JPH01172319A - Effervescent bathing agent composition - Google Patents
Effervescent bathing agent compositionInfo
- Publication number
- JPH01172319A JPH01172319A JP33154287A JP33154287A JPH01172319A JP H01172319 A JPH01172319 A JP H01172319A JP 33154287 A JP33154287 A JP 33154287A JP 33154287 A JP33154287 A JP 33154287A JP H01172319 A JPH01172319 A JP H01172319A
- Authority
- JP
- Japan
- Prior art keywords
- effervescent
- composition
- stabilizer
- carbonate
- amount
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 238000003287 bathing Methods 0.000 title abstract 3
- 239000003381 stabilizer Substances 0.000 claims abstract description 11
- 150000007524 organic acids Chemical class 0.000 claims abstract description 9
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims abstract description 5
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims abstract description 5
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims abstract description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 5
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims abstract description 3
- 239000000654 additive Substances 0.000 claims description 15
- 230000000996 additive effect Effects 0.000 claims description 9
- 238000005187 foaming Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 abstract description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 abstract description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 abstract description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 abstract description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 abstract description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract description 2
- 239000011975 tartaric acid Substances 0.000 abstract description 2
- 235000002906 tartaric acid Nutrition 0.000 abstract description 2
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000013329 compounding Methods 0.000 abstract 1
- 235000015320 potassium carbonate Nutrition 0.000 abstract 1
- 235000011118 potassium hydroxide Nutrition 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 24
- 239000001569 carbon dioxide Substances 0.000 description 12
- 229910002092 carbon dioxide Inorganic materials 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000013040 bath agent Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 2
- 239000001095 magnesium carbonate Substances 0.000 description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 235000002639 sodium chloride Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000001099 ammonium carbonate Substances 0.000 description 1
- 235000012501 ammonium carbonate Nutrition 0.000 description 1
- 229940059913 ammonium carbonate Drugs 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000002651 laminated plastic film Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 1
- 239000002370 magnesium bicarbonate Substances 0.000 description 1
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 description 1
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011736 potassium bicarbonate Substances 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- 229910000028 potassium bicarbonate Inorganic materials 0.000 description 1
- 229940093956 potassium carbonate Drugs 0.000 description 1
- 235000011181 potassium carbonates Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical compound [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 229940086066 potassium hydrogencarbonate Drugs 0.000 description 1
- 235000007715 potassium iodide Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/731—Cellulose; Quaternized cellulose derivatives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
- A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/20—Chemical, physico-chemical or functional or structural properties of the composition as a whole
- A61K2800/22—Gas releasing
- A61K2800/222—Effervescent
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
この発明は、浴中に投入して炭酸ガスを発生せしめ、こ
れによって皮膚に程よい刺激を与えて血行をよ（し、疲
労回復および新陳代謝を早める発泡性入浴剤組成物に関
する。[Detailed Description of the Invention] Industrial Application Field This invention is a foaming product that is poured into a bath to generate carbon dioxide gas, which provides moderate stimulation to the skin, improves blood circulation, and speeds up recovery from fatigue and metabolism. The present invention relates to a sex bath additive composition.
従来技術およびその問題点
一般に、この種の発泡性入浴剤は、炭酸塩と有機酸を含
有し、水中でこれらが反応して炭酸ガスを発生するもの
であるが、空気中においても、わずかに存在する湿気に
よって、炭酸塩と有機酸が反応して分解していくという
問題があった。またこの組成物を密閉容器に封入しても
徐々に発生する炭酸ガスのために容器が膨脂して商品価
値を損ねるうらみがあった。Prior art and its problems In general, this type of effervescent bath additive contains carbonate and organic acid, which react in water to generate carbon dioxide gas, but even in air, it produces a small amount of carbon dioxide gas. The problem was that the carbonate and organic acid reacted and decomposed due to the presence of moisture. Furthermore, even if this composition is sealed in a sealed container, the container may swell due to the gradual generation of carbon dioxide gas, which may impair its commercial value.
