NO317994B1 - Baerer for metallocenkatalysatorer, og fremgangsmate ved fremstilling av baereren, samt katalysatorsystem og polymeriseringsfremgangsmate - Google Patents
Baerer for metallocenkatalysatorer, og fremgangsmate ved fremstilling av baereren, samt katalysatorsystem og polymeriseringsfremgangsmate Download PDFInfo
- Publication number
- NO317994B1 NO317994B1 NO19984568A NO984568A NO317994B1 NO 317994 B1 NO317994 B1 NO 317994B1 NO 19984568 A NO19984568 A NO 19984568A NO 984568 A NO984568 A NO 984568A NO 317994 B1 NO317994 B1 NO 317994B1
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- NO
- Norway
- Prior art keywords
- particles
- carrier
- carried out
- groups
- metallocene
- Prior art date
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- 239000012968 metallocene catalyst Substances 0.000 title claims abstract description 28
- 239000003054 catalyst Substances 0.000 title claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 238000006116 polymerization reaction Methods 0.000 title claims description 47
- 239000007787 solid Substances 0.000 claims abstract description 70
- 238000000034 method Methods 0.000 claims abstract description 50
- 239000002245 particle Substances 0.000 claims abstract description 49
- 150000001336 alkenes Chemical class 0.000 claims abstract description 33
- 230000003197 catalytic effect Effects 0.000 claims abstract description 28
- 239000000725 suspension Substances 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 238000003682 fluorination reaction Methods 0.000 claims abstract description 17
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 16
- 238000006243 chemical reaction Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 238000007306 functionalization reaction Methods 0.000 claims abstract description 13
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002841 Lewis acid Substances 0.000 claims abstract description 10
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 10
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 9
- 239000011707 mineral Substances 0.000 claims abstract description 9
- 229910019077 Mg—F Inorganic materials 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 46
- 150000001875 compounds Chemical class 0.000 claims description 39
- 238000011282 treatment Methods 0.000 claims description 37
- 230000003213 activating effect Effects 0.000 claims description 34
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 28
- 239000005977 Ethylene Substances 0.000 claims description 27
- -1 tetrahydroindenyl Chemical group 0.000 claims description 26
- 238000010438 heat treatment Methods 0.000 claims description 23
- 239000000377 silicon dioxide Substances 0.000 claims description 23
- 125000001485 cycloalkadienyl group Chemical group 0.000 claims description 18
- 239000003446 ligand Substances 0.000 claims description 15
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- 235000010210 aluminium Nutrition 0.000 claims description 12
- 150000003624 transition metals Chemical class 0.000 claims description 12
- 239000011261 inert gas Substances 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000002904 solvent Substances 0.000 claims description 10
- 229910052723 transition metal Inorganic materials 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- 125000003118 aryl group Chemical group 0.000 claims description 9
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 230000029936 alkylation Effects 0.000 claims description 8
- 238000005804 alkylation reaction Methods 0.000 claims description 8
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 8
- 239000007789 gas Substances 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 8
- 229910019975 (NH4)2SiF6 Inorganic materials 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 7
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 6
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 125000004400 (C1-C12) alkyl group Chemical group 0.000 claims description 5
- 238000007334 copolymerization reaction Methods 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 5
