NO145779B - CLEANING TABLE FOR SELF-CLEAR CLEANING OF DENTAL PROTEINS AFTER SOLUTION IN WATER - Google Patents
CLEANING TABLE FOR SELF-CLEAR CLEANING OF DENTAL PROTEINS AFTER SOLUTION IN WATER Download PDFInfo
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- NO145779B NO145779B NO773149A NO773149A NO145779B NO 145779 B NO145779 B NO 145779B NO 773149 A NO773149 A NO 773149A NO 773149 A NO773149 A NO 773149A NO 145779 B NO145779 B NO 145779B
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- weight
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- 238000004140 cleaning Methods 0.000 title claims description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 6
- 102000004169 proteins and genes Human genes 0.000 title 1
- 108090000623 proteins and genes Proteins 0.000 title 1
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 12
- -1 ethylenediamine compound Chemical class 0.000 claims description 9
- LNOPIUAQISRISI-UHFFFAOYSA-N n'-hydroxy-2-propan-2-ylsulfonylethanimidamide Chemical compound CC(C)S(=O)(=O)CC(N)=NO LNOPIUAQISRISI-UHFFFAOYSA-N 0.000 claims description 9
- 229920001223 polyethylene glycol Polymers 0.000 claims description 9
- 239000004094 surface-active agent Substances 0.000 claims description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 6
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 5
- 101100399296 Mus musculus Lime1 gene Proteins 0.000 claims description 5
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 5
- 239000012876 carrier material Substances 0.000 claims description 5
- 239000004571 lime Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 5
- 150000007524 organic acids Chemical class 0.000 claims description 5
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 5
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 5
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 5
- 235000016257 Mentha pulegium Nutrition 0.000 claims description 4
- 244000246386 Mentha pulegium Species 0.000 claims description 4
- 235000004357 Mentha x piperita Nutrition 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 235000001050 hortel pimenta Nutrition 0.000 claims description 4
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 claims description 3
- 235000019820 disodium diphosphate Nutrition 0.000 claims description 3
- GYQBBRRVRKFJRG-UHFFFAOYSA-L disodium pyrophosphate Chemical compound [Na+].[Na+].OP([O-])(=O)OP(O)([O-])=O GYQBBRRVRKFJRG-UHFFFAOYSA-L 0.000 claims description 3
- 229940038485 disodium pyrophosphate Drugs 0.000 claims description 3
- 239000007800 oxidant agent Substances 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 description 10
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 8
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 7
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 7
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 239000008187 granular material Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000012459 cleaning agent Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000008139 complexing agent Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 3
- 235000010234 sodium benzoate Nutrition 0.000 description 3
- 239000004299 sodium benzoate Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- 230000000845 anti-microbial effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- JMGZBMRVDHKMKB-UHFFFAOYSA-L disodium;2-sulfobutanedioate Chemical compound [Na+].[Na+].OS(=O)(=O)C(C([O-])=O)CC([O-])=O JMGZBMRVDHKMKB-UHFFFAOYSA-L 0.000 description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 2
- 159000000000 sodium salts Chemical class 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 208000002064 Dental Plaque Diseases 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- 229920000168 Microcrystalline cellulose Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 229940089206 anhydrous dextrose Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940043430 calcium compound Drugs 0.000 description 1
- 150000001674 calcium compounds Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000000249 desinfective effect Effects 0.000 description 1
- QPXWUAQRJLSJRT-UHFFFAOYSA-N diethoxyphosphinothioyl diethyl phosphate Chemical compound CCOP(=O)(OCC)OP(=S)(OCC)OCC QPXWUAQRJLSJRT-UHFFFAOYSA-N 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000010794 food waste Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 235000019813 microcrystalline cellulose Nutrition 0.000 description 1
- 239000008108 microcrystalline cellulose Substances 0.000 description 1
- 229940016286 microcrystalline cellulose Drugs 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000007903 penetration ability Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 210000003296 saliva Anatomy 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/24—Phosphorous; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q11/00—Preparations for care of the teeth, of the oral cavity or of dentures; Dentifrices, e.g. toothpastes; Mouth rinses
- A61Q11/02—Preparations for deodorising, bleaching or disinfecting dentures
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
- A61K2800/222—Effervescent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/51—Chelating agents
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Inorganic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Detergent Compositions (AREA)
- Cosmetics (AREA)
Description
Oppfinnelsen angår en rensetablett til selvstendig rensing av tannproteser efter oppløsning i vann og som har en spaltningstid på 1-2 minutter og en samlet rensetid på The invention relates to a cleaning tablet for independent cleaning of dental prostheses after dissolution in water and which has a disintegration time of 1-2 minutes and a total cleaning time of
3-5 minutter, inneholdende 15-25 vekt% natriumhydrogencarbonat som gassdannelsesmiddel,. peroxymonosulfater som oxydasjonsmiddel, 8-15 vekt% natriumhexametafosfat henholdsvis surt dinatriumpyrofosfat, over 15 vekt% av en kalkbindende organisk syre, 2-6 vekt% av en ethylendiaminforbindelse, 1,4 vekt% polyethylenglycol med høy molekylvekt, 3-5 minutes, containing 15-25% by weight of sodium bicarbonate as a gas-forming agent. peroxymonosulfates as oxidizing agent, 8-15% by weight of sodium hexametaphosphate or acidic disodium pyrophosphate, over 15% by weight of a lime-binding organic acid, 2-6% by weight of an ethylenediamine compound, 1.4% by weight of polyethylene glycol with a high molecular weight,
minst 1 vekt% polymert farvestoffbærermateriale, fortrinns- at least 1% by weight polymeric dye carrier material, preferably
vis natriumpolyacrylat med tilsatt farvestoff, over 0,5 vekt% tensider i form av alkyl- eller alkylarylsulfonater og dessuten alkylbenzensulfonater, 0,5-1,5 vekt% peppermynte- show sodium polyacrylate with added dye, more than 0.5% by weight of surfactants in the form of alkyl or alkylaryl sulfonates and also alkylbenzene sulfonates, 0.5-1.5% by weight of peppermint
eller annet aromamateriale samt bærer og smøremidler og med en pH-verdi av en 1%-ig oppløsning av tabletten i vann på or other flavoring material as well as carriers and lubricants and with a pH value of a 1% solution of the tablet in water of
under 7,0. below 7.0.
