NO310863B1 - Kogenerering av metanol og elektrisk kraft - Google Patents
Kogenerering av metanol og elektrisk kraft Download PDFInfo
- Publication number
- NO310863B1 NO310863B1 NO19995679A NO995679A NO310863B1 NO 310863 B1 NO310863 B1 NO 310863B1 NO 19995679 A NO19995679 A NO 19995679A NO 995679 A NO995679 A NO 995679A NO 310863 B1 NO310863 B1 NO 310863B1
- Authority
- NO
- Norway
- Prior art keywords
- methanol
- plant
- gas
- reactor
- reformer
- Prior art date
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 228
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 63
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 62
- 238000000034 method Methods 0.000 claims abstract description 41
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 claims abstract description 27
- 238000006243 chemical reaction Methods 0.000 claims abstract description 25
- 230000008569 process Effects 0.000 claims abstract description 13
- 230000009467 reduction Effects 0.000 claims abstract description 4
- 239000007789 gas Substances 0.000 claims description 94
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 80
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 45
- 239000001257 hydrogen Substances 0.000 claims description 42
- 229910052739 hydrogen Inorganic materials 0.000 claims description 42
- 238000000926 separation method Methods 0.000 claims description 24
- 239000003345 natural gas Substances 0.000 claims description 21
- 238000002407 reforming Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 14
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 13
- 229910052760 oxygen Inorganic materials 0.000 claims description 13
- 239000001301 oxygen Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims description 12
- 239000000446 fuel Substances 0.000 claims description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 238000002203 pretreatment Methods 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 69
- 229910002092 carbon dioxide Inorganic materials 0.000 description 63
- 239000001569 carbon dioxide Substances 0.000 description 35
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 31
- 229910002091 carbon monoxide Inorganic materials 0.000 description 30
- 238000002453 autothermal reforming Methods 0.000 description 25
- 239000000203 mixture Substances 0.000 description 20
- 238000002485 combustion reaction Methods 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 12
- 238000005516 engineering process Methods 0.000 description 9
- 229910052799 carbon Inorganic materials 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 239000012528 membrane Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 230000006835 compression Effects 0.000 description 6
- 238000007906 compression Methods 0.000 description 6
- 230000008021 deposition Effects 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 238000000629 steam reforming Methods 0.000 description 5
- 230000010354 integration Effects 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000013589 supplement Substances 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- -1 alcohol amines Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910002090 carbon oxide Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000002211 methanization Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002829 nitrogen Chemical class 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001991 steam methane reforming Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
- C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
- C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Insulating Materials (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO19995679A NO310863B1 (no) | 1999-11-19 | 1999-11-19 | Kogenerering av metanol og elektrisk kraft |
| MXPA02005038A MXPA02005038A (es) | 1999-11-19 | 2000-11-20 | Cogeneracion de metanol y energia electrica. |
| AT00978120T ATE259340T1 (de) | 1999-11-19 | 2000-11-20 | Gleichzeitige gewinnung von methanol und elektrizität |
| PCT/NO2000/000389 WO2001036357A1 (fr) | 1999-11-19 | 2000-11-20 | Cogeneration de methanol et d'energie electrique |
| DE60008288T DE60008288T2 (de) | 1999-11-19 | 2000-11-20 | Gleichzeitige gewinnung von methanol und elektrizität |
| US10/130,539 US6809121B1 (en) | 1999-11-19 | 2000-11-20 | Cogeneration of methanol and electrical power |
| AU15612/01A AU778771B2 (en) | 1999-11-19 | 2000-11-20 | Cogeneration of methanol and electrical power |
| EP00978120A EP1230203B1 (fr) | 1999-11-19 | 2000-11-20 | Cogeneration de methanol et d'energie electrique |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO19995679A NO310863B1 (no) | 1999-11-19 | 1999-11-19 | Kogenerering av metanol og elektrisk kraft |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO995679D0 NO995679D0 (no) | 1999-11-19 |
