NO310625B1 - Kontinuerlig fremgangsmåte for aminolyse av etylenkopolymerer - Google Patents
Kontinuerlig fremgangsmåte for aminolyse av etylenkopolymerer Download PDFInfo
- Publication number
- NO310625B1 NO310625B1 NO19962917A NO962917A NO310625B1 NO 310625 B1 NO310625 B1 NO 310625B1 NO 19962917 A NO19962917 A NO 19962917A NO 962917 A NO962917 A NO 962917A NO 310625 B1 NO310625 B1 NO 310625B1
- Authority
- NO
- Norway
- Prior art keywords
- structural units
- amine
- ethylene
- extruder
- containing compound
- Prior art date
Links
- 238000007098 aminolysis reaction Methods 0.000 title claims description 11
- 238000010924 continuous production Methods 0.000 title claims description 4
- 229920001038 ethylene copolymer Polymers 0.000 title description 3
- 238000000034 method Methods 0.000 claims description 63
- 229920000642 polymer Polymers 0.000 claims description 38
- 238000006243 chemical reaction Methods 0.000 claims description 35
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 34
- 150000001412 amines Chemical class 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 26
- 239000002184 metal Substances 0.000 claims description 26
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 20
- 150000002148 esters Chemical class 0.000 claims description 19
- 150000001875 compounds Chemical class 0.000 claims description 17
- 229920000573 polyethylene Polymers 0.000 claims description 16
- 150000001735 carboxylic acids Chemical class 0.000 claims description 14
- -1 hydroxy-substituted nitrogen Chemical class 0.000 claims description 14
- 125000004432 carbon atom Chemical group C* 0.000 claims description 13
- 239000000155 melt Substances 0.000 claims description 13
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 12
- 229920006225 ethylene-methyl acrylate Polymers 0.000 claims description 12
- 239000007791 liquid phase Substances 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 11
- 150000001408 amides Chemical class 0.000 claims description 10
- 239000000908 ammonium hydroxide Substances 0.000 claims description 10
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical class OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical group NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 7
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 150000003973 alkyl amines Chemical class 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 239000004711 α-olefin Substances 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- 150000004982 aromatic amines Chemical class 0.000 claims description 4
- 150000003983 crown ethers Chemical class 0.000 claims description 4
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 125000005210 alkyl ammonium group Chemical group 0.000 claims description 3
- 150000008064 anhydrides Chemical class 0.000 claims description 3
- 150000002391 heterocyclic compounds Chemical class 0.000 claims description 3
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 description 29
- 239000000047 product Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 18
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 16
- 235000011114 ammonium hydroxide Nutrition 0.000 description 11
- 239000002861 polymer material Substances 0.000 description 11
- 229920000554 ionomer Polymers 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 8
- 239000005977 Ethylene Substances 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- UBQKCCHYAOITMY-UHFFFAOYSA-N pyridin-2-ol Chemical compound OC1=CC=CC=N1 UBQKCCHYAOITMY-UHFFFAOYSA-N 0.000 description 8
- 239000005043 ethylene-methyl acrylate Substances 0.000 description 7
- 239000011888 foil Substances 0.000 description 7
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229940048053 acrylate Drugs 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 230000003287 optical effect Effects 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 125000005250 alkyl acrylate group Chemical group 0.000 description 4
- 238000007872 degassing Methods 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920012753 Ethylene Ionomers Polymers 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 229920000800 acrylic rubber Polymers 0.000 description 3
- 238000005915 ammonolysis reaction Methods 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 125000002843 carboxylic acid group Chemical group 0.000 description 3
- 150000001734 carboxylic acid salts Chemical group 0.000 description 3