このような点から、従来、安定化剤として、メタホウ酸
を配合したもの（特開昭５０−１１６６２２号公報参照
）、無水硫酸ナトリウムのような吸湿性で非潮解性の水
溶性物質を配合したもの（特公昭５８−５６９５号公報
参照）、炭酸マグネシウムおよび／またはアルミン酸ナ
トリウムを配合したもの（特公昭６０−９００９号公報
参照）、さらには無水ホウ酸および／または酸化バリウ
ムを配合したもの（特開昭６１−２２８１００号公報参
照）などが知られている。From this point of view, conventional stabilizers have been formulated with metaboric acid (see JP-A-50-116622) and hygroscopic, non-deliquescent water-soluble substances such as anhydrous sodium sulfate. (see Japanese Patent Publication No. 58-5695), those containing magnesium carbonate and/or sodium aluminate (see Japanese Patent Publication No. 60-9009), and those containing boric anhydride and/or barium oxide (see Japanese Patent Publication No. 60-9009). (see Japanese Patent Laid-Open No. 61-228100), etc. are known.
しかし、これらの組成物はいずれも長期安定性の点で未
だ満足いくものではながった。However, all of these compositions were still unsatisfactory in terms of long-term stability.
この発明は、上記の如き点に鑑み、保存安定性にすこぶ
る優れた発泡性入浴剤を提供することを目的とする。In view of the above points, it is an object of the present invention to provide a foaming bath additive with extremely excellent storage stability.
問題点の解決手段
この発明による発泡性入浴剤組成物は、上記の目的を達
成すべく、炭酸塩と有機酸を含有する発泡性入浴剤にお
いて、安定化剤として、ポリビニルピロリドン、ハイド
ロキシプロピルセルロース、ポリビニルアルコールより
なる群がら選ばれた水溶性高分子を配合することを特徴
とする。Means for Solving the Problems In order to achieve the above object, the foaming bath additive composition according to the present invention is a foaming bath additive containing a carbonate and an organic acid, and contains polyvinylpyrrolidone, hydroxypropyl cellulose, It is characterized by containing a water-soluble polymer selected from the group consisting of polyvinyl alcohol.
この発明の好ましい実施態様においては、安定化剤は組
成物全量に対して０．１〜１５重量％の割合で配合され
る。この安定化剤の配合量が０． １ｆｆｉｆｆｉ％未
満であると、その安定化効果が充分に発揮されず、逆に
配合量が１５重量％を超えると、欲湯にぬめり感がでて
きて反って弊害になることがある。最も好ましい配合量
は組成物全量に対して０．１〜１５重量％である。In a preferred embodiment of the present invention, the stabilizer is blended in an amount of 0.1 to 15% by weight based on the total amount of the composition. The blending amount of this stabilizer is 0. If the amount is less than 1ffiffi%, the stabilizing effect will not be sufficiently exhibited, and if the amount is more than 15% by weight, the hot water may become slimy and warp, which may be harmful. The most preferable amount is 0.1 to 15% by weight based on the total amount of the composition.
この発明の発泡性入浴剤組成物における炭酸塩としては
、たとえば、炭酸水素ナトリウム、炭酸ナトリウム、セ
スキ炭酸ナトリウム、炭酸カリウム、炭酸水素カリウム
、炭酸アンモニウムなどの各乾燥品が用いられる。特に
好ましい炭酸塩は、炭酸水素ナトリウムおよび炭酸ナト
リウムである。炭酸塩の含有量は、組成物全量に対して
５〜８０重量％、好ましくは１０〜６０重量％である。As the carbonate in the effervescent bath agent composition of the present invention, for example, dried products such as sodium hydrogen carbonate, sodium carbonate, sodium sesquicarbonate, potassium carbonate, potassium hydrogen carbonate, and ammonium carbonate are used. Particularly preferred carbonates are sodium bicarbonate and sodium carbonate. The content of carbonate is 5 to 80% by weight, preferably 10 to 60% by weight based on the total amount of the composition.