- 238000002844 melting Methods 0.000 claims description 5
- 230000008018 melting Effects 0.000 claims description 5
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 claims description 4
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 4
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011737 fluorine Substances 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 150000002430 hydrocarbons Chemical group 0.000 claims description 4
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 239000004711 α-olefin Substances 0.000 claims description 4
- 125000004642 (C1-C12) alkoxy group Chemical group 0.000 claims description 3
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 claims description 3
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 3
- DBNGNEQZXBWPTJ-UHFFFAOYSA-N CCCC[Mg]C(C)CC Chemical compound CCCC[Mg]C(C)CC DBNGNEQZXBWPTJ-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 3
- 239000012986 chain transfer agent Substances 0.000 claims description 3
- 239000011148 porous material Substances 0.000 claims description 3
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 claims description 2
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 claims description 2
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 claims description 2
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 claims description 2
- CTNFGBKAHAEKFE-UHFFFAOYSA-N bis(2-methylpropyl)alumanyloxy-bis(2-methylpropyl)alumane Chemical compound CC(C)C[Al](CC(C)C)O[Al](CC(C)C)CC(C)C CTNFGBKAHAEKFE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 2
- 125000006574 non-aromatic ring group Chemical group 0.000 claims description 2
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 2
- 230000007704 transition Effects 0.000 claims 2
- 239000003426 co-catalyst Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 claims 1
- 239000002184 metal Substances 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims 1
- 239000012190 activator Substances 0.000 abstract description 6
- 150000007517 lewis acids Chemical class 0.000 abstract 2
- 229910018085 Al-F Inorganic materials 0.000 abstract 1
- 229910018179 Al—F Inorganic materials 0.000 abstract 1
- 150000002222 fluorine compounds Chemical class 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 39
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 30
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 18
- 230000000694 effects Effects 0.000 description 16
- 150000003254 radicals Chemical class 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 229910052786 argon Inorganic materials 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 239000006228 supernatant Substances 0.000 description 9
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 238000002360 preparation method Methods 0.000 description 8
- 238000005470 impregnation Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 229910000077 silane Inorganic materials 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 4
- 125000002091 cationic group Chemical group 0.000 description 4
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 4
- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910052726 zirconium Inorganic materials 0.000 description 4
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 208000005156 Dehydration Diseases 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 238000005243 fluidization Methods 0.000 description 3
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 125000006318 tert-butyl amino group Chemical group [H]N(*)C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 229910007928 ZrCl2 Inorganic materials 0.000 description 2
- 229940100198 alkylating agent Drugs 0.000 description 2
- 239000002168 alkylating agent Substances 0.000 description 2
- DCFKHNIGBAHNSS-UHFFFAOYSA-N chloro(triethyl)silane Chemical compound CC[Si](Cl)(CC)CC DCFKHNIGBAHNSS-UHFFFAOYSA-N 0.000 description 2
