NO316374B1 - Fremgangsmåte ved fremstilling av i det vesentlige vannfritt magnesiumklorid - Google Patents
Fremgangsmåte ved fremstilling av i det vesentlige vannfritt magnesiumklorid Download PDFInfo
- Publication number
- NO316374B1 NO316374B1 NO19961675A NO961675A NO316374B1 NO 316374 B1 NO316374 B1 NO 316374B1 NO 19961675 A NO19961675 A NO 19961675A NO 961675 A NO961675 A NO 961675A NO 316374 B1 NO316374 B1 NO 316374B1
- Authority
- NO
- Norway
- Prior art keywords
- magnesium chloride
- alcohol
- ammonia
- solution
- precipitate
- Prior art date
Links
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 title claims description 358
- 238000000034 method Methods 0.000 title claims description 89
- 238000002360 preparation method Methods 0.000 title description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 327
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 225
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 159
- 239000000243 solution Substances 0.000 claims description 159
- 229910021529 ammonia Inorganic materials 0.000 claims description 144
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 134
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 115
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 102
- 229910001868 water Inorganic materials 0.000 claims description 99
- 239000002244 precipitate Substances 0.000 claims description 60
- 238000006243 chemical reaction Methods 0.000 claims description 49
- 238000004821 distillation Methods 0.000 claims description 32
- 238000010438 heat treatment Methods 0.000 claims description 25
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 22
- 229920006395 saturated elastomer Polymers 0.000 claims description 22
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 20
- 239000001110 calcium chloride Substances 0.000 claims description 20
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 20
- 238000005406 washing Methods 0.000 claims description 20
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 claims description 19
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 claims description 19
- 235000014824 magnesium bicarbonate Nutrition 0.000 claims description 19
- 239000002370 magnesium bicarbonate Substances 0.000 claims description 19
- 239000002904 solvent Substances 0.000 claims description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 15
- 239000007864 aqueous solution Substances 0.000 claims description 15
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 239000002798 polar solvent Substances 0.000 claims description 13
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 12
- KJFFWRRGVMFLJJ-UHFFFAOYSA-L magnesium;azane;dichloride Chemical compound N.N.N.N.N.N.[Mg+2].[Cl-].[Cl-] KJFFWRRGVMFLJJ-UHFFFAOYSA-L 0.000 claims description 12
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 8
- 230000001476 alcoholic effect Effects 0.000 claims description 8
- 238000011084 recovery Methods 0.000 claims description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 229960004756 ethanol Drugs 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 2
- 235000011147 magnesium chloride Nutrition 0.000 description 150
- 229960002337 magnesium chloride Drugs 0.000 description 145
- FQUPMIQUWINAGY-UHFFFAOYSA-L magnesium ethane-1,2-diol dichloride Chemical compound [Mg+2].[Cl-].[Cl-].OCCO FQUPMIQUWINAGY-UHFFFAOYSA-L 0.000 description 38
- 239000013078 crystal Substances 0.000 description 23