また、この発明の発泡性入浴剤組成物における有機酸と
しては、たとえば、クエン酸、酒石酸、リンゴ酸、マロ
ン酸、コハク酸、フマル酸、ないしこれら酸の塩などの
各乾燥品が、その各作用に応じて適宜選択され使用され
る。有機酸の含有量は、組成物全量に対して３〜９０重
量％、好ましくは１０〜６０重量％である。The organic acids in the foaming bath agent composition of the present invention include, for example, citric acid, tartaric acid, malic acid, malonic acid, succinic acid, fumaric acid, and salts of these acids. It is appropriately selected and used depending on the effect. The content of the organic acid is 3 to 90% by weight, preferably 10 to 60% by weight based on the total amount of the composition.
この発明の発泡性入浴剤組成物には、上記の必須成分の
外に、塩化ナトリウム、ヨウ化カリウム、塩化アンモニ
ウム、硫酸ナトリウム、硫酸アルミニウム、硫化カリウ
ム、硫酸カリウム、炭酸マグネシウム、重炭酸マグネシ
ウム、ホウ酸、リン酸、イオウ、湯の花などの無機物が
添加されることもある。さらに保湿剤、生薬、ビタミン
類、酵素、界面活性剤、香料、色素などが添加されるこ
ともある。In addition to the above-mentioned essential ingredients, the effervescent bath agent composition of the present invention contains sodium chloride, potassium iodide, ammonium chloride, sodium sulfate, aluminum sulfate, potassium sulfide, potassium sulfate, magnesium carbonate, magnesium bicarbonate, boron. Inorganic substances such as acid, phosphoric acid, sulfur, and yunohana may also be added. Additionally, moisturizers, herbal medicines, vitamins, enzymes, surfactants, fragrances, and pigments may be added.
この発明の発泡性入浴剤組成物は、粉体、顆粒、結晶、
錠剤などの形態をとることができる。The effervescent bath agent composition of this invention includes powder, granules, crystals,
It can take the form of tablets, etc.
これらの形態の製剤化のために、必要に応じて賦形剤、
結合剤、崩壊剤、滑沢剤などが添加される。製剤化され
た発泡性入浴剤組成物は、実質的に水を透過しない包装
材料、たとえばアルミニウムをラミネートしたプラスチ
ックフィルムなどで１回の使用量毎に包装されるか、ま
たは全量が密封容器に封入されて、製品となされる。For the formulation of these forms, excipients,
Binders, disintegrants, lubricants, etc. are added. The formulated effervescent bath salt composition is packaged for each single use in a substantially water-impermeable packaging material, such as an aluminum-laminated plastic film, or the entire amount is enclosed in a sealed container. made into a product.
発明の効果
この発明によれば、安定化剤として、ポリビニルピロリ
ドン、ハイドロキシプロピルセルロース、ポリビニルア
ルコールよりなる群から選ばれた水溶性高分子を用いる
ので、長期保存後も炭酸ガスの発生量の低下をきたすこ
とがなく、かつ包装の外観を損ねることがなく、保存安
定性のすこぶるよい発泡性入浴剤を得ることができる。Effects of the Invention According to the present invention, since a water-soluble polymer selected from the group consisting of polyvinylpyrrolidone, hydroxypropyl cellulose, and polyvinyl alcohol is used as a stabilizer, the amount of carbon dioxide gas generated can be reduced even after long-term storage. It is possible to obtain an effervescent bath additive which has excellent storage stability without causing any damage or impairing the appearance of the packaging.
実 施 例
つぎに、この発明について実施例を挙げて具体的に説明
する。またこの発明による安定化剤を用いない場合を比
較例として挙げる。EXAMPLES Next, the present invention will be specifically explained by giving examples. In addition, a case in which the stabilizer according to the present invention is not used will be given as a comparative example.
