-12-04 | ||
| US3630965A (en) * | 1969-03-11 | 1971-12-28 | Exxon Research Engineering Co | Hydrocarbon conversion catalyst |
| US3620960A (en) * | 1969-05-07 | 1971-11-16 | Chevron Res | Catalytic dewaxing |
| US3644220A (en) * | 1969-11-13 | 1972-02-22 | Exxon Research Engineering Co | Metal halide containing zeolites and method for their preparation |
| US3702312A (en) * | 1970-10-05 | 1972-11-07 | Shell Oil Co | Fluoride-containing crystalline alumino-silicates |
| US3692665A (en) * | 1971-05-03 | 1972-09-19 | Grace W R & Co | Catalytic cracking with catalyst of high-activity zeolite stabilized by cation and thermal stabilization |
| US3933983A (en) * | 1971-06-07 | 1976-01-20 | W. R. Grace & Co. | Method of increasing the thermal stability of crystalline zeolites |
| US4324697A (en) * | 1980-10-20 | 1982-04-13 | Texaco Inc. | Fluorided composite catalyst |
| US4324698A (en) * | 1980-10-20 | 1982-04-13 | Texaco Inc. | Fluorided cracking catalyst |
| EP0082211B2 (de) * | 1981-12-20 | 1993-07-28 | Union Carbide Corporation | Mit Silicium substituierte Zeolithzusammensetzungen und Verfahren zu ihrer Herstellung |
| JPS58110420A (ja) * | 1981-12-21 | 1983-07-01 | ユニオン・カ−バイド・コ−ポレ−シヨン | 珪素置換ゼオライト組成物及びその調製方法 |
| US4427786A (en) * | 1982-03-08 | 1984-01-24 | Mobil Oil Corporation | Activation of high silica zeolites |
| US4427787A (en) * | 1982-03-08 | 1984-01-24 | Mobil Oil Corporation | Activation of zeolites |
| US4427790A (en) * | 1982-03-08 | 1984-01-24 | Mobil Oil Corporation | Activation of zeolites |
| US4427788A (en) * | 1982-03-08 | 1984-01-24 | Mobil Oil Corporation | Activation of zeolites |
| US4427789A (en) * | 1982-03-08 | 1984-01-24 | Mobil Oil Corporation | Activation of zeolites |
| US4427791A (en) * | 1983-08-15 | 1984-01-24 | Mobil Oil Corporation | Activation of inorganic oxides |
-
1984
- 1984-10-03 US US06/659,641 patent/US4591576A/en not_active Expired - Fee Related
-
1985
- 1985-09-26 CA CA000491658A patent/CA1255283A/en not_active Expired
- 1985-10-01 BR BR8506963A patent/BR8506963A/pt unknown
- 1985-10-01 JP JP60504404A patent/JPS62500502A/ja active Pending
- 1985-10-01 AU AU49614/85A patent/AU585548B2/en not_active Expired - Fee Related
- 1985-10-01 EP EP85905036A patent/EP0197995B1/de not_active Expired
- 1985-10-01 FI FI862366A patent/FI862366A7/fi not_active Application Discontinuation
- 1985-10-01 WO PCT/US1985/001877 patent/WO1986002019A1/en not_active Ceased
- 1985-10-01 DE DE8585905036T patent/DE3566501D1/de not_active Expired
- 1985-10-02 CN CN85108056A patent/CN1006525B/zh not_active Expired
-
1986
- 1986-05-30 NO NO862155A patent/NO862155L/no unknown
- 1986-06-03 DK DK261186A patent/DK261186A/da not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| AU4961485A (en) | 1986-04-17 |
| DK261186A (da) | 1986-07-24 |
| DK261186D0 (da) | 1986-06-03 |
| EP0197995A1 (de) | 1986-10-22 |
| FI862366L (fi) | 1986-06-03 |
| AU585548B2 (en) | 1989-06-22 |
| JPS62500502A (ja) | 1987-03-05 |
| EP0197995B1 (de) | 1988-11-30 |
| CN85108056A (zh) | 1986-08-27 |
| WO1986002019A1 (en) | 1986-04-10 |
| FI862366A0 (fi) | 1986-06-03 |
| US4591576A (en) | 1986-05-27 |
| BR8506963A (pt) | 1986-12-23 |
| CN1006525B (zh) | 1990-01-24 |
| DE3566501D1 (en) | 1989-01-05 |
| FI862366A7 (fi) | 1986-06-03 |
| CA1255283A (en) | 1989-06-06 |
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