- 239000000047 product Substances 0.000 description 23
- 235000012245 magnesium oxide Nutrition 0.000 description 21
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical class [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 21
- 238000004448 titration Methods 0.000 description 21
- 239000000395 magnesium oxide Substances 0.000 description 20
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 20
- 239000007789 gas Substances 0.000 description 19
- WIBVHXDIQAOXSH-UHFFFAOYSA-L magnesium;2-hydroxyacetate;chloride Chemical class [Mg+2].[Cl-].OCC([O-])=O WIBVHXDIQAOXSH-UHFFFAOYSA-L 0.000 description 18
- 239000002002 slurry Substances 0.000 description 17
- -1 magnesium chloride glycolate compound Chemical class 0.000 description 16
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 14
- 239000007787 solid Substances 0.000 description 14
- 239000007788 liquid Substances 0.000 description 13
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 12
- 238000002441 X-ray diffraction Methods 0.000 description 12
- 238000001556 precipitation Methods 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 9
- 238000002425 crystallisation Methods 0.000 description 9
- 230000008025 crystallization Effects 0.000 description 9
- 239000004744 fabric Substances 0.000 description 9
- 239000011777 magnesium Substances 0.000 description 9
- 229910052749 magnesium Inorganic materials 0.000 description 9
- 235000001055 magnesium Nutrition 0.000 description 9
- 229940091250 magnesium supplement Drugs 0.000 description 9
- 238000010992 reflux Methods 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 8
- 239000012300 argon atmosphere Substances 0.000 description 8
- 238000002474 experimental method Methods 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- 238000004128 high performance liquid chromatography Methods 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 230000018044 dehydration Effects 0.000 description 6
- 238000006297 dehydration reaction Methods 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 238000002479 acid--base titration Methods 0.000 description 5
- 238000013459 approach Methods 0.000 description 5
- VFAXGZLIPBSFQU-UHFFFAOYSA-N azanium;magnesium;chloride Chemical compound [NH4+].[Mg].[Cl-] VFAXGZLIPBSFQU-UHFFFAOYSA-N 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005485 electric heating Methods 0.000 description 5
- ISPLNFNSGSAGJF-UHFFFAOYSA-L magnesium 2-(2-hydroxyethoxy)ethanol dichloride Chemical class [Mg++].[Cl-].[Cl-].OCCOCCO ISPLNFNSGSAGJF-UHFFFAOYSA-L 0.000 description 5
- 238000004064 recycling Methods 0.000 description 5
- XOKJUJMYGNKBTR-UHFFFAOYSA-L CO.Cl[Mg]Cl Chemical compound CO.Cl[Mg]Cl XOKJUJMYGNKBTR-UHFFFAOYSA-L 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 238000010923 batch production Methods 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000010924 continuous production Methods 0.000 description 4
- 239000000498 cooling water Substances 0.000 description 4
- 239000012065 filter cake Substances 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- PHTQWCKDNZKARW-UHFFFAOYSA-N isoamylol Chemical compound CC(C)CCO PHTQWCKDNZKARW-UHFFFAOYSA-N 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- 238000001157 Fourier transform infrared spectrum Methods 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- ZMVXJBWKHIUBDU-UHFFFAOYSA-L magnesium ethane-1,2-diol dichloride hydrate Chemical compound O.[Mg++].[Cl-].[Cl-].OCCO ZMVXJBWKHIUBDU-UHFFFAOYSA-L 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000619 316 stainless steel Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- DGMGURNEKYVNPM-UHFFFAOYSA-L C(CO)(=O)[O-].C(CO)(=O)O.C(CO)(=O)O.[Cl-].[Mg+2] Chemical compound C(CO)(=O)[O-].C(CO)(=O)O.C(CO)(=O)O.[Cl-].[Mg+2] DGMGURNEKYVNPM-UHFFFAOYSA-L 0.000 description 2