実施例 １〜１０
下記の表１に示すように、炭酸塩、有機酸、安定化剤お
よび添加剤を表１の配合割合（重量％）になるようにそ
れぞれ所要量ずつ採り、これらを粉体混合機でよく混合
した。ついで得られた混合物を打錠機で圧力４００ｋｇ
／ｃｊで２分間加圧し、直径５ｃｍ５重Ｒ５０ｇの錠剤
形態の発泡性入浴剤を製造した。Examples 1 to 10 As shown in Table 1 below, carbonates, organic acids, stabilizers, and additives were each taken in the required amounts so as to have the blending ratios (wt%) shown in Table 1, and these were powdered. Mix well with a mixer. The resulting mixture was then compressed using a tablet press at a pressure of 400 kg.
/cj for 2 minutes to produce effervescent bath additives in the form of tablets with a diameter of 5 cm, 5 weights, and 50 g.
つぎに、こうして得た各入浴剤について、下記の試験法
によって、炭酸ガスの発生量および保存安定性を測定し
た。ａｌｌｌ定結果を表１に示す。Next, the amount of carbon dioxide gas generated and the storage stability of each of the bath additives thus obtained were measured by the following test methods. All determination results are shown in Table 1.
試験 １ （製造直後の炭酸ガス発生量）製造直後の入
浴剤のサンプル１０．を温度４０℃の温水に投入し、発
生した炭酸ガスの量を測定した。Test 1 (Amount of carbon dioxide gas generated immediately after production) Sample 10 of bath additives immediately after production. was poured into hot water at a temperature of 40°C, and the amount of carbon dioxide gas generated was measured.
試験 ２ （６ケ月間保存後の炭酸ガス発生ｆｆ１）ア
ルミニウムをラミネートしたプラスチックフィルムで錠
剤形態の入浴剤を密封包装し、包装品を温度４０℃で相
対湿度７５％ＲＨで６ケ月間保存した。ついでこれを開
封し、入浴剤のサンプル１０ｇを温度４０℃の温水に投
入し、発生した炭酸ガスの量を測定した。Test 2 (Carbon dioxide generation after storage for 6 months ff1) Tablet-shaped bath additives were sealed and packaged with a plastic film laminated with aluminum, and the packaged products were stored at a temperature of 40° C. and a relative humidity of 75% RH for 6 months. The package was then opened, 10 g of the bath salt sample was poured into warm water at a temperature of 40° C., and the amount of carbon dioxide gas generated was measured.
試験 ３ （保存安定性）
アルミニウムをラミネートしたプラスチックフィルムで
錠剤形態の入浴剤を密封包装し、包装品を温度４０℃で
相対湿度７５％ＲＨで６ケ月間保存した。ついでこの包
装品の外観を観測した。Test 3 (Storage Stability) Tablet-shaped bath additives were hermetically packaged with a plastic film laminated with aluminum, and the packaged products were stored at a temperature of 40° C. and a relative humidity of 75% RH for 6 months. Next, the appearance of this packaged product was observed.
表１に示した結果かられかるように、この発明による入
浴剤は、製造直後の炭酸ガスの発生量と６ケ月保存後の
炭酸ガスの発生量との間で全く差がないものであり、ま
た６ケ月保存後も包装の外観を損ねることがなく、保存
安定性の優れたものである。As can be seen from the results shown in Table 1, the bath additive according to the present invention shows no difference in the amount of carbon dioxide gas generated immediately after manufacture and the amount of carbon dioxide gas generated after storage for 6 months. Furthermore, the packaging does not lose its appearance even after being stored for 6 months, and has excellent storage stability.
Claims (2)
、安定化剤として、ポリビニルピロリドン、ハイドロキ
シプロピルセルロース、ポリビニルアルコールよりなる
群から選ばれた水溶性高分子を配合することを特徴とす
る発泡性入浴剤組成物。(1) A foaming bath additive containing a carbonate and an organic acid, which is characterized by containing a water-soluble polymer selected from the group consisting of polyvinylpyrrolidone, hydroxypropyl cellulose, and polyvinyl alcohol as a stabilizer. Effervescent bath additive composition.
１５重量％である特許請求の範囲第１項記載の組成物。(2) The blending amount of the stabilizer is 0.1 to 0.1 to the total amount of the composition.