- 239000000470 constituent Substances 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 239000012467 final product Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- LISFMEBWQUVKPJ-UHFFFAOYSA-N quinolin-2-ol Chemical compound C1=CC=C2NC(=O)C=CC2=C1 LISFMEBWQUVKPJ-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- AICIYIDUYNFPRY-UHFFFAOYSA-N 1,3-dihydro-2H-imidazol-2-one Chemical compound O=C1NC=CN1 AICIYIDUYNFPRY-UHFFFAOYSA-N 0.000 description 2
- XYVMOLOUBJBNBF-UHFFFAOYSA-N 3h-1,3-oxazol-2-one Chemical class OC1=NC=CO1 XYVMOLOUBJBNBF-UHFFFAOYSA-N 0.000 description 2
- CZWWCTHQXBMHDA-UHFFFAOYSA-N 3h-1,3-thiazol-2-one Chemical class OC1=NC=CS1 CZWWCTHQXBMHDA-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Chemical compound [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 description 2
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 2
- 229920005680 ethylene-methyl methacrylate copolymer Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910000000 metal hydroxide Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 229940047670 sodium acrylate Drugs 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920006029 tetra-polymer Polymers 0.000 description 2
- 230000007306 turnover Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 229910019440 Mg(OH) Inorganic materials 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910003514 Sr(OH) Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 150000003939 benzylamines Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 1
- 229920005648 ethylene methacrylic acid copolymer Polymers 0.000 description 1
- 239000011953 free-radical catalyst Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical class [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000012808 vapor phase Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/181,027 US5498785A (en) | 1994-01-14 | 1994-01-14 | Continuous process for the aminolysis of ethylene copolymers |
| PCT/US1995/000500 WO1995019377A2 (en) | 1994-01-14 | 1995-01-13 | A continuous process for the aminolysis of ethylene copolymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO962917L NO962917L (no) | 1996-07-11 |
| NO962917D0 NO962917D0 (no) | 1996-07-11 |
| NO310625B1 true NO310625B1 (no) | 2001-07-30 |
Family
ID=22662599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO19962917A NO310625B1 (no) | 1994-01-14 | 1996-07-11 | Kontinuerlig fremgangsmåte for aminolyse av etylenkopolymerer |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5498785A (de) |
| EP (1) | EP0739364B1 (de) |
| JP (1) | JPH09507682A (de) |
| AU (1) | AU1603295A (de) |
| CA (1) | CA2178725A1 (de) |
| DE (1) | DE69501946T2 (de) |
| FI (1) | FI962839A0 (de) |
| NO (1) | NO310625B1 (de) |
| WO (1) | WO1995019377A2 (de) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6107405A (en) * | 1996-10-18 | 2000-08-22 | Kimberly Clark Corporation | Method of making grafted polyolefin compositions |
| US6297326B1 (en) | 1996-10-18 | 2001-10-02 | Kimberly-Clark Corporation | Grafted polyolefin compositions |
| US5916969A (en) * | 1996-11-22 | 1999-06-29 | Kimberly-Clark Corporation | Article and composition of matter made from polyolefins and PEO blend and method of making the same |
| US6255386B1 (en) | 1996-12-31 | 2001-07-03 | Kimberly-Clark Worldwide, Inc. | Blends of polyolefin and poly(ethylene oxide) and process for making the blends |
| US5700872A (en) * | 1996-12-31 | 1997-12-23 | Kimberly Clark Worlwide, Inc. | Process for making blends of polyolefin and poly(ethylene oxide) |
| US6153700A (en) * | 1996-12-31 | 2000-11-28 | Kimberly-Clark Worldwide, Inc. | Water-degradable flushable film of polyolefin and poly(ethylene oxide) and personal care article therewith |
| US5912076A (en) | 1996-12-31 | 1999-06-15 | Kimberly-Clark Worldwide, Inc. | Blends of polyethylene and peo having inverse phase morphology and method of making the blends |
| US6063866A (en) * | 1996-12-31 | 2000-05-16 | Kimberly-Clark Worldwide, Inc. | Blends of polyolefin and poly(ethylene oxide) and process for making the blends |
| US6100330A (en) * | 1996-12-31 | 2000-08-08 | Kimberly-Clark Worldwide, Inc. | Water-degradable film of monomer grafted to polyolefin and poly(ethylene oxide) |
| US6111014A (en) * | 1996-12-31 | 2000-08-29 | Kimberly-Clark Worldwide, Inc. | Film of monomer-grafted polyolefin and poly(ethylene oxide) |
| US5976694A (en) | 1997-10-03 | 1999-11-02 | Kimberly-Clark Worldwide, Inc. | Water-sensitive compositions for improved processability |
| US6172177B1 (en) * | 1997-12-31 | 2001-01-09 | Kimberly-Clark Worldwide, Inc. | Grafted poly(ethylene oxide) compositions |