- DFVGJLNZLPTSBO-UHFFFAOYSA-L C(CO)O.[Cl-].[Mg+2].[Cl-].[Ca+2] Chemical compound C(CO)O.[Cl-].[Mg+2].[Cl-].[Ca+2] DFVGJLNZLPTSBO-UHFFFAOYSA-L 0.000 description 2
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 125000003158 alcohol group Chemical group 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- 239000005337 ground glass Substances 0.000 description 2
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 description 2
- 238000003760 magnetic stirring Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001103 potassium chloride Substances 0.000 description 2
- 235000011164 potassium chloride Nutrition 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical class C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 102100021587 Embryonic testis differentiation protein homolog A Human genes 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 1
- 101000898120 Homo sapiens Embryonic testis differentiation protein homolog A Proteins 0.000 description 1
- QPFYXYFORQJZEC-FOCLMDBBSA-N Phenazopyridine Chemical class NC1=NC(N)=CC=C1\N=N\C1=CC=CC=C1 QPFYXYFORQJZEC-FOCLMDBBSA-N 0.000 description 1
- HGOZKRJJCGNXTA-UHFFFAOYSA-N [Mg].OCCO Chemical compound [Mg].OCCO HGOZKRJJCGNXTA-UHFFFAOYSA-N 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 238000004176 ammonification Methods 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- OYPRJOBELJOOCE-LZFNBGRKSA-N calcium-46 Chemical compound [46Ca] OYPRJOBELJOOCE-LZFNBGRKSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000010961 commercial manufacture process Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000010908 decantation Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 235000012243 magnesium silicates Nutrition 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000013022 venting Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F5/00—Compounds of magnesium
- C01F5/26—Magnesium halides
- C01F5/30—Chlorides
- C01F5/34—Dehydrating magnesium chloride containing water of crystallisation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AUPM206593 | 1993-10-28 | ||
| PCT/AU1994/000662 WO1995011859A1 (en) | 1993-10-28 | 1994-10-28 | Anhydrous magnesium chloride |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO961675D0 NO961675D0 (no) | 1996-04-26 |
| NO961675L NO961675L (no) | 1996-06-20 |
| NO316374B1 true NO316374B1 (no) | 2004-01-19 |
Family
ID=3777308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19961675A NO316374B1 (no) | 1993-10-28 | 1996-04-26 | Fremgangsmåte ved fremstilling av i det vesentlige vannfritt magnesiumklorid |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6143270A (de) |
| EP (1) | EP0725761B1 (de) |
| CN (1) | CN1043215C (de) |
| BR (1) | BR9407898A (de) |
| CA (1) | CA2175183C (de) |
| CZ (1) | CZ293993B6 (de) |
| DE (1) | DE69433408T2 (de) |
| ES (1) | ES2213151T3 (de) |
| IL (1) | IL111438A (de) |
| NO (1) | NO316374B1 (de) |
| NZ (1) | NZ275053A (de) |
| RU (1) | RU2134658C1 (de) |
| UA (1) | UA55365C2 (de) |
| WO (1) | WO1995011859A1 (de) |
| ZA (1) | ZA948495B (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NO308352B1 (no) * | 1997-06-20 | 2000-09-04 | Norsk Hydro As | Prosess for Õ fremstille vannfri MgCl2 |