15. A composition according to claim 1, wherein the amount is 15% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33154287A JPH01172319A (en) | 1987-12-25 | 1987-12-25 | Effervescent bathing agent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33154287A JPH01172319A (en) | 1987-12-25 | 1987-12-25 | Effervescent bathing agent composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01172319A true JPH01172319A (en) | 1989-07-07 |
Family
ID=18244827
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33154287A Pending JPH01172319A (en) | 1987-12-25 | 1987-12-25 | Effervescent bathing agent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01172319A (en) |
Cited By (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997046655A1 (en) * | 1996-06-05 | 1997-12-11 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, (bi)carbonate and pva |
| EP1043023A1 (en) * | 1997-11-07 | 2000-10-11 | Medion Research Laboratories Inc. | Viscous compositions containing carbon dioxide |
| KR100520242B1 (en) * | 2002-10-28 | 2005-10-11 | 주식회사 서흥캅셀 | Process for preparing tablet or granule for cleaning the feet |
| WO2018140675A1 (en) * | 2017-01-27 | 2018-08-02 | The Procter & Gamble Company | Compositions in the form of dissolvable solid structures comprising effervescent agglomerated particles |
| USD910434S1 (en) | 2018-07-16 | 2021-02-16 | The Procter And Gamble Company | Container |
| USD939359S1 (en) | 2019-10-01 | 2021-12-28 | The Procter And Gamble Plaza | Packaging for a single dose personal care product |
| USD941051S1 (en) | 2020-03-20 | 2022-01-18 | The Procter And Gamble Company | Shower hanger |
| US11351094B2 (en) | 2017-05-16 | 2022-06-07 | The Procter And Gamble Company | Conditioning hair care compositions in the form of dissolvable solid structures |
| US11352474B2 (en) | 2014-04-22 | 2022-06-07 | The Procter And Gamble Company | Compositions in the form of dissolvable solid structures |
| US11395789B2 (en) | 2017-01-27 | 2022-07-26 | The Procter & Gamble Company | Compositions in the form of dissolvable solid structures |
| US11419808B2 (en) | 2019-07-03 | 2022-08-23 | The Procter & Gamble Company | Fibrous structures containing cationic surfactants and soluble acids |
| USD962050S1 (en) | 2020-03-20 | 2022-08-30 | The Procter And Gamble Company | Primary package for a solid, single dose beauty care composition |
| USD965440S1 (en) | 2020-06-29 | 2022-10-04 | The Procter And Gamble Company | Package |
| US11525104B2 (en) | 2019-11-20 | 2022-12-13 | The Procter & Gamble Company | Porous dissolvable solid structure |
| US11597191B2 (en) | 2019-10-14 | 2023-03-07 | The Procter & Gamble Company | Biodegradable and/or home compostable sachet containing a solid article |
| US11633336B2 (en) | 2020-08-11 | 2023-04-25 | The Procter & Gamble Company | Low viscosity hair conditioner compositions containing brassicyl valinate esylate |
| US11633338B2 (en) | 2020-08-11 | 2023-04-25 | The Procter & Gamble Company | Moisturizing hair conditioner compositions containing brassicyl valinate esylate |
| US11666514B2 (en) | 2018-09-21 | 2023-06-06 | The Procter & Gamble Company | Fibrous structures containing polymer matrix particles with perfume ingredients |
| US11672748B2 (en) | 2020-12-01 | 2023-06-13 | The Procter & Gamble Company | Aqueous hair conditioner compositions containing solubilized anti-dandruff actives |
| US11679066B2 (en) | 2019-06-28 | 2023-06-20 | The Procter & Gamble Company | Dissolvable solid fibrous articles containing anionic surfactants |
| US11696882B2 (en) | 2020-08-11 | 2023-07-11 | The Procter & Gamble Company | Clean rinse hair conditioner compositions containing brassicyl valinate esylate |
| US11896693B2 (en) | 2019-12-01 | 2024-02-13 | The Procter & Gamble Company | Hair conditioner compositions with a preservative system containing sodium benzoate and glycols and/or glyceryl esters |