- IJOOHPMOJXWVHK-UHFFFAOYSA-N chlorotrimethylsilane Chemical compound C[Si](C)(C)Cl IJOOHPMOJXWVHK-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- DVSDBMFJEQPWNO-UHFFFAOYSA-N methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000002444 silanisation Methods 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- BRHODLBZJKAKRN-UHFFFAOYSA-N C1=CC=CC1[Zr](C)(C)C1C=CC=C1 Chemical compound C1=CC=CC1[Zr](C)(C)C1C=CC=C1 BRHODLBZJKAKRN-UHFFFAOYSA-N 0.000 description 1
- PXCWOMBHWLFECP-UHFFFAOYSA-N C1=CC=CC1[Zr](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1C=CC=C1 Chemical compound C1=CC=CC1[Zr](C=1C=CC=CC=1)(C=1C=CC=CC=1)C1C=CC=C1 PXCWOMBHWLFECP-UHFFFAOYSA-N 0.000 description 1
- DLZJQXSNPNJLLT-UHFFFAOYSA-N C=1C=CC=CC=1C[Zr](C1C=CC=C1)(C1C=CC=C1)CC1=CC=CC=C1 Chemical compound C=1C=CC=CC=1C[Zr](C1C=CC=C1)(C1C=CC=C1)CC1=CC=CC=C1 DLZJQXSNPNJLLT-UHFFFAOYSA-N 0.000 description 1
- UHRDIFZTSNJQII-UHFFFAOYSA-L CC(C)=[Zr](Cl)(Cl)(C1C=CC(=C1)C(C)(C)C)C1C=CC(=C1)C(C)(C)C Chemical compound CC(C)=[Zr](Cl)(Cl)(C1C=CC(=C1)C(C)(C)C)C1C=CC(=C1)C(C)(C)C UHRDIFZTSNJQII-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 208000012868 Overgrowth Diseases 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910020169 SiOa Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010068 TiCl2 Inorganic materials 0.000 description 1
- 229910007926 ZrCl Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000002877 alkyl aryl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- KZUKCLOWAMFDDB-UHFFFAOYSA-L butylcyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.CCCC[C]1[CH][CH][CH][CH]1.CCCC[C]1[CH][CH][CH][CH]1 KZUKCLOWAMFDDB-UHFFFAOYSA-L 0.000 description 1
- FQGXXPOPDMJRDS-UHFFFAOYSA-N carbanide;1h-inden-1-ide;zirconium(4+) Chemical compound [CH3-].[CH3-].[Zr+4].C1=CC=C2[CH-]C=CC2=C1.C1=CC=C2[CH-]C=CC2=C1 FQGXXPOPDMJRDS-UHFFFAOYSA-N 0.000 description 1
- YNBJMIXWGPOBGE-UHFFFAOYSA-N carbanide;cyclopenta-1,3-diene;titanium(4+) Chemical compound [CH3-].[CH3-].[Ti+4].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 YNBJMIXWGPOBGE-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical compound [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 1
- XKLWATAZDMHTSH-UHFFFAOYSA-L cyclopentane;dichlorotitanium Chemical compound Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 XKLWATAZDMHTSH-UHFFFAOYSA-L 0.000 description 1
- QRUYYSPCOGSZGQ-UHFFFAOYSA-L cyclopentane;dichlorozirconium Chemical compound Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1 QRUYYSPCOGSZGQ-UHFFFAOYSA-L 0.000 description 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- IVTQDRJBWSBJQM-UHFFFAOYSA-L dichlorozirconium;indene Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)C1C2=CC=CC=C2C=C1 IVTQDRJBWSBJQM-UHFFFAOYSA-L 0.000 description 1
- JZZIHCLFHIXETF-UHFFFAOYSA-N dimethylsilicon Chemical group C[Si]C JZZIHCLFHIXETF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical class [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- VXWPONVCMVLXBW-UHFFFAOYSA-M magnesium;carbanide;iodide Chemical compound [CH3-].[Mg+2].[I-] VXWPONVCMVLXBW-UHFFFAOYSA-M 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- HZVOZRGWRWCICA-UHFFFAOYSA-N methanediyl Chemical compound [CH2] HZVOZRGWRWCICA-UHFFFAOYSA-N 0.000 description 1
- POPACFLNWGUDSR-UHFFFAOYSA-N methoxy(trimethyl)silane Chemical compound CO[Si](C)(C)C POPACFLNWGUDSR-UHFFFAOYSA-N 0.000 description 1
- LAQFLZHBVPULPL-UHFFFAOYSA-N methyl(phenyl)silicon Chemical group C[Si]C1=CC=CC=C1 LAQFLZHBVPULPL-UHFFFAOYSA-N 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 150000002901 organomagnesium compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- ZWYDDDAMNQQZHD-UHFFFAOYSA-L titanium(ii) chloride Chemical compound [Cl-].[Cl-].[Ti+2] ZWYDDDAMNQQZHD-UHFFFAOYSA-L 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
- C08F2410/07—Catalyst support treated by an anion, e.g. Cl-, F-, SO42-
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9712270A FR2769245B1 (fr) | 1997-10-02 | 1997-10-02 | Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO984568D0 NO984568D0 (no) | 1998-09-30 |
| NO984568L NO984568L (no) | 1999-04-06 |
| NO317994B1 true NO317994B1 (no) | 2005-01-17 |
Family