| US7905770B2 (en) * | 2004-02-02 | 2011-03-15 | Shuffle Master, Inc. | Special multiplier bonus game in Pai Gow Poker variant |
| CN1295151C (zh) * | 2004-07-24 | 2007-01-17 | 陈瑜 | 微波能制取无水氯化镁生产工艺 |
| CN100379682C (zh) * | 2004-11-01 | 2008-04-09 | 中信国安盟固利新能源科技有限公司 | 一种制备无水氯化镁的方法 |
| KR100798417B1 (ko) | 2007-07-26 | 2008-01-28 | 한국지질자원연구원 | 염화마그네슘 수용액으로부터 염화암모늄을 이용한 무수염화마그네슘의 제조방법 |
| CN101462746B (zh) * | 2007-12-19 | 2012-06-27 | 中国科学院过程工程研究所 | 由水氯镁石制备无水氯化镁的方法 |
| CN101343073B (zh) * | 2008-05-12 | 2010-06-09 | 部燕茹 | 一种光卤石加水氯镁石的脱水工业炉 |
| WO2012000168A1 (zh) * | 2010-06-29 | 2012-01-05 | 中国科学院过程工程研究所 | 一种利用离子液体低温脱水生产无水化合物的方法 |
| CN101983922B (zh) * | 2010-11-16 | 2012-05-09 | 华东理工大学 | 一种六氨氯化镁煅烧脱氨制备无水氯化镁的方法 |
| CN103145159B (zh) * | 2013-03-26 | 2014-11-26 | 连云港日丰钙镁有限公司 | 一种氯化镁颗粒的生产工艺 |
| CN113620324B (zh) * | 2021-08-03 | 2023-05-16 | 安徽亚格盛电子新材料有限公司 | 利用水蒸气使六氨氯化镁的脱氨的方法 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2381994A (en) * | 1941-11-21 | 1945-08-14 | Kellogg M W Co | Production of anhydrous magnesium chloride |
| US2381995A (en) * | 1942-05-29 | 1945-08-14 | Kellogg M W Co | Production of anhydrous magnesium chloride |
| US3014780A (en) * | 1959-06-22 | 1961-12-26 | Dow Chemical Co | Calcination of magnesium chlorideammonia complexes |
| US3092450A (en) * | 1960-12-27 | 1963-06-04 | Dow Chemical Co | Preparation of anhydrous magnesium chloride |
| US3347626A (en) * | 1965-03-24 | 1967-10-17 | Exxon Research Engineering Co | Dehydration of magnesium chloride using gaseous ammonia |
| US3345128A (en) * | 1965-04-12 | 1967-10-03 | Exxon Research Engineering Co | Dehydration of magnesium chloride utilizing heavy hydrocarbons |
| US3341282A (en) * | 1965-04-14 | 1967-09-12 | Exxon Research Engineering Co | Dehydration magnesium chloride utilizing alcohol solution and ammonia |
| US3352634A (en) * | 1965-05-25 | 1967-11-14 | Exxon Research Engineering Co | Pure magnesium chloride prepared by the simultaneous extraction and azeotropic drying of a salt mixture |
| US3433604A (en) * | 1965-09-22 | 1969-03-18 | Dow Chemical Co | Calcium chloride and boric acid extraction from magnesium chloride brines using diols and catechols |
| US3962408A (en) * | 1975-07-14 | 1976-06-08 | The United States Of America As Represented By The Secretary Of The Interior | Dehydration of magnesium chloride |
| US4056599A (en) * | 1975-10-20 | 1977-11-01 | Bechtel International Corporation | Process for the recovery of magnesium chloride hydrate and potassium chloride from carnallite and bischofite |
| US3966888A (en) * | 1975-10-29 | 1976-06-29 | Nalco Chemical Company | Anhydrous magnesium chloride using ethylene glycol and ammonia |
| US3983224A (en) * | 1976-04-26 | 1976-09-28 | Nalco Chemical Company | Anhydrous magnesium chloride process |
| US4105747A (en) * | 1977-06-10 | 1978-08-08 | The United States Of America As Represented By The Secretary Of The Interior | Method for dehydrating metal chlorides |
| JPS54112396A (en) * | 1978-02-22 | 1979-09-03 | Ube Ind Ltd | Production of high purity anhydrous magnesium chloride |
| DE2855038A1 (de) * | 1978-12-20 | 1980-07-10 | Bayer Ag | Verfahren zur reinigung von niedermolekularen polyhydroxylverbindungen |
| US4195071A (en) * | 1979-03-01 | 1980-03-25 | Nalco Chemical Company | Polyethers to obtain anhydrous magnesium chloride |
| GB2045736A (en) * | 1979-03-21 | 1980-11-05 | Nalco Chemical Co | Preparation of magnesium chloride |