I tysk tilgjengeliggjort patentsøknad nr. 2357720 er allerede en rensetablett beskrevet hvorav minst ett av de to skikt som danner rensetabletten, har den ovennevnte sammen- ' setning. Hvert skikt har en pH i en 1%-ig oppløsning av 6,5-7,0. Som kompleksmiddel som danner chelatelignende kom-plekser med metallioner, inneholder den kjente rensetablett ethylendiamintetraacetat. I den kjente rensetablett anvendes sitronsyre som kalkbindende organisk syre. In German patent application no. 2357720, a cleaning tablet is already described, of which at least one of the two layers forming the cleaning tablet has the above-mentioned composition. Each layer has a pH in a 1% solution of 6.5-7.0. As a complexing agent that forms chelate-like complexes with metal ions, the known cleaning tablet contains ethylenediaminetetraacetate. In the known cleaning tablet, citric acid is used as a lime-binding organic acid.
I rensetabletten ifølge tysk tilgjengeliggjort patent-søknad 2357720. tjener det samlede innhold av natriumhydrogencarbonat som pH-stabiliserende, gassdannende bærermateriale. Natriumhexametafosfatet virker som vannbløtgjøringsmiddel, In the cleansing tablet according to German patent application 2357720, the total content of sodium hydrogen carbonate serves as a pH-stabilizing, gas-forming carrier material. The sodium hexametaphosphate acts as a water softener,
mens sitronsyren har en reduserende, antimikrobiell virkning while the citric acid has a reducing, antimicrobial effect
og dessuten oppløser tannstem som forekommer på tannprotesen som skal renses. Ethylendiamintetraacetatet virker som bløtgjøringsmiddel, nærmere bestemt på grunn av chelate-dannelsen, og dessuten kan det iakttas at det har en tannsten-oppløsende virkning. Den anvendte polyethylenglycol med høy molekylvekt virker som antimikrobielt nedbrytningsmiddel. Tensidene har alle en emulgerende virkning, og i den kjente rensetablett virker de på grunn av deres overflateaktivitet and also dissolves dental plaque that occurs on the denture to be cleaned. The ethylenediamine tetraacetate acts as a softening agent, more specifically due to the chelate formation, and it can also be observed that it has a calculus-dissolving effect. The high molecular weight polyethylene glycol used acts as an antimicrobial disintegrant. The surfactants all have an emulsifying effect, and in the known cleaning tablet they work because of their surface activity
til å avbygge belegget på tannprotesen. Natriumpyrofosfatet virker reduserende og bløtgjørende og avbygger belegget på tannprotesen på grunn av dets overflateaktive virkning. to break down the coating on the denture. The sodium pyrophosphate has a reducing and softening effect and breaks down the coating on the denture due to its surface-active effect.