| US11925698B2 (en) | 2020-07-31 | 2024-03-12 | The Procter & Gamble Company | Water-soluble fibrous pouch containing prills for hair care |
| US11944696B2 (en) | 2010-07-02 | 2024-04-02 | The Procter & Gamble Company | Detergent product and method for making same |
| US11944693B2 (en) | 2010-07-02 | 2024-04-02 | The Procter & Gamble Company | Method for delivering an active agent |
| US11970789B2 (en) | 2010-07-02 | 2024-04-30 | The Procter & Gamble Company | Filaments comprising an active agent nonwoven webs and methods for making same |
| US12029799B2 (en) | 2022-04-27 | 2024-07-09 | The Procter & Gamble Company | Conditioning hair care compositions in the form of dissolvable solid structures |
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|---|---|---|---|---|
| JPS59106415A (en) * | 1982-12-09 | 1984-06-20 | Kao Corp | Bathing agent |
| JPS61277611A (en) * | 1985-06-03 | 1986-12-08 | Kao Corp | Weakly acidic bathing agent |
| JPS62234015A (en) * | 1986-04-02 | 1987-10-14 | Lion Corp | Foamable bathing agent |
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|---|---|---|---|---|
| JPS59106415A (en) * | 1982-12-09 | 1984-06-20 | Kao Corp | Bathing agent |
| JPS61277611A (en) * | 1985-06-03 | 1986-12-08 | Kao Corp | Weakly acidic bathing agent |
| JPS62234015A (en) * | 1986-04-02 | 1987-10-14 | Lion Corp | Foamable bathing agent |
Cited By (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5885949A (en) * | 1996-06-05 | 1999-03-23 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, BI carbonate and polyvinyl alcohol |
| US6057281A (en) * | 1996-06-05 | 2000-05-02 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, (Bi)carbonate and polyvinyl alcohol |
| WO1997046655A1 (en) * | 1996-06-05 | 1997-12-11 | Amway Corporation | Tableted household cleaner comprising carboxylic acid, (bi)carbonate and pva |
| EP1043023A1 (en) * | 1997-11-07 | 2000-10-11 | Medion Research Laboratories Inc. | Viscous compositions containing carbon dioxide |
| EP1043023A4 (en) * | 1997-11-07 | 2002-05-15 | Medion Res Lab Inc | Viscous compositions containing carbon dioxide |
| EP1574207A1 (en) * | 1997-11-07 | 2005-09-14 | Medion Research Laboratories Inc. | Cosmetic use of viscous compositions containing carbon dioxide |
| EP1604645A1 (en) * | 1997-11-07 | 2005-12-14 | Medion Research Laboratories Inc. | Viscous compositions containing carbon dioxide |
| EP1604646A1 (en) * | 1997-11-07 | 2005-12-14 | Medion Research Laboratories Inc. | Viscous compositions containing carbon dioxide |
| KR100520242B1 (en) * | 2002-10-28 | 2005-10-11 | 주식회사 서흥캅셀 | Process for preparing tablet or granule for cleaning the feet |
| US11970789B2 (en) | 2010-07-02 | 2024-04-30 | The Procter & Gamble Company | Filaments comprising an active agent nonwoven webs and methods for making same |
| US11944696B2 (en) | 2010-07-02 | 2024-04-02 | The Procter & Gamble Company | Detergent product and method for making same |
| US11944693B2 (en) | 2010-07-02 | 2024-04-02 | The Procter & Gamble Company | Method for delivering an active agent |
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| US11529292B2 (en) | 2017-01-27 | 2022-12-20 | The Procter & Gamble Company | Compositions in the form of dissolvable solid structures |
| US11395789B2 (en) | 2017-01-27 | 2022-07-26 | The Procter & Gamble Company | Compositions in the form of dissolvable solid structures |
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| US11896693B2 (en) | 2019-12-01 | 2024-02-13 | The Procter & Gamble Company | Hair conditioner compositions with a preservative system containing sodium benzoate and glycols and/or glyceryl esters |
| US11957773B2 (en) | 2019-12-01 | 2024-04-16 | The Procter & Gamble Company | Hair conditioner compositions containing behenamidopropyl dimethylamine |
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