| NO995679L NO995679L (no) | 2001-05-21 |
| NO310863B1 true NO310863B1 (no) | 2001-09-10 |
Family
ID=19904002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19995679A NO310863B1 (no) | 1999-11-19 | 1999-11-19 | Kogenerering av metanol og elektrisk kraft |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6809121B1 (fr) |
| EP (1) | EP1230203B1 (fr) |
| AT (1) | ATE259340T1 (fr) |
| AU (1) | AU778771B2 (fr) |
| DE (1) | DE60008288T2 (fr) |
| MX (1) | MXPA02005038A (fr) |
| NO (1) | NO310863B1 (fr) |
| WO (1) | WO2001036357A1 (fr) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6706770B2 (en) * | 2002-04-04 | 2004-03-16 | Air Products And Chemicals, Inc. | Co-production of hydrogen and methanol from steam reformate |
| DE102004014292A1 (de) * | 2004-03-22 | 2005-10-20 | Lurgi Ag | Koproduktion von Methanol und Ammoniak aus Erdgas |
| US20060149423A1 (en) * | 2004-11-10 | 2006-07-06 | Barnicki Scott D | Method for satisfying variable power demand |
| US20070129450A1 (en) * | 2005-11-18 | 2007-06-07 | Barnicki Scott D | Process for producing variable syngas compositions |
| EP1944268A1 (fr) | 2006-12-18 | 2008-07-16 | BP Alternative Energy Holdings Limited | Processus |
| US7655703B2 (en) * | 2007-01-26 | 2010-02-02 | Inentec Llc | Method and apparatus for methanol and other fuel production |
| WO2010121260A1 (fr) | 2009-04-17 | 2010-10-21 | Gtlpetrol Llc | Génération de puissance à partir du gaz naturel avec une capture de dioxyde de carbone |
| GB201019940D0 (en) | 2010-11-24 | 2011-01-05 | Davy Process Techn Ltd | Process |
| DE102011017300A1 (de) * | 2011-04-15 | 2012-10-18 | Lurgi Gmbh | Verfahren und Anlage zur Herstellung vom Methanol aus inertenreichem Synthesegas |
| EP3150549A1 (fr) * | 2015-10-01 | 2017-04-05 | L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Procede et installation de production de gaz de synthese presentant une composition variable |
| US11873268B2 (en) | 2019-03-15 | 2024-01-16 | Topsoe A/S | Process for the production of urea formaldehyde concentrate |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4946477A (en) * | 1988-04-07 | 1990-08-07 | Air Products And Chemicals, Inc. | IGCC process with combined methanol synthesis/water gas shift for methanol and electrical power production |
| US5496859A (en) | 1995-01-28 | 1996-03-05 | Texaco Inc. | Gasification process combined with steam methane reforming to produce syngas suitable for methanol production |
| US5624964A (en) * | 1995-06-06 | 1997-04-29 | Mobil Oil Corporation | Integration of steam reforming unit and cogeneration power plant |
| NO970322L (no) * | 1997-01-24 | 1998-07-27 | Norske Stats Oljeselskap | FremgangsmÕte og integrert prosessanlegg for fremstilling av synfuel, LNG og el-kraft |
| NO311696B1 (no) | 1997-01-24 | 2002-01-07 | Norske Stats Oljeselskap | Fremgangsmåte og integrert prosessanlegg for fremstilling av synfuel og el-kraft |
| US5799482A (en) * | 1997-08-28 | 1998-09-01 | Mobil Oil Corporation | Process for improved heat integration of an oxidant-supplemented autothermal reformer and cogeneration power plant |
| US6048472A (en) * | 1997-12-23 | 2000-04-11 | Air Products And Chemicals, Inc. | Production of synthesis gas by mixed conducting membranes |
| US5980857A (en) * | 1998-03-18 | 1999-11-09 | The Boc Group, Inc. | Production of carbon monoxide from syngas |
-
1999
- 1999-11-19 NO NO19995679A patent/NO310863B1/no not_active IP Right Cessation
-
2000
- 2000-11-20 WO PCT/NO2000/000389 patent/WO2001036357A1/fr active IP Right Grant
- 2000-11-20 MX MXPA02005038A patent/MXPA02005038A/es active IP Right Grant
- 2000-11-20 AT AT00978120T patent/ATE259340T1/de not_active IP Right Cessation
- 2000-11-20 EP EP00978120A patent/EP1230203B1/fr not_active Expired - Lifetime
- 2000-11-20 US US10/130,539 patent/US6809121B1/en not_active Expired - Lifetime
- 2000-11-20 DE DE60008288T patent/DE60008288T2/de not_active Expired - Lifetime
- 2000-11-20 AU AU15612/01A patent/AU778771B2/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| EP1230203B1 (fr) | 2004-02-11 |
| ATE259340T1 (de) | 2004-02-15 |
| DE60008288T2 (de) | 2004-11-25 |
| US6809121B1 (en) | 2004-10-26 |
| MXPA02005038A (es) | 2003-10-14 |
| DE60008288D1 (de) | 2004-03-18 |
| AU778771B2 (en) | 2004-12-23 |
| NO995679L (no) | 2001-05-21 |
| NO995679D0 (no) | 1999-11-19 |
| WO2001036357A1 (fr) | 2001-05-25 |
| AU1561201A (en) | 2001-05-30 |
| EP1230203A1 (fr) | 2002-08-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| CHAD | Change of the owner's name or address (par. 44 patent law, par. patentforskriften) |
Owner name: STATOIL ASA, NO |
|
| CHAD | Change of the owner's name or address (par. 44 patent law, par. patentforskriften) |
Owner name: STATOIL PETROLEUM AS, NO |
|
| MK1K | Patent expired |