ID=9511728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19984568A NO317994B1 (no) | 1997-10-02 | 1998-09-30 | Baerer for metallocenkatalysatorer, og fremgangsmate ved fremstilling av baereren, samt katalysatorsystem og polymeriseringsfremgangsmate |
Country Status (11)
| Country | Link |
|---|---|
| US (3) | US6239059B1 (ja) |
| EP (1) | EP0906920B1 (ja) |
| JP (1) | JP4292288B2 (ja) |
| KR (1) | KR100522281B1 (ja) |
| CN (1) | CN1146592C (ja) |
| AT (1) | ATE240353T1 (ja) |
| CA (1) | CA2246003C (ja) |
| DE (1) | DE69814554T2 (ja) |
| ES (1) | ES2200286T3 (ja) |
| FR (1) | FR2769245B1 (ja) |
| NO (1) | NO317994B1 (ja) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6300271B1 (en) * | 1998-05-18 | 2001-10-09 | Phillips Petroleum Company | Compositions that can produce polymers |
| EP1995258B1 (en) * | 1998-05-18 | 2013-08-21 | Chevron Phillips Chemical Company Lp | Catalyst composition for polymerizing monomers |
| BR9913221B1 (pt) | 1998-08-26 | 2008-11-18 | composiÇço catalisadora suportada de metaloceno. | |
| IT1304181B1 (it) * | 1998-12-17 | 2001-03-08 | Enichem Spa | Composizione attivante di complessi metallocenici nella catalisi deiprocessi di (co)polimerizzazione delle olefine. |
| DE19917985A1 (de) | 1999-04-21 | 2000-10-26 | Targor Gmbh | Katalysatorsystem |
| DE19917984A1 (de) * | 1999-04-21 | 2000-11-09 | Targor Gmbh | Chemische Verbindung, Verfahren zu deren Herstellung und deren Verwendung in Katalysatorsystem zur Herstellung von Polyolefinen |
| US6355594B1 (en) * | 1999-09-27 | 2002-03-12 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6395666B1 (en) * | 1999-09-29 | 2002-05-28 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6391816B1 (en) | 1999-10-27 | 2002-05-21 | Phillips Petroleum | Organometal compound catalyst |
| US6548441B1 (en) * | 1999-10-27 | 2003-04-15 | Phillips Petroleum Company | Organometal catalyst compositions |
| US6548442B1 (en) | 1999-12-03 | 2003-04-15 | Phillips Petroleum Company | Organometal compound catalyst |
| US6750302B1 (en) | 1999-12-16 | 2004-06-15 | Phillips Petroleum Company | Organometal catalyst compositions |
| HUP0203789A2 (en) * | 1999-12-16 | 2003-04-28 | Phillips Petroleum Co | Organometal compound catalyst |
| US6524987B1 (en) * | 1999-12-22 | 2003-02-25 | Phillips Petroleum Company | Organometal catalyst compositions |
| US7041617B2 (en) | 2004-01-09 | 2006-05-09 | Chevron Phillips Chemical Company, L.P. | Catalyst compositions and polyolefins for extrusion coating applications |
| US20080281063A9 (en) * | 1999-12-30 | 2008-11-13 | Sukhadia Ashish M | Ethylene polymers and copolymers with high optical opacity and methods of making the same |
| DE50110557D1 (de) * | 2000-09-28 | 2006-09-07 | Basell Polyolefine Gmbh | Verfahren zur herstellung von hochverzweigten ethylenpolymerisaten |
| CA2357385C (en) | 2001-09-17 | 2010-06-15 | Nova Chemicals Corporation | Supported phosphinimine polymerization catalyst |
| US20030207757A1 (en) * | 2002-04-30 | 2003-11-06 | Daelim Industries Co., Ltd. | Catalyst composition comprising metallocene compound having bulky cycloalkyl-substituted cyclopentadienyl ligand, and process for olefin polymerization using the same |
| US7309677B2 (en) * | 2002-08-20 | 2007-12-18 | B.P. Chemicals Limited | Supported polymerisation catalysts |
| AU2003260718A1 (en) * | 2002-08-20 | 2004-03-11 | Bp Chemicals Limited | Supported polymerisation catalysts |
| DE10252557C5 (de) | 2002-11-08 | 2011-08-11 | Scott Sports S.A. | Umschaltvorrichtung |
| US6900154B2 (en) * | 2002-11-26 | 2005-05-31 | Univation Technologies, Llc | Methods of forming a supported activated catalyst composition |
| WO2004074329A1 (fr) * | 2003-02-24 | 2004-09-02 | China Petroleum & Chemical Corporation | Support complexe pour catalyseur de polymerisation du propylene, composant de catalyseur et catalyseur contenant ce composant |
| US6908876B2 (en) * | 2003-04-16 | 2005-06-21 | Saudi Basic Industries Corporation | Supported metallocene catalyst system for olefin polymerization, method for making and using the same |