| US4195070A (en) * | 1979-03-21 | 1980-03-25 | Nalco Chemical Company | Preparation of a MgCl2 solution for Nalco's MgCl2 process from MgSO4 and other MgSO4 salts |
| US4248838A (en) * | 1979-03-21 | 1981-02-03 | Nalco Chemical Company | Preparation of useful MgCl2. solution with subsequent recovery of KCl from carnallite |
| US4201758A (en) * | 1979-03-22 | 1980-05-06 | Nalco Chemical Co. | Boron removal from ethylene glycol-magnesium chloride solutions |
| US4208392A (en) * | 1979-03-23 | 1980-06-17 | Nalco Chemical Co. | Two-step process for removing boron compounds from aqueous solutions of magnesium chloride |
| CA1277144C (en) * | 1986-11-21 | 1990-12-04 | G. Bryn Harris | Production of magnesium metal from magnesium containing materials |
| EP0522415A1 (de) * | 1991-07-04 | 1993-01-13 | Nittetsu Mining Co., Ltd. | Dispersion von kristallines Calciumcarbonat in Äthylengylcol, kristallines Calciumcarbonat und diese enthaltende Kunststoff Formteile und Polyesterfilm |
| IL109189A (en) * | 1993-04-06 | 1997-11-20 | Alcan Int Ltd | Process for making anhydrous magnesium chloride |
| US5439563A (en) * | 1993-08-25 | 1995-08-08 | Alcan International Limited | Electrolytic production of magnesium metal with feed containing magnesium chloride ammoniates |
| US5565080A (en) * | 1994-05-17 | 1996-10-15 | Noranda Metallurgy Inc. | Preparation of anhydrous magnesium chloride-containing melts from hydrated magnesium chloride |
-
1994
- 1994-10-28 DE DE69433408T patent/DE69433408T2/de not_active Expired - Fee Related
- 1994-10-28 CA CA002175183A patent/CA2175183C/en not_active Expired - Fee Related
- 1994-10-28 BR BR9407898A patent/BR9407898A/pt not_active IP Right Cessation
- 1994-10-28 CN CN94194221A patent/CN1043215C/zh not_active Expired - Fee Related
- 1994-10-28 NZ NZ275053A patent/NZ275053A/en unknown
- 1994-10-28 ZA ZA948495A patent/ZA948495B/xx unknown
- 1994-10-28 WO PCT/AU1994/000662 patent/WO1995011859A1/en active IP Right Grant
- 1994-10-28 CZ CZ19961220A patent/CZ293993B6/cs not_active IP Right Cessation
- 1994-10-28 ES ES94931455T patent/ES2213151T3/es not_active Expired - Lifetime
- 1994-10-28 UA UA96041712A patent/UA55365C2/uk unknown
- 1994-10-28 IL IL111438A patent/IL111438A/en not_active IP Right Cessation
- 1994-10-28 RU RU96110184/25A patent/RU2134658C1/ru not_active IP Right Cessation
- 1994-10-28 EP EP94931455A patent/EP0725761B1/de not_active Expired - Lifetime
-
1996
- 1996-04-26 NO NO19961675A patent/NO316374B1/no not_active IP Right Cessation
- 1996-04-29 US US08/638,778 patent/US6143270A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US6143270A (en) | 2000-11-07 |
| CN1043215C (zh) | 1999-05-05 |
| NZ275053A (en) | 1996-12-20 |
| IL111438A (en) | 1998-06-15 |
| NO961675L (no) | 1996-06-20 |
| DE69433408T2 (de) | 2004-10-14 |
| IL111438A0 (en) | 1994-12-29 |
| ES2213151T3 (es) | 2004-08-16 |
| WO1995011859A1 (en) | 1995-05-04 |
| CZ122096A3 (en) | 1997-03-12 |
| UA55365C2 (uk) | 2003-04-15 |
| CN1135743A (zh) | 1996-11-13 |
| CA2175183C (en) | 2005-08-30 |
| EP0725761A4 (de) | 1998-01-07 |
| DE69433408D1 (de) | 2004-01-22 |
| RU2134658C1 (ru) | 1999-08-20 |
| BR9407898A (pt) | 1996-11-19 |
| EP0725761B1 (de) | 2003-12-10 |
| NO961675D0 (no) | 1996-04-26 |
| CZ293993B6 (cs) | 2004-09-15 |
| CA2175183A1 (en) | 1995-05-04 |
| ZA948495B (en) | 1996-04-29 |
| EP0725761A1 (de) | 1996-08-14 |
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