| US6372850B2 (en) | 1997-12-31 | 2002-04-16 | Kimberly-Clark Worldwide, Inc. | Melt processable poly (ethylene oxide) fibers |
| US6117947A (en) * | 1997-12-31 | 2000-09-12 | Kimberly-Clark Worldwide, Inc. | Method of modifying poly(ethylene oxide) |
| US6350518B1 (en) | 1998-06-01 | 2002-02-26 | Kimberly-Clark Worldwide, Inc. | Methods of making blend compositions of an unmodified poly vinyl alcohol and a thermoplastic elastomer |
| KR20010099995A (ko) * | 1998-12-29 | 2001-11-09 | 로날드 디. 맥크레이 | 열-활성화 접착제 |
| US6576576B1 (en) | 1999-12-29 | 2003-06-10 | Kimberly-Clark Worldwide, Inc. | Multicomponent fibers |
| US6790519B1 (en) | 2000-05-26 | 2004-09-14 | Kimberly-Clark Worldwide, Inc. | Moisture-induced poly(ethylene oxide) gel, method of making same and articles using same |
| US6610793B1 (en) | 2000-05-26 | 2003-08-26 | Kimberly-Clark Worldwide, Inc. | Modified poly(ethylene oxide), method of making same and articles using same |
| WO2001096416A2 (en) * | 2000-06-12 | 2001-12-20 | Uniroyal Chemical Company, Inc. | Ethylene/(meth)acrylate copolymers having aromatic amines grafted thereto |
| US6607819B2 (en) | 2000-12-28 | 2003-08-19 | Kimberly-Clark Worldwide, Inc. | Polymer/dispersed modifier compositions |
| US6403706B1 (en) | 2000-12-28 | 2002-06-11 | Kimberly-Clark Worldwide, Inc. | Methods of making polymer/dispersed modifier compositions |
| US6515075B1 (en) | 2001-07-12 | 2003-02-04 | Kimberly-Clark Worldwide, Inc. | Films, fibers and articles of chemically modified polyethylene oxide compositions with improved environmental stability and method of making same |
| US20090108488A1 (en) * | 2005-08-18 | 2009-04-30 | Kazuaki Matsumoto | Process for Production of Hybrid Polymeric Material |
| US8491770B2 (en) * | 2010-12-10 | 2013-07-23 | Axalta Coating Systems IP Co. LLC | Cathodic electrocoating compositions |
| US20120149847A1 (en) * | 2010-12-10 | 2012-06-14 | E. I. Du Pont De Nemours And Company | Process for making functionalized polymers |
| US8779069B2 (en) * | 2011-12-12 | 2014-07-15 | Axalta Coating Systems Ip Co., Llc | Cathodic electrocoating compositions |
| US9056954B2 (en) * | 2011-12-12 | 2015-06-16 | Axalta Coating Systems Ip Co., Llc | Cathodic electrocoating compositions |
| CN105164169A (zh) * | 2012-09-19 | 2015-12-16 | 陶氏环球技术有限责任公司 | 通过转酰胺化制备高分子量、官能化的聚(甲基)丙烯酰胺聚合物 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3350372A (en) * | 1960-08-22 | 1967-10-31 | Gulf Oil Corp | Ethylene/acrylate ester copolymers |
| US3429860A (en) * | 1967-04-11 | 1969-02-25 | Gulf Oil Corp | Method of preparing amide polymers |
| US4233193A (en) * | 1978-10-18 | 1980-11-11 | Sandoz Ltd. | Salts of polymeric basic amides |
| JPS59129202A (ja) * | 1983-01-17 | 1984-07-25 | Nippon Oil Co Ltd | 樹脂金属塩の製造方法 |
| US4874824A (en) * | 1987-11-23 | 1989-10-17 | Rohm And Haas Company | Process for manufacturing low-acid, glutaric-anhydride-containing copolymers |
| DE3827587A1 (de) * | 1988-08-13 | 1990-03-01 | Basf Lacke & Farben | Aminogruppenhaltige copolymerisate, verfahren zu ihrer herstellung sowie ihre verwendung in beschichtungsmitteln |
| FR2693202B1 (fr) * | 1992-07-06 | 1994-12-30 | Hoechst France | Polymères amphiphiles hydrosolubles, leur procédé de préparation et leur application comme épaississant. |
-
1994
- 1994-01-14 US US08/181,027 patent/US5498785A/en not_active Expired - Fee Related
-
1995
- 1995-01-13 JP JP7519145A patent/JPH09507682A/ja not_active Ceased
- 1995-01-13 DE DE69501946T patent/DE69501946T2/de not_active Expired - Fee Related
- 1995-01-13 CA CA002178725A patent/CA2178725A1/en not_active Abandoned
- 1995-01-13 WO PCT/US1995/000500 patent/WO1995019377A2/en active IP Right Grant
- 1995-01-13 AU AU16032/95A patent/AU1603295A/en not_active Abandoned
- 1995-01-13 EP EP95908046A patent/EP0739364B1/de not_active Expired - Lifetime
-
1996
- 1996-07-11 NO NO19962917A patent/NO310625B1/no not_active IP Right Cessation
- 1996-07-12 FI FI962839A patent/FI962839A0/fi unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CA2178725A1 (en) | 1995-07-20 |
| EP0739364A1 (de) | 1996-10-30 |
| FI962839A (fi) | 1996-07-12 |
| AU1603295A (en) | 1995-08-01 |
| NO962917L (no) | 1996-07-11 |
| DE69501946D1 (de) | 1998-05-07 |
| NO962917D0 (no) | 1996-07-11 |
| EP0739364B1 (de) | 1998-04-01 |
| WO1995019377A2 (en) | 1995-07-20 |
| WO1995019377A3 (en) | 1995-08-10 |
| DE69501946T2 (de) | 1998-08-06 |
| FI962839A0 (fi) | 1996-07-12 |
| US5498785A (en) | 1996-03-12 |
| JPH09507682A (ja) | 1997-08-05 |
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| MM1K | Lapsed by not paying the annual fees |