| US7501372B2 (en) * | 2003-11-21 | 2009-03-10 | Chevron Phillips Chemical Company Lp | Catalyst compositions for producing polyolefins in the absence of cocatalysts |
| US7217676B2 (en) * | 2004-01-16 | 2007-05-15 | Exxon Mobil Chemical Patents Inc. | Hydrophobization and silica for supported catalyst |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| EP1709091A2 (en) * | 2004-01-30 | 2006-10-11 | Total Petrochemicals Research Feluy | Activating supports for metallocene catalysis |
| EP1559730A1 (en) * | 2004-01-30 | 2005-08-03 | Total Petrochemicals Research Feluy | Activating supports for metallocene catalysis |
| US7094857B2 (en) * | 2004-03-10 | 2006-08-22 | Chevron Phillips Chemical Company, L.P. | Ethylene polymers and copolymers with high optical opacity |
| US7294599B2 (en) * | 2004-06-25 | 2007-11-13 | Chevron Phillips Chemical Co. | Acidic activator-supports and catalysts for olefin polymerization |
| EP1734058A1 (en) * | 2005-06-13 | 2006-12-20 | Total Petrochemicals Research Feluy | Ethylene and alpha-olefins polymerisation catalyst system based on fluorenyl ligand |
| EP1749841A1 (en) * | 2005-08-03 | 2007-02-07 | Total Petrochemicals Research Feluy | Activating fluorinated supports with iron-based post-metallocene complexes |
| EP1749842A1 (en) * | 2005-08-03 | 2007-02-07 | Total Petrochemicals Research Feluy | Transition metal complexes supported on activating fluorinated support |
| US20070255022A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| US8110518B2 (en) | 2006-04-28 | 2012-02-07 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| US20070255026A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Process for polyolefin production using fluorinated transition metal catalysts having a low pH |
| US20070254800A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| US20070255028A1 (en) * | 2006-04-28 | 2007-11-01 | Fina Technology, Inc. | Fluorinated transition metal catalysts and formation thereof |
| EP1972642A1 (en) | 2007-03-19 | 2008-09-24 | Total Petrochemicals Research Feluy | Homo-or co-polymers of ethylene with combination of processability and toughness properties |
| US8138285B2 (en) * | 2007-10-26 | 2012-03-20 | Fina Technology, Inc. | Fluorinated impregnated catalyst systems and methods of forming the same |
| EP2172493A1 (en) | 2008-10-02 | 2010-04-07 | Total Petrochemicals Research Feluy | Activating supports based on perfluorinated boronic acids |
| EP2251362A1 (en) | 2009-05-07 | 2010-11-17 | Total Petrochemicals Research Feluy | Activating supports with controlled distribution of OH groups |
| NZ597113A (en) | 2009-06-16 | 2014-03-28 | Chevron Phillips Chemical Co | Oligomerization of alpha olefins using metallocene-ssa catalyst systems and use of the resultant polyalphaolefins to prepare lubricant blends |
| WO2011044150A1 (en) * | 2009-10-06 | 2011-04-14 | Chevron Phillips Chemical Company Lp | Oligomerization of olefin waxes using metallocene-based catalyst systems |
| ES2693720T3 (es) * | 2010-02-22 | 2018-12-13 | Univation Technologies, Llc | Sistemas catalíticos y métodos para usar los mismos para producir productos poliolefínicos |
| CN101942047B (zh) * | 2010-08-27 | 2013-02-20 | 吉化集团吉林市星云工贸有限公司 | 一种烯烃聚合用复合载体催化剂及其制备方法 |
| EP2465876A1 (en) | 2010-12-15 | 2012-06-20 | INEOS Manufacturing Belgium NV | Activating supports |
| CN103370344A (zh) | 2011-01-20 | 2013-10-23 | 英尼奥斯商业服务英国有限公司 | 活化载体 |
| ES2682252T3 (es) | 2011-12-14 | 2018-09-19 | Ineos Europe Ag | Nuevos polímeros |
| US8895679B2 (en) | 2012-10-25 | 2014-11-25 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US8937139B2 (en) | 2012-10-25 | 2015-01-20 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| US9034991B2 (en) | 2013-01-29 | 2015-05-19 | Chevron Phillips Chemical Company Lp | Polymer compositions and methods of making and using same |
| US8877672B2 (en) | 2013-01-29 | 2014-11-04 | Chevron Phillips Chemical Company Lp | Catalyst compositions and methods of making and using same |
| KR101610879B1 (ko) | 2013-06-18 | 2016-04-08 | 주식회사 엘지화학 | 실리카 담체 및 그 제조방법과 이를 이용한 메탈로센 촉매 |