De anvendte peroxymonosulfater tjener The peroxymonosulfates used serve
som oxydasjonsmiddel. Som polymere farvestoffbærermateri-aler med overflateaktivitet og rensevirkning anvendes i den kjente rensetablett fortrinnsvis et handelstilgjengelig natriumsalt av en polycarboxylsyre, som beskrevet i tysk tilgjengeliggjort patentsøknad nr. 2357720, s. 17, linjene 15 og 16, og som også forbedrer rensevirkningene. Som alkyl-benzensulfonat som er anvendbart som tensid, er i tysk tilgjengeliggjort patentsøknad nr. 2357720 f.eks. natriumdodecylbenzensulfonat angitt, og dessuten kan fettsyre- dinatrium-sulfosuccinater tilsettes. Den foretrukne molekylvekt for den anvendte polyethylenglycol kan for den kjente rensetablett være 4000-25000, fortrinnsvis ca. 20000. as an oxidizing agent. As polymeric dye carrier materials with surface activity and cleaning effect, the known cleaning tablet preferably uses a commercially available sodium salt of a polycarboxylic acid, as described in German patent application no. 2357720, p. 17, lines 15 and 16, and which also improves the cleaning effects. As alkyl benzene sulphonate which can be used as a surfactant, patent application no. 2357720 has been made available in German, e.g. sodium dodecylbenzene sulphonate indicated, and in addition fatty acid disodium sulphosuccinates can be added. The preferred molecular weight for the polyethylene glycol used can for the known cleaning tablet be 4000-25000, preferably approx. 20000.
Rensetabletten ifølge tysk tilgjengeliggjort patentsøk-nad nr. 2357720 har generelt gitt et godt resultat. Det har imidlertid for en rekke anvendelsesformål vist seg ønsket å erholde vesentlig kortere rensetider istedenfor de rensetider av 10-15 minutter som er nødvendige ved anvendelse av rensetabletten ifølge den tilgjengeliggjorte tyske patent-søknad nr. 2357720. Dessuten har oppbygningen av den kjente rensetablett i to skikt vist seg økonomisk forholdsvis ugunstig for en rekke anvendelsesformål. The cleansing tablet according to German patent application no. 2357720 has generally given a good result. However, for a number of purposes it has proved desirable to obtain significantly shorter cleaning times instead of the cleaning times of 10-15 minutes which are necessary when using the cleaning tablet according to the available German patent application no. 2357720. Furthermore, the structure of the known cleaning tablet in two proved economically relatively unfavorable for a number of application purposes.
Det er riktignok kjent at avleiringer av kalsiumfor-bindelser på proteser hhv. metalldeler av proteser, deriblant også for kjevereguleringsapparater, bedre lar seg oppløse ved anvendelse av spesielt sure rensemidler, som f.eks. beskrevet i sveitsisk patentskrift nr. 480840, hvor pH er 1,5-5, men det er en ulempe ved slike spesielt sure rensemidler at de anvendte chelatedannende kompleksdannelsesmidler ikke lenger er virksomme fordi den øvre grense for pH for er-holdelse av en slik virkning av kompleksdannelsesmidlene er ca. 6 . It is admittedly known that deposits of calcium compounds on prostheses or metal parts of prostheses, including those for jaw adjustment devices, are better able to dissolve when using particularly acidic cleaning agents, such as e.g. described in Swiss patent document no. 480840, where the pH is 1.5-5, but it is a disadvantage of such particularly acidic cleaning agents that the chelating complex-forming agents used are no longer effective because the upper limit of pH for obtaining such an effect of the complexing agents is approx. 6.
Det tas derfor ved oppfinnelsen sikte på å tilveiebringe en rensetablett av den nevnte type som er bygget opp av ett enkelt skikt og som gir en meget hurtig og pålitelig rensing. The invention therefore aims to provide a cleaning tablet of the aforementioned type which is built up from a single layer and which provides a very fast and reliable cleaning.
Rensetabletten ifølge oppfinnelsen er særpreget ved at den The cleansing tablet according to the invention is characterized by the fact that it
er oppbygget i ett skikt, inneholder sulfamidsyre som den kalkbindende organiske syre sammen med 1,5-2,5 vekt% dialkyl-urinstoff,hvis alkylgrupper inneholder 1-6 carbonatomer, at ethylendiaminforbindelsen er ethylendiamintetraeddiksyre og at tabletten som tensider ytterligere inneholder 0,2-0,5 is built up in one layer, contains sulfamic acid as the lime-binding organic acid together with 1.5-2.5% by weight of dialkyl-urea, whose alkyl groups contain 1-6 carbon atoms, that the ethylenediamine compound is ethylenediaminetetraacetic acid and that the tablet as surfactants further contains 0.2 -0.5
vekt% av et ikke-ionogent fluortensid bestående av forbindelser med den generelle formel C0F., cO (CHoCH„0) -CH-, hvori % by weight of a non-ionic fluorosurfactant consisting of compounds of the general formula C0F., cO (CHoCH„0) -CH-, in which
o lo z z n J o lo z z n J
CgF^j.- er resten av tetrameren av tetrafluorethylen og n har CgF^j.- is the residue of the tetramer of tetrafluoroethylene and n has
en gjennomsnittlig verdi av 8, og dessuten en forbindelse med formelen CgF^O (CH2CH20) n, hvori CgF^ - er resten av en tetramer av tetrafluorethylen og n har en gjennomsnittlig verdi av 23, idet pH-verdien av tabletten er regulert slik at en 1%-ig oppløsning har en pH-verdi på 6,3-6,5. an average value of 8, and also a compound with the formula CgF^O (CH2CH20) n, in which CgF^ - is the residue of a tetramer of tetrafluoroethylene and n has an average value of 23, the pH value of the tablet being regulated so that a 1% solution has a pH value of 6.3-6.5.