| US9303106B1 (en) * | 2014-10-17 | 2016-04-05 | Chevron Phillips Chemical Company Lp | Processes for preparing solid metallocene-based catalyst systems |
| US9732300B2 (en) | 2015-07-23 | 2017-08-15 | Chevron Phillipa Chemical Company LP | Liquid propylene oligomers and methods of making same |
| US11015001B2 (en) * | 2017-05-19 | 2021-05-25 | Exxonmobil Chemical Patents Inc. | Catalyst systems and polymerization processes for using the same |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR427697A (fr) | 1911-03-27 | 1911-08-10 | Jens Frederik Johnsen Lenler | Machine à coudre les doublures |
| US4077904A (en) * | 1976-06-29 | 1978-03-07 | Union Carbide Corporation | Olefin polymerization process and catalyst therefor |
| US4806513A (en) | 1984-05-29 | 1989-02-21 | Phillips Petroleum Company | Silicon and fluorine-treated alumina containing a chromium catalyst and method of producing same |
| ATE81512T1 (de) * | 1986-08-26 | 1992-10-15 | Mitsui Petrochemical Ind | Katalysator zur polymerisierung von alpha-olefin und verfahren. |
| AU616642B2 (en) | 1987-01-30 | 1991-11-07 | Sony Corporation | Device for loading a tape like substance |
| JPH0783036B2 (ja) | 1987-12-11 | 1995-09-06 | 三菱電機株式会社 | キヤリアテープ |
| ATE137770T1 (de) | 1989-10-10 | 1996-05-15 | Fina Technology | Metallocenkatalysator mit lewissäure und alkylaluminium |
| ATE186918T1 (de) | 1990-01-02 | 1999-12-15 | Exxon Chemical Patents Inc | Ionische metallocenkatalysatoren auf träger für olefinpolymerisation |
| US5064796A (en) * | 1991-01-07 | 1991-11-12 | Exxon Chemical Patents Inc. | Support adjuvant for improved vanadium polymerization catalyst |
| EP0594914A1 (en) * | 1992-10-26 | 1994-05-04 | Bp Chemicals S.N.C. | Preparation of a catalyst for the manufacture of polyethylene |
| US5543376A (en) | 1994-02-25 | 1996-08-06 | Phillips Petroleum Company | Process for producing polyolefins |
| US5939347A (en) | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
| DE69600892T2 (de) | 1995-02-21 | 1999-04-01 | Mitsubishi Chem Corp | Katalysatoren für Olefinpolymerisation und Verfahren zur Herstellung von damit erhaltenen Olefinpolymeren |
-
1997
- 1997-10-02 FR FR9712270A patent/FR2769245B1/fr not_active Expired - Fee Related
-
1998
- 1998-09-30 EP EP98402400A patent/EP0906920B1/fr not_active Expired - Lifetime
- 1998-09-30 DE DE69814554T patent/DE69814554T2/de not_active Expired - Lifetime
- 1998-09-30 CN CNB981243142A patent/CN1146592C/zh not_active Expired - Fee Related
- 1998-09-30 NO NO19984568A patent/NO317994B1/no not_active IP Right Cessation
- 1998-09-30 AT AT98402400T patent/ATE240353T1/de active
- 1998-09-30 ES ES98402400T patent/ES2200286T3/es not_active Expired - Lifetime
- 1998-10-01 JP JP27987598A patent/JP4292288B2/ja not_active Expired - Fee Related
- 1998-10-01 CA CA002246003A patent/CA2246003C/fr not_active Expired - Fee Related
- 1998-10-02 US US09/165,345 patent/US6239059B1/en not_active Expired - Lifetime
- 1998-10-02 KR KR1019980041605A patent/KR100522281B1/ko not_active IP Right Cessation
-
2001
- 2001-04-02 US US09/822,840 patent/US6605561B1/en not_active Expired - Lifetime
-
2003
- 2003-04-01 US US10/402,939 patent/US6780946B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATE240353T1 (de) | 2003-05-15 |
| FR2769245B1 (fr) | 1999-10-29 |
| CN1214342A (zh) | 1999-04-21 |
| CN1146592C (zh) | 2004-04-21 |
| JP4292288B2 (ja) | 2009-07-08 |
| DE69814554D1 (de) | 2003-06-18 |
| US6239059B1 (en) | 2001-05-29 |
| FR2769245A1 (fr) | 1999-04-09 |
| US20040014596A1 (en) | 2004-01-22 |
| NO984568D0 (no) | 1998-09-30 |
| CA2246003A1 (fr) | 1999-04-02 |
| EP0906920B1 (fr) | 2003-05-14 |
| CA2246003C (fr) | 2003-06-03 |
| KR100522281B1 (ko) | 2006-01-27 |
| ES2200286T3 (es) | 2004-03-01 |
| EP0906920A1 (fr) | 1999-04-07 |
| DE69814554T2 (de) | 2004-04-08 |
| JPH11171911A (ja) | 1999-06-29 |
| US6780946B2 (en) | 2004-08-24 |
| NO984568L (no) | 1999-04-06 |
| KR19990036831A (ko) | 1999-05-25 |
| US6605561B1 (en) | 2003-08-12 |
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| MM1K | Lapsed by not paying the annual fees |