I en spesielt foretrukken utførelsesform av den foreliggende rensetablett er det polymere farvestoffbærermateriale 1-2 vekt% av et handelstilgjengelig natriumsalt av en polycarboxylsyre (se tysk tilgjengeliggjort patentsøknad nr. 3257720, s. 17, linjene 15 og 16), fortrinnsvis natriumpolyacrylat. Dessuten kan rensetabletten også inneholde 1-2 vekt% av et fornettet polyvinylpyrrolidon. In a particularly preferred embodiment of the present cleaning tablet, the polymeric dye carrier material is 1-2% by weight of a commercially available sodium salt of a polycarboxylic acid (see German Patent Application No. 3257720, p. 17, lines 15 and 16), preferably sodium polyacrylate. In addition, the cleaning tablet can also contain 1-2% by weight of a cross-linked polyvinylpyrrolidone.
Den følgende sammensetning for en rensetablett ifølge oppfinnelsen har vist seg å være spesielt gunstig: 10-12 vekt% natriumhexametafosfat, 18-20 vekt% natriumhydrogencarbonat, 1,5-2,0 vekt% polyethylenglycol med en molekylvekt av 20000,24-30 vekt% sulfamidsyre, 20-24 vekt% caroat, 5,5-7,5 vekt% surt dinatriumpyrofosfat, 2-3 vekt% ethylendiamintetraeddiksyre, 0,5-2,0 vekt% natriumpolyacrylat med tilsatt farvestoff, 0,5-1,5 vekt% peppermyntepulver, 0,5-1,5 vekt% natriumdodecylbenzensulfonat, 0,3-1,0 vekt% laurylpolyglycolethersulfosuccinat, 0,2-0,4 vekt% av et ikke-ionogent fluortensid fra gruppen be- The following composition for a cleansing tablet according to the invention has proven to be particularly beneficial: 10-12% by weight sodium hexametaphosphate, 18-20% by weight sodium hydrogencarbonate, 1.5-2.0% by weight polyethylene glycol with a molecular weight of 20,000.24-30% by weight % sulfamic acid, 20-24 wt% caroate, 5.5-7.5 wt% acid disodium pyrophosphate, 2-3 wt% ethylenediaminetetraacetic acid, 0.5-2.0 wt% sodium polyacrylate with added dye, 0.5-1.5 wt% peppermint powder, 0.5-1.5 wt% sodium dodecylbenzene sulfonate, 0.3-1.0 wt% lauryl polyglycol ether sulfosuccinate, 0.2-0.4 wt% of a non-ionic fluorosurfactant from the group be-
stående av forbindelser med den generelle formel C8F15° (CH2CH20) n~CH3' hvori C8F15~ ut<3^ r "sten av tetrameren av tetrafluorethylen og n har en gjennomsnittlig verdi av 8, consisting of compounds of the general formula C8F15° (CH2CH20) n~CH3' where C8F15~ is the tetramer of tetrafluoroethylene and n has an average value of 8,
og dessuten en forbindelse med den generelle formel C0F,c-0(CH2CH20)n, hvori CgF^- utgjør resten av en tetramer av tetra- and furthermore a compound of the general formula C0F,c-0(CH2CH20)n, in which CgF^- forms the residue of a tetramer of tetra-
fluorethylen og n har en gjennomsnittlig verdi av 23, fluoroethylene and n has an average value of 23,
0,8-1,1 vekt% natriumbenzoat, 1,5-2,0 vekt% dialkylthio-urinstoff, 1,5-2,0 vekt% fornettet polyvinylpyrrolidon, 0,5-1,5 vekt% dinatriumsulfosuccinat og 0,8-1,2 vekt% alkylarylsulfonat. 0.8-1.1 wt% sodium benzoate, 1.5-2.0 wt% dialkylthiourea, 1.5-2.0 wt% cross-linked polyvinylpyrrolidone, 0.5-1.5 wt% disodium sulfosuccinate and 0.8 -1.2% by weight of alkylaryl sulphonate.
Ved fremstilling av den foreliggende rensetablett kan de angitte mengder av natriumhydrogencarbonat, natriumhexametafosfat, polyethylenglycol og dessuten 30-50 vekt% av den samlede sulfamidsyremengde først blandes med hverandre og overføres til et granulat, hvorefter granulatet blandes med de øvrige bestanddeler og rensetabletten fremstilles fra denne blanding. When producing the present cleaning tablet, the stated amounts of sodium hydrogen carbonate, sodium hexametaphosphate, polyethylene glycol and also 30-50% by weight of the total amount of sulfamic acid can first be mixed with each other and transferred to a granule, after which the granulate is mixed with the other ingredients and the cleaning tablet is produced from this mixture .
I motsetning til de hittil vanlige rensetabletter for tannproteser som er sterkt alkaliske, nøytrale eller svakt sure (f.eks. rensetabletten ifølge tysk tilgjengeliggjort patentsøknad nr. 2357720), fås ved anvendelse av rensetabletten ifølge oppfinnelsen en nøyaktig regulert pH av 6,3-6,5 'med avvik av høyst - 0,3. Rensetabletten ifølge oppfinnelsen gjør det ikke lenger ubetinget nødvendig å foreta en daglig rensing av tannprotesen for å fjerne de i løpet av dagen dannede avleiringer som består av matrester og spyttrester. Derimot sikrer rensetabletten ifølge oppfinnelsen da den har en usedvanlig hurtig og tidligere ikke oppnådd spaltningstid på 1-2 minutter, en fullstendig rensevirkning i løpet av en samlet rensetid på 3-5 minutter. Det er for rensetabletten ifølge oppfinnelsen av viktighet at sulfamidsyren anvendes sammen med dialkylthiourinstoffet som virker som antikorrosjonsmiddel og altså tjener som inhibitor for sulfamidsyren,for med sikkerhet å utelukke eventuelle beskadigelser av protesematerialet eller av metalldelene. Dette antikorrosjonsmiddel hhv. denne inhibitor gir en synergistisk virkning sammen med det ifølge oppfinnelsen anvendte natriumbenzoat som har en kjent desinfiserende virkning, hvorved fås en ytterligere synergistisk virkning med det aktive oxygen (fra peroxymonosulfatet) da inhibitoren er virk-som som antioxydasjonsmiddel. En synergistisk virkning fås også mellom antikorrosjonsmidlet og sulfamidsyren. Derved hindres at en nedbrytning av peroxydene kan finne sted ved lagring av rensetabletten. Som natriumhexametafosfat er et "instantisert" natriumhexametafosfat spesielt egnet. In contrast to the previously common cleaning tablets for dental prostheses which are strongly alkaline, neutral or weakly acidic (e.g. the cleaning tablet according to German patent application no. 2357720), when using the cleaning tablet according to the invention, a precisely regulated pH of 6.3-6 is obtained .5 'with a deviation of at most - 0.3. The cleaning tablet according to the invention no longer makes it absolutely necessary to carry out a daily cleaning of the dental prosthesis in order to remove the deposits formed during the day which consist of food residues and saliva residues. In contrast, the cleaning tablet according to the invention, as it has an exceptionally fast and previously unachieved decomposition time of 1-2 minutes, ensures a complete cleaning effect during a total cleaning time of 3-5 minutes. It is important for the cleaning tablet according to the invention that the sulfamic acid is used together with the dialkylthiourea, which acts as an anti-corrosion agent and thus serves as an inhibitor for the sulfamic acid, in order to safely exclude any damage to the prosthetic material or the metal parts. This anti-corrosion agent or this inhibitor gives a synergistic effect together with the sodium benzoate used according to the invention, which has a known disinfecting effect, whereby a further synergistic effect is obtained with the active oxygen (from the peroxymonosulphate) as the inhibitor acts as an antioxidant. A synergistic effect is also obtained between the anti-corrosion agent and the sulfamic acid. This prevents a breakdown of the peroxides from taking place when the cleaning tablet is stored. As sodium hexametaphosphate, an "instantized" sodium hexametaphosphate is particularly suitable.
På grunn av at pulverformig ethylendiamintetraeddiksyre som har en ph i mettet, vandig oppløsning av 2,5-3,0, anvendes i rensetabletten ifølge oppfinnelsen, er det nød-vendig med en vesentlig lavere tilsetning av chelatedannende kompleksdannelsesmiddel enn hva som" ville ha vært tilfellet dersom ethylendiamintetraacetat var blitt anvendt i den kjente form. Due to the fact that powdered ethylenediaminetetraacetic acid, which has a ph in saturated, aqueous solution of 2.5-3.0, is used in the cleaning tablet according to the invention, it is necessary to add a substantially lower amount of chelating complexing agent than would have been the case if ethylenediaminetetraacetate had been used in the known form.
Dessuten har kombinasjonen av de i rensetabletten ifølge oppfinnelsen anvendte tensider og det ikke-ionogene fluortensid den virkning at det kan oppnås en rensevæske med en usedvanlig lav overflatespenning av 25-26 dyn/cm. På grunn av denne lave overflatespenning økes rensevæskens fuktningsevne hhv. emulgeringsevne sterkt, og da først kan den korte rensetid erholdes. Som tensider fore-trekkes det å anvende slike som gir et varig, fløtelignende og stivt skum, og hvor overflatespenningen for en 0,1%-ig vandig oppløsning er 25-35 dyn/cm. På grunn av tilset-ningen til rensetabletten ifølge oppfinnelsen av det ikke-ionogene fluorltensid i en konsentrasjon av Moreover, the combination of the surfactants used in the cleaning tablet according to the invention and the non-ionic fluorosurfactant has the effect that a cleaning liquid can be obtained with an exceptionally low surface tension of 25-26 dyne/cm. Due to this low surface tension, the wetting ability of the cleaning liquid is increased or emulsifying ability strongly, and only then can the short cleaning time be obtained. As surfactants, it is preferred to use those which give a lasting, cream-like and stiff foam, and where the surface tension for a 0.1% aqueous solution is 25-35 dyne/cm. Due to the addition to the cleaning tablet according to the invention of the non-ionic fluorosurfactant in a concentration of
0,2-0,5% i tabletten, synker overflatespenningen for den samlede rensevæske til 25-26 dyn/cm. Derved økes tensidenes fuktningsevne og inntrengningsevne spesielt sterkt. 0.2-0.5% in the tablet, the surface tension of the total cleaning liquid drops to 25-26 dyne/cm. This increases the wetting ability and penetration ability of the surfactants particularly strongly.
Rensetabletten ifølge oppfinnelsen byr for første gang på den mulighet å kunne tilveiebringe et ytterst hurtig arbeidende rensemiddel som er virksomt i en rensevæske med en overflatespenning av bare 25-26 dyn/cm, mens gjennom-snittsoverflatespenningen for andre rensemidler er 35-90 dyn/cm. The cleaning tablet according to the invention offers for the first time the possibility of being able to provide an extremely fast-acting cleaning agent which is effective in a cleaning liquid with a surface tension of only 25-26 dyne/cm, while the average surface tension for other cleaning agents is 35-90 dyne/cm .
Som presse- og hjelpemidler kan lignende materialer anvendes som for rensetabletten ifølge tysk tilgjengeliggjort patentsøknad nr. 2357720. For dette formål kan f.eks. sukkerfettsyreestere tilsettes. Som presse- og glidemidler kan egnede naturlige stivelser, forsukrede stivelser og derivat derav, som stivelsessukker, vannfri dextrose, polyethylenglycol og mikrokrystallinske celluloser, anvendes. As pressing and auxiliary materials, similar materials can be used as for the cleaning tablet according to German patent application no. 2357720 made available. For this purpose, e.g. sugar fatty acid esters are added. Suitable natural starches, saccharified starches and derivatives thereof, such as starch sugar, anhydrous dextrose, polyethylene glycol and microcrystalline cellulose, can be used as pressing and sliding agents.
Eksempel Example
For fremstilling av en rensetablett ifølge oppfinnelsen tilsettes først 10,55 vekt% "instantisert" natrium-hexametaf osf at, 10,85 vektdeler sulfamidsyre, 19,00 vektdeler natriumhydrogencarbonat og 1,81 vektdeler polyethylenglycol med en molekylvekt av 20000 til en blandekjele fra en vanlig tilførselssilo og elevator. Blandekjelen kobles derefter til en granulator av typen "GLATT". Bestanddelene som skal granuleres, oppvarmes med varmluft med en temperatur av 100-115°C med åpningen for lufttilførsel innstilt på trinn 5-6 og åpningen for fjernelse av luft på trinn 2-3. Bestanddelene som skal granuleres, oppvarmes under konstant omhvirvling, og granuleringen finner da sted ved en temperatur av 60-65°C. Denne temperatur må opprettholdes i ca. 10 minutter. Ved denne temperatur av 60-65°C smelter poly-ethylenglycolen med en molekylvekt av 20000 fullstendig i løpet av den angitte tid av ca. 10 minutter, hvorved granuleringen fullføres. Granulatet avkjøles til en temperatur av ca. 25°C ved lik innstilling av åpningen for tilførsel av luft og åpningen for fjernelse av luft og med tilførsel av kjøleluft ved en temperatur av 6-10°C. Derefter fylles granulatet i en luft- og fuktighetstett beholder, f.eks. For the production of a cleaning tablet according to the invention, first 10.55% by weight of "instantized" sodium hexametaphosphate, 10.85 parts by weight of sulfamic acid, 19.00 parts by weight of sodium hydrogencarbonate and 1.81 parts by weight of polyethylene glycol with a molecular weight of 20,000 are added to a mixing vessel from a normal supply silo and elevator. The mixing boiler is then connected to a granulator of the "GLATT" type. The ingredients to be granulated are heated with hot air at a temperature of 100-115°C with the opening for air supply set to steps 5-6 and the opening for removing air at steps 2-3. The components to be granulated are heated under constant stirring, and the granulation then takes place at a temperature of 60-65°C. This temperature must be maintained for approx. 10 minutes. At this temperature of 60-65°C, the polyethylene glycol with a molecular weight of 20,000 melts completely during the indicated time of approx. 10 minutes, during which the granulation is completed. The granulate is cooled to a temperature of approx. 25°C with the same setting of the opening for the supply of air and the opening for the removal of air and with the supply of cooling air at a temperature of 6-10°C. The granulate is then filled into an airtight and moisture-tight container, e.g.
i polyethylensekker, og det kontrolleres ved regelmessig prøvetagning at fuktigheten er høyst 0,25% B^O. 4 2,21 vektdeler av det således fremstilte granulat blandes derefter, som detaljert beskrevet i tysk tilgjengeliggjort patentsøknad nr. 2357720, med de øvrige bestanddeler for rensetabletten, dvs. ifølge dette utførelseseksempel med 22,60 vektdeler peroxymonosulfat, 6,23 vektdeler dinatriumpyrofos f at. 2,26 vektdeler ethylendiamintetraeddiksyre, 1,18 vektdeler natriumpolyacrylat med tilsatt farvestoff, 1,00 vektdel peppermyntepulver, 0,81 vektdeler natriumdodecylbenzensulfonat, 0,54 vektdel laurylpolyglykolethersulfosuccinat, 0,30 vektdel av et ikke-ionogen<t> fluortensid fra gruppen bestående av forbindelser med den generelle formel C0F,c0(CH„CH~0) -CHn, hvor n har en gjennomsnittlig 8 15 2 2 n 3 in polyethylene bags, and it is checked by regular sampling that the humidity is no more than 0.25% B^O. 4 2.21 parts by weight of the thus produced granules are then mixed, as described in detail in German patent application no. 2357720, with the other ingredients for the cleaning tablet, i.e. according to this embodiment with 22.60 parts by weight peroxymonosulphate, 6.23 parts by weight disodium pyrophos f that . 2.26 parts by weight of ethylenediaminetetraacetic acid, 1.18 parts by weight of sodium polyacrylate with added dye, 1.00 parts by weight of peppermint powder, 0.81 parts by weight of sodium dodecylbenzene sulfonate, 0.54 parts by weight of lauryl polyglycol ether sulfosuccinate, 0.30 parts by weight of a non-ionic<t> fluorosurfactant from the group consisting of compounds with the general formula C0F,c0(CH„CH~0) -CHn, where n has an average 8 15 2 2 n 3
verdi av 8, og CQF.c0(CH.CH-O) , hvor n har en gjennomsnittlig verdi av 23, og CgF - er en tetramer av tetrafluor- value of 8, and CQF.c0(CH.CH-O) , where n has an average value of 23, and CgF - is a tetramer of tetrafluoro-
ethylen, 0,90 vektdel natriumbenzoat, 1,81 vektdeler dialkyl-thiourinstoff, 1,81 vektdeler polyvinylpyrrolidon, 1,00 vektdel dinatriumsulfosuccinat, 1,00 vektdel alkylarylsulfonat og ytterligere 16,27 vektdeler sulfamidsyre. Efter blandingen, tørking og sikting presses blandingen til en rensetablett . ethylene, 0.90 parts by weight of sodium benzoate, 1.81 parts by weight of dialkylthiourea, 1.81 parts by weight of polyvinylpyrrolidone, 1.00 parts by weight of disodium sulfosuccinate, 1.00 parts by weight of alkylaryl sulfonate and a further 16.27 parts by weight of sulfamic acid. After mixing, drying and sifting, the mixture is pressed into a cleaning tablet.
Claims (2)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2658450A DE2658450C3 (en) | 1976-12-23 | 1976-12-23 | Cleaning tablet for automatic cleaning of dentures in an aqueous solution as well as processes for their manufacture |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO773149L NO773149L (en) | 1978-06-26 |
| NO145779B true NO145779B (en) | 1982-02-22 |
| NO145779C NO145779C (en) | 1982-06-02 |
Family
ID=5996414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO773149A NO145779C (en) | 1976-12-23 | 1977-09-13 | CLEANING TABLE FOR SELF-CLEAR CLEANING OF DENTAL PROTEINS AFTER SOLUTION IN WATER |
Country Status (21)
| Country | Link |
|---|---|
| AT (1) | AT361125B (en) |
| AU (1) | AU518376B2 (en) |
| BE (1) | BE861767A (en) |
| CA (1) | CA1105387A (en) |
| CH (1) | CH633710A5 (en) |
| DD (1) | DD134484A5 (en) |
| DE (1) | DE2658450C3 (en) |
| DK (2) | DK159373C (en) |
| ES (1) | ES465220A1 (en) |
| FR (1) | FR2374899A1 (en) |
| GB (1) | GB1579401A (en) |
| HK (1) | HK55781A (en) |
| HU (1) | HU176692B (en) |
| IT (1) | IT1087496B (en) |
| LU (1) | LU78519A1 (en) |
| NL (1) | NL175137C (en) |
| NO (1) | NO145779C (en) |
| SE (1) | SE433303B (en) |
| SG (1) | SG882G (en) |
| YU (1) | YU281677A (en) |
| ZA (1) | ZA776880B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ZA792044B (en) * | 1978-05-08 | 1980-05-28 | Scherico Ltd | Substituted 1-phenyl-2,3,4,5-tetrahydro-1h-3-benzazepines,process for the preparation thereof,and pharmaceutical compositions containing them |
| DK435881A (en) * | 1981-10-01 | 1983-04-02 | Niels Ole Vesterager | WASHING ACTIVE DOSAGE UNIT, METHOD OF PREPARING IT AND THE USE OF IT |
| MY106919A (en) * | 1990-08-31 | 1995-08-30 | Kao Corp | Composition for use in oral cavity. |
| GB9723531D0 (en) * | 1997-11-05 | 1998-01-07 | Procter & Gamble | Cleansing tablets |
| US6077501A (en) * | 1998-06-30 | 2000-06-20 | Block Drug Company, Inc. | Denture cleanser |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1186342A (en) * | 1966-12-22 | 1970-04-02 | Unilever Ltd | Cleansing Compositions |
| DE2357720C3 (en) * | 1973-11-19 | 1983-01-13 | Kukident Richardson GmbH & Co. KG, 6940 Weinheim | Cleaning tablets for dentures or the like and processes for their manufacture |
-
1976
- 1976-12-23 DE DE2658450A patent/DE2658450C3/en not_active Expired
-
1977
- 1977-09-13 NO NO773149A patent/NO145779C/en unknown
- 1977-09-14 SE SE7710284A patent/SE433303B/en not_active IP Right Cessation
- 1977-09-21 DK DK416977A patent/DK159373C/en not_active IP Right Cessation
- 1977-09-21 DK DK476977A patent/DK416977A/en unknown
- 1977-09-23 NL NLAANVRAGE7710421,A patent/NL175137C/en not_active IP Right Cessation
- 1977-11-04 AT AT789977A patent/AT361125B/en not_active IP Right Cessation
- 1977-11-09 IT IT29485/77A patent/IT1087496B/en active
- 1977-11-14 GB GB47377/77A patent/GB1579401A/en not_active Expired
- 1977-11-15 LU LU78519A patent/LU78519A1/xx unknown
- 1977-11-17 ZA ZA00776880A patent/ZA776880B/en unknown
- 1977-11-18 AU AU30793/77A patent/AU518376B2/en not_active Expired
- 1977-11-25 YU YU02816/77A patent/YU281677A/en unknown
- 1977-12-06 CH CH1491177A patent/CH633710A5/en not_active IP Right Cessation
- 1977-12-12 BE BE183380A patent/BE861767A/en not_active IP Right Cessation
- 1977-12-15 FR FR7737914A patent/FR2374899A1/en active Granted
- 1977-12-19 ES ES77465220A patent/ES465220A1/en not_active Expired
- 1977-12-21 DD DD77202845A patent/DD134484A5/en not_active IP Right Cessation
- 1977-12-22 CA CA293,728A patent/CA1105387A/en not_active Expired
- 1977-12-22 HU HU77KU528A patent/HU176692B/en unknown
-
1981
- 1981-11-12 HK HK557/81A patent/HK55781A/en unknown
-
1982
- 1982-01-11 SG SG8/82A patent/SG882G/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATA789977A (en) | 1980-07-15 |
| SG882G (en) | 1983-07-08 |
| DK416977A (en) | 1978-06-24 |
| SE7710284L (en) | 1978-06-24 |
| DK159373C (en) | 1991-03-11 |
| AT361125B (en) | 1981-02-25 |
| NL175137C (en) | 1984-10-01 |
| FR2374899B1 (en) | 1981-12-31 |
| LU78519A1 (en) | 1978-03-20 |
| AU3079377A (en) | 1979-05-24 |
| CH633710A5 (en) | 1982-12-31 |
| NL175137B (en) | 1984-05-01 |
| YU281677A (en) | 1984-04-30 |
| DK159373B (en) | 1990-10-08 |
| CA1105387A (en) | 1981-07-21 |
| SE433303B (en) | 1984-05-21 |
| FR2374899A1 (en) | 1978-07-21 |
| DE2658450C3 (en) | 1979-06-21 |
| HK55781A (en) | 1981-11-20 |
| BE861767A (en) | 1978-06-12 |
| NO145779C (en) | 1982-06-02 |
| DE2658450A1 (en) | 1978-06-29 |
| GB1579401A (en) | 1980-11-19 |
| HU176692B (en) | 1981-04-28 |
| DD134484A5 (en) | 1979-03-07 |
| ZA776880B (en) | 1978-09-27 |
| AU518376B2 (en) | 1981-10-01 |
| NL7710421A (en) | 1978-06-27 |
| DE2658450B2 (en) | 1978-10-26 |
| NO773149L (en) | 1978-06-26 |
| IT1087496B (en) | 1985-06-04 |
| ES465220A1 (en) | 1979-01-01 |
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